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{{Short description|Substance introduced to reduce friction between surfaces in mutual contact}} | |||
== MIRA MAMÁ SOY UN ANONYMOUS DE 4CHAN :) == | |||
{{About|industrial lubricants}} | |||
{{Use dmy dates|date=April 2020}} | |||
{{More citations needed|date=March 2023}} | |||
], a common lubricant.]] | |||
A '''lubricant''' (sometimes shortened to '''lube''') is a substance that helps to reduce ] between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, transporting foreign particles, or heating or cooling the surfaces. The property of reducing friction is known as ]. | |||
In addition to industrial applications, lubricants are used for many other purposes. Other uses include cooking (]s and ]s in use in ]s and baking to prevent food sticking), to reduce rusting and friction in ], through the use of ] and ], bioapplications on humans (e.g., lubricants for ]s), ultrasound examination, medical examination, and sexual intercourse. It is mainly used to reduce friction and to contribute to a better, more efficient functioning of a mechanism. | |||
okay | |||
==History== | |||
{{Cleanup|date=May 2008}} | |||
Lubricants have been in some use for thousands of years. ]s have been identified on the axles of chariots dated to 1400 BC. Building stones were slid on oil-impregnated lumber in the time of the pyramids. In the ], lubricants were based on ] and ], as well as animal fats. The growth of lubrication accelerated in the ] with the accompanying use of metal-based machinery. Relying initially on natural oils, needs for such machinery shifted toward petroleum-based materials early in the 1900s. A breakthrough came with the development of ] of petroleum, as described by the ]. This technology allowed the purification of very non-volatile substances, which are common in many lubricants.<ref name=Fundamentals>{{cite book|title=Lubrication Fundamentals|edition=Third Edition, Revised and Expanded|author1=Don M. Pirro|author2=Martin Webster|author3=Ekkehard Daschner|publisher=CRC Press|year= 2016|isbn=978-1-4987-5290-9}} (print) {{ISBN|978-1-4987-5291-6}} (eBook)</ref> | |||
{{Nofootnotes|date=February 2008}} | |||
A '''lubricant''' (sometimes referred to as "lube") is a substance (often a liquid) introduced between two moving surfaces to reduce the ] between them, improving ] and reducing ]. They may also have the function of dissolving or transporting foreign particles and of distributing heat. | |||
== Properties == | |||
One of the single largest applications for lubricants, in the form of ], is to protect the ]s in motor vehicles and powered equipment. | |||
A good lubricant generally possesses the following characteristics: | |||
Typically lubricants contain 90% base oil (most often ] fractions, called ]s) and less than 10% additives. ]s or synthetic liquids such as hydrogenated ]s, ]s, ]s, ]s and many others are sometimes used as base oils. Additives deliver reduced friction and wear, increased ], improved viscosity index, resistance to ] and ], aging or contamination, etc. | |||
* A high boiling point and low freezing point (in order to stay ] within a wide range of temperature) | |||
* A high ] | |||
* Thermal stability | |||
* Hydraulic stability | |||
* Demulsibility | |||
* Corrosion prevention | |||
* A high resistance to ] | |||
* Pour Point (the minimum temperature at which oil will flow under prescribed test conditions) | |||
=== Formulation === | |||
Lubricants such as ] are also added to some ]s. ] impurities in fuels also provide some lubrication properties, which has to be taken in account when switching to a low-sulfur ]; ] is a popular diesel fuel additive providing additional lubricity. | |||
Typically lubricants contain 90% base oil (most often ] fractions, called ]s) and less than 10% ]. ]s or synthetic liquids such as hydrogenated ]s, ]s, ]s, ]s and many others are sometimes used as base oils. Additives deliver reduced friction and wear, increased ], improved viscosity index, resistance to ] and ], aging or contamination, etc. | |||
Non-liquid lubricants include ], powders (dry ], ], ], ], etc.), teflon tape used in plumbing, air cushion and others. ]s such as graphite, molybdenum disulfide and tungsten disulfide also offer lubrication at temperatures (up to 350 °C) higher than liquid and oil-based lubricants are able to operate. Limited interest has been shown in low friction properties of ]s formed at several hundred degrees Celsius in metallic sliding systems, however, practical use is still many years away due to their physically unstable nature. | |||
Non-liquid lubricants include powders (dry ], ], ], ], etc.), PTFE tape used in plumbing, air cushion and others. ]s such as graphite, molybdenum disulphide and tungsten disulphide also offer lubrication at temperatures (up to 350 °C) higher than liquid and oil-based lubricants are able to operate. Limited interest has been shown in low friction properties of ]s formed at several hundred degrees Celsius in metallic sliding systems; however, practical use is still many years away due to their physically unstable nature. | |||
Another approach to reducing friction and wear is to use ] such as ]s, ]s or ]s, which in turn require internal lubrication themselves, or to use sound, in the case of ]. | |||
=== Additives === | |||
In addition to industrial applications, lubricants are used for many other purposes. Other uses include cooking (oils and fats in use in frypans, baking to prevent food sticking), bio-] applications on humans (e.g. lubricants for ]s), ultrasound examination, internal examinations for males and females, and the use of ] for sexual purposes. | |||
{{main|Oil additive}} | |||
== Purpose == | |||
Lubricants perform the following key functions. | |||
*Keep moving parts apart | |||
*Reduce friction | |||
*Transfer heat | |||
*Carry away contaminants & debris | |||
*Transmit power | |||
*Protect against wear | |||
*Prevent corrosion | |||
*Seal for gasses | |||
*Stop the risk of smoke and fire of objects | |||
A large number of additives are used to impart performance characteristics to the lubricants. Modern automotive lubricants contain as many as ten additives, comprising up to 20% of the lubricant, the main families of additives are:<ref name=Fundamentals/> | |||
===Keep moving parts apart=== | |||
* ] depressants are compounds that prevent crystallization of waxes. Long chain ]s adhere to small crystallites of wax, preventing crystal growth. | |||
Lubricants are typically used to separate moving parts in a system. This has the benefit of reducing friction and surface fatigue together with reduced heat generation, operating noise and vibrations. Lubricants achieve this by several ways. The most common is by forming a physical barrier i.e. a thin layer of lubricant separates the moving parts. This is termed hydrodynamic lubrication. In cases of high surface pressures or temperatures the fluid film is much thinner and some of the forces are transmitted between the surfaces through the lubricant. This is termed elasto-hydrodynamic lubrication. | |||
* ]s are typically ] compounds which increase ] in order to discourage foam formation. | |||
* ]s (VIIs) are compounds that allow lubricants to remain viscous at higher temperatures. Typical VIIs are ]s and ]. | |||
* ]s suppress the rate of oxidative degradation of the hydrocarbon molecules within the lubricant. At low temperatures, free radical inhibitors such as hindered phenols are used, e.g. ]. At temperatures >90 °C, where the metals ] the oxidation process, dithiophosphates are more useful. In the latter application the additives are called ]s. | |||
* ]s ensure the cleanliness of engine components by preventing the formation of deposits on contact surfaces at high temperatures. | |||
* ]s (rust inhibitors) are usually alkaline materials, such as alkylsulfonate salts, that absorb acids that would corrode metal parts. | |||
* ] additives form protective 'tribofilms' on metal parts, suppressing ]. They come in two classes depending on the strength with which they bind to the surface. Popular examples include ]s and ]s.<ref>{{Cite journal|last=Spikes|first=H.|date=2004-10-01|title=The History and Mechanisms of ZDDP|journal=Tribology Letters|language=en|volume=17|issue=3|pages=469–489|doi=10.1023/B:TRIL.0000044495.26882.b5|s2cid=7163944|issn=1023-8883}}</ref> | |||
* ] (anti-scuffing) additives form protective films on sliding metal parts. These agents are often sulfur compounds, such as dithiophosphates. | |||
* ]s reduce friction and wear, particularly in the boundary lubrication regime where surfaces come into direct contact.<ref>{{Cite journal|last=Spikes|first=Hugh|date=2015-10-01|title=Friction Modifier Additives|journal=Tribology Letters|language=en|volume=60|issue=1|pages=5|doi=10.1007/s11249-015-0589-z|issn=1023-8883|hdl=10044/1/25879|s2cid=137884697|url=http://spiral.imperial.ac.uk/bitstream/10044/1/25879/2/post%20review%20Friction%20modifier%20additives.pdf|hdl-access=free|access-date=23 September 2019|archive-date=22 September 2017|archive-url=https://web.archive.org/web/20170922050548/http://spiral.imperial.ac.uk/bitstream/10044/1/25879/2/post%20review%20Friction%20modifier%20additives.pdf|url-status=live}}</ref> | |||
<!--* ]s | |||
* Stickiness improver | |||
* Complexing agent (in case of greases) | |||
Note that many of the basic chemical compounds used as detergents (example: calcium sulfonate) serve the purpose of the first seven items in the list as well. Usually it is not economically or technically feasible to use a single do-it-all additive compound. Oils for ] gear lubrication will contain high content of EP additives. Grease lubricants may contain large amount of solid particle friction modifiers, such as graphite, molybdenum sulfide.--> | |||
In 1999, an estimated 37,300,000 tons of lubricants were consumed worldwide.<ref>{{Cite book |doi=10.1002/14356007.a15_423|chapter=Lubricants and Lubrication|title=Ullmann's Encyclopedia of Industrial Chemistry|year=2003|last1=Bartels|first1=Thorsten|last2=Bock|first2=Wolfgang|last3=Braun|first3=Jürgen|last4=Busch|first4=Christian|last5=Buss|first5=Wolfgang|last6=Dresel|first6=Wilfried|last7=Freiler|first7=Carmen|last8=Harperscheid|first8=Manfred|last9=Heckler|first9=Rolf-Peter|last10=Hörner|first10=Dietrich|last11=Kubicki|first11=Franz|last12=Lingg|first12=Georg|last13=Losch|first13=Achim|last14=Luther|first14=Rolf|last15=Mang|first15=Theo|last16=Noll|first16=Siegfried|last17=Omeis|first17=Jürgen|isbn=978-3527306732}}</ref> Automotive applications dominate, including electric vehicles<ref>{{Cite book|last1=Beyer|first1=Monica|last2=Brown|first2=Gareth|last3=Gahagan|first3=Michael|last4=Higuchi|first4=Tomoya|last5=Hunt|first5=Gregory|last6=Huston|first6=Michael|last7=Jayne|first7=Doug|last8=McFadden|first8=Chris|last9=Newcomb|first9=Timothy|last10=Patterson|first10=Suzanne|last11=Prengaman|first11=Christopher|last12=Shamszad|first12=Mariam|date=2019-12-12|chapter=Lubricant Concepts for Electrified Vehicle Transmissions and Axles|chapter-url=https://www.jstage.jst.go.jp/article/trol/14/5/14_428/_article/-char/ja/|pages=428–437|doi=10.2474/trol.14.428|title=Tribology Online|volume=14|issue=5|s2cid=210160024|access-date=17 February 2020|archive-date=17 February 2020|archive-url=https://web.archive.org/web/20200217161625/https://www.jstage.jst.go.jp/article/trol/14/5/14_428/_article/-char/ja/|url-status=live}}</ref> but other industrial, marine, and metal working applications are also big consumers of lubricants. Although air and other gas-based lubricants are known (e.g., in ]s), liquid lubricants dominate the market, followed by solid lubricants. | |||
