A tellurite fluoride is a mixed anion compound containing tellurite and fluoride ions. They have also been called oxyfluorotellurate(IV) where IV is the oxidation state of tellurium in tellurite.
Comparable compounds are sulfite fluorides or selenite fluorides.
List
| name | formula | ratio
TeO3:F |
mw | crystal system |
space group | unit cell Å | volume | density | optical | comment | references |
|---|---|---|---|---|---|---|---|---|---|---|---|
| Li7(TeO3)3F | P63 | a =11.4178 c =4.8433 | band gap 4.75 eV | ||||||||
| KTe3O6F | 3:1 | rhombohedral | R3 | a=9.486, c=13.774, Z=6 | |||||||
| ScTeO3F | 239.56 | orthorhombic | Pnma | a = 5.7740 b = 22.062 c = 5.500 | 700.6 | colourless | |||||
| titanium(IV) tellurium(IV) trioxide difluoride | TiTeO3F2 | 1:1 | 361.50 | orthorhombic | Pnma | a = 7.392 b = 16.369 c=6.4886 Z=8 | 785.1 | colourless | |||
| divanadium(IV) ditellurium(IV) heptaoxide difluoride | V2Te2O7F2 | 2:2 | 507.38 | triclinic | P1 | a = 4.882 b = 5.112 c = 7.243 α = 108.17° β = 91.64° γ = 92.63° | 171.4 | green-brown | |||
| CrTeO3F | 1:1 | ||||||||||
| FeTeO3F | 1:1 | 250.45 | monoclinic | P21/n | a = 5.0667 b = 5.0550 c = 12.397 β = 97.63° Z=4 | 314.72 | green | ||||
| Co2TeO3F2 | 1:2 | 331.46 | orthorhombic | Pnma | a=7.3810 b=10.1936 c=5.3013 Z=4 | 398.86 | 5.520 | purple | |||
| Co15F2(TeO3)14 | 14:2 | 3380.35 | trigonal | R3 | a =11.6649 c =27.317 Z=3 | 3219.1 | 5.231 | blue | |||
| Cu7(TeO3)6F2 | 6:2 | triclinic | P1 | a =4.9844 b =9.4724 c =9.958, α =82.318° β =76.275° γ =78.847° | |||||||
| GaTeO3F | 1:1 | monoclinic | P21/n | a = 5.0625 b = 4.9873 c = 12.166 β = 97.952 (13)° Z=4 | 304.22 | colourless | |||||
| RbTe3O6F | 3:1 | ||||||||||
| InTeO3F | 1:1 | 309.42 | a = 7.939 b = 5.3867 c = 8.053 β = 91.06° | 344.35 | colourless | ||||||
| InTe2O5F | 2:1 | orthorhombic | Cmmm | a = 7.850, b = 27.637, c = 4.098, Z = 4 | 889.1 | ||||||
| In3TeO3F7 | 1:7 | orthorhombic | Cmmm | a = 7.850(2) A, b = 27.637(6) A, c = 4.098 | |||||||
| In3(SO4)(TeO3)2F3(H2O) | P212121 | a =8.3115 b =9.4341 c =14.807 | band gap 4.10 eV | ||||||||
| BaF2TeF2(OH)2 | Pmn21 | SHG ~3 × KDP | fluorotellurite | ||||||||
| Ba2Ga3F3(Te6F2O16) | a =8.8753 b =8.8753 c =11.655 | band gap 4.4 eV | |||||||||
| Ba(MoOF2)(TeO4) | 1:2 | 478.87 | monoclinic | P21/c | a 5.4281 b 10.1306 c 12.3186 β 116.145° Z=4 | 608.09 | 5.231 | colourless | |||
| Ba(MoO2F)2(TeO3)2 | 2:2 | 782.42 | orthorhombic | Aba2 | a=12.5605 b=11.0264 c=7.2858 Z=4 | 1009.1 | 5.150 | colourless | |||
| Ba(WOF2)(TeO4) | 566.77 | monoclinic | P21/c | a 5.4483 b 10.0179 c 12.3134 β 115.422(6)° Z=4 | 607.00 | 6.202 | green | ||||
| Pb2Al3F3(Te6F2O16) | orthorhombic | P4/mbm | a =8.7627 b =8.7627 c =11.235 | band gap 4.1 eV | |||||||
| PbVTeO5F | 484.73 | orthorhombic | Pbca | a=9.8976 b=8.0685 c=13.070 | 1043.8 | 6.169 | orange;
birefringence 0.142 at 590 nm |
||||
| Pb2Ga3F3(Te6F2O16) | orthorhombic | P4/mbm | a =8.8439 b =8.8439 c =11.580 | band gap 4.2 eV | |||||||
| Bi4TeO4F2(TeO3)2(SeO3)2 | 2:2 | 1670.64 | monoclinic | P21/c | a=7.0304 b=6.6782 c=17.355 β=106.155 Z=2 | 782.66 | 7.089 | colourless |
References
- Laval, J.P.; Guillet, L.; Frit, B. (April 2002). "KTe3O6F: a new layer TeO2 structure, stuffed with KF units". Solid State Sciences. 4 (4): 549–556. Bibcode:2002SSSci...4..549L. doi:10.1016/S1293-2558(02)01290-6.
