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| {{About|the |
{{About|the chemical element}} | ||
| {{featured article}} | {{featured article}}{{Use dmy dates|date=January 2021}} | ||
| {{Infobox lead}} | |||
| {{Use dmy dates|date=October 2016}} | |||
| '''Lead''' ({{IPAc-en|l|ɛ|d}}) is a ]; it has ] '''Pb''' (from ] {{lang|la|plumbum}}) and ] 82. It is a ] that is ] than most common materials. Lead is ] and ], and also has a relatively low ]. When freshly cut, lead is a shiny gray with a hint of blue. It ]es to a dull gray color when exposed to air. Lead has the highest atomic number of any ] and three of its ]s are endpoints of major nuclear ]s of heavier elements. | |||
| {{infobox lead}} | |||
| Lead is a relatively unreactive ]. Its weak metallic character is illustrated by its ] nature; lead and ]s react with ]s and ], and it tends to form ]s. ] are usually found in the +2 ] rather than the +4 state common with lighter members of the ]. Exceptions are mostly limited to ]. Like the lighter members of the group, lead tends to ]; it can form chains and polyhedral structures. | |||
| '''Lead''' is a ] with symbol '''Pb''' (from the ] ''plumbum'') and ] 82. It is a ] that is ] than most common materials. Lead is ] and ], and has a relatively low ]. When freshly cut, lead is bluish-white; it ]es to a dull gray color when exposed to air. Lead has the highest atomic number of any ] and three of its isotopes each conclude a major ] of heavier elements. | |||
| Since lead is easily extracted from its ]s, prehistoric people in the Near East ]. ] is a principal ore of lead which often bears silver. Interest in silver helped initiate widespread extraction and use of lead in ]. Lead production declined after the ] and did not reach comparable levels until the ]. Lead played a crucial role in the development of the ], as ] could be relatively easily cast from lead alloys.{{sfn|Theodore Low De Vinne|1899|pp=9–36}} In 2014, the annual global production of lead was about ten million tonnes, over half of which was from recycling. Lead's high density, low melting point, ] and relative inertness to ] make it useful. These properties, combined with its relative abundance and low cost, resulted in its extensive use in ], ], ], ], ], ], ]s, ]s, ]s, ]s, ], and ]ing. | |||
| Lead is a relatively unreactive ]. Its weak metallic character is illustrated by its ] nature; lead and ]s react with ]s and ], and it tends to form ]s. ] of lead are usually found in the +2 ] rather than the +4 state common with lighter members of the ]. Exceptions are mostly limited to ]s. Like the lighter members of the group, lead tends to ] with itself; it can form chains, rings and polyhedral structures. | |||
| Lead is a ] that accumulates in soft tissues and bones. It damages the nervous system and interferes with the function of biological ]s, causing ]s ranging from behavioral problems to brain damage, and also affects general health, cardiovascular, and renal systems. Lead's toxicity was first documented by ancient Greek and Roman writers, who noted some of the symptoms of ], but became widely recognized in Europe in the late 19th century AD. | |||
| Lead is easily extracted from its ]s; prehistoric people in Western Asia ]. ], a principal ore of lead, often bears ], interest in which helped initiate widespread extraction and use of lead in ]. Lead production declined after the ] and did not reach comparable levels until the ]. In 2014, annual global production of lead was about ten million tonnes, over half of which was from recycling. Lead's high density, low melting point, ] and relative inertness to ] make it useful. These properties, combined with its relative abundance and low cost, resulted in its extensive use in construction, ], ], ]s and ], weights, ]s, ]s, ]s, ], ], and ]ing. | |||
| In the late 19th century, ] was recognized, and its use has since been phased out of many applications. Lead is a ] that accumulates in soft tissues and bones, damages the ], and causes blood disorders. It is particularly problematic in children, in that permanent brain damage may result, even if blood levels are promptly ]. | |||
| == Physical properties == | == Physical properties == | ||
| === Atomic === | === Atomic === | ||
| A lead ] has 82 ]s, arranged in an ] of []]4f<sup>14</sup>5d<sup>10</sup>6s<sup>2</sup>6p<sup>2</sup>. The sum of lead's first and second ]—the total energy required to remove the two 6p electrons—is close to that of ], lead's upper neighbor in the ]. This is unusual; ionization energies generally fall going down a group, as an element's outer electrons become more distant from the ], and more ] by smaller orbitals. |
A lead ] has 82 ]s, arranged in an ] of []]4f<sup>14</sup>5d<sup>10</sup>6s<sup>2</sup>6p<sup>2</sup>. The sum of lead's first and second ]—the total energy required to remove the two 6p electrons—is close to that of ], lead's upper neighbor in the ]. This is unusual; ionization energies generally fall going down a group, as an element's outer electrons become more distant from the ], and more ] by smaller orbitals. | ||
| The sum of the first four ionization energies of lead exceeds that of tin,{{sfn|Lide|2005|p=10-179}} contrary to what ] would predict. This is explained by ], which become significant in heavier atoms,{{sfn|Pyykkö|1988|pp=563–594}} which contract s and p orbitals such that lead's 6s electrons have larger binding energies than its 5s electrons.{{sfn|Claudio|Godwin|Magyar|2002|pp=1–144}} A consequence is the so-called ]: the 6s electrons of lead become reluctant to participate in bonding, stabilising the +2 ] and making the distance between nearest atoms in ] lead unusually long.{{sfn|Norman|1996|p=36}} | |||
| Lead's lighter carbon group ] form stable or metastable ]s with the tetrahedrally coordinated and ] ] structure. The energy levels of their outer ] and ]s are close enough to allow mixing into four ] sp<sup>3</sup> orbitals. In lead, the inert pair effect increases the separation between its s- and p-orbitals, and the gap cannot be overcome by the energy that would be released by extra bonds following hybridization.{{sfn|Greenwood|Earnshaw|1998|pp=226–27, 374}} Rather than having a diamond cubic structure, lead forms ] in which only the p-electrons are delocalized and shared between the Pb<sup>2+</sup> ions. Lead consequently has a ] structure like the similarly sized ] metals ] and ].{{sfn|Christensen|2002|p=867}}{{efn|The tetrahedral allotrope of tin is called α- or gray tin and is stable only at or below 13.2 °C (55.8 °F). The stable form of tin above this temperature is called β- or white tin and has a distorted face centered cubic (tetragonal) structure which can be derived by compressing the tetrahedra of gray tin along their cubic axes. White tin effectively has a structure intermediate between the regular tetrahedral structure of gray tin, and the regular face centered cubic structure of lead, consistent with the general trend of increasing metallic character going down any representative group.{{sfn|Parthé|1964|p=13}}}}{{efn|A ]line ] allotrope of lead, with pentagonal symmetry, was reported in 2013. The allotrope was obtained by depositing lead atoms on the surface of an ] silver-]-] quasicrystal. Its conductivity was not recorded.{{sfn|Sharma |Nozawa |Smerdon|Nugent|2013}}{{sfn|Sharma|Smerdon|Nugent|Ribeiro|2014|p=174710}}}} | |||
| Lead's lighter carbon group ] form stable or metastable ] with the tetrahedrally coordinated and ] ] structure. The energy levels of their outer ] and ] are close enough to allow mixing into four ] sp<sup>3</sup> orbitals. In lead, the inert pair effect increases the separation between its s- and p-orbitals, and the gap cannot be overcome by the energy that would be released by extra bonds following hybridization.{{sfn|Greenwood|Earnshaw|1998|pp=226–227, 374}} Rather than having a diamond cubic structure, lead forms ] in which only the p-electrons are delocalized and shared between the Pb<sup>2+</sup> ions. Lead consequently has a ] structure{{sfn|Christensen|2002|p=867}} like the similarly sized{{sfn|Slater|1964}} ] metals ] and ].{{sfn|Considine|Considine|2013|pp=501, 2970}}{{efn|The tetrahedral allotrope of tin is called α- or gray tin and is stable only at or below 13.2 °C (55.8 °F). The stable form of tin above this temperature is called β- or white tin and has a distorted face centered cubic (tetragonal) structure which can be derived by compressing the tetrahedra of gray tin along their cubic axes. White tin effectively has a structure intermediate between the regular tetrahedral structure of gray tin, and the regular face centered cubic structure of lead, consistent with the general trend of increasing metallic character going down any representative group.{{sfn|Parthé|1964|p=13}}}}{{efn|A ]line ] allotrope of lead, with pentagonal symmetry, was reported in 2013. The allotrope was obtained by depositing lead atoms on the surface of an ] silver-]-] quasicrystal. Its conductivity was not recorded.{{sfn|Sharma|Nozawa|Smerdon|Nugent|2013}}{{sfn|Sharma|Smerdon|Nugent|Ribeiro|2014|p=174710}}}}{{efn|Diamond cubic structures with lattice parameters around the lattice parameter of silicon exists both in thin lead and tin films, and in massive lead and tin, freshly solidified in vacuum of ~5 x 10<sup>−6</sup> Torr. Experimental evidence for almost identical structures of at least three oxide types is presented, demonstrating that lead and tin behave like silicon not only in the initial stages of crystallization, but also in the initial stages of oxidation.{{sfn|Peneva|Djuneva|Tsukeva|1981}}}} | |||
| === Bulk === | === Bulk === | ||
| Pure lead has a bright |
Pure lead has a bright, shiny gray appearance with a hint of blue.{{sfn|Greenwood|Earnshaw|1998|p=372}} It tarnishes on contact with moist air and takes on a dull appearance, the hue of which depends on the prevailing conditions. Characteristic properties of lead include high ], malleability, ductility, and high resistance to ] due to ].{{sfn|Greenwood|Earnshaw|1998|pp=372–373}} | ||
| ] | ] | ||
| Lead's close-packed face-centered cubic structure and high atomic weight result in a density{{sfn|Thornton|Rautiu |
Lead's close-packed face-centered cubic structure and high atomic weight result in a density{{sfn|Thornton|Rautiu|Brush|2001|p=6}} of 11.34 g/cm<sup>3</sup>, which is greater than that of common metals such as ] (7.87 g/cm<sup>3</sup>), ] (8.93 g/cm<sup>3</sup>), and ] (7.14 g/cm<sup>3</sup>).{{sfn|Lide|2005|pp=12–35, 12–40}} This density is the origin of the idiom ''to go over like a lead balloon''.{{sfn|Brenner|2003|p=396}}{{sfn|Jones|2014|p=42}}{{efn|]: ''to go down like a lead balloon''.}} Some rarer metals are denser: ] and ] are both at 19.3 g/cm<sup>3</sup>, and ]—the densest metal known—has a density of 22.59 g/cm<sup>3</sup>, almost twice that of lead.{{sfn|Lide|2005|pp=4–13, 4–21, 4–33}} | ||
| Lead is a very soft metal with a ] of 1.5; it can be scratched with a fingernail.{{sfn|Vogel|Achilles|2013|p=8}} It is quite malleable and somewhat ductile.{{sfn|Anderson|1869|pp= |
Lead is a very soft metal with a ] of 1.5; it can be scratched with a fingernail.{{sfn|Vogel|Achilles|2013|p=8}} It is quite malleable and somewhat ductile.{{sfn|Anderson|1869|pp=341–343}}{{efn|Malleability describes how easily it deforms under compression, whereas ductility means its ability to stretch.}} The ] of lead—a measure of its ease of compressibility—is 45.8 ]. In comparison, that of ] is 75.2 GPa; copper 137.8 GPa; and ] 160–169 GPa.{{sfn|Gale|Totemeier|2003|pp=15–2–15–3}} Lead's ], at 12–17 MPa, is low (that of aluminium is 6 times higher, copper 10 times, and mild steel 15 times higher); it can be strengthened by adding small amounts of copper or ].{{sfn|Thornton|Rautiu|Brush|2001|p=8}} | ||
| The melting point of lead—at 327.5 °C (621.5 °F){{sfn|Lide|2005|p=12-219<!--do not correct punctuation here, please; it's a hyphen, that's how numeration of pages runs in the source. This is not a range of pages; this is one page.-->}}—is very low compared to most metals.{{sfn|Thornton|Rautiu |
The melting point of lead—at 327.5 °C (621.5 °F){{sfn|Lide|2005|p=12-219<!--do not correct punctuation here, please; it's a hyphen, that's how numeration of pages runs in the source. This is not a range of pages; this is one page.-->}}—is very low compared to most metals.{{sfn|Thornton|Rautiu|Brush|2001|p=6}}{{efn|A (wet) finger can be dipped into molten lead without risk of a burning injury.{{sfn|Willey|1999}}}} Its ] of 1749 °C (3180 °F){{sfn|Lide|2005|p=12-219}} is the lowest among the carbon-group elements. The ] of lead at 20 °C is 192 ]-meters, almost an ] higher than those of other industrial metals (copper at {{val|15.43|u=nΩ·m}}; gold {{val|20.51|u=nΩ·m}}; and aluminium at {{val|24.15|u=nΩ·m}}).{{sfn|Lide|2005|p=12-45}} Lead is a ] at temperatures lower than 7.19 ];{{sfn|Blakemore|1985|p=272}} this is the highest ] of all ]s and the third highest of the elemental superconductors.{{sfn|Webb|Marsiglio|Hirsch|2015}} | ||
| {{Clear}} | |||
| {{infobox lead isotopes}} | |||
| === Isotopes === | === Isotopes === | ||
| {{Main |
{{Main|Isotopes of lead}} | ||
| Natural lead consists of four stable ]s with mass numbers of 204, 206, 207, and 208,{{sfn|IAEA |
Natural lead consists of four stable ]s with mass numbers of 204, 206, 207, and 208,{{sfn|IAEA – Nuclear Data Section|2017}} and traces of six short-lived radioisotopes with mass numbers 209–214 inclusive. The high number of isotopes is consistent with lead's ] being even.{{efn|An even number of either protons or neutrons generally increases the nuclear stability of isotopes, compared to isotopes with odd numbers. No elements with odd atomic numbers have more than two stable isotopes; even-numbered elements have multiple stable isotopes, with tin (element 50) having the highest number of isotopes of all elements, ten.{{sfn|IAEA – Nuclear Data Section|2017}} See ] for more details.}} Lead has a ] of protons (82), for which the ] accurately predicts an especially stable nucleus.{{sfn|Stone|1997}} Lead-208 has 126 neutrons, another magic number, which may explain why lead-208 is extraordinarily stable.{{sfn|Stone|1997}} | ||
| With its high atomic number, lead is the heaviest element whose natural isotopes are regarded as stable; lead-208 is the heaviest stable nucleus. (This distinction formerly fell to bismuth, with an atomic number of 83, until its only ], bismuth-209, was found in 2003 to decay very slowly.){{efn|The half-life found in the experiment was 1.9{{e|19}} years.{{sfn|Marcillac|Coron|Dambier|Leblanc|2003|pp=876–78}} A kilogram of natural bismuth would have an activity value of approximately 0.003 ]s (decays per second). For comparison, the activity value of natural radiation in the human body is around 65 becquerels per kilogram of body weight (4500 becquerels on average).{{sfn|World Nuclear Association|2015}} }} The four stable isotopes of lead could theoretically undergo ] to isotopes of ] with a release of energy, but this has not been observed for any of them; their predicted half-lives range from 10<sup>35</sup> to 10<sup>189</sup> years{{sfn|Beeman|Bellini|Cardani|2013}} (at least 10<sup>25</sup> times the current age of the universe). | With its high atomic number, lead is the heaviest element whose natural isotopes are regarded as stable; lead-208 is the heaviest stable nucleus. (This distinction formerly fell to ], with an atomic number of 83, until its only ], bismuth-209, was found in 2003 to decay very slowly.){{efn|The half-life found in the experiment was 1.9{{e|19}} years.{{sfn|de Marcillac|Coron|Dambier|Leblanc|2003|pp=876–78}} A kilogram of natural bismuth would have an activity value of approximately 0.003 ]s (decays per second). For comparison, the activity value of natural radiation in the human body is around 65 becquerels per kilogram of body weight (4500 becquerels on average).{{sfn|World Nuclear Association|2015}} }} The four stable isotopes of lead could theoretically undergo ] to isotopes of ] with a release of energy, but this has not been observed for any of them; their predicted half-lives range from 10<sup>35</sup> to 10<sup>189</sup> years{{sfn|Beeman|Bellini|Cardani|Casali|2013}} (at least 10<sup>25</sup> times the current age of the universe). | ||
| Three of the stable isotopes are found in three of the four major ]: lead-206, lead-207, and lead-208 are the final decay products of uranium-238, uranium-235, and thorium-232, respectively. These decay chains are called the uranium |
Three of the stable isotopes are found in three of the four major ]s: lead-206, lead-207, and lead-208 are the final decay products of ], ], and ], respectively.{{sfn|Radioactive Decay Series|2012}} These decay chains are called the ], the ], and the ].{{sfn|Committee on Evaluation of EPA Guidelines for Exposure to Naturally Occurring Radioactive Materials|Commission on Life Sciences|Division on Earth and Life Studies|National Research Council|1999}} Their isotopic concentrations in a natural rock sample depends greatly on the presence of these three parent uranium and thorium isotopes. For example, the relative abundance of lead-208 can range from 52% in normal samples to 90% in thorium ores;{{sfn|Smirnov|Borisevich|Sulaberidze|2012}} for this reason, the standard atomic weight of lead is given to only one decimal place.{{sfn|Greenwood|Earnshaw|1998|p=368}} As time passes, the ratio of lead-206 and lead-207 to lead-204 increases, since the former two are supplemented by radioactive decay of heavier elements while the latter is not; this allows for ]. As uranium decays into lead, their relative amounts change; this is the basis for ].{{sfn|Levin|2009|pp=40–41}} Lead-207 exhibits ], a property that has been used to study its compounds in solution and solid state,{{sfn|Webb|2000|p=115}}{{sfn|Wrackmeyer|Horchler|1990}} including in the human body.{{sfn|Cangelosi|Pecoraro|2015}} | ||
| ] meteorite. ] and ] on this meteorite allowed refinement of the ] to 4.55 billion ± |
] meteorite. ] and ] on this meteorite allowed refinement of the ] to 4.55 billion ± 70 million years.|alt=A piece of a gray meteorite on a pedestal]] | ||
| Apart from the stable isotopes, which make up almost all lead that exists naturally, there are ] of a few radioactive isotopes. One of them is lead-210; although it has a half-life of only 22. |
Apart from the stable isotopes, which make up almost all lead that exists naturally, there are ] of a few radioactive isotopes. One of them is lead-210; although it has a half-life of only 22.2 years,{{sfn|IAEA – Nuclear Data Section|2017}} small quantities occur in nature because lead-210 is produced by a long decay series that starts with uranium-238 (that has been present for billions of years on Earth). Lead-211, −212, and −214 are present in the decay chains of uranium-235, thorium-232, and uranium-238, respectively, so traces of all three of these lead isotopes are found naturally. Minute traces of lead-209 arise from the very rare ] of radium-223, one of the ] of natural uranium-235, and the decay chain of neptunium-237, traces of which are produced by ] in uranium ores. Lead-213 also occurs in the decay chain of neptunium-237. Lead-210 is particularly useful for helping to identify the ages of samples by measuring its ratio to lead-206 (both isotopes are present in a single decay chain).{{sfn|Fiorini|2010|pp=7–8}} | ||
| In total, 43 lead isotopes have been synthesized, with mass numbers 178–220.{{sfn|IAEA |
In total, 43 lead isotopes have been synthesized, with mass numbers 178–220.{{sfn|IAEA – Nuclear Data Section|2017}} Lead-205 is the most stable radioisotope, with a half-life of around 1.70{{e|7}} years.{{NUBASE2020|ref}}{{efn|Lead-205 decays solely via ], which means when there are no electrons available and lead is fully ionized with all 82 electrons removed it cannot decay. Fully ionized thallium-205, the isotope lead-205 would decay to, becomes unstable and can decay into a ] of lead-205.{{sfn|Takahashi|Boyd|Mathews|Yokoi|1987}} }} The second-most stable is lead-202, which has a half-life of about 52,500 years, longer than any of the natural trace radioisotopes.{{sfn|IAEA – Nuclear Data Section|2017}} | ||
| {{Clear}} | {{Clear}} | ||
| Line 50: | Line 46: | ||
| == Chemistry == | == Chemistry == | ||
| ]: lead colors flame pale blue|alt=A flame with a small metal rod penetrating it; the flame near the rod is pale blue.]] | ]: lead colors flame pale blue|alt=A flame with a small metal rod penetrating it; the flame near the rod is pale blue.]] | ||
| Bulk lead exposed to moist air forms a protective layer of varying composition. ] is a common constituent;{{sfn|Thürmer|Williams|Reutt-Robey|2002|pp= |
Bulk lead exposed to moist air forms a protective layer of varying composition. ] is a common constituent;{{sfn|Thürmer|Williams|Reutt-Robey|2002|pp=2033–2035}}{{sfn|Tétreault|Sirois|Stamatopoulou|1998|pp=17–32}}{{sfn|Thornton|Rautiu|Brush|2001|pp=10–11}} the ] or ] may also be present in urban or maritime settings.{{sfn|Greenwood|Earnshaw|1998|p=373}} This layer makes bulk lead effectively chemically inert in the air.{{sfn|Greenwood|Earnshaw|1998|p=373}} Finely powdered lead, as with many metals, is ],{{sfn|Bretherick|2016|p=1442}} and burns with a bluish-white flame.{{sfn|Harbison|Bourgeois|Johnson|2015|p=132}} | ||
| ] reacts with lead at room temperature, forming ]. The reaction with ] is similar but requires heating as the resulting chloride layer diminishes the reactivity of the elements.{{sfn|Greenwood|Earnshaw|1998|p=373}} Molten lead reacts with the ]s to give lead(II) chalcogenides.{{sfn|Greenwood|Earnshaw|1998|p=374}} | ] reacts with lead at room temperature, forming ]. The reaction with ] is similar but requires heating, as the resulting chloride layer diminishes the reactivity of the elements.{{sfn|Greenwood|Earnshaw|1998|p=373}} Molten lead reacts with the ]s to give lead(II) chalcogenides.{{sfn|Greenwood|Earnshaw|1998|p=374}} | ||
| Lead metal resists ] and ] but not ] or ]; the outcome depends on insolubility and subsequent passivation of the product salt.{{sfn|Thornton|Rautiu|Brush|2001|pp=11–12}} Organic acids, such as ], dissolve lead in the presence of oxygen.{{sfn|Greenwood|Earnshaw|1998|p=373}} Concentrated ]s |
Lead metal resists ] and ] but not ] or ]; the outcome depends on insolubility and subsequent passivation of the product salt.{{sfn|Thornton|Rautiu|Brush|2001|pp=11–12}} Organic acids, such as ], dissolve lead in the presence of oxygen.{{sfn|Greenwood|Earnshaw|1998|p=373}} Concentrated ]s dissolve lead and form ]s.{{sfn|Polyanskiy|1986|p=20}} | ||
| === Inorganic compounds === | === Inorganic compounds === | ||
| {{see also| |
{{see also|Lead compounds}} | ||
| Lead shows two main oxidation states: +4 and +2. The ] state is common for the carbon group. The divalent state is rare for ] and ], minor for germanium, important (but not prevailing) for tin, and is the more important for lead.{{sfn|Greenwood|Earnshaw|1998|p=373}} This is attributable to ], specifically the ], which manifests itself when there is a large difference in ] between lead and ], ], or ] anions, leading to a significant partial positive charge on lead. The result is a stronger contraction of the lead 6s orbital than is the case for the 6p orbital, making it rather inert in ionic compounds. This is less applicable to compounds in which lead forms covalent bonds with elements of similar electronegativity such as carbon in organolead compounds. In these, the 6s and 6p orbitals remain similarly sized and sp<sup>3</sup> hybridization is still energetically favorable. Lead, like carbon, is predominantly tetravalent in such compounds.{{sfn|Kaupp|2014|pp=9–10}} | |||
| Lead shows two main oxidation states: +4 and +2. The ] state is common for the carbon group. The divalent state is rare for ] and ], minor for germanium, important (but not prevailing) for tin, and is the more important of the two oxidation states for lead.{{sfn|Greenwood|Earnshaw|1998|p=373}} This is attributable to ], specifically the ], which manifests itself when there is a large difference in ] between lead and ], ], or ] anions, leading to a significant partial positive charge on lead. The result is a stronger contraction of the lead 6s orbital than is the case for the 6p orbital, making it rather inert in ionic compounds. The inert pair effect is less applicable to compounds in which lead forms covalent bonds with elements of similar electronegativity, such as carbon in organolead compounds. In these, the 6s and 6p orbitals remain similarly sized and sp<sup>3</sup> hybridization is still energetically favorable. Lead, like carbon, is predominantly tetravalent in such compounds.{{sfn|Kaupp|2014|pp=9–10}} | |||
| There is a relatively large difference in the electronegativity of lead(II) at 1.87 and lead(IV) at 2.33. This difference marks the reversal in the trend of increasing stability of the +4 oxidation state going down carbon group; tin, by comparison, has values of 1.80 in the +2 oxidation state and 1.96 in the +4 state.{{sfn|Dieter|Watson|2009|page=509}} | |||
| There is a relatively large difference in the electronegativity of lead(II) at 1.87 and lead(IV) at 2.33. This difference marks the reversal in the trend of increasing stability of the +4 oxidation state going down the carbon group; tin, by comparison, has values of 1.80 in the +2 oxidation state and 1.96 in the +4 state.{{sfn|Dieter|Watson|2009|p=509}} | |||
| ]|alt=Cream powder]] | |||
| ==== Lead(II) ==== | ==== Lead(II) ==== | ||
| Lead(II) compounds are characteristic of the inorganic chemistry of lead. Even strong ]s like fluorine and chlorine react with lead to give only PbF<sub>2</sub> and PbCl<sub>2</sub>.{{sfn|Greenwood|Earnshaw|1998|p=373}} Lead(II) ions are usually colorless in solution,{{sfn|Hunt|2014|p=215}} and partially hydrolyze to form Pb(OH)<sup>+</sup> and finally Pb<sub>4</sub>(OH)<sub>4</sub> (in which the ] ions act as ]s),{{sfn|King|1995| |
]|alt=Cream powder]]Lead(II) compounds are characteristic of the inorganic chemistry of lead. Even strong ]s like fluorine and chlorine react with lead to give only ] and ].{{sfn|Greenwood|Earnshaw|1998|p=373}} Lead(II) ions are usually colorless in solution,{{sfn|Hunt|2014|p=215}} and partially hydrolyze to form Pb(OH)<sup>+</sup> and finally <sup>4+</sup> (in which the ] ions act as ]s),{{sfn|King|1995|pp=43–63}}{{sfn|Bunker|Casey|2016|p=89}} but are not ]s as tin(II) ions are. ] for identifying the presence of the Pb<sup>2+</sup> ion in water generally rely on the precipitation of lead(II) chloride using dilute hydrochloric acid. As the chloride salt is sparingly soluble in water, in very dilute solutions the precipitation of lead(II) sulfide is instead achieved by bubbling ] through the solution.{{sfn|Whitten|Gailey|David|1996|pp=904–905}} | ||
| Lead monoxide exists in two ] |
] exists in two ], ] α-PbO (red) and ] β-PbO (yellow), the latter being stable only above around 488 °C. Litharge is the most commonly used inorganic compound of lead.{{sfn|Greenwood|Earnshaw|1998|p=384}} There is no lead(II) hydroxide; increasing the pH of solutions of lead(II) salts leads to hydrolysis and condensation.{{sfn|Greenwood|Earnshaw|1998|p=387}} Lead commonly reacts with heavier chalcogens. ] is a ], a ], and an extremely sensitive ]. The other two chalcogenides, ] and ], are likewise photoconducting. They are unusual in that their color becomes lighter going down the group.{{sfn|Greenwood|Earnshaw|1998|p=389}} | ||
| Lead commonly reacts with heavier chalcogens. Lead sulfide is a ], a ], and an extremely sensitive ]. The other two chalcogenides, ] and ], are likewise photoconducting. They are unusual in that their color becomes lighter going down the group.{{sfn|Greenwood|Earnshaw|1998|p=389}} | |||
| ] in a tetragonal ] of ]|alt=Alternating dark gray and red balls connected by dark gray-red cylinders]] | ] in a tetragonal ] of ]|alt=Alternating dark gray and red balls connected by dark gray-red cylinders]] | ||
| Lead dihalides are well-characterized; this includes the diastatide |
Lead dihalides are well-characterized; this includes the diastatide{{sfn|Zuckerman|Hagen|1989|p=426}} and mixed halides, such as PbFCl. The relative insolubility of the latter forms a useful basis for the ] determination of fluorine. The difluoride was the first solid ] compound to be discovered (in 1834, by ]).{{sfn|Funke|2013}} The other dihalides decompose on exposure to ultraviolet or visible light, especially ].{{sfn|Greenwood|Earnshaw|1998|p=382}} Many lead(II) ] are known, such as the cyanide, cyanate, and ].{{sfn|Greenwood|Earnshaw|1998|p=389}}{{sfn|Bharara|Atwood|2006|p=4}} Lead(II) forms an extensive variety of halide ]es, such as <sup>2−</sup>, <sup>4−</sup>, and the <sub>''n''</sub><sup>5''n''−</sup> chain anion.{{sfn|Greenwood|Earnshaw|1998|p=382}} | ||
| ] is insoluble in water, like the sulfates of other heavy divalent ] |
] is insoluble in water, like the sulfates of other heavy divalent ]. ] and ] are very soluble, and this is exploited in the synthesis of other lead compounds.{{sfn|Greenwood|Earnshaw|1998|p=388}} | ||
| ==== Lead(IV) ==== | ==== Lead(IV) ==== | ||
| Few inorganic lead(IV) compounds are known |
Few inorganic lead(IV) compounds are known. They are only formed in highly oxidizing solutions and do not normally exist under standard conditions.{{sfn|Toxicological Profile for Lead|2007|p=277}} Lead(II) oxide gives a mixed oxide on further oxidation, Pb<sub>3</sub>O<sub>4</sub>. It is described as ], or structurally 2PbO·PbO<sub>2</sub>, and is the best-known mixed valence lead compound. ] is a strong oxidizing agent, capable of oxidizing hydrochloric acid to chlorine gas.{{sfn|Downs|Adams|2017|p=1128}} This is because the expected PbCl<sub>4</sub> that would be produced is unstable and spontaneously decomposes to PbCl<sub>2</sub> and Cl<sub>2</sub>.{{sfn|Brescia|2012|p=234}} Analogously to ], lead dioxide is capable of forming ] anions. ]{{sfn|Macintyre|1992|p=3775}} and lead diselenide{{sfn|Silverman|1966|pp=2067–2069}} are only stable at high pressures. ], a yellow crystalline powder, is stable, but less so than the ]. ] (a yellow oil) decomposes at room temperature, lead tetrabromide is less stable still, and the existence of lead tetraiodide is questionable.{{sfn|Greenwood|Earnshaw|1998|p=381}} | ||
| ] anion <sup>4−</sup> from <sub>2</sub>K<sub>2</sub>Pb<sub>9</sub>·(en)<sub>1.5</sub>{{sfn|Yong|Hoffmann|Fässler|2006|pp=4774–78}}|alt=Nine dark gray spheres connected by cylinders of the same color forming a convex shape]] | |||
| ==== Other oxidation states ==== | ==== Other oxidation states ==== | ||
| {{see also|Plumbide}} | {{see also|Plumbide}} | ||
| ] anion <sup>4−</sup> from <sub>2</sub>K<sub>2</sub>Pb<sub>9</sub>·(en)<sub>1.5</sub>{{sfn|Yong|Hoffmann|Fässler|2006|pp=4774–4778}}|alt=Nine dark gray spheres connected by cylinders of the same color forming a convex shape]] | |||
| Some lead compounds exist in formal oxidation states other than +4 or +2. Lead(III) may be obtained, as an intermediate between lead(II) and lead(IV), in larger organolead complexes; this oxidation state is not stable as both the lead(III) ion and the larger complexes containing it are ].{{sfn|Becker|Förster|Franzen|Hartrath|2008|pp=9965–78}}{{sfn|Mosseri|Henglein|Janata|1990|pp=2722–26}}{{sfn|Konu|Chivers|2011|p=391–92}} The same applies for lead(I), which can be found in such species.{{sfn|Hadlington|2017|p=59}} | |||
| Some lead compounds exist in formal oxidation states other than +4 or +2. Lead(III) may be obtained, as an intermediate between lead(II) and lead(IV), in larger organolead complexes; this oxidation state is not stable, as both the lead(III) ion and the larger complexes containing it are ].{{sfn|Becker|Förster|Franzen|Hartrath|2008|pp=9965–9978}}{{sfn|Mosseri|Henglein|Janata|1990|pp=2722–2726}}{{sfn|Konu|Chivers|2011|pp=391–392}} The same applies for lead(I), which can be found in such radical species.{{sfn|Hadlington|2017|p=59}} | |||
| Numerous mixed lead(II,IV) oxides are known. When PbO<sub>2</sub> is heated in air, it becomes Pb<sub>12</sub>O<sub>19</sub> at 293 °C, Pb<sub>12</sub>O<sub>17</sub> at 351 °C, Pb<sub>3</sub>O<sub>4</sub> at 374 °C, and finally PbO at 605 °C. A further ] Pb<sub>2</sub>O<sub>3</sub> can be obtained at high pressure, along with several non-stoichiometric phases. Many of them show defective ] structures in which some oxygen atoms are replaced by vacancies: PbO can be considered as having such a structure, with every alternate layer of oxygen atoms absent.{{sfn|Greenwood|Earnshaw|1998|pp=384–86}} | |||
| Numerous mixed lead(II,IV) oxides are known. When PbO<sub>2</sub> is heated in air, it becomes Pb<sub>12</sub>O<sub>19</sub> at 293 °C, Pb<sub>12</sub>O<sub>17</sub> at 351 °C, Pb<sub>3</sub>O<sub>4</sub> at 374 °C, and finally PbO at 605 °C. A further ], Pb<sub>2</sub>O<sub>3</sub>, can be obtained at high pressure, along with several non-stoichiometric phases. Many of them show defective ] structures in which some oxygen atoms are replaced by vacancies: PbO can be considered as having such a structure, with every alternate layer of oxygen atoms absent.{{sfn|Greenwood|Earnshaw|1998|pp=384–386}} | |||
| Negative oxidation states can occur as ], as either free lead anions, as in Ba<sub>2</sub>Pb, with lead formally being lead(−IV),{{sfn|Röhr|2017}} or in oxygen-sensitive ring-shaped or polyhedral cluster ions such as the ] Pb<sub>5</sub><sup>2−</sup> ion, where two lead atoms are lead(−I) and three are lead(0).{{sfn|Alsfasser|2007|pages=261–63}} In such anions, each atom is at a polyhedral vertex and contributes two electrons to each covalent bond along an edge from their sp<sup>3</sup> hybrid orbitals, the other two being an external ].{{sfn|King|1995|pages=43–63}} They may be made in ] via the reduction of lead by ].{{sfn|Greenwood|Earnshaw|1998|p=393}} | |||
| Negative oxidation states can occur as ], as either free lead anions, as in Ba<sub>2</sub>Pb, with lead formally being <!--to avoid false positives in search for 'being led/lead' typo -->lead(−IV),{{sfn|Röhr|2017}} or in oxygen-sensitive ring-shaped or polyhedral cluster ions such as the ] Pb<sub>5</sub><sup>2−</sup> ion, where two lead atoms are lead(−I) and three are lead(0).{{sfn|Alsfasser|2007|pp=261–263}} In such anions, each atom is at a polyhedral vertex and contributes two electrons to each covalent bond along an edge from their sp<sup>3</sup> hybrid orbitals, the other two being an external ].{{sfn|King|1995|pp=43–63}} They may be made in ] via the reduction of lead by ].{{sfn|Greenwood|Earnshaw|1998|p=393}} | |||
| {{Clear}} | {{Clear}} | ||
| ] molecule:<br> | |||
| {{Color box|#505050}} ]<br> | |||
| {{Color box|#F0F0F0}} ]<br> | |||
| {{Color box|#4B7373}} Lead|alt=A gray-green sphere linked to four black spheres, each, in turn, linked also to three white ones]] | |||
| === Organolead === | === Organolead === | ||
| {{Main |
{{Main|Organolead compound}} | ||
| ] molecule:<br /> | |||
| {{Color box|#505050}} ]<br /> | |||
| {{Color box|#eeeeee}} ]<br /> | |||
| {{Color box|#577179}} Lead|alt=A gray-green sphere linked to four black spheres, each, in turn, linked also to three white ones]] | |||
| Lead can form ], a property it shares with its lighter ] |
Lead can form ], a property it shares with its lighter ] in the carbon group. Its capacity to do so is much less because the Pb–Pb ] is over three and a half times lower than that of the ].{{sfn|Greenwood|Earnshaw|1998|p=374}} With itself, lead can build metal–metal bonds of an order up to three.{{sfn|Stabenow|Saak|Weidenbruch|2003}} With carbon, lead forms organolead compounds similar to, but generally less stable<!--as can be seen below--> than, typical organic compounds{{sfn|Polyanskiy|1986|p=43}} (due to the Pb–C bond being rather weak).{{sfn|King|1995|pp=43–63}} This makes the ] of lead far less wide-ranging than that of tin.{{sfn|Greenwood|Earnshaw|1998|p=404}} Lead predominantly forms organolead(IV) compounds, even when starting with inorganic lead(II) reactants; very few organolead(II) compounds are known. The most well-characterized exceptions are Pb<sub>2</sub> and ].{{sfn|Greenwood|Earnshaw|1998|p=404}} | ||
| The lead analog of the simplest ], ], is ]. Plumbane may be obtained in a reaction between metallic lead and |
The lead analog of the simplest ], ], is ]. Plumbane may be obtained in a reaction between metallic lead and atomic hydrogen.{{sfn|Wiberg|Wiberg|Holleman|2001|p=918}} Two simple derivatives, ] and ], are the best-known ] compounds. These compounds are relatively stable: tetraethyllead only starts to decompose if heated{{sfn|Toxicological Profile for Lead|2007|p=287}} or if exposed to sunlight or ultraviolet light.{{sfn|Polyanskiy|1986|p=44}}{{efn|] is even more thermally stable, decomposing at 270 °C.{{sfn|Greenwood|Earnshaw|1998|p=404}}}} With sodium metal, lead readily forms an equimolar alloy that reacts with ] to form ] compounds such as tetraethyllead.{{sfn|Windholz|1976}} The oxidizing nature of many organolead compounds is usefully exploited: ] is an important laboratory reagent for oxidation in organic synthesis.{{sfn|Zýka|1966|p=569}} Tetraethyllead, once added to automotive gasoline, was produced in larger quantities than any other organometallic compound,{{sfn|Greenwood|Earnshaw|1998|p=404}} and is still widely used in ].<ref>{{cite web|url=https://www.flyingmag.com/when-will-we-see-unleaded-av-gas/|title=When will we see unleaded AvGas?|date=5 August 2019 |access-date=2024-05-26}}</ref> | ||
| Other organolead compounds are less chemically stable.{{sfn|Polyanskiy|1986|p=43}} For many organic compounds, a lead analog does not exist.{{sfn|Wiberg|Wiberg|Holleman|2001|p=918}} | |||
| == Origin and occurrence == | == Origin and occurrence == | ||
| {| class="wikitable" style="float:left; margin-right:15px; margin-down:0; font-size:10pt; line-height:11pt;" | {| class="wikitable" style="float:left; margin-right:15px; margin-down:0; font-size:10pt; line-height:11pt;" | ||
| |+ style="margin-bottom: 5px;" | Solar System abundances{{sfn|Lodders|2003|pp= |
|+ style="margin-bottom: 5px;" | Solar System abundances{{sfn|Lodders|2003|pp=1222–1223}} | ||
| ! style="text-align:center;" | Atomic<br />number | ! style="text-align:center;" | Atomic<br />number | ||
| ! style="width:45%;"| Element | ! style="width:45%;"| Element | ||
| Line 152: | Line 147: | ||
| === In space === | === In space === | ||
| Lead's per-particle abundance in the ] is 0.121 |
Lead's per-particle abundance in the ] is 0.121 ] (parts per billion).{{sfn|Lodders|2003|pp=1222–1223}}{{efn|Abundances in the source are listed relative to silicon rather than in per-particle notation. The sum of all elements per 10<sup>6</sup> parts of silicon is 2.6682{{e|10}} parts; lead comprises 3.258 parts.}} This figure is two and a half times higher than that of ], eight times more than ], and seventeen times more than ].{{sfn|Lodders|2003|pp=1222–1223}} The amount of lead in the ] is slowly increasing{{sfn|Roederer|Kratz|Frebel|Christlieb|2009|pp=1963–1980}} as most heavier atoms (all of which are unstable) gradually decay to lead.{{sfn|Lochner|Rohrbach|Cochrane|2005|p=12}} The abundance of lead in the Solar System since its formation 4.5 billion years ago has increased by about 0.75%.{{sfn|Lodders|2003|p=1224}} The solar system abundances table shows that lead, despite its relatively high atomic number, is more prevalent than most other elements with atomic numbers greater than 40.{{sfn|Lodders|2003|pp=1222–1223}} | ||
| Primordial lead—which comprises the isotopes lead-204, lead-206, lead-207, and lead-208—was mostly created as a result of repetitive neutron capture processes occurring in stars. The two main modes of capture are the ] and ]es.{{sfn|Burbidge|Burbidge|Fowler|Hoyle|1957|pp=608–615}} | Primordial lead—which comprises the isotopes lead-204, lead-206, lead-207, and lead-208—was mostly created as a result of repetitive neutron capture processes occurring in stars. The two main modes of capture are the ] and ]es.{{sfn|Burbidge|Burbidge|Fowler|Hoyle|1957|pp=608–615}} | ||
| In the s-process (s is for "slow"), captures are separated by years or decades, allowing less stable nuclei to undergo ]. A stable thallium-203 nucleus can capture a neutron and become thallium-204; this undergoes beta decay to give stable lead-204; on capturing another neutron, it becomes lead-205, which has a half-life of around |
