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Gallium indium antimonide

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Gallium indium antimonide, also known as indium gallium antimonide, GaInSb, or InGaSb (GaxIn1-xSb), is a ternary III-V semiconductor compound. It can be considered as an alloy between gallium antimonide and indium antimonide. The alloy can contain any ratio between gallium and indium. GaInSb refers generally to any composition of the alloy.

Preparation

GaInSb films have been grown by molecular beam epitaxy, chemical beam epitaxy and liquid phase epitaxy on gallium arsenide and gallium antimonide substrates. It is often incorporated into layered heterostructures with other III-V compounds.

Electronic Properties

Dependence of the direct and indirect band gaps of GaInSb on composition at room temperature (T = 300 K).

The bandgap and lattice constant of GaInSb alloys are between those of pure GaSb (a = 0.610 nm, Eg = 0.73 eV) and InSb (a = 0.648 nm, Eg = 0.17 eV). Over all compositions, the bandgap is direct, like in pure GaSb and InSb.

Applications

InGaSb and InGaSb-containing heterostructures have been studied for use in near- to mid-infrared photodetectors, transistors, and hall effect sensors.

References

  1. Kodama, M., Kimata, M. (1985). "Molecular beam epitaxy of GaSb and InGaSb". Journal of Crystal Growth. 73 (3): 641–645. Bibcode:1985JCrGr..73..641K. doi:10.1016/0022-0248(85)90031-4.
  2. Kaneko, T., Asahi, H., Okuno, Y., Gonda, S. (1989). "MOMBE (Metalorganic Molecular Beam Epitaxy) growth of InGaSb on GaSb". Journal of Crystal Growth. 95 (1): 158–162. Bibcode:1989JCrGr..95..158K. doi:10.1016/0022-0248(89)90372-2.
  3. Mauk, M. G., Tata, A. N., Cox, J. A. (2001). "Solution growth of thick III–V antimonide alloy epilayers (InAsSb, InGaSb, InGaAsSb, AlGaAsSb, and InAsSbP) for "virtual substrates"". Journal of Crystal Growth. 225 (2): 236–243. Bibcode:2001JCrGr.225..236M. doi:10.1016/S0022-0248(01)00843-0.
  4. ^ Vurgaftman, I., Meyer, J. R., Ram-Mohan, L. R. (2001). "Band parameters for III–V compound semiconductors and their alloys". Journal of Applied Physics. 89 (11): 5815–5875. Bibcode:2001JAP....89.5815V. doi:10.1063/1.1368156.
  5. Adachi, S. (1987). "Band gaps and refractive indices of AlGaAsSb, GaInAsSb, and InPAsSb: Key properties for a variety of the 2–4 μm optoelectronic device applications". Journal of Applied Physics. 61 (10): 4869–4876. doi:10.1063/1.338352.
  6. Rogalski, A., Martyniuk, P. (2006). "InAs/GaInSb superlattices as a promising material system for third generation infrared detectors". Infrared Physics & Technology. 48 (1): 39–52. Bibcode:2006InPhT..48...39R. doi:10.1016/j.infrared.2005.01.003.
  7. Li, D., Lan, C., Manikandan, A., Yip, S., Zhou, Z., Liang, X., Shu, L., Chueh, Y.-L., Han, N., Ho, J. C. (2019). "Ultra-fast photodetectors based on high-mobility indium gallium antimonide nanowires". Nature Communications. 10 (1). Nature Publishing Group: 1664. Bibcode:2019NatCo..10.1664L. doi:10.1038/s41467-019-09606-y. PMC 6458123. PMID 30971702.
  8. Refaat, T. F., Abedin, M. N., Bhagwat, V., Bhat, I. B., Dutta, P. S., Singh, U. N. (2004). "InGaSb photodetectors using an InGaSb substrate for 2μm applications". Applied Physics Letters. 85 (11): 1874–1876. Bibcode:2004ApPhL..85.1874R. doi:10.1063/1.1787893.
  9. Ho, H.-C., Gao, Z.-Y., Lin, H.-K., Chiu, P.-C., Hsin, Y.-M., Chyi, J.-I. (2012). "Device Characteristics of InGaSb/AlSb High-Hole-Mobility FETs". IEEE Electron Device Letters. 33 (7): 964–966. Bibcode:2012IEDL...33..964H. doi:10.1109/LED.2012.2193656. S2CID 6254124.
  10. Loesch, R., Aidam, R., Kirste, L., Leuther, A. (2011). "Molecular beam epitaxial growth of metamorphic AlInSb/GaInSb high-electron-mobility-transistor structures on GaAs substrates for low power and high frequency applications". Journal of Applied Physics. 109 (3): 033706–033706–5. Bibcode:2011JAP...109c3706L. doi:10.1063/1.3544041.
  11. Partin, D. L., Heremans, J. P., Schroeder, T., Thrush, C. M., Flores-Mena, L. A. (2006). "Temperature stable Hall effect sensors". IEEE Sensors Journal. 6 (1): 106–110. Bibcode:2006ISenJ...6..106P. doi:10.1109/JSEN.2005.860362. S2CID 40140622.

External links

Salts and covalent derivatives of the antimonide ion
-SbH
SbH3
+H
He
Li3Sb Be ?BSb R3Sb SbN -SbO
various
-SbF4
-SbF6
Ne
Na3Sb
NaSb3
Mg3Sb2 AlSb Si +P +S
-SbS3
-SbS4
+Cl4
+Cl2
-SbCl6
Ar
?K3Sb Ca ScSb Ti V CrSb MnSb
Mn2Sb
Fe2Sb
FeSb2
CoSb
CoSb3
NiSb
Ni3Sb
NiSb2
CuSb
Cu2Sb
Cu3Sb
Cu5Sb
ZnSb
Zn3Sb2
Zn4Sb3
GaSb GeSb AsSb
-As1-xSbx
+Se +Br
+Br2
Kr
Rb3Sb
RbSb3
SrSb3 YSb ZrSb Nb3Sb Mo Tc Ru RhSb various Ag1-xSbx
Ag3Sb
CdSb
Cd3Sb2
InSb SnSb Sb
Sb4
-Sb
+Te +I Xe
Cs3Sb
Cs4Sb2
Ba3Sb2
BaSb3
* LuSb ?HfSb ?TaSb W Re Os Ir PtSb
Pt3Sb
PtSb2
Pt4Sb3
AuSb
AuSb2
Hg TlSb PbSb BiSb
Bi1−xSbx

Bi2Sb2
Po At Rn
Fr3Sb Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaSb ?CeSb PrSb NdSb PmSb SmSb Eu5Sb3
Eu11Sb10
Eu2Sb3
GdSb TbSb DySb HoSb
HoSb2
ErSb TmSb
TmSb
YbSb
** Ac ?ThSb
ThSb2
Th3Sb4
Pa U NpSb Pu AmSb CmSb BkSb
?BkSb
Cf Es Fm Md No
Gallium compounds
Gallium(−V)
Gallium(I)
Gallium(II)
Gallium(I,III)
Gallium(III)
Organogallium(III) compounds
  • Ga(C5H7O2)3
  • Ga(CH3)3
  • Ga(C2H5)3
  • Indium compounds
    Indium(I)
    Organoindium(I) compounds
    Indium(I,III)
    Indium(III)
    Organoindium(III) compounds
  • In(C2H5)3
  • In(CH3)3
  • Antimony compounds
    Antimonides
    Sb(III)
    Organoantimony(III) compounds
    Sb(III,V)
    Sb(V)
    Organoantimony(V) compounds
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