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Magnesium bicarbonate

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Magnesium bicarbonate
Magnesium bicarbonate
Names
IUPAC name Magnesium hydrogencarbonate
Other names Magnesium bicarbonate
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.016.582 Edit this at Wikidata
EC Number
  • 218-240-1
E number E504(ii) (acidity regulators, ...)
PubChem CID
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/2CH2O3.Mg/c2*2-1(3)4;/h2*(H2,2,3,4);/q;;+2/p-2Key: QWDJLDTYWNBUKE-UHFFFAOYSA-L
SMILES
  • OC(=O)OOC(=O)O
  • .OC()=O.OC()=O
Properties
Chemical formula Mg(HCO3)2
Molar mass 146.34 g/mol
Solubility in water 5.7 g / (100 mL)
Related compounds
Other cations Calcium bicarbonate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkverify (what is  ?) Infobox references
Chemical compound

Magnesium bicarbonate or magnesium hydrogencarbonate, Mg(HCO3)2, is the bicarbonate salt of magnesium. It can be formed through the reaction of dilute solutions of carbonic acid (such as seltzer water) and magnesium hydroxide (milk of magnesia).

It can be prepared through the synthesis of magnesium acetate and sodium bicarbonate:

Mg(CH3COO)2 + 2 NaHCO3 → Mg(HCO3)2 + 2 CH3COONa

Magnesium bicarbonate exists only in aqueous solution. Magnesium does not form solid bicarbonate as does lithium. To produce it, a suspension of magnesium hydroxide is treated with pressurized carbon dioxide, producing a solution of magnesium bicarbonate:

Mg(OH)2 + 2 CO2 → Mg(HCO3)2

Drying the resulting solution causes the magnesium bicarbonate to decompose, yielding magnesium carbonate, carbon dioxide, and water:

Mg + 2 HCO3 → MgCO3 + CO2 + H2O

References

  1. Margarete Seeger; Walter Otto; Wilhelm Flick; Friedrich Bickelhaupt; Otto S. Akkerman. "Magnesium Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a15_595.pub2. ISBN 978-3527306732.
Magnesium compounds
Compounds containing the carbonate group
H2CO3 He
Li2CO3,
LiHCO3
BeCO3 +BO3 (RO)(R'O)CO
+C2O4
(NH4)2CO3,
NH4HCO3,
+NO3
O +F Ne
Na2CO3,
NaHCO3,
Na3H(CO3)2
MgCO3,
Mg(HCO3)2
Al2(CO3)3 SiCO4,
+SiO4
P +SO4 +Cl Ar
K2CO3,
KHCO3
CaCO3,
Ca(HCO3)2
Sc Ti V CrCO3,
Cr2(CO3)3
MnCO3 FeCO3 CoCO3,
Co2(CO3)3
NiCO3 Cu2CO3,
CuCO3, Cu2CO3(OH)2
ZnCO3 Ga Ge As Se Br Kr
Rb2CO3 SrCO3 Y Zr Nb Mo Tc Ru Rh PdCO3 Ag2CO3 CdCO3 In Sn Sb Te I Xe
Cs2CO3,
CsHCO3
BaCO3 * Lu2(CO3)3 Hf Ta W Re Os Ir Pt Au HgCO3 Tl2CO3 PbCO3 (BiO)2CO3 Po(CO3)2 At Rn
Fr RaCO3 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La2(CO3)3 Ce2(CO3)3 Pr2(CO3)3 Nd2(CO3)3 Pm Sm2(CO3)3 EuCO3,
Eu2(CO3)3
Gd2(CO3)3 Tb2(CO3)3 Dy2(CO3)3 Ho2(CO3)3 Er2(CO3)3 Tm2(CO3)3 Yb2(CO3)3
** Ac Th(CO3)2 Pa UO2CO3 Np Pu Am Cm Bk Cf Es Fm Md No
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