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Ytterbium(III) bromate

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Ytterbium(III) bromate
Identifiers
CAS Number
3D model (JSmol)
EC Number
  • anhydrous: 249-344-5
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/3BrHO3.Yb/c3*2-1(3)4;/h3*(H,2,3,4);/q;;;+3/p-3Key: AOIRCHZDHBOTFE-UHFFFAOYSA-K
  • nonahydrate: InChI=1S/3BrHO3.9H2O.Yb/c3*2-1(3)4;;;;;;;;;;/h3*(H,2,3,4);9*1H2;/q;;;;;;;;;;;;+3/p-3Key: WUBFCEQYBPEONT-UHFFFAOYSA-K
SMILES
  • anhydrous: Br(=O)=O.Br(=O)=O.Br(=O)=O.
  • nonahydrate: Br(=O)=O.Br(=O)=O.Br(=O)=O..O.O.O.O.O.O.O.O.O
Properties
Chemical formula Br3O9Yb
Molar mass 556.748 g·mol
Appearance colourless needle crystals (nonahydrate)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Ytterbium(III) bromate is an inorganic compound with the chemical formula Yb(BrO3)3. It can be produced by the reaction of ytterbium(III) sulfate and barium bromate. After filtering out the barium sulfate, the solution is concentrated to crystallize ytterbium(III) bromate nonahydrate. The nonahydrate is thermally decomposed via anhydrate to obtain ytterbium oxybromide.

References

  1. ^ Neogy, D.; Chakrabarti, P. K.; Chattopadhyay, K. N.; Chatterji, A. (Apr 1996). "Magnetic measurements and crystal field investigations on Yb(BrO 3 ) 3 · 9 H 2 O". Physica Status Solidi B. 194 (2): 717–721. Bibcode:1996PSSBR.194..717N. doi:10.1002/pssb.2221940227. ISSN 0370-1972.
  2. ^ Mayer, I.; Glasner, Y. (Jul 1967). "Rare earth bromate hydrates". Journal of Inorganic and Nuclear Chemistry. 29 (7): 1605–1609. doi:10.1016/0022-1902(67)80203-3.

External reading

  • Serebrennikov, V. V.; Batyreva, V. A.; Tsybakova, T. N. Neodymium bromate-ytterbium bromate-water and neodymium selenate-ytterbium selenate-water systems at 25°. Zhurnal Neorganicheskoi Khimii, 1981. 26 (10). 2837–2840. ISSN 0044-457X.
Ytterbium compounds
Yb(II)
Yb(III)
Other
Compounds containing the bromate group
HBrO3 He
Li Be B C N O F Ne
NaBrO3 Mg Al Si P S Cl Ar
KBrO3 Ca(BrO3)2 Sc(BrO3)3 Ti V Cr Mn(BrO3)2 Fe(BrO3)3 Co(BrO3)2 Ni(BrO3)2 Cu(BrO3)2 Zn(BrO3)2 Ga Ge As Se Br2O3
Br2O5 		Kr
RbBrO3 Sr(BrO3)2 Y(BrO3)3 Zr Nb Mo Tc Ru Rh Pd AgBrO3 Cd In Sn Sb Te I Xe
Cs Ba(BrO3)2 * Lu(BrO3)3 Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(BrO3)3 Ce(BrO3)3 Pr(BrO3)3 Nd(BrO3)3 Pm(BrO3)3 Sm(BrO3)3 Eu(BrO3)3 Gd(BrO3)3 Tb(BrO3)3 Dy(BrO3)3 Ho(BrO3)3 Er(BrO3)3 Tm(BrO3)3 Yb(BrO3)3
** Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No
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