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exo-Norborneol

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exo-Norborneol
Names
Preferred IUPAC name rel-(1R,2R,4S)-Bicycloheptan-2-ol
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.007.133 Edit this at Wikidata
PubChem CID
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1/C7H12O/c8-7-4-5-1-2-6(7)3-5/h5-8H,1-4H2/t5-,6+,7+/s2Key: ZQTYQMYDIHMKQB-YUZWJPFSNA-N
  • (2R): InChI=1S/C7H12O/c8-7-4-5-1-2-6(7)3-5/h5-8H,1-4H2/t5-,6+,7+/m0/s1Key: ZQTYQMYDIHMKQB-VQVTYTSYSA-N
  • (2S): InChI=1S/C7H12O/c8-7-4-5-1-2-6(7)3-5/h5-8H,1-4H2/t5-,6+,7+/m1/s1Key: ZQTYQMYDIHMKQB-RRKCRQDMSA-N
SMILES
  • (2R): O1C2C1CC2
  • (2S): O1C2C1CC2
Properties
Chemical formula C7H12O
Molar mass 112.172 g·mol
Melting point 124 to 126 °C (255 to 259 °F; 397 to 399 K)
Boiling point 176 to 177 °C (349 to 351 °F; 449 to 450 K)
Hazards
Safety data sheet (SDS) Fisher MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkY verify (what is  ?) Infobox references
Chemical compound

exo-Norborneol is an alcohol containing the norbornane skeleton. Commercially available, this colorless compound may be prepared by the reaction of norbornene with formic acid, followed by hydrolysis of the resultant exo-norbornyl formate.

See also

References

  1. Kleinfelter, Donald C.; von R. Schleyer, Paul (1962). "2-Norbananone". Organic Syntheses. 42: 79. doi:10.15227/orgsyn.042.0079.

Further reading

  • Reaction of organic compounds under high temperature – dilute acid (HTDA) conditions. III. The perdeuteration of bicycloheptanes PDF
  • Stille, J. K.; Sonnenberg, Fred M. (1966). "The Reaction of endo- and exo-2-Norborneol with Thionyl Chloride". Journal of the American Chemical Society. 88 (21): 4915. doi:10.1021/ja00973a027.
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