===Reduce friction=== | |||
Lubricants are generally composed of a majority of base ] plus a variety of additives to impart desirable characteristics. Although generally lubricants are based on one type of base oil, mixtures of the base oils also are used to meet performance requirements. | |||
Typically the lubricant-to-surface ] is much less than surface-to-surface friction in a system without any lubrication. Thus use of a lubricant reduces the overall system friction. Reduced friction has the benefit of reducing heat generation and reduced formation of wear particles as well as improved efficiency. Lubricants may contain additives known as friction modifiers that chemically bind to metal surfaces to reduce surface friction even when there is insufficient bulk lubricant present for hydrodynamic lubrication, e.g. protecting the valve train in a car engine at startup. | |||
=== |
=== Mineral oil === | ||
The term "]" is used to refer to lubricating base oils derived from ]. The ] (API) designates several types of lubricant base oil:<ref>{{Cite web |url=http://www.api.org/certifications/engineoil/pubs/index.cfm |title=Engine Oil Publications |access-date=30 August 2007 |archive-date=1 July 2010 |archive-url=https://web.archive.org/web/20100701174323/http://www.api.org/certifications/engineoil/pubs/index.cfm |url-status=live }}</ref> | |||
Both gas and liquid lubricants can transfer heat. However, liquid lubricants are much more effective on account of their high specific ]. Typically the liquid lubricant is constantly circulated to and from a cooler part of the system, although lubricants may be used to warm as well as to cool when a regulated temperature is required. This circulating flow also determines the amount of heat that is carried away in any given unit of time. High flow systems can carry away a lot of heat and have the additional benefit of reducing the thermal stress on the lubricant. Thus lower cost liquid lubricants may be used. The primary drawback is that high flows typically require larger sumps and bigger cooling units. A secondary drawback is that a high flow system that relies on the flow rate to protect the lubricant from thermal stress is susceptible to catastrophic failure during sudden system shut downs. An automotive oil-cooled ] is a typical example. Turbochargers get red hot during operation and the oil that is cooling them only survives as its residence time in the system is very short i.e. high flow rate. If the system is shut down suddenly (pulling into a service area after a high speed drive and stopping the engine) the oil that is in the turbo charger immediately oxidizes and will clog the oil ways with deposits. Over time these deposits can completely block the oil ways, reducing the cooling with the result that the turbo charger experiences total failure typically with seized ]. | |||
Non-flowing lubricants such as greases & pastes are not effective at heat transfer although they do contribute by reducing the generation of heat in the first place. | |||
* Group I – Saturates < 90% and/or ] > 0.03%, and ] (SAE) ] (VI) of 80 to 120 | |||
===Carry away contaminants and debris=== | |||
: Manufactured by solvent extraction, solvent or catalytic dewaxing, and hydro-finishing processes. Common Group I base oil are 150SN (solvent neutral), 500SN, and 150BS (brightstock) | |||
* Group II – Saturates > 90% and sulfur < 0.03%, and SAE viscosity index of 80 to 120 | |||
Lubricant circulation systems have the benefit of carrying away internally generated debris and external contaminants that get introduced into the system to a filter where they can be removed. Lubricants for machines that regularly generate debris or contaminants such as automotive engines typically contain detergent and dispersant additives to assist in debris and contaminant transport to the filter and removal. Over time the filter will get clogged and require cleaning or replacement, hence the recommendation to change a car's oil filter at the same time as changing the oil. In closed systems such as gear boxes the filter may be supplemented by a magnet to attract any iron fines that get created. | |||
It is apparent that in a circulatory system the oil will only be as clean as the filter can make it, thus it is unfortunate that there are no industry standards by which consumers can readily assess the filtering ability of various automotive filters. Poor filtration significantly reduces the life of the machine (engine) as well as making the system inefficient. | |||
===Transmit power=== | |||
] is at the heart of hydrostatic power transmission. Hydraulic fluids comprise a large portion of all lubricants produced in the world. | |||
===Protect against wear=== | |||
Lubricants prevent wear by keeping the moving parts apart. Lubricants may also contain anti-wear or extreme pressure additives to boost their performance against wear and fatigue. | |||
===Prevent corrosion=== | |||
Good quality lubricants are typically formulated with additives that form chemical bonds with surfaces to prevent corrosion and rust. | |||
===Seal for gasses=== | |||
Lubricants will occupy the clearance between moving parts through the capillary force, thus sealing the clearance. This effect can be used to seal pistons and shafts. | |||
== History == | |||
Romans used rags dipped in animal fat to lubricate wagon wheels; however the science of lubrication (]) really only took off with the industrial revolution in the nineteenth century. | |||
== General composition == | |||
Lubricants are generally composed of a majority of base ] and a minority of additives to impart desirable characteristics. | |||
== Types of lubricants == | |||
*] | |||
*] including emulsions and suspensions | |||
*] | |||
*]s | |||
*] | |||
===Gaseous lubricants=== | |||
Gaseous lubricants have a much lower viscosity and higher compressibility compared to liquid lubricants, but the fluid-film principles apply analogeous to gases. | |||
Some examples for gaseous lubricants are air (used in ]s), technical gases, steam or liquid-metal vapours. | |||
===Liquid lubricants=== | |||
Liquid lubricants may be characterized in many different ways. One of the most common ways is by the type of base oil used. Following are the most common types. | |||
*Lanolin (wool grease, natural water repellant) | |||
*Water | |||
*Mineral oils | |||
*Vegetable (natural oil) | |||
*]s | |||
*Other liquids | |||
Note: although generally lubricants are based on one type of base oil or another, it is quite possible to use mixtures of the base oils to meet performance requirements. | |||
====Lanolin==== | |||
A natural water repellent, lanolin is derived from ] wool grease, and is an alternative to the more common petro-chemical based lubricants. This lubricant is also a corrosion inhibitor, protecting against rust, salts, and acids. | |||
====Water==== | |||
Water can be used on its own, or as a major component in combination with one of the other base oils. Commonly used in engineering processes, such as milling and lathe turning. | |||
====Mineral oil==== | |||
This term is used to encompass lubricating base oil derived from ]. The ] (API) designates several types of lubricant base oil identified<ref>http://www.api.org/certifications/engineoil/pubs/index.cfm</ref> as: | |||
*Group I – Saturates <90% and/or ] >0.03%, and ] (SAE) ] (VI) of 80 to 120 | |||
: Manufactured by solvent extraction, solvent or catalytic dewaxing, and hydro-finishing processes. Common Group I base oil are 150SN (solvent neutral), 500SN, and 150BS (brightstok) | |||
*Group II – Saturates over 90% and sulfur under 0.03%, and SAE viscosity index of 80 to 120 | |||
: Manufactured by hydrocracking and solvent or catalytic dewaxing processes. Group II base oil has superior anti-oxidation properties since virtually all hydrocarbon molecules are saturated. It has water-white color. | : Manufactured by hydrocracking and solvent or catalytic dewaxing processes. Group II base oil has superior anti-oxidation properties since virtually all hydrocarbon molecules are saturated. It has water-white color. | ||
*Group III – Saturates > 90%, sulfur <0.03%, and SAE viscosity index over 120 | * Group III – Saturates > 90%, sulfur < 0.03%, and SAE viscosity index over 120 | ||
: Manufactured by special processes such as isohydromerization. Can be manufactured from base oil or slax wax from dewaxing process. | : Manufactured by special processes such as isohydromerization. Can be manufactured from base oil or slax wax from dewaxing process. | ||
*Group IV – ] (PAO) | * Group IV – ] (PAO) | ||
*Group V – All others not included above | * Group V – All others not included above, such as naphthenics, polyalkylene glycols (PAG), and ]s. | ||
Such as naphthenics, PAG, ]s, etc. | |||
:: In ], Groups III, IV and V are now described as ], with group III frequently described as synthesised hydrocarbons, or SHCs. In ], only Groups IV and V may be classed as synthetics. | |||
The lubricant industry commonly extends this group terminology to include: | The lubricant industry commonly extends this group terminology to include: | ||
*Group I+ with a ] of 103–108 | * Group I+ with a ] of 103–108 | ||
*Group II+ with a |
* Group II+ with a viscosity index of 113–119 | ||
*Group III+ with a |
* Group III+ with a viscosity index of at least 140 | ||
Can also be classified into three categories depending on the prevailing compositions: | Can also be classified into three categories depending on the prevailing compositions: | ||
Line 125: | Line 75: | ||
* Aromatic | * Aromatic | ||
=== Synthetic oils === | |||
:: While lubricants for use in internal combustion engines may solely consist of one of the above-mentioned oil groups, it is not desirable in practice. Additives to reduce oxidation and improve lubrication are added to the final product. The main constituent of such lubricant product is called the base oil, base stock. While it is advantageous to have a high-grade base oil in a lubricant, proper selection of the lubricant additives is equally as important. Thus some poorly selected formulation of PAO lubricant may not last as long as more expensive formulation of Group III+ lubricant. | |||
Petroleum-derived lubricant can also be produced using synthetic hydrocarbons (derived ultimately from petroleum), "]s". | |||