- ^ Jennene Boukharrata, Nefla; Laval, Jean-Paul; Thomas, Philippe (2008-07-15). "Two new types of oxyfluorotellurates(IV): ScTeO 3 F and InTeO 3 F". Acta Crystallographica Section C Crystal Structure Communications. 64 (7): i57 – i61. Bibcode:2008AcCrC..64I..57J. doi:10.1107/S0108270108017150. ISSN 0108-2701. PMID 18599966.
- ^ Laval, Jean Paul; Jennene Boukharrata, Nefla (2009-01-15). "New vanadium(IV) and titanium(IV) oxyfluorotellurates(IV): V 2 Te 2 O 7 F 2 and TiTeO 3 F 2". Acta Crystallographica Section C Crystal Structure Communications. 65 (1): i1 – i6. Bibcode:2009AcCrC..65I...1L. doi:10.1107/S0108270108036755. ISSN 0108-2701. PMID 19129587.
- ^ Laval, Jean Paul; Jennene Boukharrata, Nefla; Thomas, Philippe (2008-02-15). "New oxyfluorotellurates(IV): M TeO 3 F ( M = Fe III , Ga III and Cr III )". Acta Crystallographica Section C Crystal Structure Communications. 64 (2): i12 – i14. Bibcode:2008AcCrC..64I..12L. doi:10.1107/S0108270107062683. ISSN 0108-2701. PMID 18252985. S2CID 22908353.
- Hu, Shichao; Johnsson, Mats (2012). "Synthesis and crystal structure of two synthetic oxofluoride framework compounds – Co2TeO3F2 and Co2SeO3F2". Dalton Transactions. 41 (41): 12786–12789. doi:10.1039/c2dt31188g. ISSN 1477-9226. PMID 22968840.
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- Hu, Shichao; Mace, Amber; Johnsson, Mats; Gnezdilov, Vladimir; Lemmens, Peter; Tapp, Joshua; Möller, Angela (2014-07-21). "Crystal Structure and Magnetic Properties of the S = 1 / 2 Quantum Spin System Cu 7 (TeO 3 ) 6 F 2 with Mixed Dimensionality". Inorganic Chemistry. 53 (14): 7661–7667. doi:10.1021/ic5009686. ISSN 0020-1669. PMID 24956023.
- ^ Jennene Boukharrata, N.; Laval, J.P. (February 2011). "Synthesis and structure determination of In3TeO3F7: An indium oxyfluorotellurate IV derived from W bronze structure with Te4+ in hexagonal tunnels". Journal of Alloys and Compounds. 509 (5): 1517–1522. doi:10.1016/j.jallcom.2010.10.139.
- Jennene Boukharrata, N.; Laval, J.P. (February 2011). "Synthesis and structure determination of In3TeO3F7: An indium oxyfluorotellurate IV derived from W bronze structure with Te4+ in hexagonal tunnels". Journal of Alloys and Compounds. 509 (5): 1517–1522. doi:10.1016/j.jallcom.2010.10.139.
- Gong, Ya-Ping; Ma, Yun-Xiang; Ying, Shao-Ming; Mao, Jiang-Gao; Kong, Fang (2019-08-19). "Two Indium Sulfate Tellurites: Centrosymmetric In 2 (SO 4 )(TeO 3 )(OH) 2 (H 2 O) and Non-centrosymmetric In 3 (SO 4 )(TeO 3 ) 2 F 3 (H 2 O)". Inorganic Chemistry. 58 (16): 11155–11163. doi:10.1021/acs.inorgchem.9b01730. ISSN 0020-1669. PMID 31365247. S2CID 199054944.
- Zhou, Jinjie; Wu, Hongping; Yu, Hongwei; Jiang, Shutong; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng; Halasyamani, P. Shiv (2020-03-11). "BaF 2 TeF 2 (OH) 2 : A UV Nonlinear Optical Fluorotellurite Material Designed by Band-Gap Engineering". Journal of the American Chemical Society. 142 (10): 4616–4620. doi:10.1021/jacs.0c00702. ISSN 0002-7863. PMID 32096982. S2CID 211525259.
- ^ Li, Peng-Fei; Kong, Fang; Mao, Jiang-Gao (June 2020). "MII2M3IIIF3(Te6F2O16) (MII = Pb, Ba; MIII = Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings". Journal of Solid State Chemistry. 286: 121288. Bibcode:2020JSSCh.28621288L. doi:10.1016/j.jssc.2020.121288. S2CID 213626229.
- ^ Liang, Ming-Li; Ma, Yun-Xiang; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao (2018). "A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron". Dalton Transactions. 47 (5): 1513–1519. doi:10.1039/C7DT04442A. ISSN 1477-9226. PMID 29313546.
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| Salts and covalent derivatives of the tellurite ion | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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