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Santarelli played as libero in various lower categories of Italian league (Serie B) in Foligno, Vicenza, Legnago and Terracina before pursuing his career as a youth coach at a young age.
Coaching career
He was a coach for Italian teams such as Snoopy Pesaro, Robursport Pesaro, Robur Tiboni Urbino Volley. He currently leads Imoco Volley. With Imoco, Santarelli has won the Italian national league four times (2015, 2018, 2019, and 2021), 3 Italian Cups (2017, 2020 and 2021), 4 Italian Super Cups (2016, 2018, 2019 and 2020), 1 Club World Championship (2019) and the last edition of the CEV Champions League.
In October 2022, the Serbian national women's team headed by Santarelli won the world title at the 2022 FIVB Volleyball Women's World Championship held in Poland and the Netherlands. The team thereby successfully defended the 2018 title won under the previous coach Zoran Terzić. On 27 December 2022 it was announced by the TVF that Daniele will be the new head coach of the Turkey women's national volleyball team, and the details of the agreement would be announced at a press conference to be held jointly by TVF President Mehmet Akif Üstündağ and Daniele himself.