These include: | |||
====Vegetable (natural) oils==== | |||
* ] (PAO) | |||
These are primarily triglyceride esters derived from plants and animals. For lubricant base oil use the vegetable derived materials are preferred. Common ones include high oleic ], ], ], ] and ] from vegetable, and ] from animal sources. Many vegetable oils are often hydrolyzed to yield the acids which are subsequently combined selectively to form specialist synthetic esters. | |||
* Synthetic ] | |||
* ] (PAG) | |||
* ]s | |||
* ] (PFPE) | |||
* ] (AN) | |||
* ] | |||
* ] | |||
* ] (MAC) | |||
=== Solid lubricants === | |||
====]s==== | |||
*] (PAO) | |||
*Synthetic ] | |||
*] ] (PAG) | |||
*]s | |||
*] (AN) | |||
*] | |||
*] | |||
== Solid lubricants == | |||
{{main|Dry lubricant}} | {{main|Dry lubricant}} | ||
=== Teflon or PTFE === | |||
] |
'''PTFE:''' ] (PTFE) is typically used as a coating layer on, for example, cooking utensils to provide a non-stick surface. Its usable temperature range up to 350 °C and chemical inertness make it a useful additive in special ], where it can function both as a thickener and a lubricant. Under extreme pressures, PTFE powder or solids is of little value as it is soft and flows away from the area of contact. Ceramic or metal or alloy lubricants must be used then.<ref>{{cite journal|title=Historical developments and new trends in tribological and solid lubricant coatings | ||
|author1=Donnet, C.|author2=Erdemir, A.|journal=Surface and Coatings Technology|year=2004|volume=180-181|pages=76–84|doi=10.1016/j.surfcoat.2003.10.022}}</ref> | |||
'''Inorganic solids:''' ], hexagonal ], ] and ] are examples of ]s. Some retain their lubricity to very high temperatures. The use of some such materials is sometimes restricted by their poor resistance to oxidation (e.g., molybdenum disulfide degrades above 350 °C in air, but 1100 °C in reducing environments. | |||
=== Non-metals === | |||
'''Metal/alloy:''' Metal alloys, composites and pure metals can be used as grease additives or the sole constituents of sliding surfaces and bearings. ] and ] are used for plating surfaces which gives them good corrosion resistance and sliding properties, ], ], ] alloys and various ] alloys are used as sliding bearings, or their powder can be used to lubricate sliding surfaces alone. | |||
], hexagonal ], ] and ] are examples of materials that can be used as ]s, often to very high temperature. The use of some such materials is sometimes restricted by their poor resistance to oxidation (e.g., molybdenum disulfide can only be used up to 350°C in air, but 1100°C in reducing environments). | |||
=== |
=== Aqueous lubrication === | ||
Aqueous lubrication is of interest in a number of technological applications. Strongly hydrated ]s such as PEG can serve as lubricants at liquid solid interfaces.<ref>{{Cite journal| doi=10.1007/s11249-009-9549-9| title=Macrotribological Studies of Poly(L-lysine)-graft-Poly(ethylene glycol) in Aqueous Glycerol Mixtures| journal=Tribology Letters| volume=37| issue=3| pages=541–552| year=2010| last1=Nalam| first1=Prathima C.| last2=Clasohm| first2=Jarred N.| last3=Mashaghi| first3=Alireza| last4=Spencer| first4=Nicholas D.| hdl=20.500.11850/17055| s2cid=109928127| url=http://doc.rero.ch/record/314245/files/11249_2009_Article_9549.pdf| hdl-access=free| access-date=13 July 2019| archive-date=27 April 2019| archive-url=https://web.archive.org/web/20190427091427/http://doc.rero.ch/record/314245/files/11249_2009_Article_9549.pdf| url-status=live}}</ref> By continuous rapid exchange of bound water with other free water molecules, these polymer films keep the surfaces separated while maintaining a high fluidity at the brush–brush interface at high compressions, thus leading to a very low coefficient of friction. | |||
=== Biolubricant === | |||
Metal alloys, composites and pure metals can be used as grease additives or the sole constituents of sliding surfaces and bearings. ] and ] are used for plating surfaces which gives them good corrosion resistance and sliding properties, ], ], ] alloys and various ] alloys are used as sliding bearings, or their powder can be used to lubricate sliding surfaces alone, or as additives to greases. | |||
Biolubricants<ref>{{Cite journal |last=Duan |first=Zhenjing |last2=Li |first2=Changhe |last3=Zhang |first3=Yanbin |last4=Yang |first4=Min |last5=Gao |first5=Teng |last6=Liu |first6=Xin |last7=Li |first7=Runze |last8=Said |first8=Zafar |last9=Debnath |first9=Sujan |last10=Sharma |first10=Shubham |date=2023-02-20 |title=Mechanical behavior and semiempirical force model of aerospace aluminum alloy milling using nano biological lubricant |url=https://doi.org/10.1007/s11465-022-0720-4 |journal=Frontiers of Mechanical Engineering |language=en |volume=18 |issue=1 |pages=4 |doi=10.1007/s11465-022-0720-4 |issn=2095-0241}}</ref> are derived from vegetable oils and other renewable sources. They usually are ] esters (fats obtained from plants and animals). For lubricant base oil use, the vegetable derived materials are preferred. Common ones include high oleic ], ], ], ] and ] from vegetable, and ] from tree sources. Many vegetable oils are often hydrolyzed to yield the acids which are subsequently combined selectively to form specialist synthetic esters. Other naturally derived lubricants include ] (wool grease, a natural water repellent).<ref>{{cite journal|title=Biolubricants: raw materials, chemical modifications and environmental benefits|author1=Salimon, Jumat|author2=Salih, Nadia|author3=Yousif, Emad | |||
|journal=European Journal of Lipid Science and Technology|year=2010|volume=112|issue=5|pages=519–530|doi=10.1002/ejlt.200900205}}</ref> | |||
] was a historically important lubricant, with some uses up to the latter part of the 20th century as a friction modifier ] for ].<ref>{{Cite book |url=https://books.google.com/books?id=buwQ8a2RCUcC&q=whale+oil+dexron&pg=PA20 |page=20|title=The Turbo Hydra-Matic 350 Handbook|isbn=9780895860514|last1=Sessions|first1=Ron|year=1985}}</ref> | |||
== Other relevant phenomena == | |||
=== 'Glaze' formation (high temperature wear) === | |||
In 2008, the biolubricant market was around 1% of UK lubricant sales in a total lubricant market of 840,000 tonnes/year.<ref>]. {{Webarchive|url=https://web.archive.org/web/20150204193558/http://www.nnfcc.co.uk/publications/nnfcc-conference-poster-improved-winter-rape-varieties-for-biolubricants |date=4 February 2015 }}</ref> | |||
A further phenomenon that has undergone investigation in relation to high temperature wear prevention and lubrication, is that of ']' formation <ref>http://mysite.wanadoo-members.co.uk/high_temp_wear/mythesis.html</ref>. This is the generation of a compacted oxide layer which sinters together to form a crystalline 'glaze' (not the amorphous layer seen in pottery) generally at high temperatures, from metallic surfaces sliding against each other (or a metallic surface against a ceramic surface). Due to the elimination of metallic contact and adhesion by the generation of oxide, friction and wear is reduced. Effectively, such a surface is self-lubricating. | |||
{{as of|2020}}, researchers at Australia's ] have been studying ] oil as an engine lubricant, finding superior performance and lower emissions than ]-based lubricants in applications such as ]-driven ]s, ]s and other agricultural equipment. ]-growers trialling the product have welcomed the innovation, with one describing it as needing very little refining, ], a ] and ]. The scientists have reengineered the plant using ], creating a variety that produces up to 93% of oil, the highest currently available from any plant. Researchers at ]’s Advanced Fuel Centre in the US studying the oil’s performance in a large ], comparing it with conventional oil, have described the results as a "game-changer".<ref>{{cite web | title=Safflower oil hailed by scientists as possible recyclable, biodegradable replacement for petroleum | website=ABC News | series=Landline | publisher=Australian Broadcasting Corporation | first=Tim | last=Lee | date=7 June 2020 | url=https://www.abc.net.au/news/2020-06-07/safflower-oil-new-biofuel-to-replace-petroleum/12321028 | access-date=7 June 2020 | archive-date=7 June 2020 | archive-url=https://web.archive.org/web/20200607012058/https://www.abc.net.au/news/2020-06-07/safflower-oil-new-biofuel-to-replace-petroleum/12321028 | url-status=live }}</ref> | |||
As the 'glaze' is already an oxide, it can survive to very high temperatures in air or oxidising environments. However, it is disadvantaged by it being necessary for the base metal (or ceramic) having to undergo some wear first to generate sufficient oxide debris. | |||
== |
=== Greases === | ||
Are solid or semi-solid lubricant produced by blending thickening agents within a liquid lubricant. Greases are typically composed of about 80% lubricating oil, around 5% to 10% thickener, and approximately 10% to 15% additives. In most common greases, the thickener is a light or alkali metal soap, forming a sponge-like structure that encapsulates the oil droplets. Beyond lubrication, greases are generally expected to provide corrosion protection, typically achieved through additives. To prevent drying out at higher temperatures, dry lubricants are also added. By selecting appropriate oils, thickeners, and additives, the properties of greases can be optimized for a wide range of applications. There are greases suited for high or extremely low temperatures, vacuum applications, water-resistant and weatherproof greases, highly pressure-resistant or creeping types, food-grade, or exceptionally adhesive greases.<ref>{{Cite web |last=CarArco |date=2024-10-18 |title=Graisses lubrifiantes : Normes internationales |url=https://wodoil.ch/graisses-lubrifiantes-normes-internationales/ |access-date=2024-10-30 |website=Wodoil |language=de-DE}}</ref> | |||
A large number of additives are used to impart performance characteristics to the lubricants. The main families of additives are: | |||
*]s | |||
*]s | |||
*] | |||
*]s | |||
*], Rust inhibitors | |||
*]s | |||
*] | |||
*]s | |||
*]s | |||
*] | |||
*Stickiness improver, provide adhesive property towards tool surface (in metalworking) | |||
*Complexing agent (in case of greases) | |||
== Functions of lubricants == | |||
Note that many of the basic chemical compounds used as detergents (example: calcium sulfonate) serve the purpose of the first seven items in the list as well. Usually it is not economically or technically feasible to use a single do-it-all additive compound. Oils for ] gear lubrication will contain high content of EP additives. Grease lubricants may contain large amount of solid particle friction modifiers, such as graphite, molybden sulfide, etc. | |||
One of the largest applications for lubricants, in the form of ], is protecting the ]s in motor vehicles and powered equipment. | |||
<!--Lubricants such as ] are added to ]s like gasoline, which has low lubricity. ] impurities in fuels also provide some lubrication properties, which is absent in low-sulfur ]. ] is a popular diesel fuel additive providing lubricity. | |||
