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Selenide iodide

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Class of chemical compounds

The selenide iodides are chemical compounds that contain both selenide ions (Se) and iodide ions (I) and one or metal atoms. They are in the class of mixed anion compounds or chalcogenide halides.

Some related compounds do not actually contain a selenide ion, instead containing an iodoselenium cation. These cations include SeI3, Se2I4, Se6I2, and polymeric Se6I.

List

name formula MW system space group unit cell cell

volume

density properties ref
Ti4Se9I6 triclinic P1 a = 7.965 b = 10.339 c = 15.692; α = 79.116°, β = 75.861°, γ = 71.437°; Z = 2 black
V4O(Se2)4I6·I2 1866.64 tetragonal P42/nbc a=11.8384 c=18.689 Z=4 2619.2 4.734 dark blue
CuSe3I trigonal R3m a=9.601 V= 872.859
α AsSeI monoclinic P2s a=8.855 b=4.194 c=10.341 β=93.74 Z=4 5.14 melt 221 °C dark red metallic
β AsSeI cubic F4132 a=11.05 Z=16 5.53 dark red metallic
AsF6Se6I
NbSe2I2 triclinic P1 a=6.993 b=7.008 c=7.768 α=89.339° β=66.801° γ=61.284° Z=2 299.3 5.600 black; 2D; band gap 1 eV
triniobium selenide heptaiodide Nb3SeI7 hexagonal P63mc
(Nb4Se15I2)I2 monoclinic P21/c a=8.8807 b=25.8368 c=11.6222 β=103.437° black; 1D; band gap 0.6 eV
I 1729.54 P23/n a=10.4969 b=13.029 c=16.567 β =102.921° Z=4 2208.3 5.202
Pd2SeI3 orthorhombic metallic black
heptasilver(I) tetraseleniogermanate(IV) selenide iodide Ag7GeISe5 cubic F43m a=10.9864 Z=4 1326.1 6.740 black; silver ion conductor
CdBiSe2I monoclinic C2/m
indium selenide iodide InSeI tetragonal I41/a
Antimony selenide iodide SbSeI orthorhombic Pnma band gap 1.70 eV n-type semiconductor
SbF6Se6I
Cs3Mo6I6Se2I6
Cs3Mo6I7SeI6
tribarium tetraselenide diiodide Ba3Se4I2 monoclinic C2/c a = 15.080 Å, b = 10.400 Å, c = 8.383 Å, β = 103.206°, Z = 4
Ta2Se8I tetragonal a = 9.59 c = 12.64 Charge-density-wave Weyl semimetal
tritantalum selenide heptaiodide Ta3SeI7 hexagonal P63mc
Ta4Se9I8
WCl6Se6I
Hg3Se2I2 orthorhombic Imma a= 9.7660 b=19.381 c=9.6332 Z=8 light red
trimercury arsenic tetraselenide iodide Hg3AsSe4I 1119.43 hexagonal P63mc a = 7.6902 c = 9.968 Z = 2 510.50 7.283 dark red
Tl6SeI4 tetragonal P4/mnc 7.4 band-gap 1.6 eV; semiconductor; melt 432 °C
Bismuth selenide iodide BiSeI 414.84 orthorhombic Pnma a = 8.697 b = 4.2205 c = 10.574 388.1 7.100 band gap 1.3 eV; silver
Bi2CuSe3I
In2Bi3Se7I
InBi2Se4I

References

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