In the s-process (s is for "slow"), captures are separated by years or decades, allowing less stable nuclei to undergo ].{{sfn|Burbidge|Burbidge|Fowler|Hoyle|1957|p=551}} A stable thallium-203 nucleus can capture a neutron and become thallium-204; this undergoes beta decay to give stable lead-204; on capturing another neutron, it becomes lead-205, which has a half-life of around 17 million years. Further captures result in lead-206, lead-207, and lead-208. On capturing another neutron, lead-208 becomes lead-209, which quickly decays into bismuth-209. On capturing another neutron, bismuth-209 becomes bismuth-210, and this beta decays to polonium-210, which alpha decays to lead-206. The cycle hence ends at lead-206, lead-207, lead-208, and bismuth-209.{{sfn|Burbidge|Burbidge|Fowler|Hoyle|1957|pp=608–609}} | ||
| ], from ] to ]. Red lines and circles represent ]s; blue arrows represent ]s; the green arrow represents an ]; cyan arrows represent ]s.|alt=Uppermost part of the nuclide chart, with only practically stable isotopes and lead-205 shown, and the path of the s-process overlaid on it as well that of the cycle on lead, bismuth, and polonium]] | ], from ] to ]. Red lines and circles represent ]s; blue arrows represent ]s; the green arrow represents an ]; cyan arrows represent ]s.|alt=Uppermost part of the nuclide chart, with only practically stable isotopes and lead-205 shown, and the path of the s-process overlaid on it as well that of the cycle on lead, bismuth, and polonium]] | ||
| In the r-process (r is for "rapid"), captures happen faster than nuclei can decay. This occurs in environments with a high neutron density, such as a ] or the merger of two ]s. The neutron flux involved may be on the order of 10<sup>22</sup> neutrons per square centimeter per second.{{sfn|Frebel|2015| |
In the r-process (r is for "rapid"), captures happen faster than nuclei can decay.{{sfn|Burbidge|Burbidge|Fowler|Hoyle|1957|p=553}} This occurs in environments with a high neutron density, such as a ] or the merger of two ]s. The neutron flux involved may be on the order of 10<sup>22</sup> neutrons per square centimeter per second.{{sfn|Frebel|2015|pp=114–115}} The r-process does not form as much lead as the s-process.{{sfn|Burbidge|Burbidge|Fowler|Hoyle|1957|pp=608–610}} It tends to stop once neutron-rich nuclei reach 126 neutrons.{{sfn|Burbidge|Burbidge|Fowler|Hoyle|1957|p=595}} At this point, the neutrons are arranged in complete shells in the atomic nucleus, and it becomes harder to energetically accommodate more of them.{{sfn|Burbidge|Burbidge|Fowler|Hoyle|1957|p=596}} When the neutron flux subsides, these nuclei beta decay into stable isotopes of ], ], ].{{sfn|Burbidge|Burbidge|Fowler|Hoyle|1957|pp=582, 609–615}} | ||
| === On Earth === | === On Earth === | ||
| Lead is classified as a ] under the ], meaning it is generally found combined with sulfur.{{sfn|Langmuir|Broecker|2012|pp=183–184}} It rarely occurs in its ], metallic form.{{sfn|Davidson|Ryman|Sutherland|Milner|2014|pp=4–5}} Many lead minerals are relatively light and, over the course of the Earth's history, have remained in the ] instead of sinking deeper into the Earth's interior. This accounts for lead's relatively high ] of 14 |
Lead is classified as a ] under the ], meaning it is generally found combined with sulfur.{{sfn|Langmuir|Broecker|2012|pp=183–184}} It rarely occurs in its ], metallic form.{{sfn|Davidson|Ryman|Sutherland|Milner|2014|pp=4–5}} Many lead minerals are relatively light and, over the course of the Earth's history, have remained in the ] instead of sinking deeper into the Earth's interior. This accounts for lead's relatively high ] of 14 ppm; it is the 36th most ] element in the crust.{{sfn|Emsley|2011|pp=286, passim}}{{efn|Elemental abundance figures are estimates and their details may vary from source to source.{{sfn|Cox|1997|p=182}}}} | ||
| The main lead-bearing mineral is ] (PbS), which is mostly found with zinc ores.{{sfn|Davidson|Ryman|Sutherland|Milner|2014|p=4}} Most other lead minerals are related to galena in some way; ], Pb<sub>5</sub>Sb<sub>4</sub>S<sub>11</sub>, is a mixed sulfide derived from galena; ], PbSO<sub>4</sub>, is a product of galena oxidation; and ] or white lead ore, PbCO<sub>3</sub>, is a decomposition product of galena. ], tin, antimony, ], gold, copper, |
The main lead-bearing mineral is ] (PbS), which is mostly found with zinc ores.{{sfn|Davidson|Ryman|Sutherland|Milner|2014|p=4}} Most other lead minerals are related to galena in some way; ], Pb<sub>5</sub>Sb<sub>4</sub>S<sub>11</sub>, is a mixed sulfide derived from galena; ], PbSO<sub>4</sub>, is a product of galena oxidation; and ] or white lead ore, PbCO<sub>3</sub>, is a ] product of galena. ], ], ], ], ], ], ] are common impurities in lead minerals.{{sfn|Davidson|Ryman|Sutherland|Milner|2014|p=4}} | ||
| ] for its high atomic number (82). Most elements of atomic number greater than 40 are less abundant.|alt=A line chart generally declining towards its right]] | ] for its high atomic number (82). Most elements of atomic number greater than 40 are less abundant.|alt=A line chart generally declining towards its right]] | ||
| World lead resources exceed |
World lead resources exceed two billion tons. Significant deposits are located in Australia, China, Ireland, Mexico, Peru, Portugal, Russia, United States. Global reserves—resources that are economically feasible to extract—totaled 88 million tons in 2016, of which ] had 35 million, China 17 million, Russia 6.4 million.{{sfn|United States Geological Survey|2017|p=97}} | ||
| Typical background concentrations of lead do not exceed 0.1 μg/m<sup>3</sup> in the atmosphere; 100 mg/kg in soil; |
Typical background concentrations of lead do not exceed 0.1 μg/m<sup>3</sup> in the atmosphere; 100 mg/kg in soil; 4 mg/kg in vegetation, 5 μg/L in fresh water and seawater.{{sfn|Rieuwerts|2015|p=225}} | ||
| == Etymology == | == Etymology == | ||
| The modern English word |
The modern English word ''lead'' is of Germanic origin; it comes from the ] {{lang|enm|leed}} and ] {{lang|ang|lēad}} (with the ] above the "e" signifying that the vowel sound of that letter is long).{{sfn|Merriam-Webster}} The Old English word is derived from the hypothetical reconstructed ] {{lang|mis|*lauda-}} ('lead').{{sfn|Kroonen|2013|loc=*lauda-}} According to linguistic theory, this word bore descendants in multiple Germanic languages of exactly the same meaning.{{sfn|Kroonen|2013|loc=*lauda-}} | ||
| There is no consensus on the origin of the Proto-Germanic {{lang|mis|*lauda-}}. One hypothesis suggests it is derived from ] {{lang|mis|*lAudh-}} ('lead'; capitalization of the vowel is equivalent to the macron).{{sfn|Nikolayev|2012}}<!--this is a worthy ref, based on a very respected dictionary; the database itself has been mentioned in Proto-IE-related works--> Another hypothesis suggests it is borrowed from ] {{lang|mis|*ɸloud-io-}} ('lead'). This word is related to the ] {{lang|la|plumbum}}, which gave the element its ] ''Pb''. The word {{lang|mis|*ɸloud-io-}}<!-- Proto-Celtic --> is thought to be the origin of Proto-Germanic {{lang|mis|*bliwa-}} (which also means 'lead'), from which stemmed the German {{lang|de|Blei}}.{{sfn|Kroonen|2013|loc=*bliwa- 2}} | |||
| The name of the chemical element is not related to the verb of the same spelling, which is derived from Proto-Germanic |
The name of the chemical element is not related to the verb of the same spelling, which is derived from Proto-Germanic {{lang|mis|*laidijan-}} ('to lead').{{sfn|Kroonen|2013|loc=*laidijan-}} | ||
| {{Clear}} | {{Clear}} | ||
| == History == | == History == | ||
| ] period and the ].{{sfn|Hong|Candelone|Patterson|Boutron|1994|pp=1841–43}}|alt=A line chart generally growing to its right]] | |||
| === Prehistory and early history === | === Prehistory and early history === | ||
| Metallic lead beads ] have been found in ] and may represent the first example of metal ].{{sfn|Rich|1994|p=4}} At that time lead had few (if any) applications due to its softness and dull appearance.{{sfn|Rich|1994|p=4}} The major reason for the spread of lead production was its association with silver, which may be obtained by burning galena (a common lead mineral).{{sfn|Winder|1993b}} The ]ians were the first to use lead minerals in cosmetics, an application that spread to ] and beyond;{{sfn|History of Cosmetics}} the Egyptians |
] period and the ]{{sfn|Hong|Candelone|Patterson|Boutron|1994|pp=1841–1843}}|alt=A line chart generally growing to its right]]Metallic lead beads ] have been found in ] and may represent the first example of metal ].{{sfn|Rich|1994|p=4}} At that time, lead had few (if any) applications due to its softness and dull appearance.{{sfn|Rich|1994|p=4}} The major reason for the spread of lead production was its association with silver, which may be obtained by burning galena (a common lead mineral).{{sfn|Winder|1993b}} The ]ians were the first to use lead minerals in cosmetics, an application that spread to ] and beyond;{{sfn|History of Cosmetics}} the Egyptians had used lead for sinkers in ], ], ], ], ].{{sfn|Winder|1993b}} Various civilizations of the ] used lead as a ], as ]s,{{sfn|Chapurukha Kusimba|2017}} and as a ].{{sfn|Winder|1993b}} Lead was used by the ancient Chinese as a ],{{sfn|Winder|1993b}} as ],{{sfn|Yu|Yu|2004|p=26}} as ],{{sfn|Toronto museum explores|2003}} and in ].{{sfn|Neiburger|2018}} The ] and the ]ns used it for making ];{{sfn|Winder|1993b}} and the eastern and southern Africans used lead in ].{{sfn|Bisson|Vogel|2000|p=105}} | ||
| === Classical era === | === Classical era === | ||
| Because silver was extensively used as a decorative material and an exchange medium, lead deposits came to be worked in Asia Minor |
Because silver was extensively used as a decorative material and an exchange medium, lead deposits came to be worked in Asia Minor from 3000 BC; later, lead deposits were developed in the ] and ].{{sfn|Wood|Hsu|Bell|2021}} These three regions collectively dominated production of mined lead until {{Circa|1200 BC}}.{{sfn|Rich|1994|p=5}} Beginning c. 2000 BC, the ]ns worked deposits in the ]; by 1600 BC, lead mining existed in ], ], and ].{{sfn|United States Geological Survey|1973}} | ||
| ] | ] | ||
| ] territorial expansion in Europe and across the Mediterranean, and its development of mining, led to it becoming the greatest producer of lead during the ], with an estimated annual output peaking at 80,000 tonnes. Like their predecessors, the Romans obtained lead mostly as a by-product of silver smelting.{{sfn|Hong|Candelone|Patterson|Boutron|1994|pp= |
] territorial expansion in Europe and across the Mediterranean, and its development of mining, led to it becoming the greatest producer of lead during the ], with an estimated annual output peaking at 80,000 tonnes. Like their predecessors, the Romans obtained lead mostly as a by-product of silver smelting.{{sfn|Hong|Candelone|Patterson|Boutron|1994|pp=1841–1843}}{{sfn|de Callataÿ|2005|pp=361–372}} Lead mining occurred in ], ], ], ], ], ], the latter accounting for 40% of world production.{{sfn|Hong|Candelone|Patterson|Boutron|1994|pp=1841–1843}} | ||
| ], Italy, bears an Etruscan inscription from mid-5th century BC.|alt=A vaguely round plate illuminated from a side to increase the contrast. The characters curl around the contour.]] | |||
| Lead tablets were commonly used as a material for letters.{{sfn|Ceccarelli|2013|p=35}} Lead coffins, cast in flat sand forms and with interchangeable motifs to suit the faith of the deceased, were used in ancient ].{{sfn|Ossuaries and Sarcophagi}} Lead was used to make sling bullets from the 5th century BC. In Roman times, lead sling bullets were amply used, and were effective at a distance of between 100 and 150 meters. The ], used as mercenaries in Carthaginian and Roman armies, were famous for their shooting distance and accuracy.{{sfn|Calvo Rebollar|2019|p=45}} | |||
| ] reads: "Made when the Emperor ] was consul for the ninth term and the Emperor Titus was consul for the seventh term, when ] was imperial governor (of Britain)."}}|alt=Ancient pipes in a museum case]] | |||
| Lead tablets were commonly used as a material for letters.<ref>https://books.google.co.il/books?id=Vm5BAQAAQBAJ&pg=PA35#v=onepage&q&f=false</ref> | |||
| Lead was used for making |
Lead was used for making water pipes in the ]; the ] word for the metal, {{lang|la|plumbum}}, is the origin of the English word "]". Its ease of working, its low melting point enabling the easy fabrication of completely waterproof welded joints, and its resistance to corrosion{{sfn|Rich|1994|p=6}} ensured its widespread use in other applications, including pharmaceuticals, roofing, currency, warfare.{{sfn|Thornton|Rautiu|Brush|2001|pp=179–184}}{{sfn|Bisel|Bisel|2002|pp=459–460}}{{sfn|Retief|Cilliers|2006|pp=149–151}} Writers of the time, such as ], ], and ], recommended lead (and lead-coated) vessels for the preparation of ] added to wine and food. The lead conferred an agreeable taste due to the formation of "sugar of lead" (]), whereas ] vessels imparted a bitter flavor through ] formation.{{sfn|Grout|2017}}<!--Grout's work, the Encyclopaedia Romana, is cited by other reliable sources e.g. Davies ME & Swain H 2010, Aspects of Roman history 82 BC--AD 14: A source-based approach, Routledge, p. 388; Bakken C 2013, Honey, olives, octopus: Adventures at the Greek table, University of California, p. 61; Tschen-Emmons JB 2015, Artefacts from ancient Rome, Greenwood, p. 302--> | ||
| {{Quote box | {{Quote box | ||
| |quote = This metal was by far the most used material in classical antiquity, and it is appropriate to refer to the (Roman) Lead Age. Lead was to the Romans what plastic is to us. | |quote = This metal was by far the most used material in classical antiquity, and it is appropriate to refer to the (Roman) Lead Age. Lead was to the Romans what plastic is to us. | ||
| |salign=right| source = Heinz Eschnauer and Markus Stoeppler<br>"Wine—An enological specimen bank", 1992{{sfn|Eschnauer|Stoeppler|1992| |
|salign=right| source = Heinz Eschnauer and Markus Stoeppler<br />"Wine—An enological specimen bank", 1992{{sfn|Eschnauer|Stoeppler|1992|p=58}} | ||
| |bgcolor = Cornsilk | |bgcolor = Cornsilk | ||
| |quoted = 1 | |quoted = 1 | ||
| Line 206: | Line 201: | ||
| }} | }} | ||
| The Roman author ] reported the health dangers of lead{{sfn|Hodge|1981|pp= |
The Roman author ] reported the health dangers of lead{{sfn|Hodge|1981|pp=486–491}}<ref>{{cite book |last1= Marcus Vitruvius Pollio |title={{transliteration|la|]}}|date=1914 |orig-date=c. 15 BC| series=Book 8, 10–11 ]|author1-link=Marcus Vitruvius Pollio }}</ref> and modern writers have suggested that lead poisoning played a major role in the ].{{sfn|Gilfillan|1965|pp=53–60}}{{sfn|Nriagu|1983|pp=660–663}}{{efn|The fact that ] fathered only one child, as well as the alleged sterility of his successor, ], have been attributed to lead poisoning.{{sfn|Frankenburg|2014|p=16}}}} Other researchers have criticized such claims, pointing out, for instance, that not all ] is caused by lead poisoning.{{sfn|Scarborough|1984}}{{sfn|Waldron|1985|pp=107–108}} According to archaeological research, Roman ] increased lead levels in tap water but such an effect was "unlikely to have been truly harmful".{{sfn|Reddy|Braun|2010|p=1052}}{{sfn|Delile|Blichert-Toft|Goiran|Keay|2014|pp=6594–6599}} When lead poisoning did occur, victims were called "saturnine", dark and cynical, after the ghoulish father of the gods, ]. By association, lead was considered the father of all metals.{{sfn|Finger|2006|p=184}} Its status in Roman society was low as it was readily available{{sfn|Lewis|1985|p=15}} and cheap.{{sfn|Thornton|Rautiu|Brush|2001|p=183}} | ||
| {{Clear}} | |||
| ] reads: "Made when the Emperor ] was consul for the ninth term and the Emperor Titus was consul for the seventh term, when ] was imperial governor (of Britain)."}}|alt=Ancient pipes in a museum case]] | |||
| ==== Confusion with tin and antimony ==== | ==== Confusion with tin and antimony ==== | ||
| Since the ], metallurgists and engineers have understood the difference between rare and valuable ], essential for alloying with copper to produce tough and corrosion resistant ], and 'cheap and cheerful' lead. However, the nomenclature in some languages is similar. Romans called lead {{lang|la|plumbum nigrum}} ("black lead"), and tin {{lang|la|plumbum candidum}} ("bright lead"). The association of lead and tin can be seen in other languages: the word {{lang|cs|olovo}} in ] translates to "lead", but in Russian, its ] {{lang|ru|олово}} ({{lang|ru-Latn|olovo}}) means "tin".{{sfn|Polyanskiy|1986|p=8}} To add to the confusion, lead bore a close relation to antimony: both elements commonly occur as sulfides (galena and ]), often together. Pliny incorrectly wrote that stibnite would give lead on heating, instead of antimony.{{sfn|Thomson|1830|p=74}} In countries such as Turkey and India, the originally Persian name {{lang|fa-Latn|surma}} came to refer to either antimony sulfide or lead sulfide,{{sfn|Oxford English Dictionary|loc=surma}} and in some languages, such as Russian, gave its name to antimony ({{lang|ru|сурьма}}).{{sfn|Vasmer|1986–1987|loc=сурьма}} | |||
| During the classical era (and even up to the 17th century), tin was often not distinguished from lead: Romans called lead ''plumbum nigrum'' ("black lead"), and tin ''plumbum candidum'' ("bright lead"). The association of lead and tin can be seen in other languages: the word ''olovo'' in ] translates to "lead", but in ] the ] ''олово'' (''olovo'') means "tin".{{sfn|Polyanskiy|1986|p=8}} To add to the confusion, lead bore a close relation to antimony: both elements commonly occur as sulfides (galena and ]), often together. Pliny incorrectly wrote that stibnite would give lead on heating, instead of antimony.{{sfn|Thomson|1830|page=74}} In countries such as Turkey and India, the originally Persian name ''surma'' came to refer to either antimony sulfide or lead sulfide,{{sfn|Oxford English Dictionary|loc=surma}} and in some languages, such as Russian, gave its name to antimony ''(сурьма).''{{sfn|Vasmer|1950|loc=сурьма}} | |||
| === Middle Ages and the Renaissance === | === Middle Ages and the Renaissance === | ||
| ] was commonly depicted with a whitened face. Lead in face whiteners is thought to have contributed to her death.{{sfn|Kellett|2012|pp=106–107}}|alt=A white-faced woman in red clothes]] | |||
| Lead mining in Western Europe declined after the fall of the ], with ] being the only region having a significant output.{{sfn|Winder|1993a}}{{sfn|Rich|1994|p=7}} The largest production of lead occurred in South and East Asia, especially China and India, where lead mining grew |
Lead mining in Western Europe declined after the fall of the ], with ] being the only region having a significant output.{{sfn|Winder|1993a}}{{sfn|Rich|1994|p=7}} The largest production of lead occurred in South Asia and East Asia, especially China and India, where lead mining grew rapidly.{{sfn|Rich|1994|p=7}} | ||
| In Europe, lead production began to increase in the 11th and 12th centuries, when it was again used for roofing and piping. Starting in the 13th century, lead was used to create ].{{sfn|Rich|1994|p=8}} In the ] and ] traditions of ], lead (symbol ♄ in the European tradition){{sfn|Ede|Cormack|2016|p=54}} was considered an impure ] which, by the separation, purification and balancing of its constituent essences, could be transformed to pure and incorruptible gold.{{sfn|Cotnoir|2006|p=35}} During the period, lead was used increasingly for ] wine. The use of such wine was forbidden for use in Christian rites by a ] in 1498, but it continued to be imbibed and resulted in mass poisonings up to the late 18th century.{{sfn|Winder|1993a}}{{sfn|Samson|1885|p=388}} Lead was a key material in parts of the ], and lead dust was commonly inhaled by print workers, causing lead poisoning.{{sfn|Sinha|Shelly|Sharma|Meenakshi|1993}} Lead also became the chief material for making bullets for firearms: it was cheap, less damaging to iron gun barrels, had a higher density (which allowed for better retention of velocity), and its lower melting point made the production of bullets easier as they could be made using a wood fire.{{sfn|Ramage|1980|p=8}} Lead, in the form of ], was extensively used in cosmetics by Western European aristocracy as whitened faces were regarded as a sign of modesty.{{sfn|Tungate|2011|p=14}}{{sfn|Donnelly|2014|pp=171–172}} This practice later expanded to white wigs and eyeliners, and only faded out with the ] in the late 18th century. A similar fashion appeared in Japan in the 18th century with the emergence of the ]s, a practice that continued long into the 20th century. The white faces of women "came to represent their feminine virtue as Japanese women",{{sfn|Ashikari|2003|p=65}} with lead commonly used in the whitener.{{sfn|Nakashima|Hayashi|Tashiro|Matsushita|1998|p=59}} | |||
| ] was commonly depicted with a whitened face. Lead in face whiteners is thought to have contributed to her death.{{sfn|Kellett|2012|pages=106–07}}|alt=A white-faced woman in red clothes]] | |||
| In Europe, lead production only began to revive in the 11th and 12th centuries, when it was again used for roofing and piping. Starting in the 13th century, lead was used to create ].{{sfn|Rich|1994|p=8}} In the ] and ] traditions of ], lead (symbol ] in the European tradition){{sfn|Ede|Cormack|2016|p=54}} was considered an impure ] which, by the separation, purification and balancing of its constituent essences, could be transformed to pure and incorruptible gold.{{sfn|Cotnoir|2006|page=35}} During the period, lead was used increasingly for ] wine. The use of such wine was forbidden for use in Christian rites by a ] in 1498, but it continued to be imbibed and resulted in mass poisonings up to the late 18th century.{{sfn|Winder|1993a}}{{sfn|Samson|1885|page=388}} Lead was a key material in parts of the ], which was invented around 1440; lead dust was commonly inhaled by print workers, causing lead poisoning.{{sfn|Sinha|Shelly|Sharma|Meenakshi|1993}} Firearms were invented at around the same time, and lead, despite being more expensive than iron, became the chief material for making bullets. It was less damaging to iron gun barrels, had a higher density (which allowed for better retention of velocity), and its lower melting point made the production of bullets easier as they could be made using a wood fire.{{sfn|Ramage|1980|page=8}} Lead, in the form of ], was extensively used in cosmetics by Western European aristocracy as whitened faces were regarded as a sign of modesty.{{sfn|Tungate|2011|p=14}}{{sfn|Donnelly|2014|pp=171–172}} This practice later expanded to white wigs and eyeliners, and only faded out with the ] in the late 18th century. A similar fashion appeared in Japan in the 18th century with the emergence of the ]s, a practice that continued long into the 20th century. The white faces of women "came to represent their feminine virtue as Japanese women",{{sfn|Ashikari|2003|p=65}} with lead commonly used in the whitener.{{sfn|Nakashima|Hayashi|Tashiro|Matsushita|1998|p=59}} | |||
| === Outside Europe and Asia === | === Outside Europe and Asia === | ||
| In the ], lead production was recorded soon after the arrival of European settlers. The earliest record dates to 1621 in the English ], fourteen years after its foundation.{{sfn|Rabinowitz|1995|p=66}} In Australia, the first mine opened by colonists on the continent was a lead mine, in 1841.{{sfn|Gill|Libraries Board of South Australia|1974|p=69}} In Africa, lead mining and smelting were known in the ]{{sfn|Bisson|Vogel|2000|p=85}} and the lower ], where lead was used for trade with Europeans, and as a currency by the 17th century,{{sfn|Bisson|Vogel|2000|pp=131–132}} well before the ]. | |||
| === Industrial Revolution === | |||
| In the ], lead was produced soon after the arrival of European settlers. The earliest recorded lead production dates to 1621 in the English ], fourteen years after its foundation.{{sfn|Rabinowitz|1995|page=66}} In Australia, the first mine opened by colonists on the continent was a lead mine, in 1841.{{sfn|Gill|Libraries Board of South Australia|1974|p=69}} In Africa, lead mining and smelting were known in the ]{{sfn|Bisson|Vogel|2000|p=85}} and the lower ], where lead was used for trade with Europeans, and as a currency by the 17th century,{{sfn|Bisson|Vogel|2000|pp=131–32}} well before the ]. | |||
| {{Clear}} | |||
| ] region in the United States in 1865|alt=A black-and-white drawing of men working in a mine]] | ] region in the United States in 1865|alt=A black-and-white drawing of men working in a mine]] | ||
| In the second half of the 18th century, Britain, and later continental Europe and the United States, experienced the ]. This was the first time during which lead production rates exceeded those of Rome.{{sfn|Hong|Candelone|Patterson|Boutron|1994|pp=1841–43}} Britain was the leading producer, losing this status by the mid-19th century with the depletion of its mines and the development of lead mining in Germany, Spain, and the United States.{{sfn|Lead mining}} By 1900, the United States was the leader in global lead production, and other non-European nations—Canada, Mexico, and Australia—had begun significant production; production outside Europe exceeded that within.{{sfn|Rich|1994|p=11}} A great share of the demand for lead came from plumbing and painting—]s were in regular use.{{sfn|Riva|Lafranconi|d'Orso|Cesana|2012|pp=11–16}} At this time, more (working class) people were exposed to the metal and lead poisoning cases escalated. This led to research into the effects of lead intake. Lead was proven to be more dangerous in its fume form than as a solid metal. Lead poisoning and ] were linked; British physician ] noted a third of his gout patients were plumbers and painters. The effects of chronic ingestion of lead, including mental disorders, were also studied in the 19th century. The first laws aimed at decreasing lead poisoning in factories were enacted during the 1870s and 1880s in the United Kingdom.{{sfn|Riva|Lafranconi|d'Orso|Cesana|2012|pp=11–16}} | |||
| === Industrial Revolution === | |||
| === Modern era === | |||
| In the second half of the 18th century, Britain, and later continental Europe and the United States, experienced the ]. This was the first time during which production rates exceeded those of Rome.{{sfn|Hong|Candelone|Patterson|Boutron|1994|pp=1841–43}} Britain was the leading producer, losing this status by the mid-19th century with the depletion of its mines and the development of lead mining in Germany, Spain, and the United States.{{sfn|Lead mining}} By 1900, the United States was the leader in global lead production, and other non-European nations—Canada, Mexico, and Australia—had begun significant production; production outside Europe exceeded that within.{{sfn|Rich|1994|p=11}} A great share of the demand for lead came from plumbing and painting—]s were in regular use.{{sfn|Riva|Lafranconi|d'Orso|Cesana|2012|pp=11–16}} At this time, more (working class) people were exposed to the metal and lead poisoning cases escalated. This led to research into the effects of lead intake. Lead was proven to be more dangerous in its fume form than as a solid metal. Lead poisoning and ] were linked; British physician ] noted a third of his gout patients were plumbers and painters. The effects of chronic ingestion of lead, including mental disorders, were also studied in the 19th century. The first laws aimed at decreasing lead poisoning in factories were enacted during the 1870s and 1880s in the United Kingdom.{{sfn|Riva|Lafranconi|d'Orso|Cesana|2012|pp=11–16}} | |||
| ] lead paint, United States, 1912|alt=A promotional poster for "COLLIER White Lead" (these words are highlighted) featuring a large image of a boy]]Further evidence of the threat that lead posed to humans was discovered in the late 19th and early 20th centuries. Mechanisms of harm were better understood, lead blindness was documented, and the element was phased out of public use in the United States and Europe. The United Kingdom introduced mandatory factory inspections in 1878 and appointed the first Medical Inspector of Factories in 1898; as a result, a 25-fold decrease in lead poisoning incidents from 1900 to 1944 was reported.{{sfn|Hernberg|2000|p=246}} Most European countries banned lead paint—commonly used because of its opacity and water resistance{{sfn|Crow|2007}}—for interiors by 1930.{{sfn|Markowitz|Rosner|2000|p=37}} | |||
| The last major human exposure to lead was the addition of ] to gasoline as an ], a practice that originated in the United States in 1921. <!--The sale of leaded gasoline was temporarily phased out in some American cites from 1924, due to adverse press coverage, but reintroduced by no later than 1927 after scientific studies of the time found no good reasons for continuing the ban.{{sfn|Uekoetter|2004|p=132}}--> It was phased out in the United States and the ] by 2000.{{sfn|Riva|Lafranconi|d'Orso|Cesana|2012|pp=11–16}} | |||
| ] lead paint, United States, 1912|alt=A promotional poster for "COLLIER White Lead" (these words are highlighted) featuring a large image of a boy]] | |||
| In the 1970s, the United States and Western European countries introduced legislation to reduce lead air pollution.{{sfn|More|Spaulding|Bohleber|Handley|2017}}{{sfn|American Geophysical Union|2017}} The impact was significant: while a study conducted by the ] in the United States in 1976–1980 showed that 77.8% of the population had elevated ]s, in 1991–1994, a study by the same institute showed the share of people with such high levels dropped to 2.2%.{{sfn|Centers for Disease Control and Prevention|1997}} The main product made of lead by the end of the 20th century was the ].{{sfn|Rich|1994|p=117}} | |||
| === Modern era === | |||
| Further evidence of the threat that lead posed to humans was discovered in the late 19th and early 20th centuries. Mechanisms of harm were better understood, lead blindness was documented, and the element was phased out of public use in the United States and Europe. The United Kingdom introduced mandatory factory inspections in 1878 and appointed the first Medical Inspector of Factories in 1898; as a result, a 25-fold decrease in lead poisoning incidents from 1900 to 1944 was reported.{{sfn|Hernberg|2000|pp=246}} The last major human exposure to lead was the addition of tetraethyllead to gasoline as an ], a practice that originated in the United States in 1921. <!--The sale of leaded gasoline was temporarily phased out in some American cites from 1924, due to adverse press coverage, but reintroduced by no later than 1927 after scientific studies of the time found no good reasons for continuing the ban.{{sfn|Uekoetter|2004|p=132}}--> It was phased out in the United States and the ] by 2000.{{sfn|Riva|Lafranconi|d'Orso|Cesana|2012|pp=11–16}} Most European countries banned lead paint—commonly used because of its opacity and water resistance{{sfn|Crow|2007}}—for interiors by 1930.{{sfn|Markowitz|Rosner|2000|p=37}} | |||
| From 1960 to 1990, lead output in the ] grew by about 31%.{{sfn|Rich|1994|p=17}} The share of the world's lead production by the ] increased from 10% to 30%, from 1950 to 1990, with the ] being the world's largest producer during the mid-1970s and the 1980s, and China starting major lead production in the late 20th century.{{sfn|Rich|1994|pp=91–92}} Unlike the European communist countries, China was largely unindustrialized by the mid-20th century; in 2004, China surpassed Australia as the largest producer of lead.{{sfn|United States Geological Survey|2005}} As was the case during European industrialization, lead has had a negative effect on health in China.{{sfn|Zhang|Yang|Li|Li|2012|pp=2261–2273}} | |||
| == Production == | == Production == | ||
| ] | ] | ||
| As of 2014, production of lead is increasing worldwide due to its use in lead–acid batteries.{{sfn|Tolliday|2014}} There are two major categories of production: primary from mined ores, and secondary from scrap. In 2014, 4.58 million metric tons came from primary production and 5.64 million from secondary production. The top three producers of mined lead concentrate in that year were China, Australia, and United States.{{sfn|United States Geological Survey|2017|p=97}} The top three producers of refined lead were China, United States, and India.{{sfn|Guberman|2016|pp=42.14–15}} According to the ] of 2010, the total amount of lead in use, stockpiled, discarded, or dissipated into the environment, on a global basis, is 8 kg per capita. Much of this is in more developed countries (20–150 kg per capita) rather than less developed ones (1–4 kg per capita).{{sfn|Graedel|2010}} | |||
| The primary and secondary lead production processes are similar. Some primary production plants now supplement their operations with scrap lead, and this trend is likely to increase in the future. Given adequate techniques, lead obtained via secondary processes is indistinguishable from lead obtained via primary processes. Scrap lead from the building trade is usually fairly clean and is re-melted without the need for smelting, though refining is sometimes needed. Secondary lead production is therefore cheaper, in terms of energy requirements, than is primary production, often by 50% or more.{{sfn|Thornton|Rautiu|Brush|2001|p=56}} | |||
| {{Clear}} | {{Clear}} | ||
| Line 254: | Line 242: | ||
| === Primary === | === Primary === | ||
| Most lead ores contain a low percentage of lead (rich ores have a typical content of 3–8%) which must be concentrated for extraction.{{sfn|Davidson|Ryman|Sutherland|Milner|2014|p=6}} During initial processing, ores typically undergo crushing, |
Most lead ores contain a low percentage of lead (rich ores have a typical content of 3–8%) which must be concentrated for extraction.{{sfn|Davidson|Ryman|Sutherland|Milner|2014|p=6}} During initial processing, ores typically undergo crushing, dense-medium separation, ], ], ]. The resulting concentrate, which has a lead content of 30–80% by mass (regularly 50–60%),{{sfn|Davidson|Ryman|Sutherland|Milner|2014|p=6}} is then turned into (impure) lead metal. | ||
| There are two main ways of doing this: a two-stage process involving roasting followed by blast furnace extraction, carried out in separate vessels; or a direct process in which the extraction of the concentrate occurs in a single vessel. The latter has become the most common route, though the former is still significant.{{sfn|Davidson|Ryman|Sutherland|Milner|2014|p=17}} | There are two main ways of doing this: a two-stage process involving roasting followed by blast furnace extraction, carried out in separate vessels; or a direct process in which the extraction of the concentrate occurs in a single vessel. The latter has become the most common route, though the former is still significant.{{sfn|Davidson|Ryman|Sutherland|Milner|2014|p=17}} | ||
| <div style="float: right; margin: 2px; font-size:85%; margin-left:18px; margin-bottom:18px> | <div style="float: right; margin: 2px; font-size:85%; margin-left:18px; margin-bottom:18px> | ||
| {| class="sortable collapsible |
{| class="wikitable sortable collapsible" | ||
| |+'''World's largest mining countries of lead, 2016'''{{sfn|United States Geological Survey|2017|p=97}} | |+'''World's largest mining countries of lead, 2016'''{{sfn|United States Geological Survey|2017|p=97}} | ||
| ! Country !! data-sort-type="number"|Output<br>(thousand<br> tons) | ! Country !! data-sort-type="number"|Output<br />(thousand<br /> tons) | ||
| |- | |- | ||
| | {{flagu|China}} || align="right"|2,400 | | {{flagu|China}} || align="right"|2,400 | ||
| Line 294: | Line 282: | ||
| | {{flagu|Ireland}} || align="right"|33 | | {{flagu|Ireland}} || align="right"|33 | ||
| |- | |- | ||
| | {{flagu|Macedonia}} || align="right"|33 | | {{flagu|Macedonia}}<!--the country was not called North Macedonia in the year for which this data is provided--> || align="right"|33 | ||
| |- | |- | ||
| | Other countries || align="right"|170 | | Other countries || align="right"|170 | ||
| Line 302: | Line 290: | ||
| ==== Two-stage process ==== | ==== Two-stage process ==== | ||
| First, the sulfide concentrate is ] in air to oxidize the lead sulfide:{{sfn|Thornton|Rautiu |
First, the sulfide concentrate is ] in air to oxidize the lead sulfide:{{sfn|Thornton|Rautiu|Brush|2001|p=51}} | ||
| : 2 PbS + 3 O<sub>2</sub> → 2 PbO + 2 SO<sub>2</sub>↑ | : 2 PbS(s) + 3 O<sub>2</sub>(g) → 2 PbO(s) + 2 SO<sub>2</sub>(g)↑ | ||
| As the original concentrate was not pure lead sulfide, roasting yields lead oxide |
As the original concentrate was not pure lead sulfide, roasting yields not only the desired lead(II) oxide, but a mixture of oxides, sulfates, and silicates of lead and of the other metals contained in the ore.{{sfn|Davidson|Ryman|Sutherland|Milner|2014|pp=11–12}} This impure lead oxide is reduced in a ]-fired blast furnace to the (again, impure) metal:{{sfn|Thornton|Rautiu|Brush|2001|pp=51–52}} | ||
| : 2 PbO + C → 2 Pb + CO<sub>2</sub>↑ | : 2 PbO(s) + C(s) → 2 Pb(s) + CO<sub>2</sub>(g)↑ | ||
| Impurities are mostly arsenic, antimony, bismuth, zinc, copper, silver, and gold. The melt is treated in a ] with air, steam, |
Impurities are mostly arsenic, antimony, bismuth, zinc, copper, silver, and gold. Typically they are removed in a series of ]. The melt is treated in a ] with air, steam, sulfur, which oxidizes the impurities except for silver, gold, bismuth. Oxidized contaminants float to the ] and are skimmed off.{{sfn|Davidson|Ryman|Sutherland|Milner|2014|p=25}}{{sfn|Primary Lead Refining}} Metallic silver and gold are removed and recovered economically by means of the ], in which zinc is added to lead. Zinc, which is immiscible in lead, dissolves the silver and gold. The zinc solution can be separated from the lead, and the silver and gold retrieved.{{sfn|Primary Lead Refining}}{{sfn|Pauling|1947}} De-silvered lead is freed of bismuth by the ], treating it with metallic ] and ]. The resulting bismuth dross can be skimmed off.{{sfn|Primary Lead Refining}} | ||
| Alternatively to the pyrometallurgical processes, very pure lead can be obtained by processing smelted lead electrolytically using the ]. Anodes of impure lead and cathodes of pure lead are placed in an electrolyte of lead ] (PbSiF<sub>6</sub>). Once electrical potential is applied, impure lead at the anode dissolves and plates onto the cathode, leaving the majority of the impurities in solution.{{sfn|Primary Lead Refining}}{{sfn|Davidson|Ryman|Sutherland|Milner|2014|p=34}} This is a high-cost process and thus mostly reserved for refining bullion containing high percentages of impurities.{{sfn|Davidson|Ryman|Sutherland|Milner|2014|p=23}} | |||
| ==== Direct process ==== | ==== Direct process ==== | ||
| In this process lead bullion and slag is obtained directly from lead concentrates. The lead sulfide concentrate is melted in a furnace and oxidized, forming lead monoxide. Carbon (coke or ]{{efn|Gaseous by-product of the coking process, containing ], hydrogen and ]; used as a fuel.}}) is added to the molten charge along with ]. The lead monoxide is thereby reduced to metallic lead, in the midst of a slag rich in lead monoxide.{{sfn|Davidson|Ryman|Sutherland|Milner|2014|p=17}} | In this process, lead bullion and ] is obtained directly from lead concentrates. The lead sulfide concentrate is melted in a furnace and oxidized, forming lead monoxide. Carbon (as coke or ]{{efn|Gaseous by-product of the coking process, containing ], hydrogen and ]; used as a fuel.}}) is added to the molten charge along with ]. The lead monoxide is thereby reduced to metallic lead, in the midst of a slag rich in lead monoxide.{{sfn|Davidson|Ryman|Sutherland|Milner|2014|p=17}} | ||
| If the input is rich in lead, as much as 80% of the original lead can be obtained as bullion; the remaining 20% forms a slag rich in lead monoxide. For a low-grade feed, all of the lead can be oxidized to a high-lead slag.{{sfn|Davidson|Ryman|Sutherland|Milner|2014|p=17}} Metallic lead is further obtained from the high-lead (25–40%) slags via submerged fuel combustion or injection, reduction assisted by an electric furnace, or a combination of both.{{sfn|Davidson|Ryman|Sutherland|Milner|2014|p=17}} | |||
| ==== Alternatives ==== | ==== Alternatives ==== | ||
| Research on a cleaner, less energy-intensive lead extraction process continues; a major drawback is that either too much lead is lost as waste, or the alternatives result in a high sulfur content in the resulting lead metal. ] extraction, in which ]s of impure lead are immersed into an ] and pure lead is deposited (]) onto ], is a technique that may have potential, but is not currently economical except in cases where electricity is very cheap.{{sfn|Thornton|Rautiu|Brush|2001|pp=52–53}} | |||