Another approach to reducing friction and wear is to use ] such as ]s, ]s or ]s, which in turn require internal lubrication themselves, or to use sound, in the case of ].--> | |||
== Application by fluid types == | |||
=== Lubricant vs. anti-tack coating === | |||
*Automotive | |||
'''Anti-tack or anti-stick coatings''' are designed to reduce the adhesive condition (stickiness) of a given material. The rubber, hose, and wire and cable industries are the largest consumers of anti-tack products but virtually every industry uses some form of anti-sticking agent. Anti-sticking agents differ from ''lubricants'' in that they are designed to reduce the inherently adhesive qualities of a given compound while lubricants are designed to reduce friction between any two surfaces. | |||
**]s | |||
***Petrol (]) engine oils | |||
***] oils | |||
**] fluid | |||
**] fluids | |||
**]s | |||
**]s | |||
*Tractor (one lubricant for all systems) | |||
**] | |||
**] | |||
*Other motors | |||
**] | |||
*Industrial | |||
**Hydraulic oils | |||
**Air compressor oils | |||
**] oils | |||
**] oils | |||
**Bearing and circulating system oils | |||
**Refrigerator compressor oils | |||
**Steam and gas turbine oils | |||
*Aviation | |||
**] engine oils | |||
**] oils | |||
*Marine | |||
**Crosshead cylinder oils | |||
**Crosshead ] oils | |||
**Trunk piston engine oils | |||
**Stern tube lubricants | |||
=== Keep moving parts apart === | |||
== Marketing == | |||
Lubricants are typically used to separate ] in a system. This separation has the benefit of reducing friction, wear and surface fatigue, together with reduced heat generation, operating noise and vibrations. Lubricants achieve this in several ways. The most common is by forming a physical barrier i.e., a thin layer of lubricant separates the moving parts. This is analogous to hydroplaning, the loss of friction observed when a car tire is separated from the road surface by moving through standing water. This is termed hydrodynamic lubrication. In cases of high surface pressures or temperatures, the fluid film is much thinner and some of the forces are transmitted between the surfaces through the lubricant. | |||
=== Reduce friction === | |||
The global lubricant market is generally competitive with numerous manufacturers and marketers. Overall the western market may be considered mature with a flat to declining overall volumes while there is strong growth in the emerging economies. The lubricant marketers generally--- pursue one or more of the following strategies when pursuing business. | |||
Typically the lubricant-to-surface ] is much less than surface-to-surface friction in a system without any lubrication. Thus use of a lubricant reduces the overall system friction. Reduced friction has the benefit of reducing heat generation and reduced formation of wear particles as well as improved efficiency. Lubricants may contain ] ] known as friction modifiers that chemically bind to metal surfaces to reduce surface friction even when there is insufficient bulk lubricant present for hydrodynamic lubrication, e.g. protecting the ] in a car engine at startup. The base oil itself might also be polar in nature and as a result inherently able to bind to metal surfaces, as with ] oils. | |||
=== Transfer heat === | |||
*'''Specification:''' | |||
Both gas and liquid lubricants can transfer heat. However, liquid lubricants are much more effective on account of their high ]. Typically the liquid lubricant is constantly circulated to and from a cooler part of the system, although lubricants may be used to warm as well as to cool when a regulated temperature is required. This circulating flow also determines the amount of heat that is carried away in any given unit of time. High flow systems can carry away a lot of heat and have the additional benefit of reducing the thermal stress on the lubricant. Thus lower cost liquid lubricants may be used. The primary drawback is that high flows typically require larger sumps and bigger cooling units. A secondary drawback is that a high flow system that relies on the flow rate to protect the lubricant from thermal stress is susceptible to catastrophic failure during sudden system shut downs. An automotive oil-cooled ] is a typical example. Turbochargers get red hot during operation and the oil that is cooling them only survives as its residence time in the system is very short (i.e. high flow rate). If the system is shut down suddenly (pulling into a service area after a high-speed drive and stopping the engine) the oil that is in the turbo charger immediately oxidizes and will clog the oil ways with deposits. Over time these deposits can completely block the oil ways, reducing the cooling with the result that the turbo charger experiences total failure, typically with seized ]. Non-flowing lubricants such as greases and pastes are not effective at heat transfer although they do contribute by reducing the generation of heat in the first place. | |||
=== Carry away contaminants and debris === | |||
The lubricant is said to meet a certain specification. In the consumer market, this is often supported by a logo, symbol or words that inform the consumer that the lubricant marketer has obtained independent verification of conformance to the specification. Examples of these include the API’s donut logo or the ] tick mark. The most widely perceived is SAE viscosity specification, like ] 10W-40. Lubricity specifications are institute and manufacturer based. In the U.S. institute: API S for petrol engines, API C for diesel engines. For 2007 the current specs are API SM and API CJ. Higher second letter marks better oil properties, like lower engine wear supported by tests. In EU the ] specifications are used. There are classes A,B,C,E with number following the letter. Japan introduced the ] specification for motorbike engines. | |||
In the industrial market place the specification may take the form of a legal contract to supply a conforming fluid or purchasers may choose to buy on the basis of a manufacturers own published specification. | |||
Lubricant circulation systems have the benefit of carrying away internally generated debris and external contaminants that get introduced into the system to a filter where they can be removed. Lubricants for machines that regularly generate debris or contaminants such as automotive engines typically contain detergent and dispersant additives to assist in debris and contaminant transport to the filter and removal. Over time the filter will get clogged and require cleaning or replacement, hence the recommendation to change a car's oil filter at the same time as changing the oil. In closed systems such as gear boxes the filter may be supplemented by a magnet to attract any iron fines that get created. | |||
*'''Original equipment manufacturer (OEM) approval:''' | |||
It is apparent that in a circulatory system the oil will only be as clean as the filter can make it, thus it is unfortunate that there are no industry standards by which consumers can readily assess the filtering ability of various automotive filters. Poor automotive filters | |||
Specifications often denote a minimum acceptable performance levels. Thus many equipment manufacturers add on their own particular requirements or tighten the tolerance on a general specification to meet their particular needs (or doing a different set of tests or using different/own testbed engine). This gives the lubricant marketer an avenue to differentiate their product by designing it to meet an OEM specification. Often, the OEM carries out extensive testing and maintains an active list of approved products. This is a powerful marketing tool in the lubricant marketplace. Text on the back of the motor oil label usually has a list of conformity to some OEM specifications, such as MB, MAN, Volvo, Cummins, VW, BMW or others. Manufactures may have vastly different specifications for the range of engines they make; one may not be completely suitable for some other. | |||
significantly reduce the life of the machine (engine) as well as make the system inefficient. | |||
=== Transmit power === | |||
*'''Performance:''' | |||
{{main|Hydraulics}} | |||
The lubricant marketer claims benefits for the customer based on the superior performance of the lubricant. Such marketing is supported by glamorous advertising, sponsorships of typically sporting events and endorsements. Unfortunately broad performance claims are common in the consumer marketplace, which are difficult or impossible for a typical consumer to verify. In the B2B market place the marketer is normally expected to show data that supports the claims, hence reducing the use of broad claims. Increasing performance, reducing wear and fuel consumption is also aim of the later API, ACEA and car manufacturer oil specifications, so lubricant marketers can back their claims by doing extensive (and expensive) testing. | |||
Lubricants known as ] are used as the ] in hydrostatic power transmission. Hydraulic fluids comprise a large portion of all lubricants produced in the world. The ]'s ] is another important application for power transmission with lubricants. | |||
*'''Longevity:''' | |||
=== Protect against wear === | |||
The marketer claims that their lubricant maintains its performance over a longer period of time. For example in the consumer market, a typical motor oil change interval is around the 3000–6000 miles (7500–15000 km). The lubricant marketer may offer a lubricant that lasts for 12000 (30000 km) miles or more to convince a user to pay a premium. Typically, the consumer would need to check or balance the longer life and any warranties offered by the lubricant manufacturer with the possible loss of equipment manufacturer warranties by not following its schedule. Many car and engine manufacturers support extended drain intervals, but request extended drain interval certified oil used in that case; and sometimes a special oil filter. Example: In older Mercedes-Benz engines and in truck engines one can use engine oil MB 228.1 for basic drain interval. Engine oils conforming with higher specification MB 228.3 may be used twice as long, oil of MB 228.5 specification 3x longer. Note that the oil drain interval is valid for new engine with fuel conforming car manufacturer specification. When using lower grade fuel, or worn engine the oil change interval has to shorten accordingly. In general oils '''approved''' for extended use are of higher specification and reduce wear. | |||
In the industrial market place the longevity is generally measured in time units and the lubricant marketer can suffer large financial penalties if their claims are not substantiated. | |||
Lubricants prevent wear by reducing friction between two parts. Lubricants may also contain anti-wear or extreme pressure additives to boost their performance against wear and fatigue. | |||
*'''Efficiency:''' | |||
