For the formula describing ice formation, see Stefan's equation .
In thermodynamics , Stefan's formula says that the specific surface energy at a given interface is determined by the respective enthalpy difference
Δ
H
∗
{\displaystyle \Delta H^{*}}
.
σ
=
γ
0
(
Δ
H
∗
N
A
1
/
3
V
m
2
/
3
)
,
{\displaystyle \sigma =\gamma _{0}\left({\frac {\Delta H^{*}}{N_{\text{A}}^{1/3}V_{\text{m}}^{2/3}}}\right),}
where σ is the specific surface energy , N A is the Avogadro constant ,
γ
0
{\displaystyle \gamma _{0}}
is a steric dimensionless coefficient, and V m is the molar volume .
References
Guencheva, V.; Grantscharova, E.; Gutzow, I. (2001). "Thermodynamic Properties of the Amorphous and Crystalline Modifications of Carbon and the Metastable Synthesis of Diamond". Crystal Research and Technology . 36 (12): 1411–1428. Bibcode :2001CryRT..36.1411G . doi :10.1002/1521-4079(200112)36:12<1411::AID-CRAT1411>3.0.CO;2-8 .
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