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Iridium tetrabromide

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Iridium tetrabromide
Names
Other names Iridium(IV) bromide, tetrabromoiridium
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.255 Edit this at Wikidata
EC Number
  • 232-180-3
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/4BrH.Ir/h4*1H;/q;;;;+4/p-4Key: IYWTUWKWQJIZPO-UHFFFAOYSA-J
SMILES
  • Br(Br)(Br)Br
Properties
Chemical formula Br4Ir
Molar mass 511.833 g·mol
Appearance black crystalline solid
Solubility in water soluble
Related compounds
Related compounds Osmium tetrabromide
Hazards
GHS labelling:
Signal word Warning
Hazard statements H315, H319, H335
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Iridium tetrabromide is a binary inorganic chemical compound of iridium and bromine with the chemical formula IrBr4. This is a salt of iridium metal and hydrobromic acid.

Synthesis

Synthesis of iridium tetrabromide can be by solution of iridium(IV) oxide in hydrobromic acid:

IrO2 + 4HBr → IrBr4 + 2H2O

Physical properties

Iridium tetrabromide compound forms black crystals, soluble in water and alcohol.

Chemical properties

Iridium tetrabromide reacts with water:

IrBr4 + 4H2O → Ir(OH)4 + 4HBr

Iridium tetrabromide decomposes when heated:

IrBr4 → Ir + 2Br2

References

  1. Roscoe, Henry Enfield; Schorlemmer, Carl (1895). A Treatise on Chemistry. D. Appleton. p. 445. Retrieved 5 May 2023.
  2. "WebElements Periodic Table » Iridium » iridium tetrabromide". webelements.com. Retrieved 5 May 2023.
  3. "Iridium(IV) Bromide". American Elements. Retrieved 5 May 2023.
  4. Comey, Arthur Messinger (1896). A Dictionary of chemical solubilities. Macmillan and Company. p. 192. Retrieved 5 May 2023.
  5. Holloway, Michael D.; Holloway, Emma (15 December 2020). Dictionary of Industrial Terminology. John Wiley & Sons. p. 623. ISBN 978-1-119-36344-6. Retrieved 5 May 2023.
Iridium compounds
Iridium(0)
Iridium(I)
Organoiridium(I)
Iridium(II)
Iridium(III)
Organoiridium(III)
Iridium(IV)
Iridium(V)
Iridium(VI)
Iridium(VII)
Iridium(VIII/IX)
Salts and covalent derivatives of the bromide ion
HBr He
LiBr BeBr2 BBr3
+BO3
CBr4
+C
NBr3
BrN3
NH4Br
NOBr
+N
Br2O
BrO2
Br2O3
Br2O5
BrF
BrF3
BrF5
Ne
NaBr MgBr2 AlBr
AlBr3
SiBr4 PBr3
PBr5
PBr7
+P
S2Br2
SBr2
BrCl Ar
KBr CaBr2
ScBr3 TiBr2
TiBr3
TiBr4
VBr2
VBr3
CrBr2
CrBr3
CrBr4
MnBr2 FeBr2
FeBr3
CoBr2 NiBr2
NiBr4
CuBr
CuBr2
ZnBr2 GaBr3 GeBr2
GeBr4
AsBr3
+As
+AsO3
SeBr2
SeBr4
Br2 Kr
RbBr SrBr2 YBr3 ZrBr2
ZrBr3
ZrBr4
NbBr5 MoBr2
MoBr3
MoBr4
TcBr3
TcBr4
RuBr3 RhBr3 PdBr2 AgBr CdBr2 InBr
InBr3
SnBr2
SnBr4
SbBr3
+Sb
-Sb
Te2Br
TeBr4
+Te
IBr
IBr3
XeBr2
CsBr BaBr2 * LuBr3 HfBr4 TaBr5 WBr5
WBr6
ReBr3 OsBr3
OsBr4
IrBr3
IrBr
4
PtBr2
PtBr4
AuBr
AuBr3
Hg2Br2
HgBr2
TlBr PbBr2 BiBr3 PoBr2
PoBr4
AtBr Rn
FrBr RaBr2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaBr3 CeBr3 PrBr3 NdBr2
NdBr3
PmBr3 SmBr2
SmBr3
EuBr2
EuBr3
GdBr3 TbBr3 DyBr3 HoBr3 ErBr3 TmBr2
TmBr3
YbBr2
YbBr3
** AcBr3 ThBr4 PaBr4
PaBr5
UBr4
UBr5
NpBr3
NpBr4
PuBr3 AmBr2
AmBr3
CmBr3 BkBr3 CfBr3 EsBr2
EsBr3
Fm Md No
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