| Research on a cleaner, less energy-intensive lead extraction process continues; a major drawback is that either too much lead is lost as waste, or the alternatives result in a high sulfur content in the resulting lead metal. ] extraction, in which ]s of impure lead are immersed into an ] and pure lead is deposited onto a cathode, is a technique that may have potential.{{sfn|Thornton|Rautiu |Brush|2001|pp=52–53}} | |||
| === Secondary === | === Secondary === | ||
| {{Further|Battery recycling#Lead–acid batteries}} | |||
| Smelting, which is an essential part of the primary production, is often skipped during secondary production. It is only performed when metallic lead has undergone significant oxidation.{{sfn|Thornton|Rautiu|Brush|2001|p=56}} The process is similar to that of primary production in either a ] or a ], with the essential difference being the greater variability of yields: blast furnaces produce hard lead (10% antimony) while reverberatory and rotary kiln furnaces produce semisoft lead (3–4% antimony).{{sfn|United States Environmental Protection Agency|2010|p=1}} | |||
| The ] process is a more recent smelting method that may act as an extension to primary production; battery paste from spent lead–acid batteries (containing lead sulfate and lead oxides) has its sulfate removed by treating it with alkali, and is then treated in a coal-fueled furnace in the presence of oxygen, which yields impure lead, with antimony the most common impurity.{{sfn|Thornton|Rautiu|Brush|2001|p=57}} Refining of secondary lead is similar to that of primary lead; some refining processes may be skipped depending on the material recycled and its potential contamination.{{sfn|Thornton|Rautiu|Brush|2001|p=57}} | |||
| Of the sources of lead for recycling, lead–acid batteries are the most important; lead pipe, sheet, and cable sheathing are also significant.{{sfn|Thornton|Rautiu |
Of the sources of lead for recycling, lead–acid batteries are the most important; lead pipe, sheet, and cable sheathing are also significant.{{sfn|Thornton|Rautiu|Brush|2001|p=56}} | ||
| == Applications == | == Applications == | ||
| ] | ] | ||
| Contrary to popular belief, pencil leads in wooden pencils have never been made from lead. When the pencil originated as a wrapped graphite writing tool, the particular type of ] used was named '']'' (literally, ''lead mockup'').{{sfn|Evans|1908|pp=133–179}} | |||
| === Elemental form === | === Elemental form === | ||
| Lead metal has several useful mechanical properties, including high density, low melting point, ductility, and relative inertness. Many metals are superior to lead in some of these aspects but are generally less common and more difficult to extract from parent ores. Lead's toxicity has led to its phasing out for some uses.{{sfn|Baird|Cann|2012| |
Lead metal has several useful mechanical properties, including high density, low melting point, ductility, and relative inertness. Many metals are superior to lead in some of these aspects but are generally less common and more difficult to extract from parent ores. Lead's toxicity has led to its phasing out for some uses.{{sfn|Baird|Cann|2012|pp=537–538, 543–547}} | ||
| Lead has been used for |
Lead has been used for bullets since their invention in the Middle Ages. It is inexpensive; its low melting point means small arms ammunition and shotgun pellets can be cast with minimal technical equipment; and it is denser than other common metals, which allows for better retention of velocity. It remains the main material for bullets, alloyed with other metals as hardeners.{{sfn|Ramage|1980|p=8}} Concerns have been raised that lead bullets used for hunting can damage the environment.{{efn|California began banning lead bullets for hunting on that basis in July 2015.{{sfn|California Department of Fish and Wildlife}}}} ] ] used for ] must today be lead-free in the ],<ref>{{Cite web |date=2022-04-19 |title=Nontoxic Shot Regulations For Hunting Waterfowl and Coots in the U.S. {{!}} U.S. Fish & Wildlife Service |url=https://www.fws.gov/story/2022-04/nontoxic-shot-regulations-hunting-waterfowl-and-coots-us |access-date=2024-09-12 |website=www.fws.gov |language=en}}</ref> ],<ref>{{Cite web |last=Canada |first=Environment and Climate Change |date=2018-04-05 |title=Moving towards using more lead-free ammunition |url=https://www.canada.ca/en/environment-climate-change/services/management-toxic-substances/list-canadian-environmental-protection-act/lead/using-more-lead-free-ammunition.html |access-date=2024-09-12 |website=www.canada.ca}}</ref> and in ].<ref>{{Cite web |title=Regulation - 2021/57 - EN - EUR-Lex |url=https://eur-lex.europa.eu/eli/reg/2021/57/oj |access-date=2024-09-12 |website=eur-lex.europa.eu |language=en}}</ref> | ||
| Lead's high density and resistance to corrosion have been exploited in a number of related applications. It is used as ] in sailboat keels; its density allows it to take up a small volume and minimize water resistance, thus counterbalancing the heeling effect of wind on the sails.{{sfn|Parker|2005|pp=194–195}} It is used in ] ] to counteract the diver's buoyancy.{{sfn|Krestovnikoff|Halls|2006|p=70}} In 1993, the base of the ] was stabilized with 600 tonnes of lead.{{sfn|Street|Alexander|1998|p=182}} Because of its corrosion resistance, lead is used as a protective sheath for underwater cables.{{sfn|Jensen|2013|p=136}} | |||
| ] | ] | ||
| Lead has many uses in the construction industry; lead sheets are used as ] in roofing material, cladding, flashing, gutters and gutter joints, |
Lead has many uses in the construction industry; lead sheets are used as ] in ], ], ], ] and gutter joints, roof parapets.{{sfn|Think Lead research}}{{sfn|Weatherings to Parapets}} Lead is still used in statues and sculptures,{{efn|For example, a firm "...producing quality garden ornament from our studio in West London for over a century".{{sfn|Lead garden ornaments|2016}}}} including for ].{{sfn|Putnam|2003|p=216}} In the past it was often used to ]; for environmental reasons this use is being phased out in favor of other materials.{{sfn|United States Geological Survey|2017|p=97}} | ||
| Lead is added to copper alloys such as ] and bronze, to improve |
Lead is added to copper alloys, such as ] and ], to improve machinability and for its lubricating qualities. Being practically insoluble in copper, the lead forms solid globules in imperfections throughout the alloy, such as ]. In low concentrations, as well as acting as a lubricant, the globules hinder the formation of ] as the alloy is worked, thereby improving machinability. Copper alloys with larger concentrations of lead are used in ]. The lead provides lubrication, and the copper provides the load-bearing support.{{sfn|Copper Development Association}} | ||
| Lead's high density, atomic number, and formability form the basis for use of lead as a barrier that absorbs sound, vibration, and radiation.{{sfn|Rich|1994|p=101}} Lead has no natural resonance frequencies;{{sfn|Rich|1994|p=101}} as a result, sheet-lead is used as a sound deadening layer in the walls, floors, and ceilings of sound studios.{{sfn|Guruswamy|2000| |
Lead's high density, atomic number, and formability form the basis for use of lead as a barrier that absorbs sound, vibration, and radiation.{{sfn|Rich|1994|p=101}} Lead has no natural resonance frequencies;{{sfn|Rich|1994|p=101}} as a result, sheet-lead is used as a sound deadening layer in the walls, floors, and ceilings of sound studios.{{sfn|Guruswamy|2000|p=31}} ]s are often made from a lead alloy, mixed with various amounts of tin to control the tone of each pipe.{{sfn|Audsley|1965|pp=250–251}}{{sfn|Palmieri|2006|pp=412–413}} Lead is an established ] material from ] in nuclear science and in X-ray rooms{{sfn|National Council on Radiation Protection and Measurements|2004|p=16}} due to its denseness and high ].{{sfn|Thornton|Rautiu|Brush|2001|p=7}} Molten lead has been used as a coolant for ]s.{{sfn|Tuček|Carlsson|Wider|2006|p=1590}} | ||
| === Batteries === | |||
| The largest use of lead in the early 21st century is in ]. The lead in batteries undergoes no direct contact with humans, so there are fewer toxicity concerns.{{efn|Potential injuries to regular users of such batteries are not related to lead's toxicity.{{sfn|Concordia University|2016}}}} People who work in lead battery production or recycling plants may be exposed to lead dust and inhale it.{{sfn|Toxicological Profile for Lead|2007|pp=5–6}} The reactions in the battery between lead, lead dioxide, and sulfuric acid provide a reliable source of ].{{efn|See{{sfn|Progressive Dynamics, Inc.}} for details on how a lead–acid battery works.}} ]s incorporating lead–acid batteries have been installed in kilowatt and megawatt scale applications in Australia, Japan, and the United States in frequency regulation, solar smoothing and shifting, wind smoothing, and other applications.{{sfn|Olinsky-Paul|2013}} These batteries have lower energy density and charge-discharge efficiency than ], but are significantly cheaper.{{sfn|Gulbinska|2014}} | |||
| === Coating for cables === | |||
| The largest use of lead in the early 21st century is in lead–acid batteries. The reactions in the battery between lead, lead dioxide, and sulfuric acid provide a reliable source of ].{{efn|See{{sfn|Progressive Dynamics, Inc.}} for details on how a lead–acid battery works.}} The lead in batteries undergoes no direct contact with humans, so there are fewer toxicity concerns. ]s incorporating lead–acid batteries have been installed in kilowatt and megawatt scale applications in Australia, Japan, and the United States in frequency regulation, solar smoothing and shifting, wind smoothing, and other applications.{{sfn|Olinsky-Paul|2013}} These batteries have lower energy density and charge-discharge efficiency than ], but are significantly cheaper.{{sfn|Gulbinska|2014}} | |||
| Lead is used in high voltage power cables as shell material to prevent water diffusion into insulation; this use is decreasing as lead is being phased out.{{sfn|Rich|1994|pp=133–134}} Its use in ] for electronics is also being phased out by some countries to reduce the amount of ] waste.{{sfn|Zhao|2008|p=440}} Lead is one of three metals used in the ] for museum materials, helping detect organic acids, aldehydes, acidic gases.{{sfn|Beiner|Lavi|Seri|Rossin|2015}}{{sfn|Szczepanowska|2013|pp=84–85}} | |||
| === Compounds === | |||
| Lead is used in high voltage power cables as sheathing material to prevent water diffusion into insulation; this use is decreasing as lead is being phased out.{{sfn|Rich|1994|pp=133–34}} Its use in ] for electronics is also being phased out by some countries to reduce the amount of ] waste.{{sfn|Zhao|2008|p=440}} Lead is one of three metals used in the ] for museum materials, helping detect organic acids, aldehydes, and acidic gases.{{sfn|Beiner|Lavi|Seri|Rossin|2015}}{{sfn|Szczepanowska|2013|pp=84–85}} | |||
| ]|alt=A crystal glass|left]] | |||
| ] and ]|right]] | |||
| In addition to being the main application for lead metal, lead–acid batteries are also the main consumer of lead compounds. The energy storage/release reaction used in these devices involves ] and ]: | |||
| Contrary to popular belief, pencil leads in wooden pencils have never been made from lead. When the pencil originated as a wrapped graphite writing tool, the particular type of ] used was named ] (literally, ''act for lead'' or ''lead mockup'').{{sfn|Evans|1908|pp=133–79}} | |||
| === Compounds === | |||
| In addition to being the main application for lead metal, lead-acid batteries are also the main consumer of lead compounds. The energy storage/release reaction used in these devices involves ] and ]: | |||
| :{{chem|Pb}}(s) + {{chem|PbO|2}}(s) + 2{{chem|H|2|SO|4}}(aq) → 2{{chem|PbSO|4}}(s) + 2{{chem|H|2|O}}(l) | :{{chem|Pb}}(s) + {{chem|PbO|2}}(s) + 2{{chem|H|2|SO|4}}(aq) → 2{{chem|PbSO|4}}(s) + 2{{chem|H|2|O}}(l) | ||
| Other applications of lead compounds are very specialized and often fading. |
Other applications of lead compounds are very specialized and often fading. Lead-based coloring agents are used in ]s and glass, especially for red and yellow shades.{{sfn|Burleson|2001|p=23}} While lead paints are phased out in Europe and North America, they remain in use in less developed countries such as China,{{sfn|Insight Explorer|IPEN|2016}} India,{{sfn|Singh|2017}} or Indonesia.{{sfn|Ismawati|Primanti|Brosché|Clark|2013|p=2}} Lead tetraacetate and lead dioxide are used as oxidizing agents in organic chemistry. Lead is frequently used in the ] coating of electrical cords.{{sfn|Zweifel|2009|page=438}}{{sfn|Wilkes|Summers|Daniels|Berard|2005|p=106}} It can be used to treat candle wicks to ensure a longer, more even burn. Because of its toxicity, European and North American manufacturers use alternatives such as zinc.{{sfn|Randerson|2002}}{{sfn|Nriagu|Kim|2000|pp=37–41}} ] is composed of 12–28% ], changing its optical characteristics and reducing the transmission of ionizing radiation,{{sfn|Amstock|1997|pp=116–119}} a property used in old TVs and computer monitors with ]s. Lead-based ]s such as ] and ] are used in ] cells and ] detectors.{{sfn|Rogalski|2010|pp=485–541}} | ||
| == Biological effects == | == Biological effects == | ||
| {{Main |
{{Main|Lead poisoning}} | ||
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| Lead has no confirmed biological role, and there is no confirmed safe level of lead exposure.{{sfn|World Health Organization|2018}} A 2009 Canadian–American study concluded that even at levels that are considered to pose little to no risk, lead may cause "adverse mental health outcomes".{{sfn|Bouchard|Bellinger|Weuve|Matthews-Bellinger|2009}} Its prevalence in the human body—at an adult average of 120 mg{{efn|Rates vary greatly by country.{{sfn|World Health Organization|2000|pp=149–153}} }}—is nevertheless exceeded only by zinc (2500 mg) and iron (4000 mg) among the heavy metals.{{sfn|Emsley|2011|pp=280, 621, 255}} Lead ] are very efficiently absorbed by the body.{{sfn|Luckey|Venugopal|1979|pp=177–178}} A small amount of lead (1%) is stored in bones; the rest is excreted in urine and feces within a few weeks of exposure. Only about a third of lead is excreted by a child. Continual exposure may result in the ] of lead.{{sfn|Toxic Substances Portal}} | |||
| === Toxicity === | |||
| ] | |||
| Lead is a highly poisonous metal (whether inhaled or swallowed), affecting almost every organ and system in the human body.{{sfn|United States Food and Drug Administration|2015|p=42}} <!--The permitted daily exposure limit for lead of 5 μg (five millionths of a gram) is a recommended test benchmark for pharmaceuticals.--> At airborne levels of 100 mg/m<sup>3</sup>, it is ].{{sfn|National Institute for Occupational Safety and Health}} Most ingested lead is absorbed into the bloodstream.{{sfn|Occupational Safety and Health Administration}} The primary cause of its toxicity is its predilection for interfering with the proper functioning of enzymes. It does so by binding to the ] found on many enzymes,{{sfn|Rudolph|Rudolph|Hostetter|Lister|2003|p=369}} or mimicking and displacing other metals which act as ] in many enzymatic reactions.{{sfn|Dart|Hurlbut|Boyer-Hassen|2004|p=1426}} The essential metals that lead interacts with include calcium, iron, and zinc.{{sfn|Kosnett|2006|p=238}} High levels of calcium and iron tend to provide some protection from lead poisoning; low levels cause increased susceptibility.{{sfn|Luckey|Venugopal|1979|pp=177–178}} | |||
| === |
=== Effects === | ||
| Lead can cause severe damage to the brain and kidneys and, ultimately, death. By mimicking calcium, lead can cross the ]. It degrades the ] sheaths of ]s, reduces their numbers, interferes with ] routes, and decreases neuronal growth.{{sfn|Rudolph|Rudolph|Hostetter|Lister|2003|p=369}} In the human body, lead inhibits ] and ], preventing both ] formation and the incorporation of iron into ], the final step in ] synthesis. This causes ineffective heme synthesis and ].{{sfn|Cohen|Trotzky|Pincus|1981|pp=904–906}} | |||
| <!--At lower levels, it acts as a calcium analog, interfering with ion channels during nerve conduction. This is one of the mechanisms by which it interferes with cognition.--> | |||
| ] | |||
| Lead has no confirmed biological role.{{sfn|Emsley|2011|p=280}} Its prevalence in the human body—at an adult average of 120 mg{{efn|Rates vary greatly by country.{{sfn|World Health Organization|2000|pp=149–53}} }}—is nevertheless exceeded only by zinc (2500 mg) and iron (4000 mg) among the heavy metals.{{sfn|Emsley|2011|p=280, 621, 255}} Lead ] are very efficiently absorbed by the body.{{sfn|Luckey|Venugopal|1979|pages=177–78}} A small amount of lead (1%) is stored in bones; the rest is excreted in urine and feces within a few weeks of exposure. Only about a third of lead is excreted by a child. Continual exposure may result in the ] of lead.{{sfn|Toxic Substances Portal}} | |||
| Symptoms of lead poisoning include ], ]-like abdominal pains, and possibly weakness in the fingers, wrists, or ankles. Small blood pressure increases, particularly in middle-aged and older people, may be apparent and can cause ].{{citation needed|date=October 2022}} Several studies, mostly cross-sectional, found an association between increased lead exposure and decreased heart rate variability.{{sfn|Navas-Acien|2007}} In pregnant women, high levels of exposure to lead may cause miscarriage. Chronic, high-level exposure has been shown to reduce fertility in males.{{sfn|Sokol|2005|p=133, passim}} | |||
| ==== Toxicity ==== | |||
| Lead is a highly poisonous metal (whether inhaled or swallowed), affecting almost every organ and system in the human body.{{sfn|United States Food and Drug Administration|2015|p=42}} <!--The permitted daily exposure limit for lead of 5 μg (five millionths of a gram) is a recommended test benchmark for pharmaceuticals.--> At airborne levels of 100 mg/m<sup>3</sup>, it is ].{{sfn|National Institute for Occupational Safety and Health}} Most ingested lead is absorbed into the bloodstream.{{sfn|Occupational Safety and Health Administration}} The primary cause of its toxicity is its predilection for interfering with the proper functioning of ]s. It does so by binding to the ]s found on many enzymes,{{sfn|Rudolph|Rudolph|Hostetter|Lister|2003|p=369}} or mimicking and displacing other metals which act as ] in many enzymatic reactions.{{sfn|Dart|Hurlbut|Boyer-Hassen|2004|p=1426}} Among the essential metals that lead interacts with are calcium, iron, and zinc.{{sfn|Kosnett|2006|p=238}} High levels of calcium and iron tend to provide some protection from lead poisoning; low levels cause increased susceptibility.{{sfn|Luckey|Venugopal|1979|pages=177–78}} | |||
| In a child's developing brain, lead interferes with ] formation <!-- "syaptic modeling" --> in the ], ] development (including that of neurotransmitters), and the organization of ]s.{{sfn|Mycyk|Hryhorczuk|Amitai|2005|p=462}} Early childhood exposure has been linked with an increased risk of sleep disturbances and excessive daytime drowsiness in later childhood.{{sfn|Liu|Liu|Pak|Wang|2015|pp=1869–1874}} High blood levels are associated with delayed puberty in girls.{{sfn|Schoeters|Den Hond|Dhooge|Van Larebeke|2008|pp=168–175}} The rise and fall in exposure to airborne lead from the combustion of tetraethyl lead in gasoline during the 20th century has been linked with historical increases and ]. | |||
| ==== Effects ==== | |||
| Lead can cause severe damage to the brain and kidneys and, ultimately, death. By mimicking calcium, lead can cross the ]. It degrades the ] sheaths of ]s, reduces their numbers, interferes with ] routes, and decreases neuronal growth.{{sfn|Rudolph|Rudolph|Hostetter|Lister|2003|p=369}} | |||
| <!--In the human body, lead inhibits ] and ], preventing both ] formation and the incorporation of ] into ], the final step in ] synthesis. This causes ineffective heme synthesis and ].{{sfn|Cohen|Trotzky|Pincus|1981|pp=904–06}} At lower levels, it acts as a calcium analog, interfering with ion channels during nerve conduction. This is one of the mechanisms by which it interferes with cognition.--> | |||
| === Exposure sources === | |||
| Symptoms of lead poisoning include ], ]-like abdominal pains, and possibly weakness in the fingers, wrists, or ankles. Small blood pressure increases, particularly in middle-aged and older people, may be apparent and can cause ]. Several studies, mostly cross-sectional, found an association between increased lead exposure and decreased heart rate variability.<ref>{{cite journal|last1=Navas-Acien|first1=Ana|title=Lead Exposure and Cardiovascular Disease—A Systematic Review|journal=Environmental Health Perspectives|date=March 2007|volume=115|issue=3|pages=472–482|doi=10.1289/ehp.9785|pmid=17431501|pmc=1849948}}</ref> In pregnant women, high levels of exposure to lead may cause miscarriage. Chronic, high-level exposure has been shown to reduce fertility in males.{{sfn|Sokol|2005|p=133, passim}} | |||
| Lead exposure is a global issue since lead mining and smelting, and battery manufacturing, disposal, and ], are common in many countries. Lead enters the body via inhalation, ingestion, or skin absorption. Almost all inhaled lead is absorbed into the body; for ingestion, the rate is 20–70%, with children absorbing a higher percentage than adults.{{sfn|Tarragó|2012|p=16}} | |||
| Poisoning typically results from ingestion of food or water contaminated with lead, and less commonly after accidental ingestion of contaminated soil, dust, or lead-based paint.{{sfn|Toxicological Profile for Lead|2007|p=4}} Seawater products can contain lead if affected by nearby industrial waters.{{sfn|Bremner|2002|p=101}} Fruit and vegetables can be contaminated by high levels of lead in the soils they were grown in. Soil can be contaminated through particulate accumulation from lead in pipes, ], residual emissions from leaded gasoline.{{sfn|Agency for Toxic Substances and Disease Registry|2007}} | |||
| ] | |||
| The use of lead for water pipes is ].{{sfn|Thornton|Rautiu|Brush|2001|p=17}} Hard water forms insoluble protective layers on the inner surface of the pipes, whereas soft and acidic water dissolves the lead pipes.{{sfn|Moore|1977|pp=109–115}} Dissolved ] in the carried water may result in the formation of soluble lead ]; oxygenated water may similarly dissolve lead as ]. Drinking such water, over time, can cause health problems due to the toxicity of the dissolved lead. The ] the more ] and ] it contains, and the more the inside of the pipes are coated with a protective layer of lead carbonate or lead sulfate.{{sfn|Wiberg|Wiberg|Holleman|2001|p=914}} | |||
| In a child's developing brain, lead interferes with ] formation <!-- "syaptic modeling" --> in the ], ] development (including that of neurotransmitters), and the organization of ]s.{{sfn|Mycyk|Hryhorczuk|Amitai|2005|p=462}} Early childhood exposure has been linked with an increased risk of sleep disturbances and excessive daytime sleepiness in later childhood.{{sfn|Liu|Liu|Pak|Wang|2015|pp=1869–74}} High blood levels are associated with delayed puberty in girls.{{sfn|Schoeters|Den Hond|Dhooge|Van Larebeke|2008|pp=168–75}} The rise and fall in exposure to airborne lead from the combustion of tetraethyl lead in gasoline during the 20th century has been linked with historical increases and decreases in crime levels, a ] which is not universally accepted.{{sfn|Casciani|2014}} | |||
| ]ic recording of the effect of lead acetate on frog heart experimental set up]] | |||
| ==== Exposure sources ==== | |||
| Ingestion of applied lead-based paint is the major source of exposure for children: a direct source is chewing on old painted window sills. Additionally, as lead paint on a surface deteriorates, it peels and is pulverized into dust. The dust then enters the body through hand-to-mouth contact or contaminated food or drink. Ingesting certain ] may result in exposure to lead or its compounds.{{sfn|Tarragó|2012|p=11}} | |||
| Lead exposure is a global issue since lead mining and smelting, and battery manufacturing/disposal/recycling, are common in many countries. Lead enters the body via inhalation, ingestion, or skin absorption. Almost all inhaled lead is absorbed into the body; for ingestion, the rate is 20–70%, with children absorbing a higher percentage than adults.{{sfn|Tarragó|2012 |p=16}} | |||
| Inhalation is the second major exposure pathway, affecting smokers and especially workers in lead-related occupations.{{sfn|Occupational Safety and Health Administration}} ] contains, among other toxic substances, radioactive ].{{sfn|Centers for Disease Control and Prevention|2015}} "As a result of EPA's regulatory efforts, levels of lead in the air decreased by 86 percent between 2010 and 2020."<ref name="EPSLAP">{{cite web |title=Lead (Pb) Air Pollution |url=https://www.epa.gov/lead-air-pollution |website=epa.gov |publisher=United States Environmental Protection Agency |access-date=July 22, 2022 |date=July 8, 2022 |quote=As a result of EPA's regulatory efforts, levels of lead in the air nationally decreased by 86 percent between 2010 and 2020.}}</ref> The concentration of lead in the air in the United States fell below the national standard of 0.15 μg/m<sup>3</sup><ref name="EPAleadStandards">{{cite web |title=NAAQS Table |url=https://www.epa.gov/criteria-air-pollutants/naaqs-table#1 |website=epa.gov |publisher=United States Environmental Protection Agency |access-date=July 22, 2022 |date=April 5, 2022 |quote=National Ambient Air Quality Standards (40 CFR part 50) for six principal pollutants}}</ref> in 2014.<ref name="EPALeadTrends">{{cite web |title=Lead Trends |url=https://www.epa.gov/air-trends/lead-trends |website=epa.gov |publisher=United States Environmental Protection Agency |date=June 1, 2022}}</ref> | |||
| Poisoning typically results from ingestion of food or water contaminated with lead, and less commonly after accidental ingestion of contaminated soil, dust, or lead-based paint.{{sfn|Toxicological Profile for Lead|2007|p=4}} Seawater products can contain lead if affected by nearby industrial waters.{{sfn|Bremner|2002|p=101}} Fruit and vegetables can be contaminated by high levels of lead in the soils they were grown in. Soil can be contaminated through particulate accumulation from lead in pipes, lead paint, and residual emissions from leaded gasoline.{{sfn|Agency for Toxic Substances and Disease Registry}} | |||
| Skin exposure may be significant for people working with organic lead compounds. The rate of skin absorption is lower for inorganic lead.{{sfn|Wani|Ara|Usman|2015|pp=57, 58}} | |||
| The use of lead for water pipes is ].{{sfn|Thornton|Rautiu|Brush|2001|p=17}} Hard water forms insoluble layers in the pipes whereas soft and acidic water dissolves the lead pipes.{{sfn|Moore|1977|pp=109–15}} Dissolved ] in the carried water may result in the formation of soluble lead ]; oxygenated water may similarly dissolve lead as ].{{sfn|Polyanskiy|1986|p=32}} Drinking such water, over time, can cause health problems due to the toxicity of the dissolved lead. The ] the more ] and ] it will contain, and the more the inside of the pipes will be coated with a protective layer of lead carbonate or lead sulfate.{{sfn|Wiberg|Wiberg|Holleman|2001|p=914}} | |||
| ==== Lead in foods ==== | |||
| Ingestion of applied lead-based paint is the major source of exposure for children: | |||
| Lead may be found in food when food is grown in soil that is high in lead, airborne lead contaminates the crops, animals eat lead in their diet, or lead enters the food either from what it was stored or cooked in.<ref>{{cite book |last1=Castellino |first1=Nicolo |last2=Sannolo |first2=Nicola |last3=Castellino |first3=Pietro | name-list-style = vanc |title=Inorganic Lead Exposure and Intoxications|date=1994|publisher=CRC Press|isbn=9780873719971|page=86|url=https://books.google.com/books?id=059oObc8X48C&pg=PA86|url-status=live|archive-url=https://web.archive.org/web/20171105194927/https://books.google.com/books?id=059oObc8X48C&pg=PA86|archive-date=2017-11-05}}</ref> Ingestion of lead paint and batteries is also a route of exposure for livestock, which can subsequently affect humans.<ref>{{Cite journal |last1=Hesami |first1=Reza |last2=Salimi |first2=Azam |last3=Ghaderian |first3=Seyed Majid |date=2018-01-10 |title=Lead, zinc, and cadmium uptake, accumulation, and phytoremediation by plants growing around Tang-e Douzan lead–zinc mine, Iran |url=http://dx.doi.org/10.1007/s11356-017-1156-y |journal=Environmental Science and Pollution Research |volume=25 |issue=9 |pages=8701–8714 |doi=10.1007/s11356-017-1156-y |pmid=29322395 |bibcode=2018ESPR...25.8701H |s2cid=3938066 |issn=0944-1344}}</ref> Milk produced by contaminated cattle can be diluted to a lower lead concentration and sold for consumption.<ref>{{Cite journal |last1=Mielke |first1=Howard W. |last2=Reagan |first2=Patrick L. |date=February 1998 |title=Soil Is an Important Pathway of Human Lead Exposure |journal=Environmental Health Perspectives |volume=106 |issue=Suppl 1 |pages=217–229 |doi=10.2307/3433922 |jstor=3433922 |pmid=9539015 |pmc=1533263 |issn=0091-6765 }}</ref> | |||
| a direct source is chewing on old painted window sills. Alternatively, as the applied dry paint deteriorates, it peels, is pulverized into dust and then enters the body through hand-to-mouth contact or contaminated food, water, or alcohol. Ingesting certain ] may result in exposure to lead or its compounds.{{sfn|Tarragó|2012 |p=11}} | |||
| In Bangladesh, lead compounds have been added to ] to make it more yellow.<ref name=Stan2019>{{cite news |last1=Jordan |first1=Rob |title=Lead found in turmeric |url=https://news.stanford.edu/2019/09/24/lead-found-turmeric/ |access-date=25 September 2019 |work=Stanford News |date=24 September 2019}}</ref> This is believed to have started in the 1980s and continues {{as of|2019|lc=y}}.<ref name=Stan2019/> It is believed to be one of the main sources of high lead levels in the country.<ref>{{cite news |title=Researchers find lead in turmeric |url=https://phys.org/news/2019-09-turmeric.html |date= September 24, 2019 |access-date=25 September 2019 |work=phys.org}}</ref> In Hong Kong the maximum allowed lead level in food is 6 parts per million in solids and 1 part per million in liquids.<ref>{{cite web |title=Maximum Permitted Concentration of Certain Metals Present in Specified Foods |url=https://www.elegislation.gov.hk/hk/cap132V!en@2019-09-19T00:00:00?INDEX_CS=N&xpid=ID_1438402695833_003 |work= Cap. 132V Food Adulteration (Metallic Contamination) Regulations |publisher=Hong Kong e-Legislation |access-date=15 April 2020}}</ref> | |||
| <div style="float:left; font-size:100%; margin-right:18px; margin-bottom:0px; margin-left:0px> | |||
| {{NFPA 704|Health = 3|Flammability = 1|Reactivity = 0|S=- | |||
| |caption=Fire diamond for lead granules}} | |||
| </div> | |||
| Lead-containing dust can settle on drying cocoa beans when they are set outside near polluting industrial plants.<ref>{{Cite web |date=2023-02-01 |title=Dark chocolate is high in cadmium and lead. How much is safe to eat? |url=https://www.wbur.org/hereandnow/2023/02/01/dark-chocolate-lead-cadmium |website=Here & Now |publisher=WBUR |first1=Robin |last1=Young |first2=Karyn |last2=Miller-Medzon |language=en |url-status=live |archive-url=https://web.archive.org/web/20240208134257/https://www.wbur.org/hereandnow/2023/02/01/dark-chocolate-lead-cadmium |archive-date= Feb 8, 2024 }}</ref> In December 2022, ] tested 28 ] brands and found that 23 of them contained potentially harmful levels of lead, ] or both. They have urged the chocolate makers to reduce the level of lead which could be harmful, especially to a developing fetus.<ref>{{Cite web |title=Consumer Reports urges dark chocolate makers to reduce lead, cadmium levels |url=https://www.yahoo.com/lifestyle/consumer-reports-urges-dark-chocolate-155747068.html |access-date=2023-01-28 |website=Yahoo Life |agency=Reuters |first1=Jonathan |last1=Stempel |date=23 January 2023 |language=en-US}}</ref> | |||
| Inhalation is the second major exposure pathway, affecting smokers and especially workers in lead-related occupations.{{sfn|Occupational Safety and Health Administration}} ] contains, among other toxic substances, radioactive ].{{sfn|Centers for Disease Control and Prevention|2015}} | |||
| In March 2024, the US ] recommended a voluntary recall on 6 brands of ] due to contamination with lead,<ref>{{Cite web|url=https://www.fda.gov/food/alerts-advisories-safety-information/fda-alert-concerning-certain-cinnamon-products-due-presence-elevated-levels-lead|title=FDA Alert Concerning Certain Cinnamon Products Due to Presence of Elevated Levels of Lead|website=] |date=6 March 2024|access-date=27 May 2024}}</ref> after 500 reports of child lead poisoning.<ref>{{Cite news|url=https://apnews.com/article/cinnamon-lead-applesauce-wanabana-fda-344066a22a729d176c0c732180f48247|title=Lead-tainted cinnamon has been recalled. Here's what you should know|last=Aleccia|first=Jonel|date=8 March 2024|access-date=27 May 2024}}</ref> The FDA determined that cinnamon was adulterated with ].<ref>{{Cite web|url=https://www.fda.gov/food/outbreaks-foodborne-illness/investigation-elevated-lead-chromium-levels-cinnamon-applesauce-pouches-november-2023|title=Investigation of Elevated Lead & Chromium Levels: Cinnamon Applesauce Pouches (November 2023)|website=] |date=16 April 2024|access-date=27 May 2024}}</ref> | |||
| Skin exposure may be significant for people working with organic lead compounds. The rate of skin absorption is lower for inorganic lead.{{sfn|Wani|Ara|Usman|2015|pp=57, 58}} | |||
| ==== |
==== Lead in plastic toys ==== | ||
| According to the United States ], the use of lead in plastics has not been banned as of 2024. Lead softens the plastic and makes it more flexible so that it can go back to its original shape. Habitual chewing on colored plastic insulation from stripped electrical wires was found to cause elevated lead levels in a 46-year-old man.<ref>{{Cite web |title=Lead Intoxication Associated with Chewing Plastic Wire Coating – Ohio |url=https://www.cdc.gov/mmwr/preview/mmwrhtml/00020984.htm |access-date=8 June 2024 |website=www.cdc.gov |language=en-us}}</ref> Lead may be used in plastic toys to stabilize molecules from heat. Lead dust can be formed when plastic is exposed to sunlight, air, and detergents that break down the chemical bond between the lead and plastics.<ref>{{Cite web |date=16 April 2024 |title=About Lead in Consumer Products {{!}} Exposure {{!}} CDC |url=https://www.cdc.gov/lead-prevention/prevention/consumer-products.html |access-date=8 June 2024 |website=www.cdc.gov |language=en-us}}</ref> | |||
| === Treatment === | |||
| Treatment for lead poisoning normally involves the administration of ] and ].{{sfn|Prasad|2010|pp=651–52}} Acute cases may require the use of ], the calcium ], and the disodium salt of ethylenediaminetetraacetic acid (]). It has a greater affinity for lead than calcium, with the result that lead chelate is formed by exchange and excreted in the urine, leaving behind harmless calcium.{{sfn|Masters|Trevor|Katzung|2008|pp=481–83}} | |||
| {{See also|Chelation therapy}} | |||
| Treatment for lead poisoning normally involves the administration of ] and ].{{sfn|Prasad|2010|pp=651–652}} Acute cases may require the use of ], the calcium ], and the disodium salt of ethylenediaminetetraacetic acid (]). It has a greater affinity for lead than calcium, with the result that lead chelate is formed by exchange and excreted in the urine, leaving behind harmless calcium.{{sfn|Masters|Trevor|Katzung|2008|pp=481–483}} | |||
| == Environmental effects == | == Environmental effects == | ||
| ], Senegal, where at least 18 children died of lead poisoning in 2008|alt=A dusty dump]] | ], Senegal, where at least 18 children died of lead poisoning in 2008|alt=A dusty dump]] | ||
| The extraction, production, use, and disposal of lead and its products have caused significant contamination of the Earth's soils and waters. Atmospheric emissions of lead were at their peak during the Industrial Revolution, and the leaded gasoline period in the second half of the twentieth century |
The extraction, production, use, and disposal of lead and its products have caused significant contamination of the Earth's soils and waters. Atmospheric emissions of lead were at their peak during the Industrial Revolution, and the leaded gasoline period in the second half of the twentieth century.{{sfn|United Nations Environment Programme|2010|p=4}} | ||
| Lead releases originate from natural sources (i.e., concentration of the naturally occurring lead), industrial production, incineration and recycling, and mobilization of previously buried lead.{{sfn|United Nations Environment Programme|2010|p=4}} In particular, as lead has been phased out from other uses, in the Global South, lead recycling operations designed to extract cheap lead used for global manufacturing have become a well documented source of exposure.{{sfn|Renfrew|2019|p=8}} Elevated concentrations of lead persist in soils and sediments in post-industrial and urban areas; industrial emissions, including those arising from coal burning,{{sfn|Trace element emission|2012}} continue in many parts of the world, particularly in the developing countries.{{sfn|United Nations Environment Programme|2010|p=6}} | |||
| Lead can accumulate in soils, especially those with a high organic content, where it remains for hundreds to thousands of years. It can take the place of other metals in plants and can accumulate on their surfaces, thereby retarding ], and preventing their growth or killing them. Contamination of soils and plants then affects microorganisms and animals. Affected animals have a reduced ability to synthesize ]s, which causes anemia.{{sfn|Greene|2014}} | |||
| Lead can accumulate in soils, especially those with a high organic content, where it remains for hundreds to thousands of years. Environmental lead can compete with other metals found in and on plant surfaces potentially inhibiting ] and at high enough concentrations, negatively affecting plant growth and survival. Contamination of soils and plants can allow lead to ascend the food chain affecting microorganisms and animals. In animals, lead exhibits toxicity in many organs, damaging the nervous, ], reproductive, ], and cardiovascular systems after ingestion, inhalation, or skin absorption.{{sfn|Assi|Hezmee|Haron|Sabri|2016}} Fish uptake lead from both water and sediment;{{sfn|World Health Organization|1995}} bioaccumulation in the food chain poses a hazard to fish, birds, and sea mammals.{{sfn|UK Marine SACs Project|1999}} | |||
| Analytical methods for the determination of lead in the environment include ], ], ] and ]. A specific ] has been developed based on the ionophore S,S'-methylenebis(N,N-diisobutyl]).{{sfn|Hauser|2017|pp=49–60}} | |||
| Anthropogenic lead includes lead from ] and ]. These are among the most potent sources of lead contamination along with lead production sites.{{sfn|United Nations Environment Programme|2010|p=9}} Lead was banned for shot and sinkers in the United States in 2017,{{sfn|McCoy|2017}} although that ban was only effective for a month,{{sfn|Cama|2017}} and a similar ban is being considered in the European Union.{{sfn|Layton|2017}} | |||
| Analytical methods for the determination of lead in the environment include ], ], ], and ]. A specific ] has been developed based on the ionophore ''S'',''S'''-methylenebis(''N'',''N''-diisobutyl]).{{sfn|Hauser|2017|pp=49–60}} An important biomarker assay for lead poisoning is ] levels in plasma, serum, and urine.{{sfn|Lauwerys|Hoet|2001|pp=115, 116–117}} | |||
| == Restriction and remediation == | == Restriction and remediation == | ||
| ] (northern France), highlighting lead shot. There are hundreds of lead pellets |
] (northern France), highlighting lead shot. There are hundreds of lead pellets (a dozen is enough to kill an adult swan within a few days). Such bodies are sources of environmental contamination by lead.|alt=An X-ray picture with numerous small pellets highlighted in white]] | ||
| By the mid-1980s, |
