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Nickel azide

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Nickel azide
Names
IUPAC name Nickel(II) diazide
Other names Nickel diazide
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
PubChem CID
InChI
  • InChI=1S/2N3.Ni/c2*1-3-2;/q2*-1;+2Key: JRUBGUVYQMKOMK-UHFFFAOYSA-N
SMILES
  • ==.==.
Properties
Chemical formula Ni(N3)2
Molar mass 142.73 g/mol
Hazards
GHS labelling:
Pictograms GHS01: Explosive
Signal word Danger
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Nickel azide is an inorganic chemical compound with the formula Ni(N3)2. It can be formed through the reaction between nickel tetracarbonyl and iodine azide.

2Ni(CO)4 + 2IN3 → Ni(N3)2 + NiI2 + 8CO

Properties

Nickel azide water solution has high absorbance in the ultraviolet with a peak at 292 nm. The solution also contains hexaaquanickel cations with visible light absorption peaks at 394, 656, and 720 nm. A related mixed anion compound with nicotinic acid and nicotinate exhibits EO bridging coordination (μ-1,1) on the azide, and possesses an unusual angle between the nickel and nitrogen present within the complex. Like most azides, it is explosive.

References

  1. Dehnicke, K.; Dübgen, R. (1 September 1978). "Die Reaktionen des Jodazids mit Metallcarbonylen". Zeitschrift für anorganische und allgemeine Chemie (in German). 444 (1): 61–70. doi:10.1002/zaac.19784440106. ISSN 0044-2313. Archived from the original on 2022-10-24. Retrieved 2023-10-30.
  2. Egghart, H. C. (26 August 1968). "A study of nickel-azido complex formation in aqueous solution". J. Inorg. Nucl. Chem. 31 (5): 1538–1541. doi:10.1016/0022-1902(69)80278-2. Retrieved 30 October 2023.
  3. Liu, Fu-Chen; Zeng, Yong-Fei; Li, Jian-Rong; Bu, Xian-He; Zhang, Hong-Jie; Ribas, Joan (15 September 2005). "Novel 3-D Framework Nickel(II) Complex with Azide, Nicotinic Acid, and Nicotinate(1−) as Coligands: Hydrothermal Synthesis, Structure, and Magnetic Properties". Inorganic Chemistry. 44 (21): 7298–7300. doi:10.1021/ic051030b. PMID 16212349. Retrieved 30 October 2023.
Nickel compounds
Nickel(0)
Nickel(II)
Nickel(III)
Nickel(IV)
Salts and covalent derivatives of the azide ion
HN3 He
LiN3 Be(N3)2 B(N3)3 CH3N3
C(N3)4
CO(N3)2 		NH4N3
N3NO
N(N3)3
H2N–N3 		O FN3 Ne
NaN3 Mg(N3)2 Al(N3)3 Si(N3)4 P SO2(N3)2 ClN3 Ar
KN3 Ca(N3)2 Sc(N3)3 Ti(N3)4 VO(N3)3 Cr(N3)3
CrO2(N3)2 		Mn(N3)2 Fe(N3)2
Fe(N3)3 		Co(N3)2
Co(N3)3 		Ni(N3)2 CuN3
Cu(N3)2 		Zn(N3)2 Ga(N3)3 Ge As(N3)5 Se(N3)4 BrN3 Kr
RbN3 Sr(N3)2 Y(N3)3 Zr(N3)4 Nb Mo Tc Ru(N3)6 Rh(N3)6 Pd(N3)2 AgN3 Cd(N3)2 In Sn Sb(N3)5 Te(N3)4 IN3 Xe(N3)2
CsN3 Ba(N3)2 * Lu(N3)3 Hf Ta W Re Os Ir(N3)6 Pt(N3)6 Au(N3)4 Hg2(N3)2
Hg(N3)2 		TlN3 Pb(N3)2 Bi(N3)3 Po At Rn
Fr Ra(N3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(N3)3 Ce(N3)3
Ce(N3)4 		Pr Nd Pm Sm(N3)3 Eu(N3)2
Eu(N3)3 		Gd(N3)3 Tb Dy(N3)3 Ho(N3)3 Er Tm Yb(N3)3
** Ac(N3)3 Th(N3)4 Pa UO2(N3)2 Np Pu Am Cm Bk Cf Es Fm Md No
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