| Names | |
|---|---|
| Other names Bromine fluoride trioxide | |
| Identifiers | |
| CAS Number | |
| 3D model (JSmol) | |
| PubChem CID | |
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SMILES
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| Properties | |
| Chemical formula | BrFO3 |
| Molar mass | 146.899 g·mol |
| Appearance | colorless gas |
| Melting point | −9 °C (16 °F; 264 K) |
| Solubility in water | reacts with water |
| Related compounds | |
| Related compounds | Periodyl fluoride Perchloryl fluoride |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references | |
Perbromyl fluoride is an inorganic compound of bromine, fluorine, and oxygen with the chemical formula BrO3F.
Synthesis
Synthesis if perbromyl fluoride is by the effect of antimony pentafluoride on a solution of potassium perbromate in hydrofluoric acid:
- KBrO4 + 2SbF5 + 3HF → BrO3F + K[SbF6] + H[SbF6]•H2O
Physical properties
Perbromyl fluoride forms a colorless gas that is stable in the absence of moisture.
Chemical properties
Perbromyl fluoride reacts with water:
- BrO3F + H2O → HBrO4 + HF
References
- Johnson, Gerald K.; O'Hare, P. A. G.; Appelman, Evan H. (1972). "Perbromyl fluoride". 11 (4). NIST: 800–802. doi:10.1021/ic50110a028. Retrieved 5 June 2023.
{{cite journal}}: Cite journal requires|journal=(help) - Appleman, Evan H.; Studier, Martin H. (July 1969). "Perbromyl fluoride". Journal of the American Chemical Society. 91 (16): 4561–4562. doi:10.1021/ja01044a049. ISSN 0002-7863. Retrieved 5 June 2023.
- Steudel, Ralf (20 April 2011). Chemistry of the Non-Metals: With an Introduction to Atomic Structure and Chemical Bonding. Walter de Gruyter. p. 265. ISBN 978-3-11-083082-8. Retrieved 5 June 2023.
- U. S. Atomic Energy Commission Division of Plans and Atomic Energy Research: Life and Physical Sciences, Reactor Development, Waste Management. U.S. Government Printing Office. 1970. p. 10. Retrieved 5 June 2023.
| Bromine compounds | |
|---|---|
| Br(−I) | |
| Br(−I,I) | |
| Br(I) | |
| Br(II) | |
| Br(I,V) | |
| Br(III) | |
| Br(IV) | |
| Br(V) | |
| Br(VII) | |