By the mid-1980s, there was significant decline in the use of lead in industry.<ref>{{cite web | url=https://www.epa.gov/archive/epa/aboutepa/lead-poisoning-historical-perspective.html | title=Lead Poisoning: A Historical Perspective }}</ref> In the United States, environmental regulations reduced or eliminated the use of lead in non-battery products, including gasoline, paints, solders, and water systems. ] were installed in ] to capture lead emissions.{{sfn|Trace element emission|2012}} In 1992, U.S. Congress required the Environmental Protection Agency to reduce the blood lead levels of the country's children.{{sfn|Auer|Kover|Aidala|Greenwood|2016|p=4}} Lead use was further curtailed by the European Union's 2003 ].{{sfn|Petzel|Juuti|Sugimoto|2004|pp=122–124}} A large drop in lead deposition occurred in the Netherlands after the 1993 national ban on use of lead shot for hunting and sport shooting: from 230 tonnes in 1990 to 47.5 tonnes in 1995.{{sfn|Deltares|Netherlands Organisation for Applied Scientific Research|2016}} The usage of lead in ] for ] is allowed in the EU as of 2022.<ref name="q566">{{cite web | last=Calderwood | first=Dave | title=Europe moves to ban lead in avgas | website=FLYER | date=8 March 2022 | url=https://flyer.co.uk/europe-moves-to-ban-lead-in-avgas/ | access-date=28 July 2024}}</ref> | ||
| In the United States, the ] for lead in the workplace, comprising metallic lead, inorganic lead compounds, and lead |
In the United States, the ] for lead in the workplace, comprising metallic lead, inorganic lead compounds, and lead soaps, was set at 50 μg/m<sup>3</sup> over an 8-hour workday, and the ] limit at 5 μg per 100 g of blood in 2012.{{sfn|Agency for Toxic Substances and Disease Registry|2017}} Lead may still be found in harmful quantities in stoneware,{{sfn|Grandjean|1978|pp=303–321}} ]{{sfn|Levin|Brown|Kashtock|Jacobs|2008|p=1288}} (such as that used for tubing and the insulation of electrical cords), and Chinese brass.{{efn|An alloy of ] (copper and zinc) with lead, iron, tin, and sometimes antimony.{{sfn|Duda|1996|p=242}}}} Old houses may still contain lead paint.{{sfn|Levin|Brown|Kashtock|Jacobs|2008|p=1288}} White lead paint has been ] in industrialized countries, but specialized uses of other pigments such as yellow ] remain,{{sfn|Crow|2007}} especially in road pavement marking paint.<ref>{{cite web |title=Lead Chromate: Why it is Banned in Most Industries Apart From Road Markings |url=https://www.roadtraffic-technology.com/contractors/road_marking/prismo2/pressreleases/presslead-chromate-why-it-is-banned-in-most-industries-apart-from-road-markings/ |website=Road Traffic Technology |publisher=Verdict Media Limited |access-date=2024-05-27 |archive-date=5 March 2024 |archive-url=https://web.archive.org/web/20240305012833/https://www.roadtraffic-technology.com/contractors/road_marking/prismo2/pressreleases/presslead-chromate-why-it-is-banned-in-most-industries-apart-from-road-markings/ |url-status=dead }}</ref> | ||
| Stripping old paint by sanding produces dust which can be inhaled.{{sfn|Marino|Landrigan|Graef|Nussbaum|1990|pp=1183–1185}} ] programs have been mandated by some authorities in properties where young children live.{{sfn|Schoch|1996|p=111}} The usage of lead in ] for ] is generally allowed in United States as of 2023.<ref name="b411">{{cite web | last=Davoren | first=Haley | title=From 100LL to G100UL: What comes next for avgas and why today is historic | website=Globalair.com | date=6 June 2023 | url=https://www.globalair.com/articles/from-100ll-to-g100ul-what-comes-next-for-avgas-and-why-today-is-historic?id=5971 | access-date=28 July 2024}}</ref> | |||
| Lead waste, depending |
Lead waste, depending on the jurisdiction and the nature of the waste, may be treated as household waste (to facilitate lead abatement activities),{{sfn|United States Environmental Protection Agency|2000}} or potentially hazardous waste requiring specialized treatment or storage.{{sfn|Lead in Waste|2016}} Lead is released into the environment in shooting places and a number of lead management practices have been developed to counter the lead contamination.{{sfn|United States Environmental Protection Agency|2005|p=I-1}} Lead migration can be enhanced in acidic soils; to counter that, it is advised soils be treated with lime to ] the soils and prevent leaching of lead.{{sfn|United States Environmental Protection Agency|2005|p=III-5–III-6}} | ||
| Research has been conducted on how to remove lead from ] by biological means: Fish bones are being researched for their ability to ] lead in contaminated soil.{{sfn|Freeman|2012|pp=a20–a21}}{{sfn|Young|2012}} The fungus '']'' is effective at absorbing lead ions from industrial waste before being released to water bodies.{{sfn|Acton|2013|pp=94–95}} Several bacteria have been researched for their ability to remove lead from the environment, including the ] '']'' and '']'', both of which are highly effective in aqueous solutions.{{sfn|Park|Bolan|Meghara|Naidu|2011|pp=162–174}} Millet grass '']'' has the ability to accumulate significant amounts of metals such as lead and ] in its shoot and root tissues making it an important plant for remediation of contaminated soils.<ref>{{cite journal |last1=Lakshmi |first1=P.M. |last2=Jaison |first2=S. |last3=Muthukumar |first3=T. |last4=Muthukumar |first4=M. |title=Assessment of metal accumulation capacity of Brachiaria ramosa collected from cement waste dumping area for the remediation of metal contaminated soil. |journal=Ecological Engineering |date=1 November 2013 |volume=60 |pages=96–98 |doi=10.1016/j.ecoleng.2013.07.043|bibcode=2013EcEng..60...96L }}</ref> | |||
| ==See also== | ==See also== | ||
| * ]– one of the earliest campaigners against lead in petrol in the UK | |||
| {{Portal|Chemistry|Mining}} | |||
| {{Subject bar | |||
| |book1=Lead | |||
| |book2=Period 6 elements | |||
| |book3=Carbon group | |||
| |book4=Chemical elements (sorted alphabetically) | |||
| |book5=Chemical elements (sorted by number)}} | |||
| * ] – discovered that the addition of ] to gasoline prevented ] in ]s | * ] – discovered that the addition of ] to gasoline prevented ] in ]s | ||
| * ] – instrumental in the banning of tetraethyllead in gasoline in the US and lead solder in food cans. | |||
| * ] – foremost medical advocate for the use of tetraethyllead as an additive in gasoline. | |||
| == Notes == | == Notes == | ||
| Line 438: | Line 450: | ||
| == References == | == References == | ||
| {{Reflist| |
{{Reflist|22em}} | ||
| == Bibliography == | == Bibliography == | ||
| {{sfn whitelist|CITEREFMeijaCoplenBerglundBrand2016}} <!-- belt and suspenders for infobox --> | |||
| {{Academic peer reviewed|Q56050531|doi-access=free}} | |||
| {{Refbegin |30em}} | {{Refbegin |30em}} | ||
| * {{cite book |editor-last=Acton |editor-first=Q. A. |title=Issues in Global Environment—Pollution and Waste Management: 2012 Edition |url=https://books.google.com/books?id=3n0yqmPRwh8C |date=2013 |publisher=] |isbn=978-1-4816-4665-9 |
* {{cite book |editor-last=Acton |editor-first=Q. A. |title=Issues in Global Environment—Pollution and Waste Management: 2012 Edition |url=https://books.google.com/books?id=3n0yqmPRwh8C |date=2013 |publisher=] |isbn=978-1-4816-4665-9 }} | ||
| * {{cite web |title=Information for the Community: Lead Toxicity |url=http://www.atsdr.cdc.gov/csem/lead/community/index.html |author= |
* {{cite web |title=Information for the Community: Lead Toxicity |url=http://www.atsdr.cdc.gov/csem/lead/community/index.html |author=Agency for Toxic Substances and Disease Registry |date=August 20, 2007 |type=MP4 webcast, 82 MB |access-date=11 February 2017 |author-link=Agency for Toxic Substances and Disease Registry |archive-date=16 October 2022 |archive-url=https://web.archive.org/web/20221016195615/https://www.atsdr.cdc.gov/csem/lead/community/index.html |url-status=dead }} | ||
| * {{cite web |title=Lead Toxicity. What Are U.S. Standards for Lead Levels? |url=https://www.atsdr.cdc.gov/csem/csem.asp?csem=34&po=8 |author=Agency for Toxic Substances and Disease Registry |year=2017 |access-date=12 June 2018 |archive-date=12 March 2020 |archive-url=https://web.archive.org/web/20200312005513/https://www.atsdr.cdc.gov/csem/csem.asp?csem=34&po=8 |url-status=dead }} | |||
| * {{cite book |last=Alsfasser |first=R. |title=Moderne anorganische Chemie |year=2007 |url=https://books.google.com/?id=HwY4be5bH_sC&dq=%5BPb4%5D4-+zintl#v=onepage&q&f=false |trans-title=Modern inorganic chemistry |publisher=Walter de Gruyter |isbn=978-3-11-019060-1 |language=German |ref=harv}} | |||
| * {{cite book |last=Alsfasser |first=R. |title=Moderne anorganische Chemie |year=2007 |url=https://books.google.com/books?id=HwY4be5bH_sC&q=%5BPb4%5D4-+zintl |trans-title=Modern inorganic chemistry |publisher=Walter de Gruyter |isbn=978-3-11-019060-1 |language=de }} | |||
| * {{cite web |url=https://eos.org/scientific-press/human-activity-has-polluted-european-air-for-2000-years |author=] |title=Human Activity Has Polluted European Air for 2000 Years |publisher=Eos Science News |year=2017 |ref=harv}} | |||
| * {{cite web |url=https://eos.org/scientific-press/human-activity-has-polluted-european-air-for-2000-years |author=American Geophysical Union |title=Human Activity Has Polluted European Air for 2000 Years |publisher=Eos Science News |year=2017 |author-link=American Geophysical Union |access-date=4 July 2017 |archive-date=27 June 2017 |archive-url=https://web.archive.org/web/20170627215417/https://eos.org/scientific-press/human-activity-has-polluted-european-air-for-2000-years |url-status=dead }} | |||
| * {{cite book |last=Amstock |first=J. S. |title=Handbook of Glass in Construction |date=1997 |isbn=978-0-07-001619-4 |publisher=] |url=https://books.google.com/?id=apWvKnKKrvsC |ref=harv}} | |||
| * {{cite book |last=Amstock |first=J. S. |title=Handbook of Glass in Construction |date=1997 |isbn=978-0-07-001619-4 |publisher=] |url=https://books.google.com/books?id=apWvKnKKrvsC }} | |||
| * {{cite journal |last=Anderson |first=J. |title=Malleability and ductility of metals |year=1869 |pages=341–43 |url=http://www.scientificamerican.com/article/malleability-and-ductility-of-metal/ |journal=] |volume=21 |issue=22 |doi=10.1038/scientificamerican11271869-341 |ref=harv}} | |||
| * {{cite journal | |
* {{cite journal |last=Anderson |first=J. |title=Malleability and ductility of metals |year=1869 |pages=341–43 |journal=] |volume=21 |issue=22 |doi=10.1038/scientificamerican11271869-341 |url=https://zenodo.org/record/1429682 }} | ||
| * {{cite journal |last1=Ashikari |first1=M. |title=The memory of the women's white faces: Japaneseness and the ideal image of women |date=2003 |pages=55–79 |doi=10.1080/0955580032000077739 |journal=] |volume=15 |issue=1|s2cid=144510689 }} | |||
| * {{cite book |last=Audsley |first=G. A. |authorlink=George Ashdown Audsley |title=The Art of Organ Building |year=1965 |url=https://books.google.com/?id=I0h525OVoTgC |isbn=978-0-486-21315-6 |volume=2 |publisher=Courier |ref=harv}} | |||
| * {{cite journal|last1=Assi|first1=M. A.|last2=Hezmee|first2=M. N. M.|last3=Haron|first3=A. W.|last4=Sabri|first4=M. Yu.|last5=Rajion|first5=M. A.|display-authors=3|title=The detrimental effects of lead on human and animal health|journal=]|volume=9|issue=6|year=2016|pages=660–671|issn=0972-8988|doi=10.14202/vetworld.2016.660-671|pmid=27397992|pmc=4937060}} | |||
| * {{cite book |last1=Baird |first1=C. |last2=Cann |first2=N. |title=Environmental Chemistry |date=2012 |publisher=W. H. Freeman and Company |isbn=978-1-4292-7704-4 |edition=5th |ref=harv}} | |||
| * {{cite report | first1=Charles M. | last1=Auer | first2=Frank D. | last2=Kover | first3=James V. | last3=Aidala | first4=Mark | last4=Greenwood | publisher=EPA Alumni Association | title=Toxic Substances: A Half Century of Progress | date=1 March 2016 | url=http://www.epaalumni.org/hcp/toxics.pdf | access-date=1 January 2019 }} | |||
| * {{cite journal |last1=Becker |first1=M. |last2=Förster |first2=C. |last3=Franzen |first3=C. |last4=Hartrath |first4=J. |last5=Kirsten |first5=E. |last6=Knuth |first6=J. |last7=Klinkhammer |first7=K. W. |last8=Sharma |first8=A. |last9=H. |first9=D. |title=Persistent radicals of trivalent tin and lead |year=2008 |pages=9965–78 |doi=10.1021/ic801198p |pmid=18823115 |journal=] |volume=47 |issue=21 |display-authors=3 |ref=harv}} | |||
| * {{cite book |last=Audsley |first=G. A. |author-link=George Ashdown Audsley |title=The Art of Organ Building |year=1965 |url=https://books.google.com/books?id=I0h525OVoTgC |isbn=978-0-486-21315-6 |volume=2 |publisher=Courier }} | |||
| * {{cite news |last1=Beeman |first1=J. W. |last2=Bellini |first2=F. |last3=Cardani |first3=L. |title=New experimental limits on the α decays of lead isotopes |year=2013 |journal=] |volume=49 |issue=50 |displayauthors=etal |ref=harv}} | |||
| * {{cite book |last1=Baird |first1=C. |last2=Cann |first2=N. |title=Environmental Chemistry |date=2012 |publisher=W. H. Freeman and Company |isbn=978-1-4292-7704-4 |edition=5th}} | |||
| * {{cite journal |last1=Beiner |first1=G. G. |last2=Lavi |first2=M. |last3=Seri |first3=H. |displayauthors=3 |last4=Rossin |first4=Anna |last5=Lev |first5=Ovadia |last6=Gun |first6=Jenny |last7=Rabinovich |first7=Rivka |title=Oddy Tests: Adding the Analytical Dimension |journal=Collection Forum |volume=29 |issue=1–2 |year=2015 |pages=22–36 |issn=0831-4985 |doi=10.14351/0831-4985-29.1.22 |ref=harv}} | |||
| * {{cite journal |last1=Becker |first1=M. |last2=Förster |first2=C. |last3=Franzen |first3=C. |last4=Hartrath |first4=J. |last5=Kirsten |first5=E. |last6=Knuth |first6=J. |last7=Klinkhammer |first7=K. W. |last8=Sharma |first8=A. |last9=H. |first9=D. |title=Persistent radicals of trivalent tin and lead |year=2008 |pages=9965–78 |doi=10.1021/ic801198p |pmid=18823115 |journal=] |volume=47 |issue=21 |display-authors=3}} | |||
| * {{cite book |last1=Bisel |first1=S. C. |authorlink1=Sara C. Bisel |last2=Bisel |first2=J. F. |chapter=Health and nutrition at Herculaneum |title=The Natural History of Pompeii |year=2002 |pages=451–75 |publisher=] |isbn=978-0-521-80054-9 |editor-first1=W. F. |editor-last1=Jashemski |editor-first2=F. G. |editor-last2=Meyer |url=https://books.google.com/?id=3xfjyTqqR7IC |ref=harv}} | |||
| * {{cite journal |last1=Beeman |first1=J. W. |last2=Bellini |first2=F. |last3=Cardani |first3=L. |last4=Casali |first4=N. |title=New experimental limits on the ''α'' decays of lead isotopes |year=2013 |journal=] |volume=49 |issue=50 |pages=50 |display-authors=3|doi=10.1140/epja/i2013-13050-7|arxiv=1212.2422 |bibcode=2013EPJA...49...50B |s2cid=119280082 }} | |||
| * {{cite book |last1=Bisson |first1=M. S. |last2=Vogel |first2=J. O. |title=Ancient African Metallurgy: The Sociocultural Context |year=2000 |isbn=978-0-7425-0261-1 |publisher=] |url=https://books.google.com/?id=oMgkHFiBTMEC&printsec=frontcover&dq=ancient+african+metallurgy#v=onepage&q=lead&f=false |ref=harv}} | |||
| * {{cite journal |last1=Beiner |first1=G. G. |last2=Lavi |first2=M. |last3=Seri |first3=H. |display-authors=3 |last4=Rossin |first4=Anna |last5=Lev |first5=Ovadia |last6=Gun |first6=Jenny |last7=Rabinovich |first7=Rivka |title=Oddy Tests: Adding the Analytical Dimension |journal=] |volume=29 |issue=1–2 |year=2015 |pages=22–36 |issn=0831-4985 |doi=10.14351/0831-4985-29.1.22|doi-access=free }} | |||
| * {{cite book |last=Blakemore |first=J. S. |title=Solid State Physics |year=1985 |url=https://books.google.com/books?id=yLwIYiWo0VYC |publisher=Cambridge University Press |isbn=978-0-521-31391-9 |ref=harv}} | |||
| * {{Cite book|last1=Bharara|first1=M. S. |last2=Atwood |first2=D. A. |title=Lead: Inorganic Chemistry |year=2006 |doi=10.1002/0470862106.ia118 |chapter=Lead: Inorganic ChemistryBased in part on the article Lead: Inorganic Chemistry by Philip G. Harrison which appeared in the Encyclopedia of Inorganic Chemistry, First Edition|isbn=978-0470860786}} | |||
| * {{cite book |first=M. |last=Burleson |publisher=] |location=New York, NY |title=The Ceramic Glaze Handbook: Materials, Techniques, Formulas |year=2001 |ref=harv |url=https://books.google.com/books?id=PiJEAhMxLQgC&printsec=frontcover#v=onepage&q&f=false|isbn=9781579904395 }} | |||
| * {{cite book |last1=Bisel |first1=S. C. |author-link1=Sara C. Bisel |last2=Bisel |first2=J. F. |chapter=Health and nutrition at Herculaneum |title=The Natural History of Pompeii |year=2002 |pages=451–75 |publisher=] |isbn=978-0-521-80054-9 |editor-first1=W. F. |editor-last1=Jashemski |editor-first2=F. G. |editor-last2=Meyer |chapter-url=https://books.google.com/books?id=3xfjyTqqR7IC }} | |||
| * {{cite book |last=Bremner |first=H. A. |title=Safety and Quality Issues in Fish Processing |url=https://books.google.com/books?id=7pKkAgAAQBAJ |year=2002 |publisher=] |isbn=978-1-85573-678-8 |ref=harv}} | |||
| * {{cite book |last1= |
* {{cite book |last1=Bisson |first1=M. S. |last2=Vogel |first2=J. O. |title=Ancient African Metallurgy: The Sociocultural Context |year=2000 |isbn=978-0-7425-0261-1 |publisher=] |url=https://books.google.com/books?id=oMgkHFiBTMEC&q=lead }} | ||
| * {{cite book |last= |
* {{cite book |last=Blakemore |first=J. S. |title=Solid State Physics |year=1985 |url=https://books.google.com/books?id=yLwIYiWo0VYC |publisher=Cambridge University Press |isbn=978-0-521-31391-9 }} | ||
| * {{cite journal|last1=Bouchard|first1=M. F.|last2=Bellinger|first2=D. C.|last3=Weuve|first3=J.|last4=Matthews-Bellinger|first4=Julia|last5=Gilman|first5=Stephen E.|last6=Wright|first6=Robert O.|last7=Schwartz |first7=Joel |last8=Weisskopf|first8=Marc G.|display-authors=3|title=Blood Lead Levels and Major Depressive Disorder, Panic Disorder, and Generalized Anxiety Disorder in US Young Adults|journal=]|volume=66|issue=12 |year=2009|pages=1313–9|issn=0003-990X|doi=10.1001/archgenpsychiatry.2009.164|pmid=19996036|pmc=2917196}} | |||
| * {{cite book |last1=Bunker |first1=B. C. |last2=Casey |first2=W. H. |title=The Aqueous Chemistry of Oxides |date=2016 |publisher=] |isbn=978-0-19-938425-9 |url=https://books.google.com/books?id=BfhGCwAAQBAJ&pg=PA89 |ref=harv}} | |||
| * {{cite book |last=Bremner |first=H. A. |title=Safety and Quality Issues in Fish Processing |url=https://books.google.com/books?id=7pKkAgAAQBAJ |year=2002 |publisher=] |isbn=978-1-85573-678-8 }} | |||
| * {{cite journal |last1=Burbidge |first1=E. M. |last2=Burbidge |first2=G. R. |last3=Fowler |first3=W. A. |last4=Hoyle |first4=F. |title=Synthesis of the Elements in Stars |year=1957 |pages=547–654 |display-authors=3 |journal=] |volume=29 |issue=4 |bibcode=1957RvMP...29..547B |doi=10.1103/RevModPhys.29.547 |url=https://www.pmf.unizg.hr/_download/repository/burbidge_RMP_29_547_1957.pdf |ref=harv |format=PDF}} | |||
| * {{cite book |last1=Brenner |first1=G. A. |title=Webster's New World American Idioms Handbook |date=2003 |publisher=] |isbn=978-0-7645-2477-6}} | |||
| * {{cite web |url=https://www.wildlife.ca.gov/hunting/nonlead-ammunition |title=Nonlead Ammunition in California |website=www.wildlife.ca.gov |author=] |access-date=17 May 2017 |ref=harv}} | |||
| * {{cite book|last=Brescia|first=F.|title=Fundamentals of Chemistry: A Modern Introduction|url=https://books.google.com/books?id=fjqeMl-xSg4C&pg=PA234|year=2012|publisher=Elsevier|isbn=978-0-323-14231-1}} | |||
| * {{cite journal |last=de Callataÿ |first=F. |title=The Graeco-Roman economy in the super long-run: Lead, copper, and shipwrecks |date=2005 |pages=361–72 |journal=] |volume=18 |doi=10.1017/S104775940000742X |ref=harv}} | |||
| * {{cite |
* {{cite book |last=Bretherick |first=L. |title=Bretherick's Handbook of Reactive Chemical Hazards |url=https://books.google.com/books?id=4_PJCgAAQBAJ |year=2016 |publisher=Elsevier |isbn=978-1-4831-6250-8 }} | ||
| * {{cite book |last1=Bunker |first1=B. C. |last2=Casey |first2=W. H. |title=The Aqueous Chemistry of Oxides |date=2016 |publisher=] |isbn=978-0-19-938425-9 |url=https://books.google.com/books?id=BfhGCwAAQBAJ&pg=PA89 }} | |||
| * {{cite journal |author=] |year=1997 |title=Update: blood lead levels--United States, 1991-1994 |journal=] |volume=46 |issue=7 |pages=141–146 |issn=0149-2195 |pmid=9072671 |ref=CITEREFCenters for Disease Control and Prevention1997}} | |||
| * {{cite journal |last1=Burbidge |first1=E. M. |author-link1=Margaret Burbidge |last2=Burbidge |first2=G. R. |author-link2=Geoffrey Burbidge |last3=Fowler |first3=W. A. |author-link3=William Alfred Fowler |last4=Hoyle |first4=F. |author-link4=Fred Hoyle |title=Synthesis of the Elements in Stars |year=1957 |pages=547–654 |display-authors=3 |journal=] |volume=29 |issue=4 |bibcode=1957RvMP...29..547B |doi=10.1103/RevModPhys.29.547 |doi-access=free }} | |||
| * {{cite web |title=Radiation and Your Health |year=2015 |url=https://www.cdc.gov/nceh/radiation/smoking.htm |author=Centers for Disease Control and Prevention |access-date=28 February 2017 |ref=CITEREFCenters for Disease Control and Prevention2015}} | |||
| * {{cite book | |
* {{cite book |first=M. |last=Burleson |publisher=] |title=The Ceramic Glaze Handbook: Materials, Techniques, Formulas |year=2001 |url=https://books.google.com/books?id=PiJEAhMxLQgC |isbn=9781579904395 }} | ||
| * {{cite web |url=https://www.wildlife.ca.gov/hunting/nonlead-ammunition |title=Nonlead Ammunition in California |website=www.wildlife.ca.gov |author=California Department of Fish and Wildlife |access-date=17 May 2017 |author-link=California Department of Fish and Wildlife }} | |||
| * {{cite web |author=Copper Development Association |title=Leaded Coppers |url=http://www.copper.org/resources/properties/microstructure/cu_leaded.html |website=copper.org |access-date=10 July 2016 |ref=harv}} | |||
| * {{cite journal |last=de Callataÿ |first=F. |title=The Graeco-Roman economy in the super long-run: Lead, copper, and shipwrecks |date=2005 |pages=361–72 |journal=] |volume=18 |doi=10.1017/S104775940000742X|s2cid=232346123 }} | |||
| * {{cite book |last=Cotnoir |first1=B. |title=The Weiser Concise Guide to Alchemy |date=2006 |publisher=] |isbn=978-1-57863-379-1 |ref=harv |url=https://books.google.com/books?id=BPWDrnEJ7UsC&printsec=frontcover}} | |||
| * {{cite news |last=Cama |first=T. |date=2017 |title=Interior secretary repeals ban on lead bullets |url=https://thehill.com/policy/energy-environment/322058-interior-secretary-repeals-ban-on-lead-ammunition/ |website=] |access-date=30 May 2018 }} | |||
| * {{cite book |last=Cox |first=P. A. |date=1997 |title=The Elements: Their Origin, Abundance and Distribution |publisher=Oxford University Press |isbn=978-0-19-855298-7 |ref=harv}} | |||
| * {{cite |
* {{cite book|last1=Cangelosi|first1=V. M.|last2=Pecoraro|first2=V. L.|editor-last=Roduner|editor-first=E.|year=2015|title=Nanoscopic Materials: Size-Dependent Phenomena and Growth Principles|chapter=Lead|chapter-url=https://books.google.com/books?id=kGsoDwAAQBAJ&pg=PA875|publisher=Royal Society of Chemistry|isbn=978-1-78262-494-3|pages=843–875}} | ||
| * {{cite news|last=Casciani|first=D.|title=Did removing lead from petrol spark a decline in crime?|date=2014|url=https://www.bbc.com/news/magazine-27067615|work=]|access-date=30 January 2017}} | |||
| * {{cite book |last1=Dart |first1=R. C. |last2=Hurlbut |first2=K. M. |last3=Boyer-Hassen |first3=L. V. |chapter=Lead |title=Medical Toxicology |year=2004 |page=1426 |editor-last=Dart |editor-first=R. C. |edition=3rd |publisher=] |isbn=978-0-7817-2845-4 |ref=harv}} | |||
| * {{Cite book|last=Calvo Rebollar|first=Miguel|year=2019 |title=Construyendo la Tabla Periódica |publisher=Prames |isbn=978-84-8321-908-9|location=Zaragoza, Spain}} | |||
| * {{cite book |first1=A. |last1=Davidson |first2=J. |last2=Ryman |first3=C. A. |last3=Sutherland |first4=E. F. |last4=Milner |first5=R. C. |last5=Kerby |first6=H. |last6=Teindl |first7=A. |last7=Melin |first8=H. M. |last8=Bolt |chapter=Lead |title=Ullmann's Encyclopedia of Industrial Chemistry |year=2014 |doi=10.1002/14356007.a15_193.pub3 |displayauthors=3 |isbn=978-3-527-30673-2 |ref=harv}} | |||
| * {{cite book|last=Ceccarelli|first=P.|title=Ancient Greek Letter Writing: A Cultural History (600 BC- 150 BC)|url=https://books.google.com/books?id=Vm5BAQAAQBAJ&pg=PA35|year=2013|publisher=OUP Oxford|isbn=978-0-19-967559-3}} | |||
| * {{cite journal |last=Delile |first=H. |last2=Blichert-Toft |first2=J. |last3=Goiran |first3=J.-P. |last4=Keay |first4=Simon |last5=Albarède |first5=Francis |title=Lead in ancient Rome's city waters |date=2014 |pages=6594–99 |displayauthors=3 |url=http://www.pnas.org/content/111/18/6594 |journal=] |volume=111 |issue=18 |doi=10.1073/pnas.1400097111 |issn=0027-8424 |pmc=4020092 |pmid=24753588 |ref=harv|bibcode=2014PNAS..111.6594D }} | |||
| * {{cite journal |author=Centers for Disease Control and Prevention |year=1997 |title=Update: blood lead levels--United States, 1991-1994 |journal=] |volume=46 |issue=7 |pages=141–146 |issn=0149-2195 |pmid=9072671 |author-link=Centers for Disease Control and Prevention }} | |||
| * {{cite report |author1=Deltares |author2=] |title=Lood en zinkemissies door jacht |year=2016 |url=http://www.emissieregistratie.nl/ERPUBLIEK/documenten/Water/Factsheets/Nederlands/Lood-%20en%20zinkemissies%20door%20jacht.pdf |language=Dutch |format=PDF |trans-title=Lead and zinc emissions from hunting |access-date=18 February 2017 |ref=harv}} | |||
| * {{cite web |title=Radiation and Your Health |year=2015 |url=https://www.cdc.gov/nceh/radiation/smoking.htm |author=Centers for Disease Control and Prevention |access-date=28 February 2017 }} | |||
| * {{cite book |last1=Dieter |first1=R. K. |last2=Watson |first2=R. T. |chapter=Transmetalation reactions producing organocopper compounds |pages=443–526 |editor-last1=Rappoport |editor-first1=Z. |editor-last2=Marek |editor-first2=I. |title=The Chemistry of Organocopper Compounds |volume=1 |year=2009 |publisher=John Wiley & Sons |isbn=978-0-470-77296-6 |url=https://books.google.com/?id=263AXB0Q6tAC |ref=harv}} | |||
| * {{Cite web |title=Making Cents of Currency's Ancient Rise |author=Chapurukha Kusimba |date=June 20, 2017 |work=Smithsonian Magazine |access-date=5 November 2021 |url=https://www.smithsonianmag.com/history/making-cents-currencys-ancient-rise-180963776/ }} | |||
| * {{cite book |last=Donnelly |first=J. |title=Deep Blue |url=https://books.google.com/books?id=SKtbAwAAQBAJ |year=2014 |publisher=] |isbn=978-1-4449-2119-9 |ref=harv}} | |||
| * {{cite book |last=Christensen |first=N. E. |chapter=Relativistic Solid State Theory |title=Relativistic Electronic Structure Theory — Fundamentals |volume=11 |year=2002 |pages=867–68 |chapter-url=https://books.google.com/books?id=9tO_9Tf6dZgC |editor-last=Schwerdtfeger |editor-first=P. |publisher=Elsevier |isbn=978-0-08-054046-7 |doi=10.1016/s1380-7323(02)80041-3 |series=Theoretical and Computational Chemistry }} | |||
| * {{cite book |last=Duda |first1=M. B. |title=Traditional Chinese Toggles: Counterweights and Charms |date=1996 |publisher=Editions Didier Millet |isbn=978-981-4260-61-9 |ref=harv}} | |||
| * {{cite book |last1= |
* {{cite book |last1=Claudio |first1=Elizabeth S. |last2=Godwin |first2=Hilary Arnold |last3=Magyar |first3=John S. |title=Progress in Inorganic Chemistry, Volume 51 |year=2002 |publisher=John Wiley & Sons, Inc. |isbn=978-0-471-26534-4 |pages=1–144 |url=https://onlinelibrary.wiley.com/doi/abs/10.1002/0471267287.ch1 |language=en |chapter=Fundamental Coordination Chemistry, Environmental Chemistry, and Biochemistry of Lead(II) |doi=10.1002/0471267287.ch1 }} | ||
| * {{cite journal |last1=Cohen |first1=A. R. |last2=Trotzky |first2=M. S. |last3=Pincus |first3=D. |title=Reassessment of the Microcytic Anemia of Lead Poisoning |date=1981 |pages=904–906 |url=http://pediatrics.aappublications.org/content/67/6/904.abstract |journal=] |volume=67 |issue=6 |doi=10.1542/peds.67.6.904 |pmid=7232054 |s2cid=42146120 |url-access=subscription }} | |||
| * {{cite book |last=Emsley |first=J. |authorlink=John Emsley |title=Nature's Building Blocks: An A-Z Guide to the Elements |year=2011 |publisher=Oxford University Press |isbn=978-0-19-960563-7 |ref=harv}} | |||
| * {{cite book|author1=Committee on Evaluation of EPA Guidelines for Exposure to Naturally Occurring Radioactive Materials|author2=Commission on Life Sciences|author3=Division on Earth and Life Studies|author4=National Research Council|title=Evaluation of Guidelines for Exposures to Technologically Enhanced Naturally Occurring Radioactive Materials|url=https://books.google.com/books?id=8uhuAgAAQBAJ&pg=PA26|date=1999|publisher=National Academies Press|isbn=978-0-309-58070-0|pages=26, 30–32}} | |||
| * {{cite book |last1=Eschnauer |first1=H. R. |last2=Stoeppler |first2=M. |chapter=Wine—An enological specimen bank |title=Hazardous Materials in the Environment |year=1992 |pages=49–72 (58) |publisher=Elsevier Science |isbn=978-0-444-89078-8 |editor-last=Stoeppler |editor-first=M. |ref=harv}} | |||
| * {{cite report |author=] |title=Lead acid batteries |url=https://www.concordia.ca/content/dam/concordia/services/safety/docs/EHS-DOC-146_LeadAcidBatteries.pdf |year=2016 |access-date=17 February 2019 }} | |||
| * {{cite journal |last1=Evans |first1=J. W. |authorlink=John William Evans (geologist) |title=V.— The meanings and synonyms of plumbago |date=1908 |pages=133–79 |doi=10.1111/j.1467-968X.1908.tb00513.x |journal=] |volume=26 |issue=2 |ref=harv}} | |||
| * {{cite book |
* {{cite book|last1=Considine|first1=D. M.|last2=Considine|first2=G. D.|title=Van Nostrand's Scientific Encyclopedia|url=https://books.google.com/books?id=t4jjBwAAQBAJ&pg=PA2970|date=2013|publisher=Springer Science & Business Media|isbn=978-1-4757-6918-0}} | ||
| * {{cite |
* {{cite web |author=Copper Development Association |title=Leaded Coppers |url=http://www.copper.org/resources/properties/microstructure/cu_leaded.html |website=copper.org |access-date=10 July 2016 }} | ||
| * {{cite book | |
* {{cite book |last1=Cotnoir |first1=B. |title=The Weiser Concise Guide to Alchemy |date=2006 |publisher=] |isbn=978-1-57863-379-1 |url=https://books.google.com/books?id=BPWDrnEJ7UsC }} | ||
| * {{cite book |last= |
* {{cite book |last=Cox |first=P. A. |date=1997 |title=The Elements: Their Origin, Abundance and Distribution |url=https://archive.org/details/elementstheirori0000coxp |url-access=registration |publisher=Oxford University Press |isbn=978-0-19-855298-7 }} | ||
| * {{cite |
* {{cite news |last=Crow |first=J. M. |title=Why use lead in paint? |year=2007 |url=https://www.chemistryworld.com/news/why-use-lead-in-paint/1015354.article |newspaper=] |access-date=22 February 2017 |publisher=] }} | ||
| * {{cite book |last1=Dart |first1=R. C. |last2=Hurlbut |first2=K. M. |last3=Boyer-Hassen |first3=L. V. |chapter=Lead |title=Medical Toxicology |year=2004 |page=1426 |editor-last=Dart |editor-first=R. C. |edition=3rd |publisher=] |isbn=978-0-7817-2845-4}} | |||
| * {{cite journal |last1=Funke |first1=K. |title=Solid State Ionics: from Michael Faraday to green energy—the European dimension |journal=] |volume=14 |issue=4 |year=2013 |pages=1–50 |doi=10.1088/1468-6996/14/4/043502 |ref=harv|bibcode=2013STAdM..14d3502F }} | |||
| * {{cite book |first1=A. |last1=Davidson |first2=J. |last2=Ryman |first3=C. A. |last3=Sutherland |first4=E. F. |last4=Milner |first5=R. C. |last5=Kerby |first6=H. |last6=Teindl |first7=A. |last7=Melin |first8=H. M. |last8=Bolt |chapter=Lead |title=Ullmann's Encyclopedia of Industrial Chemistry |year=2014 |doi=10.1002/14356007.a15_193.pub3 |display-authors=3 |isbn=978-3-527-30673-2}} | |||
| * {{cite book |last=Gale |first=W. F. |last2=Totemeier |first2=T. C. |title=Smithells Metals Reference Book |year=2003 |url=https://books.google.com/books?id=zweHvqOdcs0C |publisher=] |isbn=978-0-08-048096-1 |ref=harv}} | |||
| * {{cite journal |last1=de Marcillac |first1=Pierre |last2=Coron |first2=Noël |last3=Dambier |first3=Gérard |last4=Leblanc |first4=Jacques |last5=Moalic |first5=Jean-Pierre |title=Experimental detection of α-particles from the radioactive decay of natural bismuth |date=2003 |pages=876–78 |display-authors=3 |journal=] |volume=422 |pmid=12712201 |doi=10.1038/nature01541 |issue=6934 |bibcode=2003Natur.422..876D|s2cid=4415582 }} | |||
| * {{cite journal |last=Gilfillan |first=S. C. |title=Lead poisoning and the fall of Rome |date=1965 |pages=53–60 |journal=Journal of Occupational Medicine |volume=7 |number=2 |issn=0096-1736 |pmid=14261844 |ref=harv}} | |||
| * {{cite journal |last1=Delile |first1=H. |last2=Blichert-Toft |first2=J. |last3=Goiran |first3=J.-P. |last4=Keay |first4=Simon |last5=Albarede |first5=Francis |title=Lead in ancient Rome's city waters |date=2014 |pages=6594–99 |display-authors=3 |journal=] |volume=111 |issue=18 |doi=10.1073/pnas.1400097111 |issn=0027-8424 |pmc=4020092 |pmid=24753588|bibcode=2014PNAS..111.6594D |doi-access=free }} | |||
| * {{cite book |last1=Gill |first1=T. |author2=Libraries Board of South Australia |title=The history and topography of Glen Osmond, with map and illustrations |url=https://books.google.com/books?id=oSMQAAAAYAAJ |year=1974 |publisher=Libraries Board of South Australia |ref=harv}} | |||
| * {{cite report |author1=Deltares |author2=] |title=Lood en zinkemissies door jacht |year=2016 |trans-title=Lead and zinc emissions from hunting |url=http://www.emissieregistratie.nl/ERPUBLIEK/documenten/Water/Factsheets/Nederlands/Lood-%20en%20zinkemissies%20door%20jacht.pdf |archive-url=https://wayback.archive-it.org/all/20190412090130/http://www.emissieregistratie.nl/ERPUBLIEK/documenten/Water/Factsheets/Nederlands/Lood-%20en%20zinkemissies%20door%20jacht.pdf |url-status=dead |archive-date=12 April 2019 |language=nl |access-date=18 February 2017 }} | |||
| * {{cite report |last1=Graedel |first1=T. E. |title=Metal stocks in Society – Scientific Synthesis |year=2010 |url=http://www.unep.fr/shared/publications/pdf/DTIx1264xPA-Metal%20stocks%20in%20society.pdf |isbn=978-92-807-3082-1 |publisher=International Resource Panel |accessdate=18 April 2017 |page=17 |display-authors=etal<!--only mentions the lead author; others are not named--> |ref=harv |format=PDF}} | |||
| * {{cite book |last1=Dieter |first1=R. K. |last2=Watson |first2=R. T. |chapter=Transmetalation reactions producing organocopper compounds |pages=443–526 |editor-last1=Rappoport |editor-first1=Z. |editor-last2=Marek |editor-first2=I. |title=The Chemistry of Organocopper Compounds |volume=1 |year=2009 |publisher=John Wiley & Sons |isbn=978-0-470-77296-6 |chapter-url=https://books.google.com/books?id=263AXB0Q6tAC }} | |||
| * {{cite journal |last1=Grandjean |first1=P. |authorlink=Philippe Grandjean (professor) |title=Widening perspectives of lead toxicity |year=1978 |pages=303–21 |journal=Environmental Research |volume=17 |issue=2 |doi=10.1016/0013-9351(78)90033-6 |pmid=400972 |ref=harv|bibcode=1978ER.....17..303G }} | |||
| * {{cite |
* {{cite book |last=Donnelly |first=J. |title=Deep Blue |url=https://books.google.com/books?id=SKtbAwAAQBAJ |year=2014 |publisher=] |isbn=978-1-4449-2119-9 }} | ||
| * {{cite book |
* {{cite book|last1=Downs|first1=A. J.|last2=Adams|first2=C. J.|title=The Chemistry of Chlorine, Bromine, Iodine and Astatine: Pergamon Texts in Inorganic Chemistry|url=https://books.google.com/books?id=jQNPDAAAQBAJ&pg=PA1128|year=2017|publisher=Elsevier|isbn=978-1-4831-5832-7}} | ||
| * {{cite book |last1=Duda |first1=M. B. |title=Traditional Chinese Toggles: Counterweights and Charms |date=1996 |publisher=Editions Didier Millet |isbn=978-981-4260-61-9}} | |||
| * {{cite web |last=Grout |first=J. |title=Lead poisoning and Rome |date=2017 |url=http://penelope.uchicago.edu/~grout/encyclopaedia_romana/wine/leadpoisoning.html |website=Encyclopaedia Romana |access-date=15 February 2017 |ref=harv}} | |||
| * {{cite book |last1=Ede |first1=A. |last2=Cormack |first2=L. B. |title=A History of Science in Society, Volume I: From the Ancient Greeks to the Scientific Revolution, Third Edition |url=https://books.google.com/books?id=gFZrDQAAQBAJ |year=2016 |publisher=] |isbn=978-1-4426-3503-6 }} | |||
| * {{cite report |last=Guberman |first=D. E. |chapter=Lead |title=2014 Minerals Yearbook |year=2016 |url=https://minerals.usgs.gov/minerals/pubs/commodity/lead/myb1-2014-lead.pdf |publisher=] |access-date=8 May 2017 |ref=harv |format=PDF}} | |||
| * {{cite book |last= |
* {{cite book |last=Emsley |first=J. |author-link=John Emsley |title=Nature's Building Blocks: An A-Z Guide to the Elements |year=2011 |publisher=Oxford University Press |isbn=978-0-19-960563-7}} | ||
| *{{Cite web|url=https://www.jewishvirtuallibrary.org/ossuaries-and-sarcophagi|title=Encyclopedia Judaica: Ossuaries and Sarcophagi|website=www.jewishvirtuallibrary.org|access-date=14 July 2018|ref=CITEREFOssuaries and Sarcophagi}} | |||
| * {{cite book |last=Guruswamy |first=S. |title=Engineering properties and applications of lead alloys |date=2000 |url=https://books.google.com/?id=TtGmjOv9CUAC |isbn=978-0-8247-8247-4 |publisher=Marcel Dekker |ref=harv}} | |||
| * {{cite book |last1=Eschnauer |first1=H. R. |last2=Stoeppler |first2=M. |chapter=Wine—An enological specimen bank |title=Hazardous Materials in the Environment |year=1992 |pages=49–72 (58) |publisher=Elsevier Science |isbn=978-0-444-89078-8 |editor-last=Stoeppler |editor-first=M.|doi=10.1016/s0167-9244(08)70103-3}} | |||
| * {{cite book |last=Hadlington |first=T. J. |title=On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes |url=https://books.google.com/books?id=KQshDgAAQBAJ |year=2017 |publisher=Springer |isbn=978-3-319-51807-7 |ref=harv}} | |||
| * {{cite journal |last1=Evans |first1=J. W. |author-link=John William Evans (geologist) |title=V.— The meanings and synonyms of plumbago |date=1908 |pages=133–79 |doi=10.1111/j.1467-968X.1908.tb00513.x |journal=] |volume=26 |issue=2 |url=https://zenodo.org/record/2111957 }} | |||
| * {{cite book |last1=Harbison |first1=R. D. |last2=Bourgeois |first2=M. M. |last3=Johnson |first3=G. T. |title=Hamilton and Hardy's Industrial Toxicology |date=2015 |publisher=John Wiley & Sons |isbn=978-0-470-92973-5 |ref=harv}} | |||
| * {{cite book |last=Finger |first=S. |title=Doctor Franklin's Medicine |url=https://archive.org/details/doctorfranklinsm0000fing |url-access=registration |year=2006 |publisher=] |isbn=978-0-8122-3913-3 }} | |||
| * {{cite book |last1=Hauser |first1=P. C. |chapter=Analytical Methods for the Determination of Lead in the Environment |publisher=] |publication-date=2017 |series=Metal Ions in Life Sciences |volume=17 |title=Lead: Its Effects on Environment and Health |editor1-last=Astrid |editor1-first=S. |editor2-last=Helmut |editor2-first=S. |editor3-last=Sigel |editor3-first=R. K. O. |doi=10.1515/9783110434330-003 |ref=harv}} | |||
| * {{cite journal |last= |
* {{cite journal |last=Fiorini |first=E. |title=2.000 years-old Roman Lead for physics |date=2010 |pages=7–8 |url=http://www.aspera-eu.org/images/stories/news/PAPER_VERSIONS/asperanewsletter0610.pdf |journal=] |access-date=29 October 2016 |archive-date=26 April 2018 |archive-url=https://web.archive.org/web/20180426184739/http://www.aspera-eu.org/images/stories/news/PAPER_VERSIONS/asperanewsletter0610.pdf |url-status=dead }} | ||
| * {{cite book |last=Frankenburg |first=F. R. |title=Brain-Robbers: How Alcohol, Cocaine, Nicotine, and Opiates Have Changed Human History |year=2014 |url=https://books.google.com/books?id=9cqUAwAAQBAJ |publisher=ABC-CLIO |isbn=978-1-4408-2932-1 }} | |||
| * {{cite web |title=A History of Cosmetics from Ancient Times |url=http://www.cosmeticsinfo.org/Ancient-history-cosmetics |website=Cosmetics Info |access-date=18 July 2016 |ref=CITEREFHistory of Cosmetics}} | |||
| * {{cite book |last=Frebel |first=A. |author-link=Anna Frebel |title=Searching for the Oldest Stars: Ancient Relics from the Early Universe |year=2015 |publisher=Princeton University |isbn=978-0-691-16506-6}} | |||
| * {{cite journal |last=Hodge |first=T. A. |title=Vitruvius, lead pipes and lead poisoning |year=1981 |pages=486–91 |publisher=Archaeological Institute of America |volume=85 |issue=4 |jstor=504874 |journal=] |doi=10.2307/504874 |ref=harv}} | |||
| * {{cite journal |last=Freeman |first=K. S. |title=Remediating soil lead with fishbones |date=2012 |pages=a20–a21 |journal=] |pmc=3261960 |volume=120 |issue=1 |doi=10.1289/ehp.120-a20a |pmid=22214821}} | |||
| * {{cite journal |last1=Hong |first1=S. |last2=Candelone |first2=J.-P. |last3=Patterson |first3=C. C. |last4=Boutron |first4=C. F. |title=Greenland ice evidence of hemispheric lead pollution two millennia ago by Greek and Roman civilizations |date=1994 |pages=1841–43 |doi=10.1126/science.265.5180.1841 |url=http://www.precaution.org/lib/greenland_ice_evidence_of_ancient_lead_pollution.19940923.pdf |display-authors=3 |journal=] |volume=265 |issue=5180 |pmid=17797222 |bibcode=1994Sci...265.1841H |ref=harv |format=PDF}} | |||
| * {{cite journal |last1=Funke |first1=K. |title=Solid State Ionics: from Michael Faraday to green energy—the European dimension |journal=] |volume=14 |issue=4 |year=2013 |pages=1–50 |doi=10.1088/1468-6996/14/4/043502 |pmid=27877585 |pmc=5090311|bibcode=2013STAdM..14d3502F }} | |||