=== Prevent corrosion and rusting === | |||
The lubricant marketer claims improved equipment efficiency when compared to rival products or technologies, the claim is usually valid when comparing lubricant of higher specification with previous grade. Typically the efficiency is proved by showing a reduction in energy costs to operate the system. Guaranteeing improved efficiency is the goal of some oil test specifications such as ] '''Plus''' for diesel engines. Some car/engine manufacturers also specifically request certain higher efficiency level for lubricants for extended drain intervals. | |||
Many lubricants are formulated with additives that form chemical bonds with surfaces or that exclude moisture, to prevent corrosion and rust. It reduces corrosion between two metallic surfaces and avoids contact between these surfaces to avoid immersed corrosion. | |||
=== Seal for gases === | |||
*'''Operational tolerance:''' | |||
Lubricants will occupy the clearance between moving parts through the capillary force, thus sealing the clearance. This effect can be used to seal pistons and shafts. | |||
==Fluid types== | |||
The lubricant is claimed to cope with specific operational environment needs. Some common environments include dry, wet, cold, hot, fire risk, high load, high or low speed, chemical compatibility, atmospheric compatibility, pressure or vacuum and various combinations. The usual thermal characteristics is outlined with SAE viscosity given for 100°C, like SAE 30, SAE 40. For low temperature viscosity the SAE xxW mark is used. Both markings can be combined together to form a SAE 0W-60 for example. ] (VI) marks viscosity change with temperature, with higher VI numbers being more temperature stable. | |||
* Automotive | |||
*'''Economy:''' | |||
** ]s | |||
*** Petrol (]) engine oils | |||
*** ] oils | |||
** ] fluid | |||
** ] fluids | |||
** ]s | |||
** ]s | |||
** ] oils | |||
* Tractor (one lubricant for all systems) | |||
** ] | |||
** ] | |||
* Other motors | |||
** ] | |||
* Industrial | |||
** Hydraulic oils | |||
** Air compressor oils | |||
** ] | |||
** ] oils | |||
** ]s | |||
** Bearing and circulating system oils | |||
** Refrigerator compressor oils | |||
** Steam and gas turbine oils | |||
* Aviation | |||
** ] engine oils | |||
** ] oils | |||
* Marine | |||
** Crosshead cylinder oils | |||
** Crosshead ] oils | |||
** Trunk piston engine oils | |||
** Stern tube lubricants | |||
<!--== Other relevant phenomena == | |||
The marketer offers a lubricant at a lower cost than rivals either in the same grade or a similar one that will fill the purpose for lesser price. (Stationary installations with short drain intervals.) Alternative may be offering a more expensive lubricant and promise return in lower wear, specific fuel consumption or longer drain intervals. (Expensive machinery, un-affordable downtimes.) | |||
--> | |||
== "Glaze" formation (high-temperature wear) == | |||
A further phenomenon that has undergone investigation in relation to high-temperature wear prevention and lubrication is that of a ] formation. Such glazes are generated by sintering a compacted oxide layer. Such glazes are crystalline, in contrast to the amorphous glazes seen in pottery. The required high temperatures arise from metallic surfaces sliding against each other (or a metallic surface against a ceramic surface). Due to the elimination of metallic contact and adhesion by the generation of oxide, friction and wear is reduced. Effectively, such a surface is self-lubricating. | |||
As the "glaze" is already an oxide, it can survive to very high temperatures in air or oxidising environments. However, it is disadvantaged by it being necessary for the base metal (or ceramic) having to undergo some wear first to generate sufficient oxide debris. | |||
*'''Environment friendly:''' | |||
== Disposal and environmental impact == | |||
The lubricant is said to be environmentally friendly. Typically this is supported by qualifying statements or conformance to generally accepted approvals. Several organizations, typically government sponsored, exist globally to qualify and approve such lubricants by evaluating their potential for environmental harm. Typically, the lubricant manufacturer is allowed to indicate such approval by showing some special mark. Examples include the German “]”, European “]” Eco label, Global Eco-Label “GEN mark”, Nordic, “White Swan”, Japanese “Earth friendly mark”; USA “Green Seal”, Canadian “Environmental Choice”, Chinese “Huan”, Singapore “Green Label” and the French “NF Environment mark”. | |||
It is estimated that about 50% of all lubricants are released into the environment.{{Citation needed|date=January 2021}} Common disposal methods include ], ], ] and discharge into water, though typically disposal in landfill and discharge into water are strictly regulated in most countries, as even small amount of lubricant can contaminate a large amount of water. Most regulations permit a threshold level of lubricant that may be present in waste streams and companies spend hundreds of millions of dollars annually in treating their waste waters to get to acceptable levels.{{Citation needed|date=December 2012}} | |||
*'''Composition:''' | |||
Burning the lubricant as fuel, typically to generate electricity, is also governed by regulations mainly on account of the relatively high level of additives present. Burning generates both airborne pollutants and ash rich in toxic materials, mainly heavy metal compounds. Thus lubricant burning takes place in specialized facilities that have incorporated special scrubbers to remove airborne pollutants and have access to landfill sites with permits to handle the toxic ash. | |||
The marketer claims novel composition of the lubricant which improves some tangible performance over its rivals. Typically the technology is protected via formal patents or other intellectual property protection mechanism to prevent rivals from copying. Lot of claims in this area are simple marketing buzzwords, since most of them are related to a manufacturer specific process naming (which achieves similar results than other ones) but the competition is prohibited from using a trademark. | |||
Unfortunately, most lubricant that ends up directly in the environment is due to the general public discharging it onto the ground, into drains, and directly into landfills as trash. Other direct contamination sources include runoff from roadways, accidental spillages, natural or man-made disasters, and pipeline leakages. | |||
*'''Quality:''' | |||
Improvement in filtration technologies and processes has now made recycling a viable option (with the rising price of base stock and ]). Typically various filtration systems remove particulates, additives, and oxidation products and recover the base oil. The oil may get refined during the process. This base oil is then treated much the same as virgin base oil however there is considerable reluctance to use recycled oils as they are generally considered inferior. Basestock fractionally vacuum distilled from used lubricants has superior properties to all-natural oils, but cost-effectiveness depends on many factors. Used lubricant may also be used as refinery feedstock to become part of crude oil. Again, there is considerable reluctance to this use as the additives, soot, and wear metals will seriously poison/deactivate the critical catalysts in the process. Cost prohibits carrying out both filtration (soot, additives removal) and re-refining (], isomerization, hydrocrack, etc.) however the primary hindrance to recycling still remains the collection of fluids as refineries need continuous supply in amounts measured in cisterns, rail tanks. | |||
The marketer claims broad superior quality of its lubricant with no factual evidence. The quality is “proven” by references to famous brand, sporting figure, racing team, some professional endorsement or some similar '''subjective''' claim. All motor oil labels wear mark similar to "of outstanding quality" or "quality additives," the actual comparative evidence is always lacking. | |||
== Disposal and environmental issues == | |||
It is estimated that 40% of all lubricants are released into the environment. | |||
''Disposal:'' | |||
], ], ] and discharge into water may achieve disposal of used ]. | |||
There are typically strict regulations in most countries regarding disposal in landfill and discharge into water as even small amount of lubricant can contaminate a large amount of water. Most regulations permit a threshold level of lubricant that may be present in waste streams and companies spend hundreds of millions of dollars annually in treating their waste waters to get to acceptable levels. | |||
Burning the lubricant as fuel, typically to generate electricity, is also governed by regulations mainly on account of the relatively high level of additives present. Burning generates both airborne pollutants and ash rich in toxic materials, mainly heavy metal compounds. Thus lubricant burning takes place in specialized facilities that have incorporated special scrubbers to remove airborne pollutants and have access to landfill sites with permits to handle the toxic ash. | |||
Unfortunately, most lubricant that ends up directly in the environment is due to general public discharging it onto the ground, into drains and directly into landfills as trash. Other direct contamination sources include runoff from roadways, accidental spillages, natural or man-made disasters and pipeline leakages. | |||
Improvement in filtration technologies and processes has now made recycling a viable option (with rising price of base stock and ]). Typically various filtration systems remove particulates, additives and oxidation products and recover the base oil. The oil may get refined during the process. This base oil is then treated much the same as virgin base oil however there is considerable reluctance to use recycled oils as they are generally considered inferior. Basestock fractionally vacuum distilled from used lubricants has superior properties to all natural oils, but cost effectiveness depends on many factors. Used lubricant may also be used as refinery feedstock to become part of crude oil. Again there is considerable reluctance to this use as the additives, soot and wear metals will seriously poison/deactivate the critical catalysts in the process. Cost prohibits carrying out both filtration (soot, additives removal) and re-refining (], isomerisation, hydrocrack, etc.) however the primary hindrance to recycling still remains the collection of fluids as refineries need continuous supply in amounts measured in cisterns, rail tanks. | |||
Occasionally, unused lubricant requires disposal. The best course of action in such situations is to return it to the manufacturer where it can be processed as a part of fresh batches. | Occasionally, unused lubricant requires disposal. The best course of action in such situations is to return it to the manufacturer where it can be processed as a part of fresh batches. | ||
