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Europium(II) bromide

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Europium(II) bromide
Names
IUPAC name Europium(II) bromide
Other names Europium dibromide
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.206.203 Edit this at Wikidata
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/2BrH.Eu/h2*1H;/q;;+2/p-2Key: PJVPGMOCWCUQHP-UHFFFAOYSA-L
SMILES
  • BrBr
Properties
Chemical formula EuBr2
Molar mass 311.77g
Appearance White Crystalline Solid
Structure
Crystal structure SrBr2
Coordination geometry Mixed 8 and 7
Hazards
GHS labelling:
Pictograms GHS07: Exclamation mark
Signal word Warning
Hazard statements H315, H319
Precautionary statements P305+P351+P338P264, P280, P302, P313, P321, P332, P337, P352, P362
Related compounds
Other anions Europium(II) chloride
Europium(II) fluoride
Related compounds Europium(III) bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Europium(II) bromide is a crystalline compound of one europium atom and two bromine atoms. Europium(II) bromide is a white powder at room temperature, and odorless. Europium dibromide is hygroscopic.

Reactions

Europium(II) bromide is known to be involved in three reactions:

2 EuBr3 + Eu → 3 EuBr2 (requires a temperature of 800-900 °C)
2 EuBr3 → 2 EuBr2 + Br2 (requires a temperature of 900-1000 °C)
Eu + HgBr2 → EuBr2 + Hg (requires a temperature of 700-800 °C)

References

  1. ^ "Europium(II) bromide 99.99% trace metals basis | Sigma-Aldrich". www.sigmaaldrich.com. Retrieved 21 December 2016.
  2. Sass, Ronald L.; Brackett, Thomas; Brackett, Elizabeth (December 1963). "The Crystal Structure of Strontium Bromide". The Journal of Physical Chemistry. 67 (12): 2862–2863. doi:10.1021/j100806a516.
  3. "MSDS - 751936". www.sigmaaldrich.com. Retrieved 21 December 2016.
  4. "Yunnan Titan New Materials Technology Co., Ltd". en.allinorganics.com. Retrieved 21 December 2016.
  5. "Europium(II) bromide, White crystalline powder, 99.99% (Metals..." www.fishersci.co.uk. Retrieved 21 December 2016.
  6. "Europium(II) bromide, 99.99% (metals basis) | VWR". us.vwr.com. Retrieved 21 December 2016.
  7. "CharChem. Br2Eu". easychem.org. Retrieved 21 December 2016.
Europium compounds
Europium(II)
Europium(III)
Organoeuropium(III)
  • EuFOD
  • Eu(C5H7O2)3
  • Bromine compounds
    Br(−I)
    Br(−I,I)
    Br(I)
    Br(II)
    Br(I,V)
    Br(III)
    Br(IV)
    Br(V)
    Br(VII)
    Lanthanide salts of halides
    La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
    +4 CeF4 PrF4 NdF4 TbF4 DyF4
    +3 LaF3
    LaCl3
    LaBr3
    LaI3
    CeF3
    CeCl3
    CeBr3
    CeI3
    PrF3
    PrCl3
    PrBr3
    PrI3
    NdF3
    NdCl3
    NdBr3
    NdI3
    PmF3
    PmCl3
    PmBr3
    PmI3
    SmF3
    SmCl3
    SmBr3
    SmI3
    EuF3
    EuCl3
    EuBr3
    EuI3
    GdF3
    GdCl3
    GdBr3
    GdI3
    TbF3
    TbCl3
    TbBr3
    TbI3
    DyF3
    DyCl3
    DyBr3
    DyI3
    HoF3
    HoCl3
    HoBr3
    HoI3
    ErF3
    ErCl3
    ErBr3
    ErI3
    TmF3
    TmCl3
    TmBr3
    TmI3
    YbF3
    YbCl3
    YbBr3
    YbI3
    LuF3
    LuCl3
    LuBr3
    LuI3
    +2 LaI2 CeI2 PrI2 NdF2
    NdCl2
    NdBr2
    NdI2
    SmF2
    SmCl2
    SmBr2
    SmI2
    EuF2
    EuCl2
    EuBr2
    EuI2
    GdI2 DyF2
    DyCl2
    DyBr2
    DyI2
    TmF2
    TmCl2
    TmBr2
    TmI2
    YbF2
    YbCl2
    YbBr2
    YbI2
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