Princess Maria Carolina of Bourbon-Two Sicilies may refer to:
- Princess Maria Carolina of Bourbon-Two Sicilies (1798–1870), daughter of Francis I of the Two Sicilies by his first wife Maria Clementina of Austria, wife of Charles d'Artois, Duke of Berry
- Princess Maria Carolina of Bourbon-Two Sicilies (1820–1861), daughter of Francis I of the Two Sicilies by his second wife wife María Isabella of Spain, wife of Infante Carlos, Count of Montemolin
- Princess Maria Carolina of Bourbon-Two Sicilies (1822–1869), daughter of Leopold, Prince of Salerno, wife of Henri d'Orléans, Duke of Aumale
- Princess Maria Carolina of Bourbon-Two Sicilies (1856–1941), daughter of Prince Francis, Count of Trapani, wife of Count Andrzej Zamoyski
- Princess Maria Carolina of Bourbon-Two Sicilies (born 2003), daughter of Prince Carlo, Duke of Castro, and Camilla Crociani
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