| * {{cite book |last=Hunt |first=A. |title=Dictionary of Chemistry |url=https://books.google.com/books?id=P_lRAwAAQBAJ |year=2014 |publisher=] |isbn=978-1-135-94178-9 |ref=harv}} | |||
| * {{cite book |last1=Gale |first1=W. F. |last2=Totemeier |first2=T. C. |title=Smithells Metals Reference Book |year=2003 |url=https://books.google.com/books?id=zweHvqOdcs0C |publisher=] |isbn=978-0-08-048096-1 }} | |||
| * {{cite web |url=https://www-nds.iaea.org/relnsd/vcharthtml/VChartHTML.html |title=Livechart - Table of Nuclides - Nuclear structure and decay data |author=IAEA - Nuclear Data Section |year=2017 |website=www-nds.iaea.org |publisher=] |access-date=31 March 2017 |ref=harv}} | |||
| * {{cite |
* {{cite journal |last=Gilfillan |first=S. C. |title=Lead poisoning and the fall of Rome |date=1965 |pages=53–60 |journal=] |volume=7 |number=2 |issn=0096-1736 |pmid=14261844}} | ||
| * {{cite book |last1= |
* {{cite book |last1=Gill |first1=T. |author2=Libraries Board of South Australia |title=The history and topography of Glen Osmond, with map and illustrations |url=https://books.google.com/books?id=oSMQAAAAYAAJ |year=1974 |publisher=Libraries Board of South Australia |isbn=9780724300358 }} | ||
| * {{cite report |last1=Graedel |first1=T. E. |title=Metal stocks in Society – Scientific Synthesis |year=2010 |url=http://www.unep.fr/shared/publications/pdf/DTIx1264xPA-Metal%20stocks%20in%20society.pdf |isbn=978-92-807-3082-1 |publisher=International Resource Panel |access-date=18 April 2017 |page=17 |display-authors=etal<!--only mentions the lead author; others are not named--> |archive-date=26 April 2018 |archive-url=https://web.archive.org/web/20180426184751/http://www.unep.fr/shared/publications/pdf/DTIx1264xPA-Metal%20stocks%20in%20society.pdf |url-status=dead }} | |||
| * {{cite book |last=Kaupp |first=M. |chapter=Chemical bonding of main-group elements |title=The Chemical Bond: Chemical Bonding Across the Periodic Table |year=2014 |publisher=John Wiley & Sons |doi=10.1002/9783527664658.ch1 |editor-last=Frenking |editor-first=G. |editor-last2=Shaik |editor-first2=S. |url=https://application.wiley-vch.de/books/sample/3527333150_c01.pdf |ref=harv |format=PDF}} | |||
| * {{cite journal |last1=Grandjean |first1=P. |author-link=Philippe Grandjean (professor) |title=Widening perspectives of lead toxicity |year=1978 |pages=303–21 |journal=] |volume=17 |issue=2 |doi=10.1016/0013-9351(78)90033-6 |pmid=400972|bibcode=1978ER.....17..303G }} | |||
| * {{cite book |last=Kellett |first=C. |title=Poison and Poisoning: A Compendium of Cases, Catastrophes and Crimes |year=2012 |url=https://books.google.com/books?id=Wa0hBgAAQBAJ |publisher=Accent Press |isbn=978-1-909335-05-9 |ref=harv}} | |||
| * {{cite book | |
* {{cite book |last1=Greenwood |first1=N. N. |author-link1=Norman Greenwood |last2=Earnshaw |first2=A. |title=Chemistry of the Elements |year=1998 |edition=2nd |publisher=Butterworth-Heinemann |isbn=978-0-7506-3365-9 |url=https://books.google.com/books?id=EvTI-ouH3SsC&q=chemistry+of+the+elements }} | ||
| * {{cite web |last=Grout |first=J. |title=Lead poisoning and Rome |date=2017 |url=http://penelope.uchicago.edu/~grout/encyclopaedia_romana/wine/leadpoisoning.html |website=Encyclopaedia Romana |access-date=15 February 2017 }} | |||
| * {{cite book |last1=Konu |first1=J. |last2=Chivers |first2=T. |chapter=Stable Radicals of the Heavy p-Block Elements |editor-last=Hicks |editor-first=R. G. |title=Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds |url=https://books.google.com/books?id=WuwW8QDuCKIC |year=2011 |publisher=John Wiley & Sons |isbn=978-0-470-77083-2 |ref=harv}} | |||
| * {{cite |
* {{cite report |last=Guberman |first=D. E. |chapter=Lead |title=2014 Minerals Yearbook |year=2016 |chapter-url=https://minerals.usgs.gov/minerals/pubs/commodity/lead/myb1-2014-lead.pdf |publisher=] |access-date=8 May 2017 }} | ||
| * {{cite book |last= |
* {{cite book |last=Gulbinska |first=M. K. |title=Lithium-ion Battery Materials and Engineering: Current Topics and Problems from the Manufacturing Perspective |url=https://books.google.com/books?id=ZDRxBAAAQBAJ |year=2014 |publisher=] |isbn=978-1-4471-6548-4 |page=96 }} | ||
| * {{cite book |last= |
* {{cite book |last=Guruswamy |first=S. |title=Engineering properties and applications of lead alloys |date=2000 |url=https://books.google.com/books?id=TtGmjOv9CUAC |isbn=978-0-8247-8247-4 |publisher=Marcel Dekker }} | ||
| * {{cite book | |
* {{cite book |last=Hadlington |first=T. J. |title=On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes |url=https://books.google.com/books?id=KQshDgAAQBAJ |year=2017 |publisher=Springer |isbn=978-3-319-51807-7 }} | ||
| * {{cite book |last1=Harbison |first1=R. D. |last2=Bourgeois |first2=M. M. |last3=Johnson |first3=G. T. |title=Hamilton and Hardy's Industrial Toxicology |date=2015 |publisher=John Wiley & Sons |isbn=978-0-470-92973-5}} | |||
| * {{cite web |url=http://www.britishmuseum.org/research/search_the_collection_database/search_object_details.aspx?objectid=399876&partid=1&output=Terms%2F!!%2FOR%2F!!%2F1204%2F!%2F%2F!%2FClassical+Greek%2F!%2F%2F!!%2F%2F!!!%2F&orig=%2Fresearch%2Fsearch_the_collection_database%2Fadvanced_search.aspx¤tPage=7&numpages=10 |publisher=] |title=Lead sling bullet; almond shape; a winged thunderbolt on one side and on the other, in high relief, the inscription DEXAI "Catch!" |accessdate=30 April 2012 |ref=CITEREFLead sling bullet}} | |||
| * {{cite book |last1=Hauser |first1=P. C. |chapter=Analytical Methods for the Determination of Lead in the Environment |publisher=] |date=2017 |series=Metal Ions in Life Sciences |volume=17 |title=Lead: Its Effects on Environment and Health |pages=49–60 |editor1-last=Astrid |editor1-first=S. |editor2-last=Helmut |editor2-first=S. |editor3-last=Sigel |editor3-first=R. K. O. |doi=10.1515/9783110434330-003 |pmid=28731296 |isbn=9783110434330 |url=https://edoc.unibas.ch/93775/1/10.1515_9783110434330-003.pdf }} | |||
| * {{cite web |author=<!--Not stated--> |title=Lead garden ornaments |date=2016 |url=http://www.hcrowther.co.uk/ |website=H. Crowther Ltd |access-date=20 February 2017 |ref=CITEREFLead garden ornaments2016}} | |||
| * {{cite journal |last=Hernberg |first=S. |title=Lead Poisoning in a Historical Perspective |date=2000 |pages=244–54 |url=http://rachel.org/files/document/Lead_Poisoning_in_Historical_Perspective.pdf |journal=] |volume=38 |issue=3 |doi=10.1002/1097-0274(200009)38:3<244::AID-AJIM3>3.0.CO;2-F |access-date=1 March 2017 |pmid=10940962 |archive-date=21 September 2017 |archive-url=https://web.archive.org/web/20170921183035/http://www.rachel.org/files/document/Lead_Poisoning_in_Historical_Perspective.pdf |url-status=dead }} | |||
| * {{cite web |author=<!--Not stated--> |title=Lead in Waste Disposal |date=2016 |url=https://www.epa.gov/lead/lead-regulations |publisher=] |access-date=28 February 2017 |ref=CITEREFLead in Waste2016}} | |||
| * {{cite web |title= |
* {{cite web |title=A History of Cosmetics from Ancient Times |url=http://www.cosmeticsinfo.org/Ancient-history-cosmetics |website=Cosmetics Info |access-date=18 July 2016 |ref=CITEREFHistory of Cosmetics |archive-date=14 July 2016 |archive-url=https://web.archive.org/web/20160714203854/http://www.cosmeticsinfo.org/Ancient-history-cosmetics |url-status=dead }} | ||
| * {{cite |
* {{cite journal |last=Hodge |first=T. A. |title=Vitruvius, lead pipes and lead poisoning |year=1981 |pages=486–91 |volume=85 |issue=4 |jstor=504874 |journal=] |doi=10.2307/504874|s2cid=193094209 }} | ||
| * {{cite journal |last1= |
* {{cite journal |last1=Hong |first1=S. |last2=Candelone |first2=J.-P. |last3=Patterson |first3=C. C. |last4=Boutron |first4=C. F. |title=Greenland ice evidence of hemispheric lead pollution two millennia ago by Greek and Roman civilizations |date=1994 |pages=1841–43 |doi=10.1126/science.265.5180.1841 |url=http://www.precaution.org/lib/greenland_ice_evidence_of_ancient_lead_pollution.19940923.pdf |display-authors=3 |journal=] |volume=265 |issue=5180 |pmid=17797222 |bibcode=1994Sci...265.1841H |s2cid=45080402 }} | ||
| * {{cite book |last=Hunt |first=A. |title=Dictionary of Chemistry |url=https://books.google.com/books?id=P_lRAwAAQBAJ |year=2014 |publisher=] |isbn=978-1-135-94178-9 }} | |||
| * {{cite journal |last=Lewis |first1=J. |year=1985 |title=Lead Poisoning: A Historical Perspective |url=https://archive.epa.gov/epa/aboutepa/lead-poisoning-historical-perspective.html |access-date=31 January 2017 |journal=EPA Journal |volume=11 |issue=4 |pp=15–18 |publisher=United States Environmental Protection Agency |ref=harv}} | |||
| * {{cite web |author=IAEA - Nuclear Data Section |title=Livechart - Table of Nuclides - Nuclear structure and decay data |year=2017 |website=www-nds.iaea.org |publisher=] |url=https://www-nds.iaea.org/relnsd/vcharthtml/VChartHTML.html |access-date=31 March 2017 }} | |||
| * {{cite book |title=CRC Handbook of Chemistry and Physics |date=2005 |editor-last=Lide |editor-first=D. R. |edition=85th |publisher=] |isbn=978-0-8493-0484-2 |ref=harv}} | |||
| * {{cite report |author1=Insight Explorer |author2=IPEN |date=2016 |title=New Study Finds Lead Levels in a Majority of Paints Exceed Chinese Regulation and Should Not be on Store Shelves |url=http://www.ipen.org/sites/default/files/documents/PR_New_Study_Finds_Lead_Levels_in_a_Majority_of_Paints_Exceed_Chinese_Regulation_and_Should_Not_be_on_Store_Shelves_EN_27_Jan._2016.pdf |access-date=3 May 2018 }} | |||
| * {{cite journal |last1=Liu |first1=J. |last2=Liu |first2=X. |last3=Pak |first3=V. |last4=Wang |first4=Y. |last5=Yan |first5=C. |last6=Pinto-Martin |first6=J. |last7=Dinges |first7=D. |display-authors=3 |title=Early blood lead levels and sleep disturbance in preadolescence |year=2015 |pages=1869–74 |pmid=26194570 |pmc=4667382 |doi=10.5665/sleep.5230 |journal=] |volume=38 |issue=12 |ref=harv}} | |||
| * {{cite report|first1=Yuyun|last1=Ismawati|first2=Andita|last2=Primanti|first3=Sara|last3=Brosché|first4=Scott|last4=Clark|first5=Jack|last5=Weinberg|first6=Valerie|last6=Denney|date=2013|title=Timbal dalam Cat Enamel Rumah Tangga di Indonesia|url=https://ipen.org/pdfs/ina_bf_final_report_rev_2_2013_08-v2-id.pdf|access-date=26 December 2018|publisher=BaliFokus & IPEN|language=id}} | |||
| * {{cite web |last1=Lochner |first1=J. C. |last2=Rohrbach |first2=G. |last3=Cochrane |first3=K. |year=2005 |title=What is Your Cosmic Connection to the Elements? |publisher=] |url=https://imagine.gsfc.nasa.gov/educators/elements/imagine/Cosmic.pdf |archiveurl=https://web.archive.org/web/20161229105038/https://imagine.gsfc.nasa.gov/educators/elements/imagine/Cosmic.pdf |archivedate=29 December 2016 |accessdate=2 July 2017 |ref=harv |format=PDF}} | |||
| * {{cite book |last=Jensen |first=C. F. |title=Online Location of Faults on AC Cables in Underground Transmission |year=2013 |publisher=Springer |isbn=978-3-319-05397-4}} | |||
| * {{cite journal |last1=Lodders |first1=K. |title=Solar System abundances and condensation temperatures of the elements |url=http://solarsystem.wustl.edu/wp-content/uploads/reprints/2003/Lodders%202003%20ApJ%20Elemental%20abundances.pdf |year=2003 |pages=1220–47 |journal=] |volume=591 |issue=2 |issn=0004-637X |doi=10.1086/375492 |ref=harv |bibcode=2003ApJ...591.1220L |format=PDF}} | |||
| * {{cite book | |
* {{cite book |last1=Jones |first1=P. A. |title=Jedburgh Justice and Kentish Fire: The Origins of English in Ten Phrases and Expressions |url=https://books.google.com/books?id=rfqzBAAAQBAJ |date=2014 |publisher=] |isbn=978-1-47211-389-4 }} | ||
| * {{cite book |last=Kaupp |first=M. |chapter=Chemical bonding of main-group elements |title=The Chemical Bond: Chemical Bonding Across the Periodic Table |pages=1–24 |year=2014 |publisher=John Wiley & Sons |doi=10.1002/9783527664658.ch1 |editor-last=Frenking |editor-first=G. |editor-last2=Shaik |editor-first2=S. |chapter-url=https://application.wiley-vch.de/books/sample/3527333150_c01.pdf |isbn=9783527664658 |s2cid=17979350 }} | |||
| * {{cite journal |last=Marcillac |first=P. de |last2=Coron |first2=N. |last3=Dambier |first3=G. |last4=Leblanc |first4=J. |last5=Moalic |first5=J.-P. |title=Experimental detection of α-particles from the radioactive decay of natural bismuth |date=2003 |pages=876–78 |display-authors=3 |journal=] |volume=422 |pmid=12712201 |doi=10.1038/nature01541 |issue=6934 |bibcode=2003Natur.422..876D |ref=harv}} | |||
| * {{cite book |last=Kellett |first=C. |title=Poison and Poisoning: A Compendium of Cases, Catastrophes and Crimes |year=2012 |url=https://books.google.com/books?id=Wa0hBgAAQBAJ |archive-url=https://web.archive.org/web/20190609155707/https://books.google.com/books?id=Wa0hBgAAQBAJ |url-status=dead |archive-date=9 June 2019 |publisher=Accent Press |isbn=978-1-909335-05-9 }} | |||
| * {{cite journal |last1=Marino |first1=P. E. |last2=Landrigan |first2=P. J. |last3=Graef |first3=J. |last4=Nussbaum |first4=A. |last5=Bayan |first5=G. |last6=Boch |first6=K. |last7=Boch |first7=S. |title=A case report of lead paint poisoning during renovation of a Victorian farmhouse |year=1990 |pages=1183–85 |displayauthors=3 |journal=] |volume=80 |issue=10 |doi=10.2105/AJPH.80.10.1183 |pmc=1404824 |pmid=2119148 |ref=harv}} | |||
| * {{cite book |last=King |first=R. B. |title=Inorganic Chemistry of Main Group Elements |date=1995 |publisher=] |isbn=978-1-56081-679-9}} | |||
| * {{cite journal |last1=Markowitz |first1=G. |authorlink1=Gerald Markowitz |last2=Rosner |first2=D. |title="Cater to the children": the role of the lead industry in a public health tragedy, 1900–55 |year=2000 |pages=36–46 |pmc=1446124 |pmid=10630135 |volume=90 |issue=1 |journal=American Journal of Public Health |doi=10.2105/ajph.90.1.36 |ref=harv}} | |||
| * {{cite book |last1= |
* {{cite book |last1=Konu |first1=J. |last2=Chivers |first2=T. |chapter=Stable Radicals of the Heavy p-Block Elements |editor-last=Hicks |editor-first=R. G. |title=Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds |chapter-url=https://books.google.com/books?id=WuwW8QDuCKIC |year=2011 |publisher=John Wiley & Sons |isbn=978-0-470-77083-2 |doi=10.1002/9780470666975.ch10 }} | ||
| * {{cite book |last=Kosnett |first=M. J. |chapter=Lead |title=Poisoning and Drug Overdose |year=2006 |editor-last=Olson |editor-first=K. R. |edition=5th |publisher=] |page=238 |isbn=978-0-07-144333-3}} | |||
| * {{cite journal |last1=Meija |first1=J. |last2=Coplen |first2=T. B. |last3=Berglund |first3=M. |last4=Brand |first4=W. A. |last5=De Bièvre |first5=P. |last6=Gröning |first6=M. |last7=Holden |first7=N. E. |last8=Irrgeher |first8=J. |last9=Loss |first9=R. D. |last10=Walczyk |first10=T. |last11=Prohaska |first11=T. |displayauthors=3 |year=2016 |title=Atomic weights of the elements 2013 (IUPAC Technical Report) |journal=] |volume=88 |number=3 |pages=265–291 |url=http://www.ciaaw.org/atomic-weights.htm |ref=harv |doi=10.1515/pac-2015-0305}} | |||
| * {{cite book |last1=Krestovnikoff |first1=M. |last2=Halls |first2=M. |title=Scuba Diving |year=2006 |url=https://archive.org/details/scubadiving0000hall |url-access=registration |publisher=] |isbn=978-0-7566-4063-7 }} | |||
| * {{cite web |author=] |title=Definition of LEAD |url=http://www.merriam-webster.com/dictionary/lead |website=www.merriam-webster.com |access-date=12 August 2016 |ref=harv}} | |||
| * {{cite book |last=Kroonen |first=G. |title=Etymological Dictionary of Proto-Germanic |year=2013 |publisher=] |series=Leiden Indo-European Etymological Dictionary Series |volume=11 |isbn=978-90-04-18340-7}} | |||
| * {{cite journal |last1=Moore |first1=M. R. |title=Lead in drinking water in soft water areas—health hazards |date=1977 |pages=109–15 |journal=Science of the Total Environment |volume=7 |issue=2 |doi=10.1016/0048-9697(77)90002-X |pmid=841299 |ref=harv}} | |||
| * {{cite book |last1=Langmuir |first1=C. H. |last2=Broecker |first2=W. S. |title=How to Build a Habitable Planet: The Story of Earth from the Big Bang to Humankind |url=https://books.google.com/books?id=EnlnHlmRsqAC |year=2012 |publisher=] |isbn=978-0-691-14006-3 }} | |||
| * {{cite journal |last1=More |first1=A. F. |last2=Spaulding |first2=N. E. |last3=Bohleber |first3=P. |last4=Handley |first4=M. J. |last5=Hoffmann |first5=H. |last6=Korotkikh |first6=E. V. |last7=Kurbatov |first7=A. V. |last8=Loveluck |first8=C. P. |last9=Sneed |first9=S. B. |last10=McCormick |first10=M. |last11=Mayewski |first11=P. A. |display-authors=3 |title=Next-generation ice core technology reveals true minimum natural levels of lead (Pb) in the atmosphere: Insights from the Black Death |journal=GeoHealth |volume=1 |issue=4 |pages=211 |year=2017 |issn=2471-1403 |doi=10.1002/2017GH000064 |ref=harv}} | |||
| * {{cite book|last1=Lauwerys|first1=R. R.|last2=Hoet|first2=P.|title=Industrial Chemical Exposure: Guidelines for Biological Monitoring, Third Edition|url=https://books.google.com/books?id=WUxZDwAAQBAJ&pg=PT147|year=2001|publisher=CRC Press|isbn=978-1-4822-9383-8}} | |||
| * {{cite journal |last1=Mosseri |first1=S. |last2=Henglein |first2=A. |last3=Janata |first3=E. |title=Trivalent lead as an intermediate in the oxidation of lead(II) and the reduction of lead(IV) species |year=1990 |pages=2722–26 |doi=10.1021/j100369a089 |journal=Journal of Physical Chemistry |volume=94 |issue=6 |ref=harv}} | |||
| * {{cite web |last=Layton |first=M. |date=2017 |title=Lead faces threat of new Euro ban |url=http://www.shootinguk.co.uk/news/lead-shot-faces-threat-of-new-euro-ban-93819 |publisher=shootinguk.co.uk |access-date=30 May 2018 }} | |||
| * {{cite book |last1=Mycyk |first1=M. |last2=Hryhorczuk |first2=D. |last3=Amitai |first3=Y. |chapter=Lead |title=Pediatric Toxicology: Diagnosis and Management of the Poisoned Child |year=2005 |editor-last1=Erickson |editor-first1=T. B. |editor-last2=Ahrens |editor-first2=W. R. |editor-last3=Aks |editor-first3=S. |display-authors=etal |publisher=McGraw-Hill Professional |isbn=978-0-07-141736-5 |ref=harv}} | |||
| * {{cite web |url=http://www.britishmuseum.org/research/search_the_collection_database/search_object_details.aspx?objectid=399876&partid=1&output=Terms%2F!!%2FOR%2F!!%2F1204%2F!%2F%2F!%2FClassical+Greek%2F!%2F%2F!!%2F%2F!!!%2F&orig=%2Fresearch%2Fsearch_the_collection_database%2Fadvanced_search.aspx¤tPage=7&numpages=10 |publisher=] |title=Lead sling bullet; almond shape; a winged thunderbolt on one side and on the other, in high relief, the inscription DEXAI "Catch!" |access-date=30 April 2012 |ref=CITEREFLead sling bullet |archive-date=14 February 2012 |archive-url=https://web.archive.org/web/20120214235913/http://www.britishmuseum.org/research/search_the_collection_database/search_object_details.aspx?objectid=399876&partid=1&output=Terms%2f!!%2fOR%2f!!%2f1204%2f!%2f%2f!%2fClassical+Greek%2f!%2f%2f!!%2f%2f!!!%2f&orig=%2fresearch%2fsearch_the_collection_database%2fadvanced_search.aspx¤tPage=7&numpages=10 |url-status=dead }} | |||
| * {{cite journal |last1=Nakashima |first1=T. |last2=Hayashi |first2=H. |last3=Tashiro |first3=H. |last4=Matsushita |first4=T. |title=Gender and hierarchical differences in lead-contaminated Japanese bone from the Edo period |year=1998 |pages=55–60 |doi=10.1539/joh.40.55 |display-authors=3 |journal=Journal of Occupational Health |volume=40 |issue=1 |ref=harv}} | |||
| * {{cite web |author=<!--Not stated--> |title=Lead garden ornaments |date=2016 |url=http://www.hcrowther.co.uk/ |website=H. Crowther Ltd |access-date=20 February 2017 |ref=CITEREFLead garden ornaments2016 }} | |||
| * {{cite book |author=] |title=Structural Shielding Design for Medical X-ray Imaging Facilities |date=2004 |url=https://books.google.com/?id=DKu4YDjEluoC |isbn=978-0-929600-83-3 |ref=harv}} | |||
| * {{cite web |author= |
* {{cite web |author=<!--Not stated--> |title=Lead in Waste Disposal |date=2016 |url=https://www.epa.gov/lead/lead-regulations |publisher=] |access-date=28 February 2017 |ref=CITEREFLead in Waste2016 }} | ||
| * {{cite web |title=Lead mining |url=http://www.thenorthernecho.co.uk/history/mining/lead/ |publisher=] |access-date=16 February 2016 |ref=CITEREFLead mining }} | |||
| * {{cite book |title=Indo-European Etymology |year=2012 |url=http://starling.rinet.ru/cgi-bin/response.cgi?root=config&morpho=0&basename=%5Cdata%5Cie%5Cpiet&first=1&off=&text_proto=lAudh&method_proto=substring&ic_proto=on&text_meaning=&method_meaning=substring&ic_meaning=on&text_hitt=&method_hitt=substring&ic_hitt=on&text_tokh=&method_tokh=substring&ic_tokh=on&text_ind=&method_ind=substring&ic_ind=on&text_avest=&method_avest=substring&ic_avest=on&text_iran=&method_iran=substring&ic_iran=on&text_arm=&method_arm=substring&ic_arm=on&text_greek=&method_greek=substring&ic_greek=on&text_slav=&method_slav=substring&ic_slav=on&text_balt=&method_balt=substring&ic_balt=on&text_germ=&method_germ=substring&ic_germ=on&text_lat=&method_lat=substring&ic_lat=on&text_ital=&method_ital=substring&ic_ital=on&text_celt=&method_celt=substring&ic_celt=on&text_alb=&method_alb=substring&ic_alb=on&text_rusmean=&method_rusmean=substring&ic_rusmean=on&text_refer=&method_refer=substring&ic_refer=on&text_comment=&method_comment=substring&ic_comment=on&text_any=&method_any=substring&sort=proto&ic_any=on |entry=*lAudh- |editor-first=S. |editor-last=Nikolayev |website=starling.rinet.ru |access-date=21 August 2016 |ref=CITEREFNikolayev2012}} | |||
| * {{cite book |last= |
* {{cite book |last=Levin |first=H. L. |title=The Earth Through Time |url=https://books.google.com/books?id=D0yl7Cqsu78C |year=2009 |publisher=John Wiley & Sons |isbn=978-0-470-38774-0 }} | ||
| * {{cite journal |last1=Levin |first1=R. |last2=Brown |first2=M. J. |last3=Kashtock |first3=M. E. |last4=Jacobs |first4=D. E. |last5=Whelan |first5=E. A. |last6=Rodman |first6=J. |last7=Schock |first7=M. R. |last8=Padilla |first8=A. |last9=Sinks |first9=T. |title=Lead exposures in U.S. children, 2008: Implications for prevention |year=2008 |pages=1285–93 |display-authors=3 |journal=] |volume=116 |issue=10 |doi=10.1289/ehp.11241 |pmc=2569084 |pmid=18941567|bibcode=2008EnvHP.116.1285L }} | |||
| * {{cite journal |last=Nriagu |first=J. O. |title=Saturnine gout among Roman aristocrats — Did lead poisoning contribute to the fall of the Empire? |year=1983 |pages=660–63 |journal=] |volume=308 |issue=11 |doi=10.1056/NEJM198303173081123 |pmid=6338384 |ref=harv}} | |||
| * {{cite journal | |
* {{cite journal |last1=Lewis |first1=J. |year=1985 |title=Lead Poisoning: A Historical Perspective |url=https://archive.epa.gov/epa/aboutepa/lead-poisoning-historical-perspective.html |access-date=31 January 2017 |journal=] |volume=11 |issue=4 |pages=15–18 }} | ||
| * {{cite book |title=CRC Handbook of Chemistry and Physics |date=2005 |editor-last=Lide |editor-first=D. R. |edition=85th |publisher=] |isbn=978-0-8493-0484-2}} | |||
| * {{cite web |author=] |title=Substance data sheet for occupational exposure to lead |url=https://www.osha.gov/pls/oshaweb/owadisp.show_document?p_table=STANDARDS&p_id=10031 |website=www.osha.gov |accessdate=1 July 2017 |ref=harv}} | |||
| * {{cite journal |last1=Liu |first1=J. |last2=Liu |first2=X. |last3=Pak |first3=V. |last4=Wang |first4=Y. |last5=Yan |first5=C. |last6=Pinto-Martin |first6=J. |last7=Dinges |first7=D. |display-authors=3 |title=Early blood lead levels and sleep disturbance in preadolescence |year=2015 |pages=1869–74 |pmid=26194570 |pmc=4667382 |doi=10.5665/sleep.5230 |journal=] |volume=38 |issue=12}} | |||
| * {{cite web |last=Olinsky-Paul |year=2013 |first=T. |title=East Penn and Ecoult battery installation case study webinar |url=http://www.cesa.org/assets/Uploads/ESTAP-Ecoult-Battery-Installation-Case-Study-Presentation.pdf |website=Clean Energy States Alliance |accessdate=28 February 2017 |ref=harv |format=PDF}} | |||
| * {{cite web |last1=Lochner |first1=J. C. |last2=Rohrbach |first2=G. |last3=Cochrane |first3=K. |year=2005 |title=What is Your Cosmic Connection to the Elements? |publisher=] |url=https://imagine.gsfc.nasa.gov/educators/elements/imagine/Cosmic.pdf |archive-url=https://web.archive.org/web/20161229105038/https://imagine.gsfc.nasa.gov/educators/elements/imagine/Cosmic.pdf |archive-date=29 December 2016 |access-date=2 July 2017 }} | |||
| * {{cite book |title=The Organ |date=2006 |url=https://books.google.com/?id=cgDJaeFFUPoC |isbn=978-0-415-94174-7 |editor-last=Palmieri |editor-first=R. |publisher=] |ref=CITEREFPalmieri2006}} | |||
| * {{cite journal |last1=Lodders |first1=K. |author1-link=Katharina Lodders |title=Solar System abundances and condensation temperatures of the elements |year=2003 |pages=1220–47 |journal=] |volume=591 |issue=2 |issn=0004-637X |doi=10.1086/375492 |bibcode=2003ApJ...591.1220L |s2cid=42498829 |url=http://solarsystem.wustl.edu/wp-content/uploads/reprints/2003/Lodders%202003%20ApJ%20Elemental%20abundances.pdf }} | |||
| * {{cite book |last1=Luckey |first1=T. D. |last2=Venugopal |first2=B. |title=Physiologic and Chemical Basis for Metal Toxicity |year=1979 |publisher=Plenum Press |isbn=978-1-4684-2952-7 |url=https://books.google.com/books?id=7mxyBgAAQBAJ }} | |||
| * {{cite book |last=Macintyre |first=J. E. |year=1992 |title=Dictionary of Inorganic Compounds |url=https://books.google.com/books?id=9eJvoNCSCRMC |publisher=CRC Press |isbn=978-0-412-30120-9 }} | |||
| * {{cite journal |last1=Marino |first1=P. E. |last2=Landrigan |first2=P. J. |last3=Graef |first3=J. |last4=Nussbaum |first4=A. |last5=Bayan |first5=G. |last6=Boch |first6=K. |last7=Boch |first7=S. |title=A case report of lead paint poisoning during renovation of a Victorian farmhouse |year=1990 |pages=1183–85 |display-authors=3 |journal=] |volume=80 |issue=10 |doi=10.2105/AJPH.80.10.1183 |pmc=1404824 |pmid=2119148}} | |||
| * {{cite journal |last1=Markowitz |first1=G. |author-link1=Gerald Markowitz |last2=Rosner |first2=D. |title="Cater to the children": the role of the lead industry in a public health tragedy, 1900–55 |year=2000 |pages=36–46 |pmc=1446124 |pmid=10630135 |volume=90 |issue=1 |journal=] |doi=10.2105/ajph.90.1.36}} | |||
| * {{cite book |last1=Masters |first1=S. B. |last2=Trevor |first2=A. J. |last3=Katzung |first3=B. G. |title=Katzung & Trevor's Pharmacology: Examination & Board Review |year=2008 |publisher=] |edition=8th |isbn=978-0-07-148869-3}} | |||
| * {{cite news |last=McCoy |first=S. |date=2017 |title=The End of Lead? Federal Gov't Order Bans Sinkers, Ammo |url=https://gearjunkie.com/lead-ban-ammunition-fishing-sinkers |website=GearJunkie |access-date=30 May 2018 |archive-date=8 March 2020 |archive-url=https://web.archive.org/web/20200308030342/https://gearjunkie.com/lead-ban-ammunition-fishing-sinkers |url-status=dead }} | |||
| * {{CIAAW2016|plain}} | |||
| * {{cite web |author=Merriam-Webster |title=Definition of LEAD |url=http://www.merriam-webster.com/dictionary/lead |website=www.merriam-webster.com |access-date=12 August 2016 |author-link=Merriam-Webster }} | |||
| * {{cite journal |last1=Moore |first1=M. R. |title=Lead in drinking water in soft water areas—health hazards |date=1977 |pages=109–15 |journal=] |volume=7 |issue=2 |doi=10.1016/0048-9697(77)90002-X |pmid=841299|bibcode=1977ScTEn...7..109M }} | |||
| * {{cite journal |last1=More |first1=A. F. |last2=Spaulding |first2=N. E. |last3=Bohleber |first3=P. |last4=Handley |first4=M. J. |last5=Hoffmann |first5=H. |last6=Korotkikh |first6=E. V. |last7=Kurbatov |first7=A. V. |last8=Loveluck |first8=C. P. |last9=Sneed |first9=S. B. |last10=McCormick |first10=M. |last11=Mayewski |first11=P. A. |display-authors=3 |title=Next-generation ice core technology reveals true minimum natural levels of lead (Pb) in the atmosphere: Insights from the Black Death |journal=] |year=2017 |issn=2471-1403 |doi=10.1002/2017GH000064 |volume=1 |issue=4 |pages=211–219 |pmid=32158988 |pmc=7007106 |bibcode=2017GHeal...1..211M |url=http://eprints.nottingham.ac.uk/44697/1/More%20et%20al%202017%20Geohealth%20accepted%20text%20and%20figures.pdf |access-date=28 August 2019 |archive-date=18 April 2020 |archive-url=https://web.archive.org/web/20200418212801/http://eprints.nottingham.ac.uk/44697/1/More%20et%20al%202017%20Geohealth%20accepted%20text%20and%20figures.pdf |url-status=dead }} | |||
| * {{cite journal |last1=Mosseri |first1=S. |last2=Henglein |first2=A. |last3=Janata |first3=E. |title=Trivalent lead as an intermediate in the oxidation of lead(II) and the reduction of lead(IV) species |year=1990 |pages=2722–26 |doi=10.1021/j100369a089 |journal=] |volume=94 |issue=6}} | |||
| * {{cite book |last1=Mycyk |first1=M. |last2=Hryhorczuk |first2=D. |last3=Amitai |first3=Y. |display-authors=etal |chapter=Lead |title=Pediatric Toxicology: Diagnosis and Management of the Poisoned Child |year=2005 |editor-last1=Erickson |editor-first1=T. B. |editor-last2=Ahrens |editor-first2=W. R. |editor-last3=Aks |editor-first3=S. |publisher=McGraw-Hill Professional |isbn=978-0-07-141736-5}} | |||
| * {{cite journal |last1=Nakashima |first1=T. |last2=Hayashi |first2=H. |last3=Tashiro |first3=H. |last4=Matsushita |first4=T. |title=Gender and hierarchical differences in lead-contaminated Japanese bone from the Edo period |year=1998 |pages=55–60 |doi=10.1539/joh.40.55 |display-authors=3 |journal=] |volume=40 |issue=1|doi-access= |s2cid=71451911 }} | |||
| * {{cite book |author=National Council on Radiation Protection and Measurements |title=Structural Shielding Design for Medical X-ray Imaging Facilities |date=2004 |url=https://books.google.com/books?id=DKu4YDjEluoC |isbn=978-0-929600-83-3 |author-link=National Council on Radiation Protection and Measurements }} | |||
| * {{cite web |author=National Institute for Occupational Safety and Health |title=NIOSH Pocket Guide to Chemical Hazards — Lead |url=https://www.cdc.gov/niosh/npg/npgd0368.html |website=www.cdc.gov |access-date=18 November 2016 }} | |||
| * {{cite journal|last1=Navas-Acien|first1=A.|title=Lead Exposure and Cardiovascular Disease—A Systematic Review|journal=]|date=2007|volume=115|issue=3|pages=472–482|doi=10.1289/ehp.9785|pmid=17431501|pmc=1849948|bibcode=2007EnvHP.115..472N }} | |||
| * {{cite journal |last1=Neiburger |first1=E.J. |title=X-Rays, Archaeology and the Chopsticks of Death |journal=Central States Archaeological Journal |date=April 2018 |volume=65 |issue=2 |pages=70–74 |jstor=44715698}} | |||
| * {{cite web |website=Indo-European Etymology |url=http://starling.rinet.ru/cgi-bin/response.cgi?root=config&morpho=0&basename=%5Cdata%5Cie%5Cpiet&first=1&off=&text_proto=lAudh&method_proto=substring&ic_proto=on&text_meaning=&method_meaning=substring&ic_meaning=on&text_hitt=&method_hitt=substring&ic_hitt=on&text_tokh=&method_tokh=substring&ic_tokh=on&text_ind=&method_ind=substring&ic_ind=on&text_avest=&method_avest=substring&ic_avest=on&text_iran=&method_iran=substring&ic_iran=on&text_arm=&method_arm=substring&ic_arm=on&text_greek=&method_greek=substring&ic_greek=on&text_slav=&method_slav=substring&ic_slav=on&text_balt=&method_balt=substring&ic_balt=on&text_germ=&method_germ=substring&ic_germ=on&text_lat=&method_lat=substring&ic_lat=on&text_ital=&method_ital=substring&ic_ital=on&text_celt=&method_celt=substring&ic_celt=on&text_alb=&method_alb=substring&ic_alb=on&text_rusmean=&method_rusmean=substring&ic_rusmean=on&text_refer=&method_refer=substring&ic_refer=on&text_comment=&method_comment=substring&ic_comment=on&text_any=&method_any=substring&sort=proto&ic_any=on |year=2012 |title=*lAudh- |editor-first=S. |editor-last=Nikolayev |access-date=21 August 2016 }} | |||
| * {{cite book |last=Norman |first=N. C. |title=Periodicity and the s- and p-Block Elements |date=1996 |publisher=Oxford University Press |isbn=978-0-19-855961-0}} | |||
| * {{cite journal |last=Nriagu |first=J. O. |title=Saturnine gout among Roman aristocrats — Did lead poisoning contribute to the fall of the Empire? |year=1983 |pages=660–63 |journal=] |volume=308 |issue=11 |doi=10.1056/NEJM198303173081123 |pmid=6338384}} | |||
| * {{cite journal |last1=Nriagu |first1=J. O. |last2=Kim |first2=M-J. |title=Emissions of lead and zinc from candles with metal-core wicks |date=2000 |pages=37–41 |doi=10.1016/S0048-9697(00)00359-4 |journal=] |volume=250 |pmid=10811249 |issue=1–3|bibcode=2000ScTEn.250...37N }} | |||
| * {{cite web |author=Occupational Safety and Health Administration |title=Substance data sheet for occupational exposure to lead |url=https://www.osha.gov/pls/oshaweb/owadisp.show_document?p_table=STANDARDS&p_id=10031 |archive-url=https://web.archive.org/web/20180316131738/https://www.osha.gov/pls/oshaweb/owadisp.show_document?p_table=STANDARDS&p_id=10031 |archive-date=16 March 2018 |website=www.osha.gov |access-date=1 July 2017 |author-link=Occupational Safety and Health Administration }} | |||
| * {{cite web |last=Olinsky-Paul |year=2013 |first=T. |title=East Penn and Ecoult battery installation case study webinar |url=http://www.cesa.org/assets/Uploads/ESTAP-Ecoult-Battery-Installation-Case-Study-Presentation.pdf |website=Clean Energy States Alliance |access-date=28 February 2017 }} | |||
| * {{cite book |title=The Organ |date=2006 |url=https://books.google.com/books?id=cgDJaeFFUPoC |isbn=978-0-415-94174-7 |editor-last=Palmieri |editor-first=R. |publisher=] }} | |||
| * {{cite encyclopedia |title=surma |encyclopedia=Oxford English Dictionary |edition=2nd |year=2009 |publisher=Oxford University Press |ref=CITEREFOxford English Dictionary}} | * {{cite encyclopedia |title=surma |encyclopedia=Oxford English Dictionary |edition=2nd |year=2009 |publisher=Oxford University Press |ref=CITEREFOxford English Dictionary}} | ||
| * {{cite journal |last1=Park |first1=J. H. |last2=Bolan |first2=N. |last3=Meghara |first3=M. |last4=Naidu |first4=R. |last5=Chung |first5=J. W. |title=Bacterial-assisted immobilization of lead in soils: Implications for remediation |date=2011 |pages=162–74 |url=http://pedology.ac.affrc.go.jp/specialI/SI54_3/sepPDF/03_Jinhee%20Park.pdf |display-authors=3 |journal=Pedologist |archive-url=https://web.archive.org/web/20151126050549/http://pedology.ac.affrc.go.jp/specialI/SI54_3/sepPDF/03_Jinhee%20Park.pdf |archive-date=26 November 2015 | |
* {{cite journal |last1=Park |first1=J. H. |last2=Bolan |first2=N. |last3=Meghara |first3=M. |last4=Naidu |first4=R. |last5=Chung |first5=J. W. |title=Bacterial-assisted immobilization of lead in soils: Implications for remediation |date=2011 |pages=162–74 |url=http://pedology.ac.affrc.go.jp/specialI/SI54_3/sepPDF/03_Jinhee%20Park.pdf |display-authors=3 |journal=] |archive-url=https://web.archive.org/web/20151126050549/http://pedology.ac.affrc.go.jp/specialI/SI54_3/sepPDF/03_Jinhee%20Park.pdf |archive-date=26 November 2015 |url-status=dead }} | ||
| * {{cite book |last=Parker |first=R. B. |title=The New Cold-Molded Boatbuilding: From Lofting to Launching |year=2005 |url=https://books.google.com/books?id=VnoW5YpDN7sC |publisher=WoodenBoat Books |isbn=978-0-937822-89-0 |
* {{cite book |last=Parker |first=R. B. |title=The New Cold-Molded Boatbuilding: From Lofting to Launching |year=2005 |url=https://books.google.com/books?id=VnoW5YpDN7sC |publisher=WoodenBoat Books |isbn=978-0-937822-89-0 }} | ||
| * {{cite book |title=Crystal Chemistry of Tetrahedral Structures |url=https://books.google.com/books?id=bwQgvsxftTgC |date=1964 |last=Parthé |first=E. |publisher=CRC Press |
* {{cite book |title=Crystal Chemistry of Tetrahedral Structures |url=https://books.google.com/books?id=bwQgvsxftTgC |date=1964 |last=Parthé |first=E. |publisher=CRC Press |isbn=978-0-677-00700-7 }} | ||
| * {{cite book |last=Pauling |first=L. |title=General Chemistry |date=1947 |author-link=Linus Pauling |publisher=] |isbn=978-0-486-65622-9 | |
* {{cite book |last=Pauling |first=L. |title=General Chemistry |date=1947 |author-link=Linus Pauling |publisher=] |isbn=978-0-486-65622-9 |url=https://archive.org/details/generalchemistry00paul_0 }} | ||
| * {{cite journal|last1=Peneva|first1=S. K.|last2=Djuneva|first2=K. D.|last3=Tsukeva|first3=E. A.|title=RHEED study of the initial stages of crystallization and oxidation of lead and tin|journal=] |volume=53|issue=2|year=1981|pages=382–396|issn=0022-0248|doi=10.1016/0022-0248(81)90088-9|bibcode=1981JCrGr..53..382P}} | |||
| * {{cite book |last=Polyanskiy |first=N. G. |date=1986 |script-title=ru:Аналитическая химия элементов: Свинец |trans-title=Analytical Chemistry of the Elements: Lead |editor=Fillipova, N. A |publisher=] |language=Russian |ref=harv}} | |||
| * {{cite book|editor-last1=Puttlitz|editor-first1=K. J.|editor-last2=Stalter|editor-first2=K. A.|last1=Petzel|first1=S.|last2=Juuti|first2=M.|last3=Sugimoto|first3=Yu.|chapter=Environmental Stewardship with Regional Perspectives and Drivers of the Lead-free Issue|title=Handbook of Lead-Free Solder Technology for Microelectronic Assemblies|chapter-url=https://books.google.com/books?id=7FX5LkxfRpwC&pg=PA122|year=2004|publisher=CRC Press|isbn=978-0-8247-5249-1}} | |||
| * {{cite book |last=Prasad |first=P. J. |title=Conceptual Pharmacology |date=2010 |url=https://books.google.com/books?id=s0e_FlM8LKYC |publisher=Universities Press |isbn=978-81-7371-679-9 |accessdate=21 June 2012 |ref=harv}} | |||
| * {{cite book |last=Polyanskiy |first=N. G. |date=1986 |script-title=ru:Аналитическая химия элементов: Свинец |trans-title=Analytical Chemistry of the Elements: Lead |editor=Fillipova, N. A |publisher=] |language=ru}} | |||
| * {{cite web |title=Primary Lead Refining Technical Notes |url=http://www.ldaint.org/technotes2.htm |publisher=LDA International |accessdate=7 April 2007 |archiveurl=https://web.archive.org/web/20070322191856/http://www.ldaint.org/technotes2.htm |archivedate=22 March 2007 |ref=CITEREFPrimary Lead Refining}} | |||
| * {{cite |
* {{cite book |last=Prasad |first=P. J. |title=Conceptual Pharmacology |date=2010 |url=https://books.google.com/books?id=s0e_FlM8LKYC |publisher=Universities Press |isbn=978-81-7371-679-9 |access-date=21 June 2012 }} | ||
| * {{cite web |title=Primary Lead Refining Technical Notes |url=http://www.ldaint.org/technotes2.htm |publisher=LDA International |access-date=7 April 2007 |archive-url=https://web.archive.org/web/20070322191856/http://www.ldaint.org/technotes2.htm |archive-date=22 March 2007 |ref=CITEREFPrimary Lead Refining }} | |||
| * {{cite book |last=Putnam |first1=B. |title=The Sculptor's Way: A Guide to Modelling and Sculpture |url=https://books.google.com/books?id=-DC3UDjjPvgC |date=2003 |publisher=] |isbn=978-0-486-42313-5 |ref=harv}} | |||
| * {{cite web |author=Progressive Dynamics, Inc. |title=How Lead Acid Batteries Work: Battery Basics |url=http://www.progressivedyn.com/battery_basics.html |website=progressivedyn.com |access-date=3 July 2016 |archive-url=https://web.archive.org/web/20181119073137/https://www.progressivedyn.com/service/battery-basics/ |archive-date=19 November 2018 }} | |||
| * {{cite journal |last=Pyykkö |first=P. |title=Relativistic effects in structural chemistry |year=1988 |pages=563–94 |authorlink=Pekka Pyykkö |journal=] |volume=88 |doi=10.1021/cr00085a006 |issue=3 |ref=harv}} | |||
| * {{cite book |last1=Putnam |first1=B. |title=The Sculptor's Way: A Guide to Modelling and Sculpture |url=https://books.google.com/books?id=-DC3UDjjPvgC |date=2003 |publisher=] |isbn=978-0-486-42313-5 }} | |||
| * {{cite book |last=Rabinowitz |first=M. B. |chapter=Imputing lead sources from blood lead isotope ratios |editor-last1=Beard |editor-first1=M. E. |editor-last2=Allen Iske |editor-first2=S. D. |title=Lead in Paint, Soil, and Dust: Health Risks, Exposure Studies, Control Measures, Measurement Methods, and Quality Assurance |year=1995 |publisher=ASTM |isbn=978-0-8031-1884-3 |pages=63–75 |url=https://books.google.com/?id=-wt0AXfjiUIC |ref=harv}} | |||
| * {{cite |
* {{cite journal |last=Pyykkö |first=P. |title=Relativistic effects in structural chemistry |year=1988 |pages=563–94 |author-link=Pekka Pyykkö |journal=] |volume=88 |doi=10.1021/cr00085a006 |issue=3}} | ||
| * {{cite book |last=Rabinowitz |first=M. B. |chapter=Imputing lead sources from blood lead isotope ratios |editor-last1=Beard |editor-first1=M. E. |editor-last2=Allen Iske |editor-first2=S. D. |title=Lead in Paint, Soil, and Dust: Health Risks, Exposure Studies, Control Measures, Measurement Methods, and Quality Assurance |year=1995 |publisher=ASTM |isbn=978-0-8031-1884-3 |pages=63–75 |chapter-url=https://books.google.com/books?id=-wt0AXfjiUIC |doi=10.1520/stp12967s }} | |||
| * {{cite journal |last=Randerson |first=J. |title=Candle pollution |url=https://www.newscientist.com/article/mg17423481.900-candle-pollution.html |journal=] |accessdate=7 April 2007 |issue=2348 |date=2002 |ref=harv}} | |||
| * {{cite web |url=https://ocw.mit.edu/courses/earth-atmospheric-and-planetary-sciences/12-744-marine-isotope-chemistry-fall-2012/nuclear-systematics/MIT12_744F12_Lec4.pdf |title=Radioactive Decay Series |series=Nuclear Systematics |publisher=] |date=2012 |access-date=28 April 2018 |ref=CITEREFRadioactive Decay Series2012 }} | |||
