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Ytterbium(III) bromide

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Ytterbium(III) bromide
Ytterbium(III) bromide
Names
Other names ytterbium tribromide
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.940 Edit this at Wikidata
EC Number
  • 237-350-0
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/3BrH.Yb/h3*1H;/q;;;+3/p-3Key: QNLXXQBCQYDKHD-UHFFFAOYSA-K
  • InChI=1/3BrH.Yb/h3*1H;/q;;;+3/p-3Key: QNLXXQBCQYDKHD-DFZHHIFOAH
SMILES
  • Br(Br)Br
Properties
Chemical formula YbBr3
Molar mass 412.77 g/mol
Appearance white crystalline
Melting point 677 °C (1,251 °F; 950 K)
Boiling point 1,800 °C (3,270 °F; 2,070 K)
Structure
Crystal structure Trigonal, hR24
Space group R-3, No. 148
Hazards
GHS labelling:
Pictograms GHS07: Exclamation mark
Signal word Warning
Hazard statements H315, H319, H335
Precautionary statements P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P332+P313, P337+P313, P362, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth (blue): no hazard codeFlammability (red): no hazard codeInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). ☒verify (what is  ?) Infobox references
Chemical compound

Ytterbium(III) bromide (YbBr3) is an inorganic chemical compound.

Refer to the adjacent table for the main properties of Ytterbium(III) bromide.

Preparation

Dissolving ytterbium oxide into 40% hydrobromic acid forms YbBr3·6H2O crystals. After mixing the hydrate with ammonium bromide and heating it in a vacuum, anhydrous YbBr3 can be obtained.

Yb2O3 + 6 HBr → 2 YbBr3 + 3 H2O

Ytterbium(III) bromide can also be prepared by directly heating ytterbium oxide and ammonium bromide.

References

  1. ^ Walter Benenson; John W. Harris; Horst Stöcker (2002). Handbook of Physics. Springer. p. 781. ISBN 0-387-95269-1.
  2. 林平娣, 吴国庆. 无水三溴化钐和三溴化镱的制备 Archived November 12, 2017, at the Wayback Machine. 化学试剂, 1991(1):13-14.
  3. Gerd Meyer, Siegfried Dötsch, Thomas Staffel (1987). "The ammonium-bromide route to anhydrous rare earth bromides MBr3". Journal of the Less Common Metals. 127: 155–160. doi:10.1016/0022-5088(87)90372-9. Retrieved 2020-05-29.{{cite journal}}: CS1 maint: multiple names: authors list (link)
Ytterbium compounds
Yb(II)
Yb(III)
Other
Salts and covalent derivatives of the bromide ion
HBr He
LiBr BeBr2 BBr3
+BO3
CBr4
+C
NBr3
BrN3
NH4Br
NOBr
+N
Br2O
BrO2
Br2O3
Br2O5
BrF
BrF3
BrF5
Ne
NaBr MgBr2 AlBr
AlBr3
SiBr4 PBr3
PBr5
PBr7
+P
S2Br2
SBr2
BrCl Ar
KBr CaBr2
ScBr3 TiBr2
TiBr3
TiBr4
VBr2
VBr3
CrBr2
CrBr3
CrBr4
MnBr2 FeBr2
FeBr3
CoBr2 NiBr2
NiBr4
CuBr
CuBr2
ZnBr2 GaBr3 GeBr2
GeBr4
AsBr3
+As
+AsO3
SeBr2
SeBr4
Br2 Kr
RbBr SrBr2 YBr3 ZrBr2
ZrBr3
ZrBr4
NbBr5 MoBr2
MoBr3
MoBr4
TcBr3
TcBr4
RuBr3 RhBr3 PdBr2 AgBr CdBr2 InBr
InBr3
SnBr2
SnBr4
SbBr3
+Sb
-Sb
Te2Br
TeBr4
+Te
IBr
IBr3
XeBr2
CsBr BaBr2 * LuBr3 HfBr4 TaBr5 WBr5
WBr6
ReBr3 OsBr3
OsBr4
IrBr3
IrBr
4
PtBr2
PtBr4
AuBr
AuBr3
Hg2Br2
HgBr2
TlBr PbBr2 BiBr3 PoBr2
PoBr4
AtBr Rn
FrBr RaBr2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaBr3 CeBr3 PrBr3 NdBr2
NdBr3
PmBr3 SmBr2
SmBr3
EuBr2
EuBr3
GdBr3 TbBr3 DyBr3 HoBr3 ErBr3 TmBr2
TmBr3
YbBr2
YbBr3
** AcBr3 ThBr4 PaBr4
PaBr5
UBr4
UBr5
NpBr3
NpBr4
PuBr3 AmBr2
AmBr3
CmBr3 BkBr3 CfBr3 EsBr2
EsBr3
Fm Md No
Lanthanide salts of halides
La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
+4 CeF4 PrF4 NdF4 TbF4 DyF4
+3 LaF3
LaCl3
LaBr3
LaI3
CeF3
CeCl3
CeBr3
CeI3
PrF3
PrCl3
PrBr3
PrI3
NdF3
NdCl3
NdBr3
NdI3
PmF3
PmCl3
PmBr3
PmI3
SmF3
SmCl3
SmBr3
SmI3
EuF3
EuCl3
EuBr3
EuI3
GdF3
GdCl3
GdBr3
GdI3
TbF3
TbCl3
TbBr3
TbI3
DyF3
DyCl3
DyBr3
DyI3
HoF3
HoCl3
HoBr3
HoI3
ErF3
ErCl3
ErBr3
ErI3
TmF3
TmCl3
TmBr3
TmI3
YbF3
YbCl3
YbBr3
YbI3
LuF3
LuCl3
LuBr3
LuI3
+2 LaI2 CeI2 PrI2 NdF2
NdCl2
NdBr2
NdI2
SmF2
SmCl2
SmBr2
SmI2
EuF2
EuCl2
EuBr2
EuI2
GdI2 DyF2
DyCl2
DyBr2
DyI2
TmF2
TmCl2
TmBr2
TmI2
YbF2
YbCl2
YbBr2
YbI2


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