''Environment:'' | |||
Lubricants both fresh and used can cause considerable damage to the environment mainly due to their high potential of serious water pollution. Further the additives typically contained in lubricant can be toxic to flora and fauna. In used fluids the oxidation products can be toxic as well. Lubricant persistence in the environment largely depends upon the base fluid, however if very toxic additives are used they may negatively affect the persistence. ] lubricants are non-toxic making them the environmental alternative which is safe for both users and the environment. | ''Environment:'' Lubricants both fresh and used can cause considerable damage to the environment mainly due to their high potential of serious water pollution. Further, the additives typically contained in lubricant can be toxic to flora and fauna. In used fluids, the oxidation products can be toxic as well. Lubricant persistence in the environment largely depends upon the base fluid, however if very toxic additives are used they may negatively affect the persistence. ] lubricants are non-toxic making them the environmental alternative which is safe for both users and the environment. | ||
== Societies and industry bodies == | == Societies and industry bodies == | ||
;]: American Petroleum Institute | |||
* ] (API) | |||
;]: Society of Tribologists and Lubrication Engineers | |||
* ] (STLE) | |||
;]: National Lubricating Grease institute | |||
* ] (NLGI) | |||
;]: Society of Automotive Engineers | |||
* ] (SAE) | |||
;]: Independent lubricant manufacturer association | |||
* ] (ILMA) | |||
* ] (ACEA) | |||
;]: JASO | |||
* ] (JASO) | |||
* ] (PPC) | |||
== Major publications == | == Major publications == | ||
{{Unreferenced section|date=August 2019}}{{Missing information|section|basic details, e.g. publisher, website, publication period|date=August 2019}} | |||
*Peer reviewed | |||
**Tribology Transactions | |||
* Peer reviewed | |||
**Journal of Synthetic Lubricants | |||
** ''ASME Journal of Tribology'' | |||
*Trade periodicals | |||
**Tribology |
** ''Tribology International'' | ||
** ''Tribology Transactions'' | |||
**Fuels & Lubes International | |||
** ''Journal of Synthetic Lubricants'' | |||
**Oiltrends | |||
** ''Tribology Letters'' | |||
**Lubes n’ Greases | |||
** ''Lubrication Science'' | |||
**Compoundings | |||
* Trade periodicals | |||
**Chemical Market Review | |||
** ''Tribology and Lubrication Technology'' | |||
**Machinery lubrication | |||
** ''Fuels & Lubes International'' | |||
** ''Oiltrends'' | |||
** ''Lubes n' Greases'' | |||
** ''Compoundings'' | |||
** ''Chemical Market Review'' | |||
** ''Machinery lubrication'' | |||
== See also == | == See also == | ||
{{Portal|Manufacturing}} | |||
* ] | |||
{{Commons category|Lubricants}} | |||
*] | |||
*{{annotated link|Lubrication}} | |||
*] | |||
* {{annotated link|Motor oil}} | |||
*] | |||
* {{annotated link|Oil analysis}} | |||
* {{annotated link|Penetrating oil}} | |||
* {{annotated link|Tribology}} | |||
==References== | == References == | ||
===Notes=== | |||
{{reflist}} | |||
=== |
=== Notes === | ||
*API 1509, Engine Oil Licensing and Certification System, 15th Edition, 2002. Appendix E, API Base Oil Interchangeability Guidelines for Passenger Car Motor Oils and Diesel Engine Oils (revised) | |||
* | |||
* | |||
* | |||
* | |||
* | |||
* | |||
{{Reflist}} | |||
==External links== | |||
* | |||
=== Sources === | |||
* | |||
* API 1509, Engine Oil Licensing and Certification System, 15th Edition, 2002. Appendix E, API Base Oil Interchangeability Guidelines for Passenger Car Motor Oils and Diesel Engine Oils (revised) | |||
* | |||
* {{ISBN|1-58112-321-3}} | |||
* | |||
* | |||
* | |||
* {{cite book|author=Leslie R. Rudnick|title=Lubricant Additives: Chemistry and Applications|url=https://books.google.com/books?id=cwWgbmL5fyIC|year=2003|publisher=CRC Press|isbn=978-0-8247-4740-4}} | |||
== External links == | |||
{{Wiktionary|lubricant}} | |||
* | |||
* | |||
{{Authority control}} | |||
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Latest revision as of 17:35, 8 January 2025
Substance introduced to reduce friction between surfaces in mutual contact This article is about industrial lubricants. For other uses, see Lubricant (disambiguation).
This article needs additional citations for verification. Please help improve this article by adding citations to reliable sources. Unsourced material may be challenged and removed. Find sources: "Lubricant" – news · newspapers · books · scholar · JSTOR (March 2023) (Learn how and when to remove this message) |
A lubricant (sometimes shortened to lube) is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, transporting foreign particles, or heating or cooling the surfaces. The property of reducing friction is known as lubricity.
In addition to industrial applications, lubricants are used for many other purposes. Other uses include cooking (oils and fats in use in frying pans and baking to prevent food sticking), to reduce rusting and friction in machinery, through the use of motor oil and grease, bioapplications on humans (e.g., lubricants for artificial joints), ultrasound examination, medical examination, and sexual intercourse. It is mainly used to reduce friction and to contribute to a better, more efficient functioning of a mechanism.
History
Lubricants have been in some use for thousands of years. Calcium soaps have been identified on the axles of chariots dated to 1400 BC. Building stones were slid on oil-impregnated lumber in the time of the pyramids. In the Roman era, lubricants were based on olive oil and rapeseed oil, as well as animal fats. The growth of lubrication accelerated in the Industrial Revolution with the accompanying use of metal-based machinery. Relying initially on natural oils, needs for such machinery shifted toward petroleum-based materials early in the 1900s. A breakthrough came with the development of vacuum distillation of petroleum, as described by the Vacuum Oil Company. This technology allowed the purification of very non-volatile substances, which are common in many lubricants.
Properties
A good lubricant generally possesses the following characteristics:
- A high boiling point and low freezing point (in order to stay liquid within a wide range of temperature)
- A high viscosity index
- Thermal stability
- Hydraulic stability
- Demulsibility
- Corrosion prevention
- A high resistance to oxidation
- Pour Point (the minimum temperature at which oil will flow under prescribed test conditions)
Formulation
Typically lubricants contain 90% base oil (most often petroleum fractions, called mineral oils) and less than 10% additives. Vegetable oils or synthetic liquids such as hydrogenated polyolefins, esters, silicones, fluorocarbons and many others are sometimes used as base oils. Additives deliver reduced friction and wear, increased viscosity, improved viscosity index, resistance to corrosion and oxidation, aging or contamination, etc.
Non-liquid lubricants include powders (dry graphite, PTFE, molybdenum disulphide, tungsten disulphide, etc.), PTFE tape used in plumbing, air cushion and others. Dry lubricants such as graphite, molybdenum disulphide and tungsten disulphide also offer lubrication at temperatures (up to 350 °C) higher than liquid and oil-based lubricants are able to operate. Limited interest has been shown in low friction properties of compacted oxide glaze layers formed at several hundred degrees Celsius in metallic sliding systems; however, practical use is still many years away due to their physically unstable nature.
Additives
Main article: Oil additiveA large number of additives are used to impart performance characteristics to the lubricants. Modern automotive lubricants contain as many as ten additives, comprising up to 20% of the lubricant, the main families of additives are:
- Pour point depressants are compounds that prevent crystallization of waxes. Long chain alkylbenzenes adhere to small crystallites of wax, preventing crystal growth.
- Anti-foaming agents are typically silicone compounds which increase surface tension in order to discourage foam formation.
- Viscosity index improvers (VIIs) are compounds that allow lubricants to remain viscous at higher temperatures. Typical VIIs are polyacrylates and butadiene.
- Antioxidants suppress the rate of oxidative degradation of the hydrocarbon molecules within the lubricant. At low temperatures, free radical inhibitors such as hindered phenols are used, e.g. butylated hydroxytoluene. At temperatures >90 °C, where the metals catalyze the oxidation process, dithiophosphates are more useful. In the latter application the additives are called metal deactivators.
- Detergents ensure the cleanliness of engine components by preventing the formation of deposits on contact surfaces at high temperatures.
- Corrosion inhibitors (rust inhibitors) are usually alkaline materials, such as alkylsulfonate salts, that absorb acids that would corrode metal parts.
- Anti-wear additives form protective 'tribofilms' on metal parts, suppressing wear. They come in two classes depending on the strength with which they bind to the surface. Popular examples include phosphate esters and zinc dithiophosphates.
- Extreme pressure (anti-scuffing) additives form protective films on sliding metal parts. These agents are often sulfur compounds, such as dithiophosphates.
- Friction modifiers reduce friction and wear, particularly in the boundary lubrication regime where surfaces come into direct contact.
In 1999, an estimated 37,300,000 tons of lubricants were consumed worldwide. Automotive applications dominate, including electric vehicles but other industrial, marine, and metal working applications are also big consumers of lubricants. Although air and other gas-based lubricants are known (e.g., in fluid bearings), liquid lubricants dominate the market, followed by solid lubricants.
Lubricants are generally composed of a majority of base oil plus a variety of additives to impart desirable characteristics. Although generally lubricants are based on one type of base oil, mixtures of the base oils also are used to meet performance requirements.
Mineral oil
The term "mineral oil" is used to refer to lubricating base oils derived from crude oil. The American Petroleum Institute (API) designates several types of lubricant base oil:
- Group I – Saturates < 90% and/or sulfur > 0.03%, and Society of Automotive Engineers (SAE) viscosity index (VI) of 80 to 120
- Manufactured by solvent extraction, solvent or catalytic dewaxing, and hydro-finishing processes. Common Group I base oil are 150SN (solvent neutral), 500SN, and 150BS (brightstock)
- Group II – Saturates > 90% and sulfur < 0.03%, and SAE viscosity index of 80 to 120
- Manufactured by hydrocracking and solvent or catalytic dewaxing processes. Group II base oil has superior anti-oxidation properties since virtually all hydrocarbon molecules are saturated. It has water-white color.