| * {{cite journal |last=Reddy |first=A. |last2=Braun |first2=C. L. |title=Lead and the Romans |year=2010 |journal=] |volume=87 |issue=10 |doi=10.1021/ed100631y |ref=harv |pages=1052–55|bibcode=2010JChEd..87.1052R }} | |||
| * {{cite book |editor-last=Ramage |editor-first=C. K. |title=Lyman Cast Bullet Handbook |url=https://archive.org/details/lymancastbulleth00rama |url-access=registration |year=1980 |edition=3rd |publisher=Lyman Products Corporation }} | |||
| * {{cite journal |last1=Retief |first1=F. |last2=Cilliers |first2=L. P. |title=Lead poisoning in ancient Rome |year=2006 |pages=147–64 (149–51) |journal=Acta Theologica |volume=26 |issue=2 |doi=10.4314/actat.v26i2.52570 |ref=harv}} | |||
| * {{cite journal |last=Randerson |first=J. |title=Candle pollution |url=https://www.newscientist.com/article/mg17423481.900-candle-pollution.html |journal=] |access-date=7 April 2007 |issue=2348 |date=2002 }} | |||
| * {{cite book |last=Rich |first=V. |title=The International Lead Trade |year=1994 |publisher=] |isbn=978-0-85709-994-5 |url=https://books.google.com/books?id=mfPJCgAAQBAJ |ref=harv}} | |||
| * {{cite journal |last1=Reddy |first1=A. |last2=Braun |first2=C. L. |title=Lead and the Romans |year=2010 |journal=] |volume=87 |issue=10 |doi=10.1021/ed100631y |pages=1052–55|bibcode=2010JChEd..87.1052R }} | |||
| * {{cite book |last=Rieuwerts |first1=J. |title=The Elements of Environmental Pollution |date=2015 |publisher=Routledge |isbn=978-0-415-85919-6 |ref=harv}} | |||
| * {{Cite book|last=Renfrew|first=Daniel |title=Life without lead: contamination, crisis, and hope in Uruguay |date=2019 |isbn=978-0-520-96824-0|location=Oakland, California |publisher=University of California Press |oclc=1102765674}} | |||
| * {{cite journal |last1=Riva |first1=M. A. |last2=Lafranconi |first2=A. |last3=d'Orso |first3=M. I. |last4=Cesana |first4=G. |title=Lead poisoning: Historical aspects of a paradigmatic "occupational and environmental disease" |year=2012 |pages=11–16 |doi=10.5491/SHAW.2012.3.1.11 |pmid=22953225 |pmc=3430923 |journal=Safety and Health at Work |volume=3 |issue=1 |display-authors=3 |ref=harv}} | |||
| * {{cite journal |last1=Retief |first1=F. |last2=Cilliers |first2=L. P. |title=Lead poisoning in ancient Rome |year=2006 |pages=147–64 (149–51) |journal=] |volume=26 |issue=2 |doi=10.4314/actat.v26i2.52570|doi-access=free }} | |||
| * {{cite journal |last=Roederer |first=I. U. |last2=Kratz |first2=K.-L. |last3=Frebel |first3=A. |last4=Christlieb |first4=N. |last5=Pfeiffer |first5=B. |last6=Cowan |first6=J. J. |last7=Sneden |first7=C. |title=The end of nucleosynthesis: Production of lead and thorium in the early galaxy |year=2009 |pages=1963–80 |display-authors=3 |url=http://iopscience.iop.org/article/10.1088/0004-637X/698/2/1963/meta;jsessionid=DABAC204E5A01AB7C60E29E1B6D168B8.c1.iopscience.cld.iop.org |journal=The Astrophysical Journal |publisher=The American Astronomical Society |volume=698 |issue=2 |doi=10.1088/0004-637X/698/2/1963 |access-date=18 July 2016 |bibcode=2009ApJ...698.1963R |ref=harv|arxiv=0904.3105 }} | |||
| * {{cite book |last= |
* {{cite book |last=Rich |first=V. |title=The International Lead Trade |year=1994 |publisher=] |isbn=978-0-85709-994-5 |url=https://books.google.com/books?id=mfPJCgAAQBAJ }} | ||
| * {{cite book |last1=Rieuwerts |first1=J. |title=The Elements of Environmental Pollution |date=2015 |publisher=Routledge |isbn=978-0-415-85919-6}} | |||
| * {{cite book |last=Röhr |first=C. |chapter=Binäre Zintl-Phasen |trans-chapter=Binary Zintl Phases |title=Intermetallische Phasen |trans-title=Intermettallic Phases |publisher=] |language=German |url=http://ruby.chemie.uni-freiburg.de/Vorlesung/intermetallische_6_2.html |accessdate=18 February 2017 |year=2017 |ref=harv}} | |||
| * {{cite |
* {{cite journal |last1=Riva |first1=M. A. |last2=Lafranconi |first2=A. |last3=d'Orso |first3=M. I. |last4=Cesana |first4=G. |title=Lead poisoning: Historical aspects of a paradigmatic "occupational and environmental disease" |year=2012 |pages=11–16 |doi=10.5491/SHAW.2012.3.1.11 |pmid=22953225 |pmc=3430923 |journal=] |volume=3 |issue=1 |display-authors=3}} | ||
| * {{cite journal |last1=Roederer |first1=I. U. |last2=Kratz |first2=K.-L. |last3=Frebel |first3=A. |last4=Christlieb |first4=N. |last5=Pfeiffer |first5=B. |last6=Cowan |first6=J. J. |last7=Sneden |first7=C. |title=The end of nucleosynthesis: Production of lead and thorium in the early galaxy |year=2009 |pages=1963–80 |display-authors=3 |journal=] |volume=698 |issue=2 |doi=10.1088/0004-637X/698/2/1963 |bibcode=2009ApJ...698.1963R|arxiv=0904.3105 |s2cid=14814446 }} | |||
| * {{cite book |last=Samson |first=G. W. |title=The divine law as to wines |date=1885 |publisher=] |ref=harv}} | |||
| * {{cite book |last=Rogalski |first=A. |title=Infrared Detectors |edition=2nd |year=2010 |url=https://books.google.com/books?id=0VUJSafhaK0C |access-date=19 November 2016 |publisher=CRC Press |isbn=978-1-4200-7671-4 }} | |||
| * {{cite journal |last=Scarborough |first=J. |title=The myth of lead poisoning among the Romans: An essay review |date=1984 |pages=469–475 |journal=] |volume=39 |issue=4 |doi=10.1093/jhmas/39.4.469 |ref=harv |pmid=6389691}} | |||
| * {{cite book |last= |
* {{cite book |last=Röhr |first=C. |chapter=Binare Zintl-Phasen |trans-chapter=Binary Zintl Phases |title=Intermetallische Phasen |trans-title=Intermettallic Phases |publisher=] |language=de |chapter-url=http://ruby.chemie.uni-freiburg.de/Vorlesung/intermetallische_6_2.html |access-date=18 February 2017 |year=2017 }} | ||
| * {{cite |
* {{cite book |last1=Rudolph |first1=A. M. |last2=Rudolph |first2=C. D. |last3=Hostetter |first3=M. K. |last4=Lister |first4=George E. |last5=Siegel |first5=Norman J. |display-authors=3 |chapter=Lead |title=Rudolph's Pediatrics |year=2003 |page=369 |edition=21st |publisher=McGraw-Hill Professional |isbn=978-0-8385-8285-5}} | ||
| * {{cite book |last=Samson |first=G. W. |title=The divine law as to wines |url=https://archive.org/details/divinelawastowin00samsiala |date=1885 |publisher=] }} | |||
| * {{cite journal |first1=H. R. |last1=Sharma |first2=K. |last2=Nozawa |last3=Smerdon |first3=J. A. |last4=Nugent |first4=P. J. |last5=McLeod |first5=I. |last6=Dhanak |first6=V. R. |last7=Shimoda |first7=M. |last8=Ishii |first8=Y. |last9=Tsai |first9=A. P. |title=Templated three-dimensional growth of quasicrystalline lead |year=2013 |first10=R. |last10=McGrath |journal=Nature Communications |volume=4 |doi=10.1038/ncomms3715 |display-authors=3 |ref=harv|bibcode=2013NatCo...4E2715S }} | |||
| * {{cite journal |last=Scarborough |first=J. |title=The myth of lead poisoning among the Romans: An essay review |date=1984 |pages=469–475 |journal=] |volume=39 |issue=4 |doi=10.1093/jhmas/39.4.469 |pmid=6389691}} | |||
| * {{cite journal |last1=Sharma |first1=H. R. |last2=Smerdon |first2=J. A. |last3=Nugent |first3=P. J. |last4=Ribeiro |first4=A. |last5=McLeod |first5=I. |last6=Dhanak |first6=V. R. |last7=Shimoda |first7=M. |last8=Tsai |first8=A. P. |last9=McGrath |first9=R. |title=Crystalline and quasicrystalline allotropes of Pb formed on the fivefold surface of icosahedral Ag-In-Yb |year=2014 |page=174710 |journal=The Journal of Chemical Physics |volume=140 |issue=17 |doi=10.1063/1.4873596 |display-authors=3 |ref=harv|bibcode=2014JChPh.140q4710S }} | |||
| * {{cite book |last=Schoch |first=R. M. |author-link=Robert M. Schoch |title=Case Studies in Environmental Science |date=1996 |publisher=] |isbn=978-0-314-20397-7}} | |||
| * {{cite journal |last=Silverman |first=M. S. |title=High-pressure (70-k) synthesis of new crystalline lead dichalcogenides |date=1966 |pages=2067–69 |journal=] |volume=5 |issue=11 |doi=10.1021/ic50045a056 |ref=harv}} | |||
| * {{cite journal |last1= |
* {{cite journal |last1=Schoeters |first1=G. |last2=Den Hond |first2=E. |last3=Dhooge |first3=W. |last4=Van Larebeke |first4=N. |last5=Leijs |first5=M. |title=Endocrine disruptors and abnormalities of pubertal development |date=2008 |pages=168–175 |display-authors=3 |journal=] |volume=102 |issue=2 |doi=10.1111/j.1742-7843.2007.00180.x |pmid=18226071 |hdl=1854/LU-391408 |url=https://biblio.ugent.be/publication/391408/file/880739.pdf |hdl-access=free }} | ||
| * {{cite journal |first1=H. R. |last1=Sharma |first2=K. |last2=Nozawa |last3=Smerdon |first3=J. A. |last4=Nugent |first4=P. J. |last5=McLeod |first5=I. |last6=Dhanak |first6=V. R. |last7=Shimoda |first7=M. |last8=Ishii |first8=Y. |last9=Tsai |first9=A. P. |title=Templated three-dimensional growth of quasicrystalline lead |year=2013 |first10=R. |last10=McGrath |journal=] |volume=4 |page= 2715|doi=10.1038/ncomms3715 |pmid=24185350 |display-authors=3|bibcode=2013NatCo...4.2715S |doi-access=free }} | |||
| * {{cite journal |last1=Smirnov |first1=A. Yu. |last2=Borisevich |first2=V. D. |last3=Sulaberidze |first3=A. |title=Evaluation of specific cost of obtainment of lead-208 isotope by gas centrifuges using various raw materials |year=2012 |pages=373–78 |journal=Theoretical Foundations of Chemical Engineering |volume=46 |issue=4 |url=https://link.springer.com/article/10.1134%2FS0040579512040161#page-1 |doi=10.1134/s0040579512040161 |ref=harv}} | |||
| * {{cite journal |last1=Sharma |first1=H. R. |last2=Smerdon |first2=J. A. |last3=Nugent |first3=P. J. |last4=Ribeiro |first4=A. |last5=McLeod |first5=I. |last6=Dhanak |first6=V. R. |last7=Shimoda |first7=M. |last8=Tsai |first8=A. P. |last9=McGrath |first9=R. |title=Crystalline and quasicrystalline allotropes of Pb formed on the fivefold surface of icosahedral Ag-In-Yb |year=2014 |page=174710 |journal=] |volume=140 |issue=17 |doi=10.1063/1.4873596 |pmid=24811658 |display-authors=3|bibcode=2014JChPh.140q4710S }} | |||
| * {{cite journal |last1=Smith |first1=D. R. |last2=Flegal |first2=A. R. |title=Lead in the biosphere: Recent trends |year=1995 |pages=21–23 |volume=24 |jstor=4314280 |journal=] |ref=harv}} | |||
| * {{cite journal |last=Silverman |first=M. S. |title=High-pressure (70-k) synthesis of new crystalline lead dichalcogenides |date=1966 |pages=2067–69 |journal=] |volume=5 |issue=11 |doi=10.1021/ic50045a056}} | |||
| * {{cite book |last=Sokol |first=R. C. |chapter=Lead exposure and its effects on the reproductive system |title=Metals, Fertility, and Reproductive Toxicity |date=2005 |pages=117–53 |url=https://books.google.com/?id=Qt8LEB7_HyQC |publisher=CRC Press |isbn=978-0-415-70040-5 |editor-last=Golub |editor-first=M. S. |ref=harv}} | |||
| * {{cite news |last=Singh |first=P. |date=2017 |title=Over 73% of paints found to have excessive lead: Study |url=https://timesofindia.indiatimes.com/life-style/health-fitness/health-news/over-73-of-paints-found-to-have-excessive-lead-study/articleshow/61334283.cms |newspaper=] |access-date=3 May 2018 }} | |||
| * {{cite journal |last1=Stabenow |first1=F. |last2=Saak |first2=W. |last3=Weidenbruch |first3=M. |title=Tris(triphenylplumbyl)plumbate: An anion with three stretched lead–lead bonds |year=2003 |pages=2342–2343 |doi=10.1039/B305217F |journal=] |issue=18 |ref=harv}} | |||
| * {{cite journal |last1=Sinha |first1=S. P. |last2=Shelly |first2=<!--empty; same in source--> |last3=Sharma |first3=V. |last4=Meenakshi |first4=<!--empty; same in source--> |last5=Srivastava |first5=S. |last6=Srivastava |first6=M. M. |title=Neurotoxic effects of lead exposure among printing press workers |year=1993 |doi=10.1007/BF00192162 |pmid=8400649 |pages=490–93|journal=] |volume=51 |issue=4 |bibcode=1993BuECT..51..490S |s2cid=26631583 |display-authors=3}} | |||
| * {{cite journal |last=Stone |first=R. |year=1997 |title=An Element of Stability |journal=Science |volume=278 |issue=5338 |pp=571‒2 |doi=10.1126/science.278.5338.571 |ref=harv|bibcode=1997Sci...278..571S }} | |||
| * {{cite journal|last1=Slater|first1=J. C.|title=Atomic Radii in Crystals|journal=]|volume=41|issue=10|year=1964|pages=3199–3204|issn=0021-9606|doi=10.1063/1.1725697|bibcode=1964JChPh..41.3199S}} | |||
| * {{cite book |ref=harv |last1=Street |first1=A. |last2=Alexander |first2=W. |title=Metals in the Service of Man|edition=11th |url=https://books.google.com/books?id=cOCTPwAACAAJ |year=1998 |publisher=] |isbn=978-0-14-025776-2}} | |||
| * {{cite journal |last1=Smirnov |first1=A. Yu. |last2=Borisevich |first2=V. D. |last3=Sulaberidze |first3=A. |title=Evaluation of specific cost of obtainment of lead-208 isotope by gas centrifuges using various raw materials |year=2012 |pages=373–78 |journal=] |volume=46 |issue=4 |doi=10.1134/s0040579512040161|s2cid=98821122 }} | |||
| * {{cite book |last=Szczepanowska |first=H. M. |title=Conservation of Cultural Heritage: Key Principles and Approaches |url=https://books.google.com/books?id=yu9_LZ1AD_gC |year=2013 |publisher=Routledge |isbn=978-0-415-67474-4 |ref=harv}} | |||
| * {{cite book |last=Sokol |first=R. C. |chapter=Lead exposure and its effects on the reproductive system |title=Metals, Fertility, and Reproductive Toxicity |date=2005 |pages=117–53 |chapter-url=https://books.google.com/books?id=Qt8LEB7_HyQC |publisher=CRC Press |isbn=978-0-415-70040-5 |editor-last=Golub |editor-first=M. S. |doi=10.1201/9781420023282.ch6 |doi-broken-date=1 November 2024 }} | |||
| * {{cite journal |last1=Takahashi |first1=K. |last2=Boyd |first2=R. N. |last3=Mathews |first3=G. J. |last4=Yokoi |first4=K. |title=Bound-state beta decay of highly ionized atoms |date=1987 |url=http://www.ca.infn.it/~oldeman/resneu/p1522_1.pdf |display-authors=3 |accessdate=27 August 2013 |publisher=] for the ] |oclc=1639677 |volume=36 |issue=4 |journal=] C |archive-url=https://web.archive.org/web/20141021195204/http://www.ca.infn.it/~oldeman/resneu/p1522_1.pdf |archive-date=21 October 2014 |ref=harv |deadurl=yes |df= |format=PDF}} | |||
| * {{cite journal |last1=Stabenow |first1=F. |last2=Saak |first2=W. |last3=Weidenbruch |first3=M. |title=Tris(triphenylplumbyl)plumbate: An anion with three stretched lead–lead bonds |year=2003 |pages=2342–2343 |doi=10.1039/B305217F |pmid=14518905 |journal=] |issue=18}} | |||
| * {{cite web |last=Tarragó |first=A. |title=Case Studies in Environmental Medicine (CSEM) Lead Toxicity |date=2012 |url=https://www.atsdr.cdc.gov/csem/lead/docs/lead.pdf |publisher=] |ref=harv |format=PDF}} | |||
| * {{cite journal |last=Stone |first=R. |year=1997 |title=An Element of Stability |journal=] |volume=278 |issue=5338 |pages=571–572 |doi=10.1126/science.278.5338.571|bibcode=1997Sci...278..571S |s2cid=117946028 }} | |||
| * {{cite journal |last1=Tétreault |first1=J. |last2=Sirois |first2=J. |last3=Stamatopoulou |first3=E. |title=Studies of lead corrosion in acetic acid environments |date=1998 |pages=17–32 |journal=Studies in Conservation |volume=43 |issue=1 |doi=10.2307/1506633 |jstor=1506633 |ref=harv}} | |||
| * {{cite book |last1=Street |first1=A. |last2=Alexander |first2=W. |title=Metals in the Service of Man |edition=11th |url=https://books.google.com/books?id=cOCTPwAACAAJ |year=1998 |publisher=] |isbn=978-0-14-025776-2 }} | |||
| * {{cite web |author=<!--Not stated--> |title=Think Lead research summary |url=http://leadsheet.co.uk/wp-content/uploads/2016/06/lsa-research-summary.pdf |publisher=The Lead Sheet Association |access-date=20 February 2017 |ref=CITEREFThink Lead research |format=PDF}} | |||
| * {{cite book |last= |
* {{cite book |last=Szczepanowska |first=H. M. |title=Conservation of Cultural Heritage: Key Principles and Approaches |url=https://books.google.com/books?id=yu9_LZ1AD_gC |year=2013 |publisher=Routledge |isbn=978-0-415-67474-4 }} | ||
| * {{cite |
* {{cite journal |last1=Takahashi |first1=K. |last2=Boyd |first2=R. N. |last3=Mathews |first3=G. J. |last4=Yokoi |first4=K. |title=Bound-state beta decay of highly ionized atoms |date=1987 |url=http://www.ca.infn.it/~oldeman/resneu/p1522_1.pdf |display-authors=3 |access-date=27 August 2013 |oclc=1639677 |volume=36 |issue=4 |pages=1522–1528 |journal=] |archive-url=https://web.archive.org/web/20141021195204/http://www.ca.infn.it/~oldeman/resneu/p1522_1.pdf |archive-date=21 October 2014 |url-status=dead |doi=10.1103/physrevc.36.1522 |pmid=9954244 |bibcode=1987PhRvC..36.1522T }} | ||
| * {{cite web |last=Tarragó |first=A. |title=Case Studies in Environmental Medicine (CSEM) Lead Toxicity |date=2012 |url=https://www.atsdr.cdc.gov/csem/lead/docs/lead.pdf |publisher=Agency for Toxic Substances and Disease Registry |access-date=25 February 2017 |archive-date=13 October 2022 |archive-url=https://web.archive.org/web/20221013125815/https://atsdr.cdc.gov/csem/lead/docs/lead.pdf |url-status=dead }} | |||
| * {{cite journal |last1=Thürmer |first1=K. |last2=Williams |first2=E. |last3=Reutt-Robey |first3=J. |title=Autocatalytic oxidation of lead crystallite surfaces |date=2002 |pages=2033–35 |doi=10.1126/science.297.5589.2033 |journal=Science |volume=297 |issue=5589 |pmid=12242437 |bibcode=2002Sci...297.2033T |ref=harv}} | |||
| * {{cite journal |last1=Tétreault |first1=J. |last2=Sirois |first2=J. |last3=Stamatopoulou |first3=E. |title=Studies of lead corrosion in acetic acid environments |date=1998 |pages=17–32 |journal=] |volume=43 |issue=1 |doi=10.2307/1506633 |jstor=1506633}} | |||
| * {{cite web |last=Tolliday |first=B. |title=Significant growth in lead usage underlines its importance to the global economy |date=2014 |url=http://www.ila-lead.org/news/lead-in-the-news/2012-11-30/significant-growth-in-lead-usage-underlines-its--importance-to-the-global-economy- |publisher=] |access-date=28 February 2017 |quote=Global demand for lead has more than doubled since the early 1990s and almost 90% of use is now in lead-acid batteries |ref=harv}} | |||
| * {{cite book |author=Theodore Low De Vinne |year=1899 |title=The Practice of Typography: A Treatise on the Processes of Type-making, the Point System, the Names, Sizes, Styles, and Prices of Plain Printing Types |publisher=Century Company}} | |||
| * {{cite web |title=Toronto museum explores history of contraceptives |year=2003 |url=http://www.abc.net.au/news/2003-08-13/toronto-museum-explores-history-of-contraceptives/1463884 |website=ABC News |access-date=13 February 2016 |ref=CITEREFToronto museum explores2003}} | |||
| * {{cite web | |
* {{cite web |author=<!--Not stated--> |title=Think Lead research summary |url=http://leadsheet.co.uk/wp-content/uploads/2016/06/lsa-research-summary.pdf |publisher=The Lead Sheet Association |access-date=20 February 2017 |ref=CITEREFThink Lead research |archive-date=20 February 2017 |archive-url=https://web.archive.org/web/20170220173232/http://leadsheet.co.uk/wp-content/uploads/2016/06/lsa-research-summary.pdf |url-status=dead }} | ||
| * {{cite book |last=Thomson |first=T. |author-link=Thomas Thomson (chemist) |title=The History of Chemistry |year=1830 |url=https://archive.org/details/historychemistr01thomgoog |publisher=Henry Colburn and Richard Bentley (publishers) |isbn=9780405066238 }} | |||
| * {{cite web |title=Toxicological Profile for Lead |date=2007 |url=https://www.atsdr.cdc.gov/toxprofiles/tp13.pdf |work=Agency for Toxic Substances and Disease Registry/Division of Toxicology and Environmental Medicine |archiveurl=https://web.archive.org/web/20170701213753/https://www.atsdr.cdc.gov/toxprofiles/tp13.pdf |archivedate=2 July 2017 |ref=CITEREFToxicological Profile for Lead2007 |format=PDF}} | |||
| * {{cite book |last1=Thornton |first1=I. |last2=Rautiu |first2=R. |last3=Brush |first3=S. M. |title=Lead: The Facts |date=2001 |url=http://www.ila-lead.org/UserFiles/File/factbook/leadTheFacts.pdf |publisher=International Lead Association |access-date=5 February 2017 |isbn=978-0-9542496-0-1 |archive-date=26 July 2020 |archive-url=https://web.archive.org/web/20200726182045/https://www.ila-lead.org/UserFiles/File/factbook/leadTheFacts.pdf |url-status=dead }} | |||
| * {{cite web |author=<!--Not stated--> |title=Trace element emission from coal |date=2012 |url=http://www.iea-coal.org.uk/documents/83083/8631/Trace-element-emissions-from-coal,-CCC/203 |publisher=IEA Clean Coal Centre |access-date=1 March 2017 |ref=CITEREFTrace element emission2012}} | |||
| * {{cite journal | |
* {{cite journal |last1=Thürmer |first1=K. |last2=Williams |first2=E. |last3=Reutt-Robey |first3=J. |title=Autocatalytic oxidation of lead crystallite surfaces |date=2002 |pages=2033–35 |doi=10.1126/science.297.5589.2033 |journal=Science |volume=297 |issue=5589 |pmid=12242437 |bibcode=2002Sci...297.2033T |s2cid=6166273 }} | ||
| * {{cite web |last=Tolliday |first=B. |title=Significant growth in lead usage underlines its importance to the global economy |date=2014 |url=http://www.ila-lead.org/news/lead-in-the-news/2012-11-30/significant-growth-in-lead-usage-underlines-its--importance-to-the-global-economy- |publisher=] |access-date=28 February 2017 |quote=Global demand for lead has more than doubled since the early 1990s and almost 90% of use is now in lead–acid batteries |archive-date=28 February 2017 |archive-url=https://web.archive.org/web/20170228171821/http://www.ila-lead.org/news/lead-in-the-news/2012-11-30/significant-growth-in-lead-usage-underlines-its--importance-to-the-global-economy- |url-status=dead }} | |||
| * {{cite book |last=Tungate |first=M. |title=Branded Beauty: How Marketing Changed the Way We Look |url=https://books.google.com/books?id=jQA_B84aVhYC&pg=PA14 |year=2011 |publisher=Kogan Page Publishers |isbn=978-0-7494-6182-9 |ref=harv}} | |||
| * {{cite news |title=Toronto museum explores history of contraceptives |year=2003 |url=http://www.abc.net.au/news/2003-08-13/toronto-museum-explores-history-of-contraceptives/1463884 |website=ABC News |access-date=13 February 2016 |ref=CITEREFToronto museum explores2003 }} | |||
| * {{cite book |author=] |title=Final review of scientific information on lead |year=2010 |url=http://www.cms.int/sites/default/files/document/UNEP_GC26_INF_11_Add_1_Final_UNEP_Lead_review_and_apppendix_Dec_2010.pdf |publisher=Chemicals Branch, Division of Technology, Industry and Economics |access-date=31 January 2017 |ref=harv |format=PDF}} | |||
| * {{cite web |title=Toxic Substances Portal – Lead |url=http://www.atsdr.cdc.gov/PHS/PHS.asp?id=92&tid=22 |publisher=Agency for Toxic Substances and Disease Registry |url-status=dead |archive-url=https://web.archive.org/web/20110606072913/http://www.atsdr.cdc.gov/PHS/PHS.asp?id=92&tid=22 |archive-date=6 June 2011 |ref=CITEREFToxic Substances Portal }} | |||
| * {{cite web |author=United States Environmental Protection Agency |title=Regulatory Status of Waste Generated by Contractors and Residents from Lead-Based Paint Activities Conducted in Households (August 2000) |date=2000 |url=https://www.epa.gov/lead/regulatory-status-waste-generated-contractors-and-residents-lead-based-paint-activities |access-date=28 February 2017 |ref=harv}} | |||
| * {{cite web |title=Toxicological Profile for Lead |date=2007 |url=https://www.atsdr.cdc.gov/toxprofiles/tp13.pdf |work=Agency for Toxic Substances and Disease Registry/Division of Toxicology and Environmental Medicine |archive-url=https://web.archive.org/web/20170701213753/https://www.atsdr.cdc.gov/toxprofiles/tp13.pdf |archive-date=1 July 2017 |ref=CITEREFToxicological Profile for Lead2007 }} | |||
| * {{cite report |author=] |title=Q3D Elemental Impurities Guidance for Industry |date=2015 |page=41 |url=http://www.fda.gov/downloads/drugs/guidances/ucm371025.pdf |publisher=] |access-date=15 February 2017 |ref=harv |format=PDF}} | |||
| * {{cite web |author=<!--Not stated--> |title=Trace element emission from coal |date=2012 |url=https://www.iea-coal.org/trace-element-emissions-from-coal-ccc-203/ |publisher=IEA Clean Coal Centre |access-date=1 March 2017 |ref=CITEREFTrace element emission2012 |archive-date=11 March 2020 |archive-url=https://web.archive.org/web/20200311194516/https://www.iea-coal.org/trace-element-emissions-from-coal-ccc-203/ |url-status=dead }} | |||
| * {{cite book |author=] |title=Geological Survey Professional Paper |url=https://books.google.com/books?id=_LdUAAAAYAAJ |year=1973 |publisher=] |page=314 |ref=harv}} | |||
| * {{cite journal |last1=Tuček |first1=K. |last2=Carlsson |first2=J. |last3=Wider |first3=H. |title=Comparison of sodium and lead-cooled fast reactors regarding reactor physics aspects, severe safety and economical issues |date=2006 |pages=1589–98 |doi=10.1016/j.nucengdes.2006.04.019 |url=http://www.ecolo.org/documents/documents_in_english/SFRvsLFR-05.pdf |journal=] |volume=236 |issue=14–16 |bibcode=2006NuEnD.236.1589T }} | |||
| * {{cite report |author=United States Geological Survey |title=Lead |year=2005 |url=http://minerals.usgs.gov/minerals/pubs/commodity/lead/lead_mcs05.pdf |accessdate=20 February 2016 |ref=harv |format=PDF}} | |||
| * {{cite book |last=Tungate |first=M. |title=Branded Beauty: How Marketing Changed the Way We Look |url=https://books.google.com/books?id=jQA_B84aVhYC&pg=PA14 |year=2011 |publisher=Kogan Page Publishers |isbn=978-0-7494-6182-9 }} | |||
| * {{cite web |author=United States Geological Survey |title=Lead |year=2017 |url=https://minerals.usgs.gov/minerals/pubs/commodity/lead/mcs-2017-lead.pdf |access-date=8 May 2017 |series=Mineral Commodities Summaries |ref=harv |format=PDF}} | |||
| * {{cite report |author=UK Marine SACs Project |year=1999 |title=Water Quality |chapter=Lead |chapter-url=http://www.ukmarinesac.org.uk/activities/water-quality/wq8_4.htm |access-date=10 June 2018 |archive-date=17 February 2020 |archive-url=https://web.archive.org/web/20200217190442/http://www.ukmarinesac.org.uk/activities/water-quality/wq8_4.htm |url-status=dead }} | |||
| * {{cite web |author=] Nuclear Forensic Search Project |title=Decay Chains |url=http://metadata.berkeley.edu/nuclear-forensics/Decay%20Chains.html |accessdate=23 November 2015 |website=Nuclear Forensics: A Scientific Search Problem |ref=harv}} | |||
| * {{cite book |author=United Nations Environment Programme |title=Final review of scientific information on lead |year=2010 |url=http://www.cms.int/sites/default/files/document/UNEP_GC26_INF_11_Add_1_Final_UNEP_Lead_review_and_apppendix_Dec_2010.pdf |publisher=Chemicals Branch, Division of Technology, Industry and Economics |access-date=31 January 2017 |author-link=United Nations Environment Programme }} | |||
| * {{cite book |last1=Vasmer |first1=M. |author-link1=Max Vasmer |editor-last1=Trubachyov |editor-first1=O. N. |editor-link1=Oleg Trubachyov |editor-last2=Larin |editor-first2=B. O. |title=Этимологический словарь русского языка |trans-title=Russisches etymologisches Wörterbuch |year=1986–1987 |orig-year=1950–1958 |publisher=Progress |edition=2nd |language=Russian |url=http://starling.rinet.ru/cgi-bin/response.cgi?root=%2Fusr%2Flocal%2Fshare%2Fstarling%2Fmorpho&morpho=1&basename=morpho%5Cvasmer%5Cvasmer&first=1&off=&text_word=%D1%81%D1%83%D1%80%D1%8C%D0%BC%D0%B0&method_word=substring&ic_word=on&text_general=&method_general=substring&ic_general=on&text_origin=&method_origin=substring&ic_origin=on&text_trubachev=&method_trubachev=substring&ic_trubachev=on&text_editorial=&method_editorial=substring&ic_editorial=on&text_pages=&method_pages=substring&ic_pages=on&text_any=&method_any=substring&sort=word&ic_any=on |access-date=4 March 2017 |ref=CITEREFVasmer1950}} | |||
| * {{cite book |author=United States Environmental Protection Agency |title=AP 42 Compilation of Air Pollutant Emission Factors |date=2010 |chapter-url=https://www.epa.gov/lead/regulatory-status-waste-generated-contractors-and-residents-lead-based-paint-activities |edition=5th |chapter=Metallurgical Industry:Secondary Lead Processing |access-date=20 May 2018 }} | |||
| * {{cite book |last1=Luckey |first1=T. D. |last2=Venugopal |first2=B. |title=Physiologic and Chemical Basis for Metal Toxicity |year=1979 |publisher=Plenum Press |isbn=978-1-4684-2952-7 |url=https://books.google.com/books?id=7mxyBgAAQBAJ |ref=harv}} | |||
| * {{cite web |author=United States Environmental Protection Agency |title=Regulatory Status of Waste Generated by Contractors and Residents from Lead-Based Paint Activities Conducted in Households (August 2000) |date=2000 |url=https://www.epa.gov/lead/regulatory-status-waste-generated-contractors-and-residents-lead-based-paint-activities |access-date=28 February 2017 }} | |||
| * {{cite report |last1=Vogel |first1=N. A. |last2=Achilles |first2=R. |title=The Preservation and Repair of Historic Stained and Leaded Glass |year=2013 |url=https://www.nps.gov/tps/how-to-preserve/preservedocs/preservation-briefs/33Preserve-Brief-StainedGlass.pdf |publisher=] |accessdate=30 October 2016 |ref=harv |format=PDF}} | |||
| * {{cite web |author=United States Environmental Protection Agency |title=Best Management Practices for Lead at Outdoor Shooting Ranges |date=2005 |url=https://www.epa.gov/sites/production/files/documents/epa_bmp.pdf |access-date=12 June 2018 }} | |||
| * {{cite journal |last=Waldron |first=H. A. |title=Lead and lead poisoning in antiquity |date=1985 |pages=107–08 |journal=Medical History |volume=29 |issue=1 |pmc=1139494 |ref=harv|doi=10.1017/S0025727300043878}} | |||
| * {{cite report |author=] |title=Q3D Elemental Impurities Guidance for Industry |date=2015 |page=41 |url=https://www.fda.gov/downloads/drugs/guidances/ucm371025.pdf |publisher=] |access-date=15 February 2017 }} | |||
| * {{cite journal |url=https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4961898/pdf/ITX-8-055.pdf |title=Lead toxicity: A review |last1=Wani |first1=A. L. |last2=Ara |first2= A. |last3=Usman |first3=J. A. |date=2015 |volume=8 |issue=2 |pages=55–64 |doi=10.1515/intox-2015-0009 |ref=harv |journal=Interdisciplinary Toxicology |pmc=4961898 |pmid=27486361 |format=PDF}} | |||
| * {{cite book | |
* {{cite book |author=United States Geological Survey |title=Geological Survey Professional Paper |url=https://books.google.com/books?id=_LdUAAAAYAAJ |year=1973 |publisher=] |page=314 |author-link=United States Geological Survey }} | ||
| * {{cite |
* {{cite report |author=United States Geological Survey |title=Lead |year=2005 |url=http://minerals.usgs.gov/minerals/pubs/commodity/lead/lead_mcs05.pdf |access-date=20 February 2016 }} | ||
| * {{cite web |author=United States Geological Survey |title=Lead |year=2017 |series=Mineral Commodities Summaries |url=https://minerals.usgs.gov/minerals/pubs/commodity/lead/mcs-2017-lead.pdf |access-date=8 May 2017 }} | |||
| * {{cite journal |last1=Webb |first1=G. W. |last2=Marsiglio |first2=F. |last3=Hirsch |first3=J. E. |title=Superconductivity in the elements, alloys and simple compounds |journal=Physica C: Superconductivity and its Applications |volume=514 |year=2015 |pages=17–27 |doi=10.1016/j.physc.2015.02.037 |ref=harv|arxiv=1502.04724 |bibcode=2015PhyC..514...17W }} | |||
| * {{cite web |author=] Nuclear Forensic Search Project |title=Decay Chains |url=http://metadata.berkeley.edu/nuclear-forensics/Decay%20Chains.html |access-date=23 November 2015 |website=Nuclear Forensics: A Scientific Search Problem }} | |||
| * {{cite book |last1=Whitten |first1=K. W. |last2=Gailey |first2=K. D. |last3=David |first3=R. E. |title=General chemistry with qualitative analysis |date=1996 |edition=3rd |publisher=Saunders College |isbn=978-0-03-012864-6 |ref=harv}} | |||
| * {{cite book |last1=Vasmer |first1=M. |author-link1=Max Vasmer |editor-last1=Trubachyov |editor-first1=O. N. |editor-link1=Oleg Trubachyov |editor-last2=Larin |editor-first2=B. O. |title=Этимологический словарь русского языка |trans-title=Russisches etymologisches Worterbuch |year=1986–1987 |orig-date=1950–1958 |publisher=Progress |edition=2nd |language=ru |url=http://starling.rinet.ru/cgi-bin/response.cgi?root=%2Fusr%2Flocal%2Fshare%2Fstarling%2Fmorpho&morpho=1&basename=morpho%5Cvasmer%5Cvasmer&first=1&off=&text_word=%D1%81%D1%83%D1%80%D1%8C%D0%BC%D0%B0&method_word=substring&ic_word=on&text_general=&method_general=substring&ic_general=on&text_origin=&method_origin=substring&ic_origin=on&text_trubachev=&method_trubachev=substring&ic_trubachev=on&text_editorial=&method_editorial=substring&ic_editorial=on&text_pages=&method_pages=substring&ic_pages=on&text_any=&method_any=substring&sort=word&ic_any=on |access-date=4 March 2017 }} | |||
| * {{cite book |last1=Wiberg |first1=E. |last2=Wiberg |first2=N. |last3=Holleman |first3=A. F. |title=Inorganic Chemistry |date=2001 |publisher=] |isbn=978-0-12-352651-9 |ref=harv}} | |||
| * {{cite |
* {{cite report |last1=Vogel |first1=N. A. |last2=Achilles |first2=R. |title=The Preservation and Repair of Historic Stained and Leaded Glass |year=2013 |url=https://www.nps.gov/tps/how-to-preserve/preservedocs/preservation-briefs/33Preserve-Brief-StainedGlass.pdf |publisher=] |access-date=30 October 2016 }} | ||
| * {{cite journal |last= |
* {{cite journal |last=Waldron |first=H. A. |title=Lead and lead poisoning in antiquity |date=1985 |pages=107–08 |journal=] |volume=29 |issue=1 |pmc=1139494|doi=10.1017/S0025727300043878}} | ||
| * {{cite journal |title=Lead toxicity: A review |last1=Wani |first1=A. L. |last2=Ara |first2= A. |last3=Usman |first3=J. A. |date=2015 |volume=8 |issue=2 |pages=55–64 |doi=10.1515/intox-2015-0009 |journal=] |pmc=4961898 |pmid=27486361 }} | |||
| * {{Cite journal|last=Winder |first=C. |title=The history of lead — Part 1 |year=1993a |url=http://lead.org.au/lanv2n1/lanv2n1-11.html |access-date=5 February 2016 |deadurl=yes |publisher=The LEAD Group |archiveurl=https://web.archive.org/web/20070831210244/http://lead.org.au/lanv2n1/lanv2n1-11.html |archivedate=31 August 2007 |journal=LEAD Action News |volume=2 |issue=1 |issn=1324-6011 |ref=harv}} | |||
| * {{cite book |last1=Weast |first1=R. C. |last2=Astle |first2=M. J. |last3=Beyer |first3=W. H. |title=CRC Handbook of Chemistry and Physics: A Ready-reference Book of Chemical and Physical Data |url=https://books.google.com/books?id=yThsvgAACAAJ |year=1983 |publisher=CRC Press |isbn=978-0-8493-0464-4 }} | |||
| * {{cite journal |last=Winder |first=C. |title=The history of lead — Part 3 |year=1993b |url=http://lead.org.au/lanv2n3/lanv2n3-22.html |access-date=12 February 2016 |deadurl=yes |archiveurl=https://web.archive.org/web/20070831200744/http://lead.org.au/lanv2n3/lanv2n3-22.html |archivedate=31 August 2007 |journal=LEAD Action News |volume=2 |issue=3 |issn=1324-6011 |ref=harv}} | |||
| * {{cite web |author=<!--Not stated--> |title=Weatherings to Parapets and Cornices |url=http://leadsheet.co.uk/home/lsa-pocket-guide/weatherings-to-parapets-and-cornices/ |publisher=The Lead Sheet Association |access-date=20 February 2017 |ref=CITEREFWeatherings to Parapets |archive-date=20 February 2017 |archive-url=https://web.archive.org/web/20170220172917/http://leadsheet.co.uk/home/lsa-pocket-guide/weatherings-to-parapets-and-cornices/ |url-status=dead }} | |||
| * {{cite book |last=Windholz |first=M. |title=] |date=1976 |id=Monograph 8393 |edition=9th |publisher=] |isbn=978-0-911910-26-1 |ref=harv}} | |||
| * {{cite book|last=Webb|first=G. A.|title=Nuclear Magnetic Resonance|url=https://books.google.com/books?id=ofmQCwsnAHMC&pg=PA115|year=2000|publisher=Royal Society of Chemistry|isbn=978-0-85404-327-9}} | |||
| * {{cite book |author=] |chapter=Lead |title=Air quality guidelines for Europe |year=2000 |pages=149–53 |url=http://www.euro.who.int/__data/assets/pdf_file/0005/74732/E71922.pdf |publisher=Regional Office for Europe |isbn=978-92-890-1358-1 |oclc=475274390 |ref=harv |format=PDF}} | |||
| * {{cite journal |last1=Webb |first1=G. W. |last2=Marsiglio |first2=F. |last3=Hirsch |first3=J. E. |title=Superconductivity in the elements, alloys and simple compounds |journal=Physica C: Superconductivity and Its Applications |volume=514 |year=2015 |pages=17–27 |doi=10.1016/j.physc.2015.02.037|arxiv=1502.04724 |bibcode=2015PhyC..514...17W |s2cid=119290828 }} | |||
| * {{cite web |author=] |title=Nuclear Radiation and Health Effects |year=2015 |url=http://www.world-nuclear.org/info/Safety-and-Security/Radiation-and-Health/Nuclear-Radiation-and-Health-Effects/ |accessdate=12 November 2015 |ref=harv}} | |||
| * {{cite book |last1=Whitten |first1=K. W. |last2=Gailey |first2=K. D. |last3=David |first3=R. E. |title=General chemistry with qualitative analysis |date=1996 |edition=3rd |publisher=Saunders College |isbn=978-0-03-012864-6 |url=https://archive.org/details/generalchemistry00whit }} | |||
| * {{cite journal |last=Yong |first=L. |last2=Hoffmann |first2=S. D. |last3=Fässler |first3=T. F. |title=A low-dimensional arrangement of <sup>4−</sup> clusters in <sub>2</sub>K<sub>2</sub>Pb<sub>9</sub>·(en)<sub>1.5</sub> |year=2006 |pages=4774–78 |journal=Inorganica Chimica Acta |volume=359 |issue=15 |publisher=Elsevier |doi=10.1016/j.ica.2006.04.017 |ref=harv}} | |||
| * {{cite book |last1=Wiberg |first1=E. |last2=Wiberg |first2=N. |last3=Holleman |first3=A. F. |title=Inorganic Chemistry |date=2001 |publisher=] |isbn=978-0-12-352651-9}} | |||
| * {{cite web |last=Young |first=S. |title=Battling lead contamination, one fish bone at a time |date=2012 |url=http://coastguard.dodlive.mil/2012/07/battling-lead-contamination-one-fish-bone-at-a-time/ |publisher=] |work=Compass |access-date=11 February 2017 |ref=harv}} | |||
| * {{cite book |last1= |
* {{cite book |last1=Wilkes |first1=C. E. |last2=Summers |first2=J. W. |last3=Daniels |first3=C. A. |last4=Berard |first4=M. T. |title=PVC Handbook |date=2005 |url=https://books.google.com/books?id=YUkJNI9QYsUC |isbn=978-1-56990-379-7 |display-authors=3 |publisher=Hanser }} | ||
| * {{cite journal |last=Willey |first=D. G. |author-link=David Willey (physicist) |title=The physics behind four amazing demonstrations — CSI |year=1999 |journal=] |volume=23 |issue=6 |url=http://www.csicop.org/si/show/physics_behind_four_amazing_demonstrations |access-date=6 September 2016 }} | |||
| * {{cite journal |last=Zhang |first=X. |last2=Yang |first2=L. |last3=Li |first3=Y. |last4=Li |first4=H. |last5=Wang |first5=W. |last6=Ye |first6=B. |title=Impacts of lead/zinc mining and smelting on the environment and human health in China |year=2012 |pages=2261–73 |displayauthors=3 |journal=Environmental Monitoring and Assessment |volume=184 |issue=4 |doi=10.1007/s10661-011-2115-6 |pmid=21573711 |ref=harv}} | |||
| * {{Cite journal |last=Winder |first=C. |title=The history of lead — Part 1 |year=1993a |url=http://lead.org.au/lanv2n1/lanv2n1-11.html |access-date=5 February 2016 |url-status=dead |archive-url=https://web.archive.org/web/20070831210244/http://lead.org.au/lanv2n1/lanv2n1-11.html |archive-date=31 August 2007 |journal=LEAD Action News |volume=2 |issue=1 |issn=1324-6011 }} | |||
| * {{cite book |last=Zhao |first=F. |title=Information Technology Entrepreneurship and Innovation |url=https://books.google.com/books?id=aXm9AQAAQBAJ |year=2008 |publisher=IGI Global |isbn=978-1-59904-902-1 |page=440 |ref=harv}} | |||
| * {{cite journal |last=Winder |first=C. |title=The history of lead — Part 3 |year=1993b |url=http://lead.org.au/lanv2n3/lanv2n3-22.html |access-date=12 February 2016 |url-status=dead |archive-url=https://web.archive.org/web/20070831200744/http://lead.org.au/lanv2n3/lanv2n3-22.html |archive-date=31 August 2007 |journal=LEAD Action News |volume=2 |issue=3 |issn=1324-6011 }} | |||
| * {{cite book |last1=Zuckerman |first1=J. J. |last2=Hagen |first2=A. P. |title=Inorganic Reactions and Methods, the Formation of Bonds to Halogens |date=1989 |publisher=John Wiley & Sons |isbn=978-0-471-18656-4 |ref=harv}} | |||
| * {{cite book |last= |
* {{cite book |last=Windholz |first=M. |title=Merck Index of Chemicals and Drugs |date=1976 |id=Monograph 8393 |edition=9th |publisher=] |isbn=978-0-911910-26-1|title-link=Merck Index }} | ||
| * {{cite journal|last1=Wood|first1=J. R.|last2=Hsu|first2=Y-T.|last3=Bell|first3=C.|year=2021|title=Sending Laurion Back to the Future: Bronze Age Silver and the Source of Confusion|journal=]|volume=56|issue=9|s2cid=236973111|doi=10.11141/ia.56.9|url=https://discovery.ucl.ac.uk/id/eprint/10130376/1/Sending%20Laurion%20back%20to%20the%20future_ONLINE_PDF_ia.56.9.pdf}} | |||
| * {{cite journal |last=Zýka |first=J. |title=Analytical study of the basic properties of lead tetraacetate as oxidizing agent |year=1966 |pages=569–81 |journal=Pure and Applied Chemistry |volume=13 |issue=4 |doi=10.1351/pac196613040569 |url=http://www.sciencemadness.org/talk/files.php?pid=242223&aid=18041 |accessdate=2 March 2017 |ref=harv}} | |||
| * {{cite report |author=] |year=1995 |title=Environmental Health Criteria 165: Inorganic Lead |url=http://www.inchem.org/documents/ehc/ehc/ehc165.htm |access-date=10 June 2018 }} | |||
| * {{cite book |author=World Health Organization |chapter=Lead |title=Air quality guidelines for Europe |year=2000 |pages= |chapter-url=http://www.euro.who.int/__data/assets/pdf_file/0005/74732/E71922.pdf |publisher=Regional Office for Europe |isbn=978-92-890-1358-1 |oclc=475274390 |url=https://archive.org/details/airqualityguidel00ebra/page/149 }} | |||
| * {{Cite web|author=World Health Organization|url=https://www.who.int/news-room/fact-sheets/detail/lead-poisoning-and-health|title=Lead poisoning and health|year=2018|language=en|access-date=17 February 2019}} | |||
