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Stefan's formula

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For the formula describing ice formation, see Stefan's equation.

In thermodynamics, Stefan's formula says that the specific surface energy at a given interface is determined by the respective enthalpy difference Δ H {\displaystyle \Delta H^{*}} . σ = γ 0 ( Δ H N A 1 / 3 V m 2 / 3 ) , {\displaystyle \sigma =\gamma _{0}\left({\frac {\Delta H^{*}}{N_{\text{A}}^{1/3}V_{\text{m}}^{2/3}}}\right),} where σ is the specific surface energy, NA is the Avogadro constant, γ 0 {\displaystyle \gamma _{0}} is a steric dimensionless coefficient, and Vm is the molar volume.

References

  1. Guencheva, V.; Grantscharova, E.; Gutzow, I. (2001). "Thermodynamic Properties of the Amorphous and Crystalline Modifications of Carbon and the Metastable Synthesis of Diamond". Crystal Research and Technology. 36 (12): 1411–1428. Bibcode:2001CryRT..36.1411G. doi:10.1002/1521-4079(200112)36:12<1411::AID-CRAT1411>3.0.CO;2-8.
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