- Group III – Saturates > 90%, sulfur < 0.03%, and SAE viscosity index over 120
- Manufactured by special processes such as isohydromerization. Can be manufactured from base oil or slax wax from dewaxing process.
- Group IV – Polyalphaolefins (PAO)
- Group V – All others not included above, such as naphthenics, polyalkylene glycols (PAG), and polyesters.
The lubricant industry commonly extends this group terminology to include:
- Group I+ with a viscosity index of 103–108
- Group II+ with a viscosity index of 113–119
- Group III+ with a viscosity index of at least 140
Can also be classified into three categories depending on the prevailing compositions:
- Paraffinic
- Naphthenic
- Aromatic
Synthetic oils
Petroleum-derived lubricant can also be produced using synthetic hydrocarbons (derived ultimately from petroleum), "synthetic oils".
These include:
- Polyalpha-olefin (PAO)
- Synthetic esters
- Polyalkylene glycols (PAG)
- Phosphate esters
- Perfluoropolyether (PFPE)
- Alkylated naphthalenes (AN)
- Silicate esters
- Ionic fluids
- Multiply alkylated cyclopentanes (MAC)
Solid lubricants
Main article: Dry lubricantPTFE: polytetrafluoroethylene (PTFE) is typically used as a coating layer on, for example, cooking utensils to provide a non-stick surface. Its usable temperature range up to 350 °C and chemical inertness make it a useful additive in special greases, where it can function both as a thickener and a lubricant. Under extreme pressures, PTFE powder or solids is of little value as it is soft and flows away from the area of contact. Ceramic or metal or alloy lubricants must be used then.
Inorganic solids: Graphite, hexagonal boron nitride, molybdenum disulfide and tungsten disulfide are examples of solid lubricants. Some retain their lubricity to very high temperatures. The use of some such materials is sometimes restricted by their poor resistance to oxidation (e.g., molybdenum disulfide degrades above 350 °C in air, but 1100 °C in reducing environments.
Metal/alloy: Metal alloys, composites and pure metals can be used as grease additives or the sole constituents of sliding surfaces and bearings. Cadmium and gold are used for plating surfaces which gives them good corrosion resistance and sliding properties, Lead, tin, zinc alloys and various bronze alloys are used as sliding bearings, or their powder can be used to lubricate sliding surfaces alone.
Aqueous lubrication
Aqueous lubrication is of interest in a number of technological applications. Strongly hydrated brush polymers such as PEG can serve as lubricants at liquid solid interfaces. By continuous rapid exchange of bound water with other free water molecules, these polymer films keep the surfaces separated while maintaining a high fluidity at the brush–brush interface at high compressions, thus leading to a very low coefficient of friction.
Biolubricant
Biolubricants are derived from vegetable oils and other renewable sources. They usually are triglyceride esters (fats obtained from plants and animals). For lubricant base oil use, the vegetable derived materials are preferred. Common ones include high oleic canola oil, castor oil, palm oil, sunflower seed oil and rapeseed oil from vegetable, and tall oil from tree sources. Many vegetable oils are often hydrolyzed to yield the acids which are subsequently combined selectively to form specialist synthetic esters. Other naturally derived lubricants include lanolin (wool grease, a natural water repellent).
Whale oil was a historically important lubricant, with some uses up to the latter part of the 20th century as a friction modifier additive for automatic transmission fluid.
In 2008, the biolubricant market was around 1% of UK lubricant sales in a total lubricant market of 840,000 tonnes/year.
As of 2020, researchers at Australia's CSIRO have been studying safflower oil as an engine lubricant, finding superior performance and lower emissions than petroleum-based lubricants in applications such as engine-driven lawn mowers, chainsaws and other agricultural equipment. Grain-growers trialling the product have welcomed the innovation, with one describing it as needing very little refining, biodegradable, a bioenergy and biofuel. The scientists have reengineered the plant using gene silencing, creating a variety that produces up to 93% of oil, the highest currently available from any plant. Researchers at Montana State University’s Advanced Fuel Centre in the US studying the oil’s performance in a large diesel engine, comparing it with conventional oil, have described the results as a "game-changer".
Greases
Are solid or semi-solid lubricant produced by blending thickening agents within a liquid lubricant. Greases are typically composed of about 80% lubricating oil, around 5% to 10% thickener, and approximately 10% to 15% additives. In most common greases, the thickener is a light or alkali metal soap, forming a sponge-like structure that encapsulates the oil droplets. Beyond lubrication, greases are generally expected to provide corrosion protection, typically achieved through additives. To prevent drying out at higher temperatures, dry lubricants are also added. By selecting appropriate oils, thickeners, and additives, the properties of greases can be optimized for a wide range of applications. There are greases suited for high or extremely low temperatures, vacuum applications, water-resistant and weatherproof greases, highly pressure-resistant or creeping types, food-grade, or exceptionally adhesive greases.
Functions of lubricants
One of the largest applications for lubricants, in the form of motor oil, is protecting the internal combustion engines in motor vehicles and powered equipment.
Lubricant vs. anti-tack coating
Anti-tack or anti-stick coatings are designed to reduce the adhesive condition (stickiness) of a given material. The rubber, hose, and wire and cable industries are the largest consumers of anti-tack products but virtually every industry uses some form of anti-sticking agent. Anti-sticking agents differ from lubricants in that they are designed to reduce the inherently adhesive qualities of a given compound while lubricants are designed to reduce friction between any two surfaces.
Keep moving parts apart
Lubricants are typically used to separate moving parts in a system. This separation has the benefit of reducing friction, wear and surface fatigue, together with reduced heat generation, operating noise and vibrations. Lubricants achieve this in several ways. The most common is by forming a physical barrier i.e., a thin layer of lubricant separates the moving parts. This is analogous to hydroplaning, the loss of friction observed when a car tire is separated from the road surface by moving through standing water. This is termed hydrodynamic lubrication. In cases of high surface pressures or temperatures, the fluid film is much thinner and some of the forces are transmitted between the surfaces through the lubricant.
Reduce friction
Typically the lubricant-to-surface friction is much less than surface-to-surface friction in a system without any lubrication. Thus use of a lubricant reduces the overall system friction. Reduced friction has the benefit of reducing heat generation and reduced formation of wear particles as well as improved efficiency. Lubricants may contain polar additives known as friction modifiers that chemically bind to metal surfaces to reduce surface friction even when there is insufficient bulk lubricant present for hydrodynamic lubrication, e.g. protecting the valve train in a car engine at startup. The base oil itself might also be polar in nature and as a result inherently able to bind to metal surfaces, as with polyolester oils.
Transfer heat
Both gas and liquid lubricants can transfer heat. However, liquid lubricants are much more effective on account of their high specific heat capacity. Typically the liquid lubricant is constantly circulated to and from a cooler part of the system, although lubricants may be used to warm as well as to cool when a regulated temperature is required. This circulating flow also determines the amount of heat that is carried away in any given unit of time. High flow systems can carry away a lot of heat and have the additional benefit of reducing the thermal stress on the lubricant. Thus lower cost liquid lubricants may be used. The primary drawback is that high flows typically require larger sumps and bigger cooling units. A secondary drawback is that a high flow system that relies on the flow rate to protect the lubricant from thermal stress is susceptible to catastrophic failure during sudden system shut downs. An automotive oil-cooled turbocharger is a typical example. Turbochargers get red hot during operation and the oil that is cooling them only survives as its residence time in the system is very short (i.e. high flow rate). If the system is shut down suddenly (pulling into a service area after a high-speed drive and stopping the engine) the oil that is in the turbo charger immediately oxidizes and will clog the oil ways with deposits. Over time these deposits can completely block the oil ways, reducing the cooling with the result that the turbo charger experiences total failure, typically with seized bearings. Non-flowing lubricants such as greases and pastes are not effective at heat transfer although they do contribute by reducing the generation of heat in the first place.
Carry away contaminants and debris
Lubricant circulation systems have the benefit of carrying away internally generated debris and external contaminants that get introduced into the system to a filter where they can be removed. Lubricants for machines that regularly generate debris or contaminants such as automotive engines typically contain detergent and dispersant additives to assist in debris and contaminant transport to the filter and removal. Over time the filter will get clogged and require cleaning or replacement, hence the recommendation to change a car's oil filter at the same time as changing the oil. In closed systems such as gear boxes the filter may be supplemented by a magnet to attract any iron fines that get created.
It is apparent that in a circulatory system the oil will only be as clean as the filter can make it, thus it is unfortunate that there are no industry standards by which consumers can readily assess the filtering ability of various automotive filters. Poor automotive filters significantly reduce the life of the machine (engine) as well as make the system inefficient.
Transmit power
Main article: HydraulicsLubricants known as hydraulic fluid are used as the working fluid in hydrostatic power transmission. Hydraulic fluids comprise a large portion of all lubricants produced in the world. The automatic transmission's torque converter is another important application for power transmission with lubricants.
Protect against wear
Lubricants prevent wear by reducing friction between two parts. Lubricants may also contain anti-wear or extreme pressure additives to boost their performance against wear and fatigue.
Prevent corrosion and rusting
Many lubricants are formulated with additives that form chemical bonds with surfaces or that exclude moisture, to prevent corrosion and rust. It reduces corrosion between two metallic surfaces and avoids contact between these surfaces to avoid immersed corrosion.
Seal for gases
Lubricants will occupy the clearance between moving parts through the capillary force, thus sealing the clearance. This effect can be used to seal pistons and shafts.