| * {{cite web |author=World Nuclear Association |title=Nuclear Radiation and Health Effects |year=2015 |url=http://www.world-nuclear.org/info/Safety-and-Security/Radiation-and-Health/Nuclear-Radiation-and-Health-Effects/ |access-date=12 November 2015 |author-link=World Nuclear Association |archive-date=24 December 2015 |archive-url=https://web.archive.org/web/20151224005416/http://www.world-nuclear.org/info/Safety-and-Security/Radiation-and-Health/Nuclear-Radiation-and-Health-Effects/ |url-status=dead }} | |||
| * {{Cite book|last1=Wrackmeyer|first1=B.|last2=Horchler|first2=K.|chapter=<sup>207</sup>Pb-NMR Parameters|year=1990|title=Annual Reports on NMR Spectroscopy|chapter-url=https://books.google.com/books?id=y1vs0XIgDCQC&pg=PA249|publisher=Academic Press|isbn=978-0-08-058405-8|pages=249–303|volume=22|doi=10.1016/S0066-4103(08)60257-4}} | |||
| * {{cite journal |last1=Yong |first1=L. |last2=Hoffmann |first2=S. D. |last3=Fässler |first3=T. F. |title=A low-dimensional arrangement of <sup>4·</sup> clusters in <sub>2</sub>K<sub>2</sub>Pb<sub>9</sub>·(en)<sub>1.5</sub> |year=2006 |pages=4774–78 |journal=] |volume=359 |issue=15 |doi=10.1016/j.ica.2006.04.017}} | |||
| * {{cite web |last=Young |first=S. |title=Battling lead contamination, one fish bone at a time |date=2012 |url=http://coastguard.dodlive.mil/2012/07/battling-lead-contamination-one-fish-bone-at-a-time/ |publisher=] |work=Compass |access-date=11 February 2017 |archive-date=14 June 2013 |archive-url=https://web.archive.org/web/20130614104453/http://coastguard.dodlive.mil/2012/07/battling-lead-contamination-one-fish-bone-at-a-time/ |url-status=dead }} | |||
| * {{cite book |last1=Yu |first1=L. |last2=Yu |first2=H. |title=Chinese Coins: Money in History and Society |year=2004 |url=https://books.google.com/books?id=QfWQB0peEWYC |publisher=Long River Press |isbn=978-1-59265-017-0 }} | |||
| * {{cite journal |last1=Zhang |first1=X. |last2=Yang |first2=L. |last3=Li |first3=Y. |last4=Li |first4=H. |last5=Wang |first5=W. |last6=Ye |first6=B. |title=Impacts of lead/zinc mining and smelting on the environment and human health in China |year=2012 |pages=2261–73 |display-authors=3 |journal=] |volume=184 |issue=4 |doi=10.1007/s10661-011-2115-6 |pmid=21573711|bibcode=2012EMnAs.184.2261Z |s2cid=20372810 }} | |||
| * {{cite book |last=Zhao |first=F. |title=Information Technology Entrepreneurship and Innovation |url=https://books.google.com/books?id=aXm9AQAAQBAJ |year=2008 |publisher=IGI Global |isbn=978-1-59904-902-1 |page=440 }} | |||
| * {{cite book |last1=Zuckerman |first1=J. J. |last2=Hagen |first2=A. P. |title=Inorganic Reactions and Methods, the Formation of Bonds to Halogens |date=1989 |publisher=John Wiley & Sons |isbn=978-0-471-18656-4}} | |||
| * {{cite book |last=Zweifel |first=H. |title=Plastics Additives Handbook |date=2009 |url=https://books.google.com/books?id=WbBH5QFXOhoC |isbn=978-3-446-40801-2 |publisher=Hanser }} | |||
| * {{cite journal |last=Zýka |first=J. |title=Analytical study of the basic properties of lead tetraacetate as oxidizing agent |year=1966 |pages=569–81 |journal=] |volume=13 |issue=4 |doi=10.1351/pac196613040569 |doi-broken-date=3 December 2024 |s2cid=96821219 |doi-access=free }} | |||
| {{Refend}} | {{Refend}} | ||
| == Further reading == | == Further reading == | ||
| * {{cite book |publisher=De Gruyter | |
* {{cite book |publisher=De Gruyter |date=2017 |series=Metal Ions in Life Sciences |volume=17 |title=Lead: Its Effects on Environment and Health |editor1-last=Astrid |editor1-first=S. |editor2-last=Helmut |editor2-first=S. |editor3-last=Sigel |editor3-first=R. K. O. |isbn=978-3-11-044107-9}} | ||
| * {{cite book |editor1-first=J. S. |editor1-last=Casas |editor2-first=J. |editor2-last=Sordo |url=https:// |
* {{cite book |editor1-first=J. S. |editor1-last=Casas |editor2-first=J. |editor2-last=Sordo |url=https://books.google.com/books?id=D9nYWCv_FE4C |title=Lead Chemistry, Analytical Aspects. Environmental Impacts and Health Effects |date=2006 |publisher=Elsevier |isbn=978-0-444-52945-9}} | ||
| * {{cite journal | title=Toxicologic and epidemiologic clues from the characterization of the 1952 London smog fine particulate matter in archival autopsy lung tissues| year=2003| pmid=12842775| last1=Hunt| first1=A.| last2=Abraham| first2=J. L.| last3=Judson| first3=B.| last4=Berry| first4=C. L.| journal=Environmental Health Perspectives| volume=111| issue=9| pages=1209–1214| doi=10.1289/ehp.6114| pmc=1241576| bibcode=2003EnvHP.111.1209H}} | |||
| * Ingalls, Walter Renton (1865-), | |||
| * {{cite journal | url=https://www.sciencedirect.com/science/article/abs/pii/S1011134414001286 | title=Assessing the mechanism of DNA damage induced by lead through direct and indirect interactions| year=2014| doi=10.1016/j.jphotobiol.2014.04.020| last1=Zhang| first1=Hao| last2=Wei| first2=Kai| last3=Zhang| first3=Mengyu| last4=Liu| first4=Rutao| last5=Chen| first5=Yadong| journal=Journal of Photochemistry and Photobiology B: Biology| volume=136| pages=46–53| pmid=24844619| bibcode=2014JPPB..136...46Z}} | |||
| == |
==External links== | ||
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Latest revision as of 05:30, 2 January 2025
This article is about the chemical element. For other uses, see Lead (disambiguation).Chemical element with atomic number 82 (Pb)
Lead (/lɛd/) is a chemical element; it has symbol Pb (from Latin plumbum) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements.
Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases, and it tends to form covalent bonds. Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited to organolead compounds. Like the lighter members of the group, lead tends to bond with itself; it can form chains and polyhedral structures.
Since lead is easily extracted from its ores, prehistoric people in the Near East were aware of it. Galena is a principal ore of lead which often bears silver. Interest in silver helped initiate widespread extraction and use of lead in ancient Rome. Lead production declined after the fall of Rome and did not reach comparable levels until the Industrial Revolution. Lead played a crucial role in the development of the printing press, as movable type could be relatively easily cast from lead alloys. In 2014, the annual global production of lead was about ten million tonnes, over half of which was from recycling. Lead's high density, low melting point, ductility and relative inertness to oxidation make it useful. These properties, combined with its relative abundance and low cost, resulted in its extensive use in construction, plumbing, batteries, bullets, shots, weights, solders, pewters, fusible alloys, lead paints, leaded gasoline, and radiation shielding.
Lead is a neurotoxin that accumulates in soft tissues and bones. It damages the nervous system and interferes with the function of biological enzymes, causing neurological disorders ranging from behavioral problems to brain damage, and also affects general health, cardiovascular, and renal systems. Lead's toxicity was first documented by ancient Greek and Roman writers, who noted some of the symptoms of lead poisoning, but became widely recognized in Europe in the late 19th century AD.
Physical properties
Atomic
A lead atom has 82 electrons, arranged in an electron configuration of [Xe]4f5d6s6p. The sum of lead's first and second ionization energies—the total energy required to remove the two 6p electrons—is close to that of tin, lead's upper neighbor in the carbon group. This is unusual; ionization energies generally fall going down a group, as an element's outer electrons become more distant from the nucleus, and more shielded by smaller orbitals.
The sum of the first four ionization energies of lead exceeds that of tin, contrary to what periodic trends would predict. This is explained by relativistic effects, which become significant in heavier atoms, which contract s and p orbitals such that lead's 6s electrons have larger binding energies than its 5s electrons. A consequence is the so-called inert pair effect: the 6s electrons of lead become reluctant to participate in bonding, stabilising the +2 oxidation state and making the distance between nearest atoms in crystalline lead unusually long.
Lead's lighter carbon group congeners form stable or metastable allotropes with the tetrahedrally coordinated and covalently bonded diamond cubic structure. The energy levels of their outer s- and p-orbitals are close enough to allow mixing into four hybrid sp orbitals. In lead, the inert pair effect increases the separation between its s- and p-orbitals, and the gap cannot be overcome by the energy that would be released by extra bonds following hybridization. Rather than having a diamond cubic structure, lead forms metallic bonds in which only the p-electrons are delocalized and shared between the Pb ions. Lead consequently has a face-centered cubic structure like the similarly sized divalent metals calcium and strontium.
Bulk
Pure lead has a bright, shiny gray appearance with a hint of blue. It tarnishes on contact with moist air and takes on a dull appearance, the hue of which depends on the prevailing conditions. Characteristic properties of lead include high density, malleability, ductility, and high resistance to corrosion due to passivation.
Lead's close-packed face-centered cubic structure and high atomic weight result in a density of 11.34 g/cm, which is greater than that of common metals such as iron (7.87 g/cm), copper (8.93 g/cm), and zinc (7.14 g/cm). This density is the origin of the idiom to go over like a lead balloon. Some rarer metals are denser: tungsten and gold are both at 19.3 g/cm, and osmium—the densest metal known—has a density of 22.59 g/cm, almost twice that of lead.
Lead is a very soft metal with a Mohs hardness of 1.5; it can be scratched with a fingernail. It is quite malleable and somewhat ductile. The bulk modulus of lead—a measure of its ease of compressibility—is 45.8 GPa. In comparison, that of aluminium is 75.2 GPa; copper 137.8 GPa; and mild steel 160–169 GPa. Lead's tensile strength, at 12–17 MPa, is low (that of aluminium is 6 times higher, copper 10 times, and mild steel 15 times higher); it can be strengthened by adding small amounts of copper or antimony.
The melting point of lead—at 327.5 °C (621.5 °F)—is very low compared to most metals. Its boiling point of 1749 °C (3180 °F) is the lowest among the carbon-group elements. The electrical resistivity of lead at 20 °C is 192 nanoohm-meters, almost an order of magnitude higher than those of other industrial metals (copper at 15.43 nΩ·m; gold 20.51 nΩ·m; and aluminium at 24.15 nΩ·m). Lead is a superconductor at temperatures lower than 7.19 K; this is the highest critical temperature of all type-I superconductors and the third highest of the elemental superconductors.
Isotopes
Main article: Isotopes of leadNatural lead consists of four stable isotopes with mass numbers of 204, 206, 207, and 208, and traces of six short-lived radioisotopes with mass numbers 209–214 inclusive. The high number of isotopes is consistent with lead's atomic number being even. Lead has a magic number of protons (82), for which the nuclear shell model accurately predicts an especially stable nucleus. Lead-208 has 126 neutrons, another magic number, which may explain why lead-208 is extraordinarily stable.
With its high atomic number, lead is the heaviest element whose natural isotopes are regarded as stable; lead-208 is the heaviest stable nucleus. (This distinction formerly fell to bismuth, with an atomic number of 83, until its only primordial isotope, bismuth-209, was found in 2003 to decay very slowly.) The four stable isotopes of lead could theoretically undergo alpha decay to isotopes of mercury with a release of energy, but this has not been observed for any of them; their predicted half-lives range from 10 to 10 years (at least 10 times the current age of the universe).
Three of the stable isotopes are found in three of the four major decay chains: lead-206, lead-207, and lead-208 are the final decay products of uranium-238, uranium-235, and thorium-232, respectively. These decay chains are called the uranium chain, the actinium chain, and the thorium chain. Their isotopic concentrations in a natural rock sample depends greatly on the presence of these three parent uranium and thorium isotopes. For example, the relative abundance of lead-208 can range from 52% in normal samples to 90% in thorium ores; for this reason, the standard atomic weight of lead is given to only one decimal place. As time passes, the ratio of lead-206 and lead-207 to lead-204 increases, since the former two are supplemented by radioactive decay of heavier elements while the latter is not; this allows for lead–lead dating. As uranium decays into lead, their relative amounts change; this is the basis for uranium–lead dating. Lead-207 exhibits nuclear magnetic resonance, a property that has been used to study its compounds in solution and solid state, including in the human body.
Apart from the stable isotopes, which make up almost all lead that exists naturally, there are trace quantities of a few radioactive isotopes. One of them is lead-210; although it has a half-life of only 22.2 years, small quantities occur in nature because lead-210 is produced by a long decay series that starts with uranium-238 (that has been present for billions of years on Earth). Lead-211, −212, and −214 are present in the decay chains of uranium-235, thorium-232, and uranium-238, respectively, so traces of all three of these lead isotopes are found naturally. Minute traces of lead-209 arise from the very rare cluster decay of radium-223, one of the daughter products of natural uranium-235, and the decay chain of neptunium-237, traces of which are produced by neutron capture in uranium ores. Lead-213 also occurs in the decay chain of neptunium-237. Lead-210 is particularly useful for helping to identify the ages of samples by measuring its ratio to lead-206 (both isotopes are present in a single decay chain).
In total, 43 lead isotopes have been synthesized, with mass numbers 178–220. Lead-205 is the most stable radioisotope, with a half-life of around 1.70×10 years. The second-most stable is lead-202, which has a half-life of about 52,500 years, longer than any of the natural trace radioisotopes.
Chemistry
Bulk lead exposed to moist air forms a protective layer of varying composition. Lead(II) carbonate is a common constituent; the sulfate or chloride may also be present in urban or maritime settings. This layer makes bulk lead effectively chemically inert in the air. Finely powdered lead, as with many metals, is pyrophoric, and burns with a bluish-white flame.
Fluorine reacts with lead at room temperature, forming lead(II) fluoride. The reaction with chlorine is similar but requires heating, as the resulting chloride layer diminishes the reactivity of the elements. Molten lead reacts with the chalcogens to give lead(II) chalcogenides.
Lead metal resists sulfuric and phosphoric acid but not hydrochloric or nitric acid; the outcome depends on insolubility and subsequent passivation of the product salt. Organic acids, such as acetic acid, dissolve lead in the presence of oxygen. Concentrated alkalis dissolve lead and form plumbites.
Inorganic compounds
See also: Lead compoundsLead shows two main oxidation states: +4 and +2. The tetravalent state is common for the carbon group. The divalent state is rare for carbon and silicon, minor for germanium, important (but not prevailing) for tin, and is the more important of the two oxidation states for lead. This is attributable to relativistic effects, specifically the inert pair effect, which manifests itself when there is a large difference in electronegativity between lead and oxide, halide, or nitride anions, leading to a significant partial positive charge on lead. The result is a stronger contraction of the lead 6s orbital than is the case for the 6p orbital, making it rather inert in ionic compounds. The inert pair effect is less applicable to compounds in which lead forms covalent bonds with elements of similar electronegativity, such as carbon in organolead compounds. In these, the 6s and 6p orbitals remain similarly sized and sp hybridization is still energetically favorable. Lead, like carbon, is predominantly tetravalent in such compounds.
There is a relatively large difference in the electronegativity of lead(II) at 1.87 and lead(IV) at 2.33. This difference marks the reversal in the trend of increasing stability of the +4 oxidation state going down the carbon group; tin, by comparison, has values of 1.80 in the +2 oxidation state and 1.96 in the +4 state.
Lead(II)
Lead(II) compounds are characteristic of the inorganic chemistry of lead. Even strong oxidizing agents like fluorine and chlorine react with lead to give only PbF2 and PbCl2. Lead(II) ions are usually colorless in solution, and partially hydrolyze to form Pb(OH) and finally (in which the hydroxyl ions act as bridging ligands), but are not reducing agents as tin(II) ions are. Techniques for identifying the presence of the Pb ion in water generally rely on the precipitation of lead(II) chloride using dilute hydrochloric acid. As the chloride salt is sparingly soluble in water, in very dilute solutions the precipitation of lead(II) sulfide is instead achieved by bubbling hydrogen sulfide through the solution.
Lead monoxide exists in two polymorphs, litharge α-PbO (red) and massicot β-PbO (yellow), the latter being stable only above around 488 °C. Litharge is the most commonly used inorganic compound of lead. There is no lead(II) hydroxide; increasing the pH of solutions of lead(II) salts leads to hydrolysis and condensation. Lead commonly reacts with heavier chalcogens. Lead sulfide is a semiconductor, a photoconductor, and an extremely sensitive infrared radiation detector. The other two chalcogenides, lead selenide and lead telluride, are likewise photoconducting. They are unusual in that their color becomes lighter going down the group.
Lead dihalides are well-characterized; this includes the diastatide and mixed halides, such as PbFCl. The relative insolubility of the latter forms a useful basis for the gravimetric determination of fluorine. The difluoride was the first solid ionically conducting compound to be discovered (in 1834, by Michael Faraday). The other dihalides decompose on exposure to ultraviolet or visible light, especially the diiodide. Many lead(II) pseudohalides are known, such as the cyanide, cyanate, and thiocyanate. Lead(II) forms an extensive variety of halide coordination complexes, such as , , and the n chain anion.
Lead(II) sulfate is insoluble in water, like the sulfates of other heavy divalent cations. Lead(II) nitrate and lead(II) acetate are very soluble, and this is exploited in the synthesis of other lead compounds.
Lead(IV)
Few inorganic lead(IV) compounds are known. They are only formed in highly oxidizing solutions and do not normally exist under standard conditions. Lead(II) oxide gives a mixed oxide on further oxidation, Pb3O4. It is described as lead(II,IV) oxide, or structurally 2PbO·PbO2, and is the best-known mixed valence lead compound. Lead dioxide is a strong oxidizing agent, capable of oxidizing hydrochloric acid to chlorine gas. This is because the expected PbCl4 that would be produced is unstable and spontaneously decomposes to PbCl2 and Cl2. Analogously to lead monoxide, lead dioxide is capable of forming plumbate anions. Lead disulfide and lead diselenide are only stable at high pressures. Lead tetrafluoride, a yellow crystalline powder, is stable, but less so than the difluoride. Lead tetrachloride (a yellow oil) decomposes at room temperature, lead tetrabromide is less stable still, and the existence of lead tetraiodide is questionable.
Other oxidation states
See also: Plumbide
Some lead compounds exist in formal oxidation states other than +4 or +2. Lead(III) may be obtained, as an intermediate between lead(II) and lead(IV), in larger organolead complexes; this oxidation state is not stable, as both the lead(III) ion and the larger complexes containing it are radicals. The same applies for lead(I), which can be found in such radical species.
Numerous mixed lead(II,IV) oxides are known. When PbO2 is heated in air, it becomes Pb12O19 at 293 °C, Pb12O17 at 351 °C, Pb3O4 at 374 °C, and finally PbO at 605 °C. A further sesquioxide, Pb2O3, can be obtained at high pressure, along with several non-stoichiometric phases. Many of them show defective fluorite structures in which some oxygen atoms are replaced by vacancies: PbO can be considered as having such a structure, with every alternate layer of oxygen atoms absent.
Negative oxidation states can occur as Zintl phases, as either free lead anions, as in Ba2Pb, with lead formally being lead(−IV), or in oxygen-sensitive ring-shaped or polyhedral cluster ions such as the trigonal bipyramidal Pb5 ion, where two lead atoms are lead(−I) and three are lead(0). In such anions, each atom is at a polyhedral vertex and contributes two electrons to each covalent bond along an edge from their sp hybrid orbitals, the other two being an external lone pair. They may be made in liquid ammonia via the reduction of lead by sodium.
Organolead
Main article: Organolead compound
Carbon
Hydrogen
Lead
Lead can form multiply-bonded chains, a property it shares with its lighter homologs in the carbon group. Its capacity to do so is much less because the Pb–Pb bond energy is over three and a half times lower than that of the C–C bond. With itself, lead can build metal–metal bonds of an order up to three. With carbon, lead forms organolead compounds similar to, but generally less stable than, typical organic compounds (due to the Pb–C bond being rather weak). This makes the organometallic chemistry of lead far less wide-ranging than that of tin. Lead predominantly forms organolead(IV) compounds, even when starting with inorganic lead(II) reactants; very few organolead(II) compounds are known. The most well-characterized exceptions are Pb2 and plumbocene.
The lead analog of the simplest organic compound, methane, is plumbane. Plumbane may be obtained in a reaction between metallic lead and atomic hydrogen. Two simple derivatives, tetramethyllead and tetraethyllead, are the best-known organolead compounds. These compounds are relatively stable: tetraethyllead only starts to decompose if heated or if exposed to sunlight or ultraviolet light. With sodium metal, lead readily forms an equimolar alloy that reacts with alkyl halides to form organometallic compounds such as tetraethyllead. The oxidizing nature of many organolead compounds is usefully exploited: lead tetraacetate is an important laboratory reagent for oxidation in organic synthesis. Tetraethyllead, once added to automotive gasoline, was produced in larger quantities than any other organometallic compound, and is still widely used in fuel for small aircraft. Other organolead compounds are less chemically stable. For many organic compounds, a lead analog does not exist.
Origin and occurrence
| Atomic number |
Element | Relative amount |
|---|---|---|
| 42 | Molybdenum | 0.798 |
| 46 | Palladium | 0.440 |
| 50 | Tin | 1.146 |
| 78 | Platinum | 0.417 |
| 80 | Mercury | 0.127 |
| 82 | Lead | 1 |
| 90 | Thorium | 0.011 |
| 92 | Uranium | 0.003 |
In space
Lead's per-particle abundance in the Solar System is 0.121 ppb (parts per billion). This figure is two and a half times higher than that of platinum, eight times more than mercury, and seventeen times more than gold. The amount of lead in the universe is slowly increasing as most heavier atoms (all of which are unstable) gradually decay to lead. The abundance of lead in the Solar System since its formation 4.5 billion years ago has increased by about 0.75%. The solar system abundances table shows that lead, despite its relatively high atomic number, is more prevalent than most other elements with atomic numbers greater than 40.
Primordial lead—which comprises the isotopes lead-204, lead-206, lead-207, and lead-208—was mostly created as a result of repetitive neutron capture processes occurring in stars. The two main modes of capture are the s- and r-processes.
In the s-process (s is for "slow"), captures are separated by years or decades, allowing less stable nuclei to undergo beta decay. A stable thallium-203 nucleus can capture a neutron and become thallium-204; this undergoes beta decay to give stable lead-204; on capturing another neutron, it becomes lead-205, which has a half-life of around 17 million years. Further captures result in lead-206, lead-207, and lead-208. On capturing another neutron, lead-208 becomes lead-209, which quickly decays into bismuth-209. On capturing another neutron, bismuth-209 becomes bismuth-210, and this beta decays to polonium-210, which alpha decays to lead-206. The cycle hence ends at lead-206, lead-207, lead-208, and bismuth-209.
In the r-process (r is for "rapid"), captures happen faster than nuclei can decay. This occurs in environments with a high neutron density, such as a supernova or the merger of two neutron stars. The neutron flux involved may be on the order of 10 neutrons per square centimeter per second. The r-process does not form as much lead as the s-process. It tends to stop once neutron-rich nuclei reach 126 neutrons. At this point, the neutrons are arranged in complete shells in the atomic nucleus, and it becomes harder to energetically accommodate more of them. When the neutron flux subsides, these nuclei beta decay into stable isotopes of osmium, iridium, platinum.
On Earth
Lead is classified as a chalcophile under the Goldschmidt classification, meaning it is generally found combined with sulfur. It rarely occurs in its native, metallic form. Many lead minerals are relatively light and, over the course of the Earth's history, have remained in the crust instead of sinking deeper into the Earth's interior. This accounts for lead's relatively high crustal abundance of 14 ppm; it is the 36th most abundant element in the crust.
The main lead-bearing mineral is galena (PbS), which is mostly found with zinc ores. Most other lead minerals are related to galena in some way; boulangerite, Pb5Sb4S11, is a mixed sulfide derived from galena; anglesite, PbSO4, is a product of galena oxidation; and cerussite or white lead ore, PbCO3, is a decomposition product of galena. Arsenic, tin, antimony, silver, gold, copper, bismuth are common impurities in lead minerals.
World lead resources exceed two billion tons. Significant deposits are located in Australia, China, Ireland, Mexico, Peru, Portugal, Russia, United States. Global reserves—resources that are economically feasible to extract—totaled 88 million tons in 2016, of which Australia had 35 million, China 17 million, Russia 6.4 million.
Typical background concentrations of lead do not exceed 0.1 μg/m in the atmosphere; 100 mg/kg in soil; 4 mg/kg in vegetation, 5 μg/L in fresh water and seawater.
Etymology
The modern English word lead is of Germanic origin; it comes from the Middle English leed and Old English lēad (with the macron above the "e" signifying that the vowel sound of that letter is long). The Old English word is derived from the hypothetical reconstructed Proto-Germanic *lauda- ('lead'). According to linguistic theory, this word bore descendants in multiple Germanic languages of exactly the same meaning.
There is no consensus on the origin of the Proto-Germanic *lauda-. One hypothesis suggests it is derived from Proto-Indo-European *lAudh- ('lead'; capitalization of the vowel is equivalent to the macron). Another hypothesis suggests it is borrowed from Proto-Celtic *ɸloud-io- ('lead'). This word is related to the Latin plumbum, which gave the element its chemical symbol Pb. The word *ɸloud-io- is thought to be the origin of Proto-Germanic *bliwa- (which also means 'lead'), from which stemmed the German Blei.
The name of the chemical element is not related to the verb of the same spelling, which is derived from Proto-Germanic *laidijan- ('to lead').
History
Prehistory and early history
Metallic lead beads dating back to 7000–6500 BC have been found in Asia Minor and may represent the first example of metal smelting. At that time, lead had few (if any) applications due to its softness and dull appearance. The major reason for the spread of lead production was its association with silver, which may be obtained by burning galena (a common lead mineral). The Ancient Egyptians were the first to use lead minerals in cosmetics, an application that spread to Ancient Greece and beyond; the Egyptians had used lead for sinkers in fishing nets, glazes, glasses, enamels, ornaments. Various civilizations of the Fertile Crescent used lead as a writing material, as coins, and as a construction material. Lead was used by the ancient Chinese as a stimulant, as currency, as contraceptive, and in chopsticks. The Indus Valley civilization and the Mesoamericans used it for making amulets; and the eastern and southern Africans used lead in wire drawing.
Classical era
Because silver was extensively used as a decorative material and an exchange medium, lead deposits came to be worked in Asia Minor from 3000 BC; later, lead deposits were developed in the Aegean and Laurion. These three regions collectively dominated production of mined lead until c. 1200 BC. Beginning c. 2000 BC, the Phoenicians worked deposits in the Iberian peninsula; by 1600 BC, lead mining existed in Cyprus, Greece, and Sardinia.
Rome's territorial expansion in Europe and across the Mediterranean, and its development of mining, led to it becoming the greatest producer of lead during the classical era, with an estimated annual output peaking at 80,000 tonnes. Like their predecessors, the Romans obtained lead mostly as a by-product of silver smelting. Lead mining occurred in central Europe, Britain, Balkans, Greece, Anatolia, Hispania, the latter accounting for 40% of world production.
Lead tablets were commonly used as a material for letters. Lead coffins, cast in flat sand forms and with interchangeable motifs to suit the faith of the deceased, were used in ancient Judea. Lead was used to make sling bullets from the 5th century BC. In Roman times, lead sling bullets were amply used, and were effective at a distance of between 100 and 150 meters. The Balearic slingers, used as mercenaries in Carthaginian and Roman armies, were famous for their shooting distance and accuracy.
Lead was used for making water pipes in the Roman Empire; the Latin word for the metal, plumbum, is the origin of the English word "plumbing". Its ease of working, its low melting point enabling the easy fabrication of completely waterproof welded joints, and its resistance to corrosion ensured its widespread use in other applications, including pharmaceuticals, roofing, currency, warfare. Writers of the time, such as Cato the Elder, Columella, and Pliny the Elder, recommended lead (and lead-coated) vessels for the preparation of sweeteners and preservatives added to wine and food. The lead conferred an agreeable taste due to the formation of "sugar of lead" (lead(II) acetate), whereas copper vessels imparted a bitter flavor through verdigris formation.
Heinz Eschnauer and Markus StoepplerThis metal was by far the most used material in classical antiquity, and it is appropriate to refer to the (Roman) Lead Age. Lead was to the Romans what plastic is to us.
"Wine—An enological specimen bank", 1992
The Roman author Vitruvius reported the health dangers of lead and modern writers have suggested that lead poisoning played a major role in the decline of the Roman Empire. Other researchers have criticized such claims, pointing out, for instance, that not all abdominal pain is caused by lead poisoning. According to archaeological research, Roman lead pipes increased lead levels in tap water but such an effect was "unlikely to have been truly harmful". When lead poisoning did occur, victims were called "saturnine", dark and cynical, after the ghoulish father of the gods, Saturn. By association, lead was considered the father of all metals. Its status in Roman society was low as it was readily available and cheap.
Confusion with tin and antimony
Since the Bronze Age, metallurgists and engineers have understood the difference between rare and valuable tin, essential for alloying with copper to produce tough and corrosion resistant bronze, and 'cheap and cheerful' lead. However, the nomenclature in some languages is similar. Romans called lead plumbum nigrum ("black lead"), and tin plumbum candidum ("bright lead"). The association of lead and tin can be seen in other languages: the word olovo in Czech translates to "lead", but in Russian, its cognate олово (olovo) means "tin". To add to the confusion, lead bore a close relation to antimony: both elements commonly occur as sulfides (galena and stibnite), often together. Pliny incorrectly wrote that stibnite would give lead on heating, instead of antimony. In countries such as Turkey and India, the originally Persian name surma came to refer to either antimony sulfide or lead sulfide, and in some languages, such as Russian, gave its name to antimony (сурьма).
Middle Ages and the Renaissance
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Lead mining in Western Europe declined after the fall of the Western Roman Empire, with Arabian Iberia being the only region having a significant output. The largest production of lead occurred in South Asia and East Asia, especially China and India, where lead mining grew rapidly.
In Europe, lead production began to increase in the 11th and 12th centuries, when it was again used for roofing and piping. Starting in the 13th century, lead was used to create stained glass. In the European and Arabian traditions of alchemy, lead (symbol ♄ in the European tradition) was considered an impure base metal which, by the separation, purification and balancing of its constituent essences, could be transformed to pure and incorruptible gold. During the period, lead was used increasingly for adulterating wine. The use of such wine was forbidden for use in Christian rites by a papal bull in 1498, but it continued to be imbibed and resulted in mass poisonings up to the late 18th century. Lead was a key material in parts of the printing press, and lead dust was commonly inhaled by print workers, causing lead poisoning. Lead also became the chief material for making bullets for firearms: it was cheap, less damaging to iron gun barrels, had a higher density (which allowed for better retention of velocity), and its lower melting point made the production of bullets easier as they could be made using a wood fire. Lead, in the form of Venetian ceruse, was extensively used in cosmetics by Western European aristocracy as whitened faces were regarded as a sign of modesty. This practice later expanded to white wigs and eyeliners, and only faded out with the French Revolution in the late 18th century. A similar fashion appeared in Japan in the 18th century with the emergence of the geishas, a practice that continued long into the 20th century. The white faces of women "came to represent their feminine virtue as Japanese women", with lead commonly used in the whitener.
Outside Europe and Asia
In the New World, lead production was recorded soon after the arrival of European settlers. The earliest record dates to 1621 in the English Colony of Virginia, fourteen years after its foundation. In Australia, the first mine opened by colonists on the continent was a lead mine, in 1841. In Africa, lead mining and smelting were known in the Benue Trough and the lower Congo Basin, where lead was used for trade with Europeans, and as a currency by the 17th century, well before the scramble for Africa.
Industrial Revolution
In the second half of the 18th century, Britain, and later continental Europe and the United States, experienced the Industrial Revolution. This was the first time during which lead production rates exceeded those of Rome. Britain was the leading producer, losing this status by the mid-19th century with the depletion of its mines and the development of lead mining in Germany, Spain, and the United States. By 1900, the United States was the leader in global lead production, and other non-European nations—Canada, Mexico, and Australia—had begun significant production; production outside Europe exceeded that within. A great share of the demand for lead came from plumbing and painting—lead paints were in regular use. At this time, more (working class) people were exposed to the metal and lead poisoning cases escalated. This led to research into the effects of lead intake. Lead was proven to be more dangerous in its fume form than as a solid metal. Lead poisoning and gout were linked; British physician Alfred Baring Garrod noted a third of his gout patients were plumbers and painters. The effects of chronic ingestion of lead, including mental disorders, were also studied in the 19th century. The first laws aimed at decreasing lead poisoning in factories were enacted during the 1870s and 1880s in the United Kingdom.
Modern era
Further evidence of the threat that lead posed to humans was discovered in the late 19th and early 20th centuries. Mechanisms of harm were better understood, lead blindness was documented, and the element was phased out of public use in the United States and Europe. The United Kingdom introduced mandatory factory inspections in 1878 and appointed the first Medical Inspector of Factories in 1898; as a result, a 25-fold decrease in lead poisoning incidents from 1900 to 1944 was reported. Most European countries banned lead paint—commonly used because of its opacity and water resistance—for interiors by 1930.
The last major human exposure to lead was the addition of tetraethyllead to gasoline as an antiknock agent, a practice that originated in the United States in 1921. It was phased out in the United States and the European Union by 2000.
In the 1970s, the United States and Western European countries introduced legislation to reduce lead air pollution. The impact was significant: while a study conducted by the Centers for Disease Control and Prevention in the United States in 1976–1980 showed that 77.8% of the population had elevated blood lead levels, in 1991–1994, a study by the same institute showed the share of people with such high levels dropped to 2.2%. The main product made of lead by the end of the 20th century was the lead–acid battery.
From 1960 to 1990, lead output in the Western Bloc grew by about 31%. The share of the world's lead production by the Eastern Bloc increased from 10% to 30%, from 1950 to 1990, with the Soviet Union being the world's largest producer during the mid-1970s and the 1980s, and China starting major lead production in the late 20th century. Unlike the European communist countries, China was largely unindustrialized by the mid-20th century; in 2004, China surpassed Australia as the largest producer of lead. As was the case during European industrialization, lead has had a negative effect on health in China.
Production
As of 2014, production of lead is increasing worldwide due to its use in lead–acid batteries. There are two major categories of production: primary from mined ores, and secondary from scrap. In 2014, 4.58 million metric tons came from primary production and 5.64 million from secondary production. The top three producers of mined lead concentrate in that year were China, Australia, and United States. The top three producers of refined lead were China, United States, and India. According to the Metal Stocks in Society report of 2010, the total amount of lead in use, stockpiled, discarded, or dissipated into the environment, on a global basis, is 8 kg per capita. Much of this is in more developed countries (20–150 kg per capita) rather than less developed ones (1–4 kg per capita).
The primary and secondary lead production processes are similar. Some primary production plants now supplement their operations with scrap lead, and this trend is likely to increase in the future. Given adequate techniques, lead obtained via secondary processes is indistinguishable from lead obtained via primary processes. Scrap lead from the building trade is usually fairly clean and is re-melted without the need for smelting, though refining is sometimes needed. Secondary lead production is therefore cheaper, in terms of energy requirements, than is primary production, often by 50% or more.
