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Bismanol

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Bismanol
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
EC Number
  • 234-556-2
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/Bi.MnKey: KYAZRUPZRJALEP-UHFFFAOYSA-N
SMILES
  • .
Properties
Chemical formula BiMn
Molar mass 263.91844 g·mol
Structure
Crystal structure NiAs type
Space group R3m
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Bismanol is an magnetic alloy of bismuth and manganese (manganese bismuthide) developed by the US Naval Ordnance Laboratory.

History

Bismanol, a permanent magnet made from powder metallurgy of manganese bismuthide, was developed by the US Naval Ordnance Laboratory in the early 1950s – at the time of invention it was one of the highest coercive force permanent magnets available, at 3000 oersteds. Coercive force reached 3650 oersteds and magnetic flux density 4800 by the mid 1950s. The material was generally strong, and stable to shock and vibration, but had a tendency to chip. Slow corrosion of the material occurred under normal conditions.

The material was used to make permanent magnets for use in small electric motors.

Bismanol magnets have been replaced by neodymium magnets which are both cheaper and superior in other ways, by samarium-cobalt magnets in more critical applications, and by alnico magnets.

References

  1. Yang, J B; Yelon, W B; James, W J; Cai, Q; Kornecki, M; Roy, S; Ali, N; l$rquot$Heritier, Ph (2002). "Crystal structure, magnetic properties and electronic structure of the MnBi intermetallic compound". Journal of Physics: Condensed Matter. 14 (25): 6509–6519. Bibcode:2002JPCM...14.6509Y. doi:10.1088/0953-8984/14/25/318. ISSN 0953-8984. S2CID 250816327.
  2. "Bismanol", Physics Today, 5 (8): 19, August 1952, doi:10.1063/1.3067699
  3. Adams, E.; Hubbard, W.M. (1953), "BISMANOL PERMANENT MAGNETS, EVALUATION AND PROCESSING", Naval Ordnance Lab., USA, OSTI 4290472
  4. Adams, Edmond (1953). "A New Permanent Magnet from Powdered Manganese Bismuthide". Rev. Mod. Phys. 25 (1): 306–307. Bibcode:1953RvMP...25..306A. doi:10.1103/RevModPhys.25.306.
Salts and covalent derivatives of the bismuthide ion
-BiH
BiH3
+H
He
Li Be B R3Bi N -BiO
-BiO3
F Ne
Na Mg Al Si P S +Cl2 Ar
KBi2 Ca Sc Ti V Cr MnBi Fe Co Ni Cu Zn Ga Ge As Se Br Kr
RbBi2 Sr Y Zr Nb Mo Tc Ru Rh PdBi2 Ag Cd In Sn Sb Te I Xe
CsBi2 Ba * Lu Hf Ta W Re Os Ir PtBi2 Au Hg Tl Pb Bi
-Bi
Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La Ce PrBi NdBi Pm Sm Eu5Sb3
Eu4Sb3
Eu11Sb10
Gd Tb DyBi HoBi Er Tm Yb
** Ac ThBi
ThBi2
Pa U NpBi Pu AmBi Cm Bk Cf Es Fm Md No
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