Fluid types
- Automotive
- Motor oils
- Petrol (Gasolines) engine oils
- Diesel engine oils
- Automatic transmission fluid
- Gearbox fluids
- Brake fluids
- Hydraulic fluids
- Air conditioning compressor oils
- Motor oils
- Tractor (one lubricant for all systems)
- Other motors
- Industrial
- Hydraulic oils
- Air compressor oils
- Food-grade lubricant
- Gas Compressor oils
- Gear oils
- Bearing and circulating system oils
- Refrigerator compressor oils
- Steam and gas turbine oils
- Aviation
- Gas turbine engine oils
- Piston engine oils
- Marine
- Crosshead cylinder oils
- Crosshead Crankcase oils
- Trunk piston engine oils
- Stern tube lubricants
"Glaze" formation (high-temperature wear)
A further phenomenon that has undergone investigation in relation to high-temperature wear prevention and lubrication is that of a compacted oxide layer glaze formation. Such glazes are generated by sintering a compacted oxide layer. Such glazes are crystalline, in contrast to the amorphous glazes seen in pottery. The required high temperatures arise from metallic surfaces sliding against each other (or a metallic surface against a ceramic surface). Due to the elimination of metallic contact and adhesion by the generation of oxide, friction and wear is reduced. Effectively, such a surface is self-lubricating.
As the "glaze" is already an oxide, it can survive to very high temperatures in air or oxidising environments. However, it is disadvantaged by it being necessary for the base metal (or ceramic) having to undergo some wear first to generate sufficient oxide debris.
Disposal and environmental impact
It is estimated that about 50% of all lubricants are released into the environment. Common disposal methods include recycling, burning, landfill and discharge into water, though typically disposal in landfill and discharge into water are strictly regulated in most countries, as even small amount of lubricant can contaminate a large amount of water. Most regulations permit a threshold level of lubricant that may be present in waste streams and companies spend hundreds of millions of dollars annually in treating their waste waters to get to acceptable levels.
Burning the lubricant as fuel, typically to generate electricity, is also governed by regulations mainly on account of the relatively high level of additives present. Burning generates both airborne pollutants and ash rich in toxic materials, mainly heavy metal compounds. Thus lubricant burning takes place in specialized facilities that have incorporated special scrubbers to remove airborne pollutants and have access to landfill sites with permits to handle the toxic ash.
Unfortunately, most lubricant that ends up directly in the environment is due to the general public discharging it onto the ground, into drains, and directly into landfills as trash. Other direct contamination sources include runoff from roadways, accidental spillages, natural or man-made disasters, and pipeline leakages.
Improvement in filtration technologies and processes has now made recycling a viable option (with the rising price of base stock and crude oil). Typically various filtration systems remove particulates, additives, and oxidation products and recover the base oil. The oil may get refined during the process. This base oil is then treated much the same as virgin base oil however there is considerable reluctance to use recycled oils as they are generally considered inferior. Basestock fractionally vacuum distilled from used lubricants has superior properties to all-natural oils, but cost-effectiveness depends on many factors. Used lubricant may also be used as refinery feedstock to become part of crude oil. Again, there is considerable reluctance to this use as the additives, soot, and wear metals will seriously poison/deactivate the critical catalysts in the process. Cost prohibits carrying out both filtration (soot, additives removal) and re-refining (distilling, isomerization, hydrocrack, etc.) however the primary hindrance to recycling still remains the collection of fluids as refineries need continuous supply in amounts measured in cisterns, rail tanks.
Occasionally, unused lubricant requires disposal. The best course of action in such situations is to return it to the manufacturer where it can be processed as a part of fresh batches.
Environment: Lubricants both fresh and used can cause considerable damage to the environment mainly due to their high potential of serious water pollution. Further, the additives typically contained in lubricant can be toxic to flora and fauna. In used fluids, the oxidation products can be toxic as well. Lubricant persistence in the environment largely depends upon the base fluid, however if very toxic additives are used they may negatively affect the persistence. Lanolin lubricants are non-toxic making them the environmental alternative which is safe for both users and the environment.
Societies and industry bodies
- American Petroleum Institute (API)
- Society of Tribologists and Lubrication Engineers (STLE)
- National Lubricating Grease Institute (NLGI)
- Society of Automotive Engineers (SAE)
- Independent Lubricant Manufacturer Association (ILMA)
- European Automobile Manufacturers Association (ACEA)
- Japanese Automotive Standards Organization (JASO)
- Petroleum Packaging Council (PPC)
Major publications
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- Peer reviewed
- ASME Journal of Tribology
- Tribology International
- Tribology Transactions
- Journal of Synthetic Lubricants
- Tribology Letters
- Lubrication Science
- Trade periodicals
- Tribology and Lubrication Technology
- Fuels & Lubes International
- Oiltrends
- Lubes n' Greases
- Compoundings
- Chemical Market Review
- Machinery lubrication
See also
- Lubrication – The presence of a material to reduce friction between two surfaces.
- Motor oil – Lubricant used for lubrication of internal combustion engines
- Oil analysis – Laboratory analysis of an oil based lubricant's properties and contaminants
- Penetrating oil – Low-viscosity oil
- Tribology – Science and engineering of interacting surfaces in relative motion
References
Notes
- ^ Don M. Pirro; Martin Webster; Ekkehard Daschner (2016). Lubrication Fundamentals (Third Edition, Revised and Expanded ed.). CRC Press. ISBN 978-1-4987-5290-9. (print) ISBN 978-1-4987-5291-6 (eBook)
- Spikes, H. (1 October 2004). "The History and Mechanisms of ZDDP". Tribology Letters. 17 (3): 469–489. doi:10.1023/B:TRIL.0000044495.26882.b5. ISSN 1023-8883. S2CID 7163944.
- Spikes, Hugh (1 October 2015). "Friction Modifier Additives" (PDF). Tribology Letters. 60 (1): 5. doi:10.1007/s11249-015-0589-z. hdl:10044/1/25879. ISSN 1023-8883. S2CID 137884697. Archived (PDF) from the original on 22 September 2017. Retrieved 23 September 2019.
- Bartels, Thorsten; Bock, Wolfgang; Braun, Jürgen; Busch, Christian; Buss, Wolfgang; Dresel, Wilfried; Freiler, Carmen; Harperscheid, Manfred; Heckler, Rolf-Peter; Hörner, Dietrich; Kubicki, Franz; Lingg, Georg; Losch, Achim; Luther, Rolf; Mang, Theo; Noll, Siegfried; Omeis, Jürgen (2003). "Lubricants and Lubrication". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a15_423. ISBN 978-3527306732.
- Beyer, Monica; Brown, Gareth; Gahagan, Michael; Higuchi, Tomoya; Hunt, Gregory; Huston, Michael; Jayne, Doug; McFadden, Chris; Newcomb, Timothy; Patterson, Suzanne; Prengaman, Christopher; Shamszad, Mariam (12 December 2019). "Lubricant Concepts for Electrified Vehicle Transmissions and Axles". Tribology Online. Vol. 14. pp. 428–437. doi:10.2474/trol.14.428. S2CID 210160024. Archived from the original on 17 February 2020. Retrieved 17 February 2020.
- "Engine Oil Publications". Archived from the original on 1 July 2010. Retrieved 30 August 2007.
- Donnet, C.; Erdemir, A. (2004). "Historical developments and new trends in tribological and solid lubricant coatings". Surface and Coatings Technology. 180–181: 76–84. doi:10.1016/j.surfcoat.2003.10.022.
- Nalam, Prathima C.; Clasohm, Jarred N.; Mashaghi, Alireza; Spencer, Nicholas D. (2010). "Macrotribological Studies of Poly(L-lysine)-graft-Poly(ethylene glycol) in Aqueous Glycerol Mixtures" (PDF). Tribology Letters. 37 (3): 541–552. doi:10.1007/s11249-009-9549-9. hdl:20.500.11850/17055. S2CID 109928127. Archived (PDF) from the original on 27 April 2019. Retrieved 13 July 2019.
- Duan, Zhenjing; Li, Changhe; Zhang, Yanbin; Yang, Min; Gao, Teng; Liu, Xin; Li, Runze; Said, Zafar; Debnath, Sujan; Sharma, Shubham (20 February 2023). "Mechanical behavior and semiempirical force model of aerospace aluminum alloy milling using nano biological lubricant". Frontiers of Mechanical Engineering. 18 (1): 4. doi:10.1007/s11465-022-0720-4. ISSN 2095-0241.
- Salimon, Jumat; Salih, Nadia; Yousif, Emad (2010). "Biolubricants: raw materials, chemical modifications and environmental benefits". European Journal of Lipid Science and Technology. 112 (5): 519–530. doi:10.1002/ejlt.200900205.
- Sessions, Ron (1985). The Turbo Hydra-Matic 350 Handbook. p. 20. ISBN 9780895860514.
- National Non-Food Crops Centre. NNFCC Conference Poster. Improved winter rape varieties for biolubricants Archived 4 February 2015 at the Wayback Machine
- Lee, Tim (7 June 2020). "Safflower oil hailed by scientists as possible recyclable, biodegradable replacement for petroleum". ABC News. Landline. Australian Broadcasting Corporation. Archived from the original on 7 June 2020. Retrieved 7 June 2020.
- CarArco (18 October 2024). "Graisses lubrifiantes : Normes internationales". Wodoil (in German). Retrieved 30 October 2024.
Sources
- API 1509, Engine Oil Licensing and Certification System, 15th Edition, 2002. Appendix E, API Base Oil Interchangeability Guidelines for Passenger Car Motor Oils and Diesel Engine Oils (revised)
- Boughton and Horvath, 2003, Environmental Assessment of Used Oil Management Methods, Environmental Science and Technology, V38
- I.A. Inman. Compacted Oxide Layer Formation under Conditions of Limited Debris Retention at the Wear Interface during High Temperature Sliding Wear of Superalloys, Ph.D. Thesis (2003), Northumbria University ISBN 1-58112-321-3
- Mercedes-Benz oil recommendations, extracted from factory manuals and personal research
- Measuring reserve alkalinity and evaluation of wear dependence
- Testing used oil quality, list of possible measurements
- Leslie R. Rudnick (2003). Lubricant Additives: Chemistry and Applications. CRC Press. ISBN 978-0-8247-4740-4.