Primary
Most lead ores contain a low percentage of lead (rich ores have a typical content of 3–8%) which must be concentrated for extraction. During initial processing, ores typically undergo crushing, dense-medium separation, grinding, froth flotation, drying. The resulting concentrate, which has a lead content of 30–80% by mass (regularly 50–60%), is then turned into (impure) lead metal.
There are two main ways of doing this: a two-stage process involving roasting followed by blast furnace extraction, carried out in separate vessels; or a direct process in which the extraction of the concentrate occurs in a single vessel. The latter has become the most common route, though the former is still significant.
| Country | Output (thousand tons) |
|---|---|
 China |
2,400 |
 Australia |
500 |
 United States |
335 |
 Peru |
310 |
 Mexico |
250 |
 Russia |
225 |
 India |
135 |
 Bolivia |
80 |
 Sweden |
76 |
 Turkey |
75 |
 Iran |
41 |
 Kazakhstan |
41 |
 Poland |
40 |
 South Africa |
40 |
 North Korea |
35 |
 Ireland |
33 |
 Macedonia |
33 |
| Other countries | 170 |
Two-stage process
First, the sulfide concentrate is roasted in air to oxidize the lead sulfide:
- 2 PbS(s) + 3 O2(g) → 2 PbO(s) + 2 SO2(g)↑
As the original concentrate was not pure lead sulfide, roasting yields not only the desired lead(II) oxide, but a mixture of oxides, sulfates, and silicates of lead and of the other metals contained in the ore. This impure lead oxide is reduced in a coke-fired blast furnace to the (again, impure) metal:
- 2 PbO(s) + C(s) → 2 Pb(s) + CO2(g)↑
Impurities are mostly arsenic, antimony, bismuth, zinc, copper, silver, and gold. Typically they are removed in a series of pyrometallurgical processes. The melt is treated in a reverberatory furnace with air, steam, sulfur, which oxidizes the impurities except for silver, gold, bismuth. Oxidized contaminants float to the top of the melt and are skimmed off. Metallic silver and gold are removed and recovered economically by means of the Parkes process, in which zinc is added to lead. Zinc, which is immiscible in lead, dissolves the silver and gold. The zinc solution can be separated from the lead, and the silver and gold retrieved. De-silvered lead is freed of bismuth by the Betterton–Kroll process, treating it with metallic calcium and magnesium. The resulting bismuth dross can be skimmed off.
Alternatively to the pyrometallurgical processes, very pure lead can be obtained by processing smelted lead electrolytically using the Betts process. Anodes of impure lead and cathodes of pure lead are placed in an electrolyte of lead fluorosilicate (PbSiF6). Once electrical potential is applied, impure lead at the anode dissolves and plates onto the cathode, leaving the majority of the impurities in solution. This is a high-cost process and thus mostly reserved for refining bullion containing high percentages of impurities.
Direct process
In this process, lead bullion and slag is obtained directly from lead concentrates. The lead sulfide concentrate is melted in a furnace and oxidized, forming lead monoxide. Carbon (as coke or coal gas) is added to the molten charge along with fluxing agents. The lead monoxide is thereby reduced to metallic lead, in the midst of a slag rich in lead monoxide.
If the input is rich in lead, as much as 80% of the original lead can be obtained as bullion; the remaining 20% forms a slag rich in lead monoxide. For a low-grade feed, all of the lead can be oxidized to a high-lead slag. Metallic lead is further obtained from the high-lead (25–40%) slags via submerged fuel combustion or injection, reduction assisted by an electric furnace, or a combination of both.
Alternatives
Research on a cleaner, less energy-intensive lead extraction process continues; a major drawback is that either too much lead is lost as waste, or the alternatives result in a high sulfur content in the resulting lead metal. Hydrometallurgical extraction, in which anodes of impure lead are immersed into an electrolyte and pure lead is deposited (electrowound) onto cathodes, is a technique that may have potential, but is not currently economical except in cases where electricity is very cheap.
Secondary
Further information: Battery recycling § Lead–acid batteriesSmelting, which is an essential part of the primary production, is often skipped during secondary production. It is only performed when metallic lead has undergone significant oxidation. The process is similar to that of primary production in either a blast furnace or a rotary furnace, with the essential difference being the greater variability of yields: blast furnaces produce hard lead (10% antimony) while reverberatory and rotary kiln furnaces produce semisoft lead (3–4% antimony).
The ISASMELT process is a more recent smelting method that may act as an extension to primary production; battery paste from spent lead–acid batteries (containing lead sulfate and lead oxides) has its sulfate removed by treating it with alkali, and is then treated in a coal-fueled furnace in the presence of oxygen, which yields impure lead, with antimony the most common impurity. Refining of secondary lead is similar to that of primary lead; some refining processes may be skipped depending on the material recycled and its potential contamination.
Of the sources of lead for recycling, lead–acid batteries are the most important; lead pipe, sheet, and cable sheathing are also significant.
Applications
Contrary to popular belief, pencil leads in wooden pencils have never been made from lead. When the pencil originated as a wrapped graphite writing tool, the particular type of graphite used was named plumbago (literally, lead mockup).
Elemental form
Lead metal has several useful mechanical properties, including high density, low melting point, ductility, and relative inertness. Many metals are superior to lead in some of these aspects but are generally less common and more difficult to extract from parent ores. Lead's toxicity has led to its phasing out for some uses.
Lead has been used for bullets since their invention in the Middle Ages. It is inexpensive; its low melting point means small arms ammunition and shotgun pellets can be cast with minimal technical equipment; and it is denser than other common metals, which allows for better retention of velocity. It remains the main material for bullets, alloyed with other metals as hardeners. Concerns have been raised that lead bullets used for hunting can damage the environment. Shotgun cartridges used for waterfowl hunting must today be lead-free in the United States, Canada, and in Europe.
Lead's high density and resistance to corrosion have been exploited in a number of related applications. It is used as ballast in sailboat keels; its density allows it to take up a small volume and minimize water resistance, thus counterbalancing the heeling effect of wind on the sails. It is used in scuba diving weight belts to counteract the diver's buoyancy. In 1993, the base of the Leaning Tower of Pisa was stabilized with 600 tonnes of lead. Because of its corrosion resistance, lead is used as a protective sheath for underwater cables.
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Lead has many uses in the construction industry; lead sheets are used as architectural metals in roofing material, cladding, flashing, gutters and gutter joints, roof parapets. Lead is still used in statues and sculptures, including for armatures. In the past it was often used to balance the wheels of cars; for environmental reasons this use is being phased out in favor of other materials.
Lead is added to copper alloys, such as brass and bronze, to improve machinability and for its lubricating qualities. Being practically insoluble in copper, the lead forms solid globules in imperfections throughout the alloy, such as grain boundaries. In low concentrations, as well as acting as a lubricant, the globules hinder the formation of swarf as the alloy is worked, thereby improving machinability. Copper alloys with larger concentrations of lead are used in bearings. The lead provides lubrication, and the copper provides the load-bearing support.
Lead's high density, atomic number, and formability form the basis for use of lead as a barrier that absorbs sound, vibration, and radiation. Lead has no natural resonance frequencies; as a result, sheet-lead is used as a sound deadening layer in the walls, floors, and ceilings of sound studios. Organ pipes are often made from a lead alloy, mixed with various amounts of tin to control the tone of each pipe. Lead is an established shielding material from radiation in nuclear science and in X-ray rooms due to its denseness and high attenuation coefficient. Molten lead has been used as a coolant for lead-cooled fast reactors.
Batteries
The largest use of lead in the early 21st century is in lead–acid batteries. The lead in batteries undergoes no direct contact with humans, so there are fewer toxicity concerns. People who work in lead battery production or recycling plants may be exposed to lead dust and inhale it. The reactions in the battery between lead, lead dioxide, and sulfuric acid provide a reliable source of voltage. Supercapacitors incorporating lead–acid batteries have been installed in kilowatt and megawatt scale applications in Australia, Japan, and the United States in frequency regulation, solar smoothing and shifting, wind smoothing, and other applications. These batteries have lower energy density and charge-discharge efficiency than lithium-ion batteries, but are significantly cheaper.
Coating for cables
Lead is used in high voltage power cables as shell material to prevent water diffusion into insulation; this use is decreasing as lead is being phased out. Its use in solder for electronics is also being phased out by some countries to reduce the amount of environmentally hazardous waste. Lead is one of three metals used in the Oddy test for museum materials, helping detect organic acids, aldehydes, acidic gases.
Compounds
In addition to being the main application for lead metal, lead–acid batteries are also the main consumer of lead compounds. The energy storage/release reaction used in these devices involves lead sulfate and lead dioxide:
- Pb(s) + PbO
2(s) + 2H
2SO
4(aq) → 2PbSO
4(s) + 2H
2O(l)
Other applications of lead compounds are very specialized and often fading. Lead-based coloring agents are used in ceramic glazes and glass, especially for red and yellow shades. While lead paints are phased out in Europe and North America, they remain in use in less developed countries such as China, India, or Indonesia. Lead tetraacetate and lead dioxide are used as oxidizing agents in organic chemistry. Lead is frequently used in the polyvinyl chloride coating of electrical cords. It can be used to treat candle wicks to ensure a longer, more even burn. Because of its toxicity, European and North American manufacturers use alternatives such as zinc. Lead glass is composed of 12–28% lead oxide, changing its optical characteristics and reducing the transmission of ionizing radiation, a property used in old TVs and computer monitors with cathode-ray tubes. Lead-based semiconductors such as lead telluride and lead selenide are used in photovoltaic cells and infrared detectors.
Biological effects
Main article: Lead poisoning| Hazards | |
|---|---|
| GHS labelling: | |
| Pictograms |  
|
| Signal word | Danger |
| Hazard statements | H302, H332, H351, H360Df, H373, H410 |
| Precautionary statements | P201, P261, P273, P304, P308, P312, P313, P340, P391 |
| NFPA 704 (fire diamond) |
 |
Lead has no confirmed biological role, and there is no confirmed safe level of lead exposure. A 2009 Canadian–American study concluded that even at levels that are considered to pose little to no risk, lead may cause "adverse mental health outcomes". Its prevalence in the human body—at an adult average of 120 mg—is nevertheless exceeded only by zinc (2500 mg) and iron (4000 mg) among the heavy metals. Lead salts are very efficiently absorbed by the body. A small amount of lead (1%) is stored in bones; the rest is excreted in urine and feces within a few weeks of exposure. Only about a third of lead is excreted by a child. Continual exposure may result in the bioaccumulation of lead.
Toxicity
Lead is a highly poisonous metal (whether inhaled or swallowed), affecting almost every organ and system in the human body. At airborne levels of 100 mg/m, it is immediately dangerous to life and health. Most ingested lead is absorbed into the bloodstream. The primary cause of its toxicity is its predilection for interfering with the proper functioning of enzymes. It does so by binding to the sulfhydryl groups found on many enzymes, or mimicking and displacing other metals which act as cofactors in many enzymatic reactions. The essential metals that lead interacts with include calcium, iron, and zinc. High levels of calcium and iron tend to provide some protection from lead poisoning; low levels cause increased susceptibility.
Effects
Lead can cause severe damage to the brain and kidneys and, ultimately, death. By mimicking calcium, lead can cross the blood–brain barrier. It degrades the myelin sheaths of neurons, reduces their numbers, interferes with neurotransmission routes, and decreases neuronal growth. In the human body, lead inhibits porphobilinogen synthase and ferrochelatase, preventing both porphobilinogen formation and the incorporation of iron into protoporphyrin IX, the final step in heme synthesis. This causes ineffective heme synthesis and microcytic anemia.
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Symptoms of lead poisoning include nephropathy, colic-like abdominal pains, and possibly weakness in the fingers, wrists, or ankles. Small blood pressure increases, particularly in middle-aged and older people, may be apparent and can cause anemia. Several studies, mostly cross-sectional, found an association between increased lead exposure and decreased heart rate variability. In pregnant women, high levels of exposure to lead may cause miscarriage. Chronic, high-level exposure has been shown to reduce fertility in males.
In a child's developing brain, lead interferes with synapse formation in the cerebral cortex, neurochemical development (including that of neurotransmitters), and the organization of ion channels. Early childhood exposure has been linked with an increased risk of sleep disturbances and excessive daytime drowsiness in later childhood. High blood levels are associated with delayed puberty in girls. The rise and fall in exposure to airborne lead from the combustion of tetraethyl lead in gasoline during the 20th century has been linked with historical increases and decreases in crime levels.
Exposure sources
Lead exposure is a global issue since lead mining and smelting, and battery manufacturing, disposal, and recycling, are common in many countries. Lead enters the body via inhalation, ingestion, or skin absorption. Almost all inhaled lead is absorbed into the body; for ingestion, the rate is 20–70%, with children absorbing a higher percentage than adults.
Poisoning typically results from ingestion of food or water contaminated with lead, and less commonly after accidental ingestion of contaminated soil, dust, or lead-based paint. Seawater products can contain lead if affected by nearby industrial waters. Fruit and vegetables can be contaminated by high levels of lead in the soils they were grown in. Soil can be contaminated through particulate accumulation from lead in pipes, lead paint, residual emissions from leaded gasoline.
The use of lead for water pipes is a problem in areas with soft or acidic water. Hard water forms insoluble protective layers on the inner surface of the pipes, whereas soft and acidic water dissolves the lead pipes. Dissolved carbon dioxide in the carried water may result in the formation of soluble lead bicarbonate; oxygenated water may similarly dissolve lead as lead(II) hydroxide. Drinking such water, over time, can cause health problems due to the toxicity of the dissolved lead. The harder the water the more calcium bicarbonate and sulfate it contains, and the more the inside of the pipes are coated with a protective layer of lead carbonate or lead sulfate.
Ingestion of applied lead-based paint is the major source of exposure for children: a direct source is chewing on old painted window sills. Additionally, as lead paint on a surface deteriorates, it peels and is pulverized into dust. The dust then enters the body through hand-to-mouth contact or contaminated food or drink. Ingesting certain home remedies may result in exposure to lead or its compounds.
Inhalation is the second major exposure pathway, affecting smokers and especially workers in lead-related occupations. Cigarette smoke contains, among other toxic substances, radioactive lead-210. "As a result of EPA's regulatory efforts, levels of lead in the air decreased by 86 percent between 2010 and 2020." The concentration of lead in the air in the United States fell below the national standard of 0.15 μg/m in 2014.
Skin exposure may be significant for people working with organic lead compounds. The rate of skin absorption is lower for inorganic lead.
Lead in foods
Lead may be found in food when food is grown in soil that is high in lead, airborne lead contaminates the crops, animals eat lead in their diet, or lead enters the food either from what it was stored or cooked in. Ingestion of lead paint and batteries is also a route of exposure for livestock, which can subsequently affect humans. Milk produced by contaminated cattle can be diluted to a lower lead concentration and sold for consumption.
In Bangladesh, lead compounds have been added to turmeric to make it more yellow. This is believed to have started in the 1980s and continues as of 2019. It is believed to be one of the main sources of high lead levels in the country. In Hong Kong the maximum allowed lead level in food is 6 parts per million in solids and 1 part per million in liquids.
Lead-containing dust can settle on drying cocoa beans when they are set outside near polluting industrial plants. In December 2022, Consumer Reports tested 28 dark chocolate brands and found that 23 of them contained potentially harmful levels of lead, cadmium or both. They have urged the chocolate makers to reduce the level of lead which could be harmful, especially to a developing fetus.
In March 2024, the US Food and Drug Administration recommended a voluntary recall on 6 brands of cinnamon due to contamination with lead, after 500 reports of child lead poisoning. The FDA determined that cinnamon was adulterated with lead chromate.
Lead in plastic toys
According to the United States Center for Disease Control, the use of lead in plastics has not been banned as of 2024. Lead softens the plastic and makes it more flexible so that it can go back to its original shape. Habitual chewing on colored plastic insulation from stripped electrical wires was found to cause elevated lead levels in a 46-year-old man. Lead may be used in plastic toys to stabilize molecules from heat. Lead dust can be formed when plastic is exposed to sunlight, air, and detergents that break down the chemical bond between the lead and plastics.
Treatment
See also: Chelation therapyTreatment for lead poisoning normally involves the administration of dimercaprol and succimer. Acute cases may require the use of disodium calcium edetate, the calcium chelate, and the disodium salt of ethylenediaminetetraacetic acid (EDTA). It has a greater affinity for lead than calcium, with the result that lead chelate is formed by exchange and excreted in the urine, leaving behind harmless calcium.
Environmental effects
The extraction, production, use, and disposal of lead and its products have caused significant contamination of the Earth's soils and waters. Atmospheric emissions of lead were at their peak during the Industrial Revolution, and the leaded gasoline period in the second half of the twentieth century.
Lead releases originate from natural sources (i.e., concentration of the naturally occurring lead), industrial production, incineration and recycling, and mobilization of previously buried lead. In particular, as lead has been phased out from other uses, in the Global South, lead recycling operations designed to extract cheap lead used for global manufacturing have become a well documented source of exposure. Elevated concentrations of lead persist in soils and sediments in post-industrial and urban areas; industrial emissions, including those arising from coal burning, continue in many parts of the world, particularly in the developing countries.
Lead can accumulate in soils, especially those with a high organic content, where it remains for hundreds to thousands of years. Environmental lead can compete with other metals found in and on plant surfaces potentially inhibiting photosynthesis and at high enough concentrations, negatively affecting plant growth and survival. Contamination of soils and plants can allow lead to ascend the food chain affecting microorganisms and animals. In animals, lead exhibits toxicity in many organs, damaging the nervous, renal, reproductive, hematopoietic, and cardiovascular systems after ingestion, inhalation, or skin absorption. Fish uptake lead from both water and sediment; bioaccumulation in the food chain poses a hazard to fish, birds, and sea mammals.
Anthropogenic lead includes lead from shot and sinkers. These are among the most potent sources of lead contamination along with lead production sites. Lead was banned for shot and sinkers in the United States in 2017, although that ban was only effective for a month, and a similar ban is being considered in the European Union.
Analytical methods for the determination of lead in the environment include spectrophotometry, X-ray fluorescence, atomic spectroscopy, and electrochemical methods. A specific ion-selective electrode has been developed based on the ionophore S,S'-methylenebis(N,N-diisobutyldithiocarbamate). An important biomarker assay for lead poisoning is δ-aminolevulinic acid levels in plasma, serum, and urine.
Restriction and remediation
By the mid-1980s, there was significant decline in the use of lead in industry. In the United States, environmental regulations reduced or eliminated the use of lead in non-battery products, including gasoline, paints, solders, and water systems. Particulate control devices were installed in coal-fired power plants to capture lead emissions. In 1992, U.S. Congress required the Environmental Protection Agency to reduce the blood lead levels of the country's children. Lead use was further curtailed by the European Union's 2003 Restriction of Hazardous Substances Directive. A large drop in lead deposition occurred in the Netherlands after the 1993 national ban on use of lead shot for hunting and sport shooting: from 230 tonnes in 1990 to 47.5 tonnes in 1995. The usage of lead in Avgas 100LL for general aviation is allowed in the EU as of 2022.
In the United States, the permissible exposure limit for lead in the workplace, comprising metallic lead, inorganic lead compounds, and lead soaps, was set at 50 μg/m over an 8-hour workday, and the blood lead level limit at 5 μg per 100 g of blood in 2012. Lead may still be found in harmful quantities in stoneware, vinyl (such as that used for tubing and the insulation of electrical cords), and Chinese brass. Old houses may still contain lead paint. White lead paint has been withdrawn from sale in industrialized countries, but specialized uses of other pigments such as yellow lead chromate remain, especially in road pavement marking paint. Stripping old paint by sanding produces dust which can be inhaled. Lead abatement programs have been mandated by some authorities in properties where young children live. The usage of lead in Avgas 100LL for general aviation is generally allowed in United States as of 2023.
Lead waste, depending on the jurisdiction and the nature of the waste, may be treated as household waste (to facilitate lead abatement activities), or potentially hazardous waste requiring specialized treatment or storage. Lead is released into the environment in shooting places and a number of lead management practices have been developed to counter the lead contamination. Lead migration can be enhanced in acidic soils; to counter that, it is advised soils be treated with lime to neutralize the soils and prevent leaching of lead.
Research has been conducted on how to remove lead from biosystems by biological means: Fish bones are being researched for their ability to bioremediate lead in contaminated soil. The fungus Aspergillus versicolor is effective at absorbing lead ions from industrial waste before being released to water bodies. Several bacteria have been researched for their ability to remove lead from the environment, including the sulfate-reducing bacteria Desulfovibrio and Desulfotomaculum, both of which are highly effective in aqueous solutions. Millet grass Urochloa ramosa has the ability to accumulate significant amounts of metals such as lead and zinc in its shoot and root tissues making it an important plant for remediation of contaminated soils.
See also
- Derek Bryce-Smith – one of the earliest campaigners against lead in petrol in the UK
- Thomas Midgley Jr. – discovered that the addition of tetraethyllead to gasoline prevented "knocking" in internal combustion engines
- Clair Cameron Patterson – instrumental in the banning of tetraethyllead in gasoline in the US and lead solder in food cans.
- Robert A. Kehoe – foremost medical advocate for the use of tetraethyllead as an additive in gasoline.
Notes
- The tetrahedral allotrope of tin is called α- or gray tin and is stable only at or below 13.2 °C (55.8 °F). The stable form of tin above this temperature is called β- or white tin and has a distorted face centered cubic (tetragonal) structure which can be derived by compressing the tetrahedra of gray tin along their cubic axes. White tin effectively has a structure intermediate between the regular tetrahedral structure of gray tin, and the regular face centered cubic structure of lead, consistent with the general trend of increasing metallic character going down any representative group.
- A quasicrystalline thin-film allotrope of lead, with pentagonal symmetry, was reported in 2013. The allotrope was obtained by depositing lead atoms on the surface of an icosahedral silver-indium-ytterbium quasicrystal. Its conductivity was not recorded.
- Diamond cubic structures with lattice parameters around the lattice parameter of silicon exists both in thin lead and tin films, and in massive lead and tin, freshly solidified in vacuum of ~5 x 10 Torr. Experimental evidence for almost identical structures of at least three oxide types is presented, demonstrating that lead and tin behave like silicon not only in the initial stages of crystallization, but also in the initial stages of oxidation.
- British English: to go down like a lead balloon.
- Malleability describes how easily it deforms under compression, whereas ductility means its ability to stretch.
- A (wet) finger can be dipped into molten lead without risk of a burning injury.
- An even number of either protons or neutrons generally increases the nuclear stability of isotopes, compared to isotopes with odd numbers. No elements with odd atomic numbers have more than two stable isotopes; even-numbered elements have multiple stable isotopes, with tin (element 50) having the highest number of isotopes of all elements, ten. See Even and odd atomic nuclei for more details.
- The half-life found in the experiment was 1.9×10 years. A kilogram of natural bismuth would have an activity value of approximately 0.003 becquerels (decays per second). For comparison, the activity value of natural radiation in the human body is around 65 becquerels per kilogram of body weight (4500 becquerels on average).
- Lead-205 decays solely via electron capture, which means when there are no electrons available and lead is fully ionized with all 82 electrons removed it cannot decay. Fully ionized thallium-205, the isotope lead-205 would decay to, becomes unstable and can decay into a bound state of lead-205.
- Tetraphenyllead is even more thermally stable, decomposing at 270 °C.
- Abundances in the source are listed relative to silicon rather than in per-particle notation. The sum of all elements per 10 parts of silicon is 2.6682×10 parts; lead comprises 3.258 parts.
- Elemental abundance figures are estimates and their details may vary from source to source.
- The inscription reads: "Made when the Emperor Vespasian was consul for the ninth term and the Emperor Titus was consul for the seventh term, when Gnaeus Iulius Agricola was imperial governor (of Britain)."
- The fact that Julius Caesar fathered only one child, as well as the alleged sterility of his successor, Caesar Augustus, have been attributed to lead poisoning.
- Gaseous by-product of the coking process, containing carbon monoxide, hydrogen and methane; used as a fuel.
- California began banning lead bullets for hunting on that basis in July 2015.
- For example, a firm "...producing quality garden ornament from our studio in West London for over a century".
- Potential injuries to regular users of such batteries are not related to lead's toxicity.
- See for details on how a lead–acid battery works.
- Rates vary greatly by country.
- An alloy of brass (copper and zinc) with lead, iron, tin, and sometimes antimony.
References
- "Standard Atomic Weights: Lead". CIAAW. 2020.
- Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (4 May 2022). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
- ^ Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements. Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9.
- Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 28. ISBN 978-0-08-037941-8.
- Pb(0) carbonyls have been observered in reaction between lead atoms and carbon monoxide; see Ling, Jiang; Qiang, Xu (2005). "Observation of the lead carbonyls PbnCO (n=1–4): Reactions of lead atoms and small clusters with carbon monoxide in solid argon". The Journal of Chemical Physics. 122 (3): 034505. 122 (3): 34505. Bibcode:2005JChPh.122c4505J. doi:10.1063/1.1834915. ISSN 0021-9606. PMID 15740207.
- Weast, Astle & Beyer 1983, p. E110.
- ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
- Meija et al. 2016.
- Theodore Low De Vinne 1899, pp. 9–36.
- Lide 2005, p. 10-179.
- Pyykkö 1988, pp. 563–594.
- Claudio, Godwin & Magyar 2002, pp. 1–144.
- Norman 1996, p. 36.
- Greenwood & Earnshaw 1998, pp. 226–227, 374.
- Christensen 2002, p. 867.
- Slater 1964.
- Considine & Considine 2013, pp. 501, 2970.
- Parthé 1964, p. 13.
- Sharma et al. 2013.
- Sharma et al. 2014, p. 174710.
- Peneva, Djuneva & Tsukeva 1981.
- Greenwood & Earnshaw 1998, p. 372.
- Greenwood & Earnshaw 1998, pp. 372–373.
- ^ Thornton, Rautiu & Brush 2001, p. 6.
- Lide 2005, pp. 12–35, 12–40.
- Brenner 2003, p. 396.
- Jones 2014, p. 42.
- Lide 2005, pp. 4–13, 4–21, 4–33.
- Vogel & Achilles 2013, p. 8.
- Anderson 1869, pp. 341–343.
- Gale & Totemeier 2003, pp. 15–2–15–3.
- Thornton, Rautiu & Brush 2001, p. 8.
- ^ Lide 2005, p. 12-219.
- Willey 1999.
- Lide 2005, p. 12-45.
- Blakemore 1985, p. 272.
- Webb, Marsiglio & Hirsch 2015.
- ^ IAEA – Nuclear Data Section 2017. sfn error: no target: CITEREFIAEA_–_Nuclear_Data_Section2017 (help)
- ^ Stone 1997.
- de Marcillac et al. 2003, pp. 876–78.
- World Nuclear Association 2015.
- Beeman et al. 2013.
- Radioactive Decay Series 2012.
- Committee on Evaluation of EPA Guidelines for Exposure to Naturally Occurring Radioactive Materials et al. 1999.
- Smirnov, Borisevich & Sulaberidze 2012.
- Greenwood & Earnshaw 1998, p. 368.
- Levin 2009, pp. 40–41.
- Webb 2000, p. 115.
- Wrackmeyer & Horchler 1990.
- Cangelosi & Pecoraro 2015.
- Fiorini 2010, pp. 7–8.
- Takahashi et al. 1987.
- Thürmer, Williams & Reutt-Robey 2002, pp. 2033–2035.
- Tétreault, Sirois & Stamatopoulou 1998, pp. 17–32.
- Thornton, Rautiu & Brush 2001, pp. 10–11.
- ^ Greenwood & Earnshaw 1998, p. 373.
- Bretherick 2016, p. 1442.
- Harbison, Bourgeois & Johnson 2015, p. 132.
- ^ Greenwood & Earnshaw 1998, p. 374.
- Thornton, Rautiu & Brush 2001, pp. 11–12.
- Polyanskiy 1986, p. 20.
- Kaupp 2014, pp. 9–10.
- Dieter & Watson 2009, p. 509.
- Hunt 2014, p. 215.
- ^ King 1995, pp. 43–63.
- Bunker & Casey 2016, p. 89.
- Whitten, Gailey & David 1996, pp. 904–905.
- Greenwood & Earnshaw 1998, p. 384.
- Greenwood & Earnshaw 1998, p. 387.
- ^ Greenwood & Earnshaw 1998, p. 389.
- Zuckerman & Hagen 1989, p. 426.
- Funke 2013.
- ^ Greenwood & Earnshaw 1998, p. 382.
- Bharara & Atwood 2006, p. 4.
- Greenwood & Earnshaw 1998, p. 388.
- Toxicological Profile for Lead 2007, p. 277.
- Downs & Adams 2017, p. 1128.
- Brescia 2012, p. 234.
- Macintyre 1992, p. 3775.
- Silverman 1966, pp. 2067–2069.
- Greenwood & Earnshaw 1998, p. 381.
- Yong, Hoffmann & Fässler 2006, pp. 4774–4778.
- Becker et al. 2008, pp. 9965–9978.
- Mosseri, Henglein & Janata 1990, pp. 2722–2726.
- Konu & Chivers 2011, pp. 391–392.
- Hadlington 2017, p. 59.
- Greenwood & Earnshaw 1998, pp. 384–386.
- Röhr 2017.
- Alsfasser 2007, pp. 261–263.
- Greenwood & Earnshaw 1998, p. 393.
- Stabenow, Saak & Weidenbruch 2003.
- ^ Polyanskiy 1986, p. 43.
- ^ Greenwood & Earnshaw 1998, p. 404.
- ^ Wiberg, Wiberg & Holleman 2001, p. 918.
- Toxicological Profile for Lead 2007, p. 287.
- Polyanskiy 1986, p. 44.
- Windholz 1976.
- Zýka 1966, p. 569.
- "When will we see unleaded AvGas?". 5 August 2019. Retrieved 26 May 2024.
- ^ Lodders 2003, pp. 1222–1223.
- Roederer et al. 2009, pp. 1963–1980.
- Lochner, Rohrbach & Cochrane 2005, p. 12.
- Lodders 2003, p. 1224.
- Burbidge et al. 1957, pp. 608–615.
- Burbidge et al. 1957, p. 551.
- Burbidge et al. 1957, pp. 608–609.
- Burbidge et al. 1957, p. 553.
- Frebel 2015, pp. 114–115.
- Burbidge et al. 1957, pp. 608–610.
- Burbidge et al. 1957, p. 595.
- Burbidge et al. 1957, p. 596.
- Burbidge et al. 1957, pp. 582, 609–615.
- Langmuir & Broecker 2012, pp. 183–184.
- Davidson et al. 2014, pp. 4–5.
- Emsley 2011, pp. 286, passim.
- Cox 1997, p. 182.
- ^ Davidson et al. 2014, p. 4.
- ^ United States Geological Survey 2017, p. 97.
- Rieuwerts 2015, p. 225.
- Merriam-Webster.
- ^ Kroonen 2013, *lauda-.
- Nikolayev 2012.
- Kroonen 2013, *bliwa- 2.
- Kroonen 2013, *laidijan-.
- ^ Hong et al. 1994, pp. 1841–1843.
- ^ Rich 1994, p. 4.
- ^ Winder 1993b.
- History of Cosmetics.
- Chapurukha Kusimba 2017.
- Yu & Yu 2004, p. 26.
- Toronto museum explores 2003.
- Neiburger 2018.
- Bisson & Vogel 2000, p. 105.
- Wood, Hsu & Bell 2021.
- Rich 1994, p. 5.
- United States Geological Survey 1973.
- Lead sling bullet.
- de Callataÿ 2005, pp. 361–372.
- Ceccarelli 2013, p. 35.
- Ossuaries and Sarcophagi.
- Calvo Rebollar 2019, p. 45.
- Rich 1994, p. 6.
- Thornton, Rautiu & Brush 2001, pp. 179–184.
- Bisel & Bisel 2002, pp. 459–460.
- Retief & Cilliers 2006, pp. 149–151.
- Grout 2017.
- Eschnauer & Stoeppler 1992, p. 58.
- Hodge 1981, pp. 486–491.
- Marcus Vitruvius Pollio (1914) . De architectura. Book 8, 10–11 fulltext.
- Gilfillan 1965, pp. 53–60.
- Nriagu 1983, pp. 660–663.
- Frankenburg 2014, p. 16.
- Scarborough 1984.
- Waldron 1985, pp. 107–108.
- Reddy & Braun 2010, p. 1052.
- Delile et al. 2014, pp. 6594–6599.
- Finger 2006, p. 184.
- Lewis 1985, p. 15.
- Thornton, Rautiu & Brush 2001, p. 183.
- Polyanskiy 1986, p. 8.
- Thomson 1830, p. 74.
- Oxford English Dictionary, surma.
- Vasmer 1986–1987, сурьма.
- Kellett 2012, pp. 106–107.
- ^ Winder 1993a.
- ^ Rich 1994, p. 7.
- Rich 1994, p. 8.
- Ede & Cormack 2016, p. 54.
- Cotnoir 2006, p. 35.
- Samson 1885, p. 388.
- Sinha et al. 1993.
- ^ Ramage 1980, p. 8.
- Tungate 2011, p. 14.
- Donnelly 2014, pp. 171–172.
- Ashikari 2003, p. 65.
- Nakashima et al. 1998, p. 59.
- Rabinowitz 1995, p. 66.
- Gill & Libraries Board of South Australia 1974, p. 69.
- Bisson & Vogel 2000, p. 85.
- Bisson & Vogel 2000, pp. 131–132.
- Hong et al. 1994, pp. 1841–43.
- Lead mining.
- Rich 1994, p. 11.
- ^ Riva et al. 2012, pp. 11–16.
- Hernberg 2000, p. 246.
- ^ Crow 2007.
- Markowitz & Rosner 2000, p. 37.
- More et al. 2017.
- American Geophysical Union 2017.
- Centers for Disease Control and Prevention 1997.
- Rich 1994, p. 117.
- Rich 1994, p. 17.
- Rich 1994, pp. 91–92.
- United States Geological Survey 2005.
- Zhang et al. 2012, pp. 2261–2273.
- Tolliday 2014.
- Guberman 2016, pp. 42.14–15.
- Graedel 2010.
- ^ Thornton, Rautiu & Brush 2001, p. 56.
- ^ Davidson et al. 2014, p. 6.
- ^ Davidson et al. 2014, p. 17.
- Thornton, Rautiu & Brush 2001, p. 51.
- Davidson et al. 2014, pp. 11–12.
- Thornton, Rautiu & Brush 2001, pp. 51–52.
- Davidson et al. 2014, p. 25.
- ^ Primary Lead Refining.
- Pauling 1947.
- Davidson et al. 2014, p. 34.
- Davidson et al. 2014, p. 23.
- Thornton, Rautiu & Brush 2001, pp. 52–53.
- United States Environmental Protection Agency 2010, p. 1.
- ^ Thornton, Rautiu & Brush 2001, p. 57.
- Street & Alexander 1998, p. 181.
- Evans 1908, pp. 133–179.
- Baird & Cann 2012, pp. 537–538, 543–547.
- California Department of Fish and Wildlife.
- "Nontoxic Shot Regulations For Hunting Waterfowl and Coots in the U.S. | U.S. Fish & Wildlife Service". www.fws.gov. 19 April 2022. Retrieved 12 September 2024.
- Canada, Environment and Climate Change (5 April 2018). "Moving towards using more lead-free ammunition". www.canada.ca. Retrieved 12 September 2024.
- "Regulation - 2021/57 - EN - EUR-Lex". eur-lex.europa.eu. Retrieved 12 September 2024.
- Parker 2005, pp. 194–195.
- Krestovnikoff & Halls 2006, p. 70.
- Street & Alexander 1998, p. 182.
- Jensen 2013, p. 136.
- Think Lead research.
- Weatherings to Parapets.
- Lead garden ornaments 2016.
- Putnam 2003, p. 216.
- Copper Development Association.
- ^ Rich 1994, p. 101.
- Guruswamy 2000, p. 31.
- Audsley 1965, pp. 250–251.
- Palmieri 2006, pp. 412–413.
- National Council on Radiation Protection and Measurements 2004, p. 16.
- Thornton, Rautiu & Brush 2001, p. 7.
- Tuček, Carlsson & Wider 2006, p. 1590.
- Concordia University 2016.
- Toxicological Profile for Lead 2007, pp. 5–6.
- Progressive Dynamics, Inc.
- Olinsky-Paul 2013.
- Gulbinska 2014.
- Rich 1994, pp. 133–134.
- Zhao 2008, p. 440.
- Beiner et al. 2015.
- Szczepanowska 2013, pp. 84–85.
- Burleson 2001, p. 23.
- Insight Explorer & IPEN 2016.
- Singh 2017.
- Ismawati et al. 2013, p. 2.
- Zweifel 2009, p. 438.
- Wilkes et al. 2005, p. 106.
- Randerson 2002.
- Nriagu & Kim 2000, pp. 37–41.
- Amstock 1997, pp. 116–119.
- Rogalski 2010, pp. 485–541.
- "Lead 695912".
- World Health Organization 2018.
- Bouchard et al. 2009.
- World Health Organization 2000, pp. 149–153.
- Emsley 2011, pp. 280, 621, 255.
- ^ Luckey & Venugopal 1979, pp. 177–178.
- Toxic Substances Portal.
- United States Food and Drug Administration 2015, p. 42.
- National Institute for Occupational Safety and Health.
- ^ Occupational Safety and Health Administration.
- ^ Rudolph et al. 2003, p. 369.
- Dart, Hurlbut & Boyer-Hassen 2004, p. 1426.
- Kosnett 2006, p. 238.
- Cohen, Trotzky & Pincus 1981, pp. 904–906.
- Navas-Acien 2007.
- Sokol 2005, p. 133, passim.
- Mycyk, Hryhorczuk & Amitai 2005, p. 462.
- Liu et al. 2015, pp. 1869–1874.
- Schoeters et al. 2008, pp. 168–175.
- Tarragó 2012, p. 16.
- Toxicological Profile for Lead 2007, p. 4.
- Bremner 2002, p. 101.
- Agency for Toxic Substances and Disease Registry 2007.
- Thornton, Rautiu & Brush 2001, p. 17.
- Moore 1977, pp. 109–115.
- Wiberg, Wiberg & Holleman 2001, p. 914.
- Tarragó 2012, p. 11.
- Centers for Disease Control and Prevention 2015.
- "Lead (Pb) Air Pollution". epa.gov. United States Environmental Protection Agency. 8 July 2022. Retrieved 22 July 2022.
As a result of EPA's regulatory efforts, levels of lead in the air nationally decreased by 86 percent between 2010 and 2020.
- "NAAQS Table". epa.gov. United States Environmental Protection Agency. 5 April 2022. Retrieved 22 July 2022.
National Ambient Air Quality Standards (40 CFR part 50) for six principal pollutants
- "Lead Trends". epa.gov. United States Environmental Protection Agency. 1 June 2022.
- Wani, Ara & Usman 2015, pp. 57, 58.
- Castellino N, Sannolo N, Castellino P (1994). Inorganic Lead Exposure and Intoxications. CRC Press. p. 86. ISBN 9780873719971. Archived from the original on 5 November 2017.
- Hesami, Reza; Salimi, Azam; Ghaderian, Seyed Majid (10 January 2018). "Lead, zinc, and cadmium uptake, accumulation, and phytoremediation by plants growing around Tang-e Douzan lead–zinc mine, Iran". Environmental Science and Pollution Research. 25 (9): 8701–8714. Bibcode:2018ESPR...25.8701H. doi:10.1007/s11356-017-1156-y. ISSN 0944-1344. PMID 29322395. S2CID 3938066.
- Mielke, Howard W.; Reagan, Patrick L. (February 1998). "Soil Is an Important Pathway of Human Lead Exposure". Environmental Health Perspectives. 106 (Suppl 1): 217–229. doi:10.2307/3433922. ISSN 0091-6765. JSTOR 3433922. PMC 1533263. PMID 9539015.
- ^ Jordan, Rob (24 September 2019). "Lead found in turmeric". Stanford News. Retrieved 25 September 2019.
- "Researchers find lead in turmeric". phys.org. 24 September 2019. Retrieved 25 September 2019.
- "Maximum Permitted Concentration of Certain Metals Present in Specified Foods". Cap. 132V Food Adulteration (Metallic Contamination) Regulations . Hong Kong e-Legislation. Retrieved 15 April 2020.
- Young, Robin; Miller-Medzon, Karyn (1 February 2023). "Dark chocolate is high in cadmium and lead. How much is safe to eat?". Here & Now. WBUR. Archived from the original on 8 February 2024.
- Stempel, Jonathan (23 January 2023). "Consumer Reports urges dark chocolate makers to reduce lead, cadmium levels". Yahoo Life. Reuters. Retrieved 28 January 2023.
- "FDA Alert Concerning Certain Cinnamon Products Due to Presence of Elevated Levels of Lead". Food and Drug Administration. 6 March 2024. Retrieved 27 May 2024.
- Aleccia, Jonel (8 March 2024). "Lead-tainted cinnamon has been recalled. Here's what you should know". Retrieved 27 May 2024.
- "Investigation of Elevated Lead & Chromium Levels: Cinnamon Applesauce Pouches (November 2023)". Food and Drug Administration. 16 April 2024. Retrieved 27 May 2024.
- "Lead Intoxication Associated with Chewing Plastic Wire Coating – Ohio". www.cdc.gov. Retrieved 8 June 2024.
- "About Lead in Consumer Products | Exposure | CDC". www.cdc.gov. 16 April 2024. Retrieved 8 June 2024.
- Prasad 2010, pp. 651–652.
- Masters, Trevor & Katzung 2008, pp. 481–483.
- ^ United Nations Environment Programme 2010, p. 4.
- Renfrew 2019, p. 8.
- ^ Trace element emission 2012.
- United Nations Environment Programme 2010, p. 6.
- Assi et al. 2016.
- World Health Organization 1995.
- UK Marine SACs Project 1999.
- United Nations Environment Programme 2010, p. 9.
- McCoy 2017.
- Cama 2017.
- Layton 2017.
- Hauser 2017, pp. 49–60.
- Lauwerys & Hoet 2001, pp. 115, 116–117.
- "Lead Poisoning: A Historical Perspective".
- Auer et al. 2016, p. 4.
- Petzel, Juuti & Sugimoto 2004, pp. 122–124.
- Deltares & Netherlands Organisation for Applied Scientific Research 2016.
- Calderwood, Dave (8 March 2022). "Europe moves to ban lead in avgas". FLYER. Retrieved 28 July 2024.
- Agency for Toxic Substances and Disease Registry 2017.
- Grandjean 1978, pp. 303–321.
- ^ Levin et al. 2008, p. 1288.
- Duda 1996, p. 242.
- "Lead Chromate: Why it is Banned in Most Industries Apart From Road Markings". Road Traffic Technology. Verdict Media Limited. Archived from the original on 5 March 2024. Retrieved 27 May 2024.
- Marino et al. 1990, pp. 1183–1185.
- Schoch 1996, p. 111.
- Davoren, Haley (6 June 2023). "From 100LL to G100UL: What comes next for avgas and why today is historic". Globalair.com. Retrieved 28 July 2024.
- United States Environmental Protection Agency 2000.
- Lead in Waste 2016.
- United States Environmental Protection Agency 2005, p. I-1.
- United States Environmental Protection Agency 2005, p. III-5–III-6.
- Freeman 2012, pp. a20–a21.
- Young 2012.
- Acton 2013, pp. 94–95.
- Park et al. 2011, pp. 162–174.
- Lakshmi, P.M.; Jaison, S.; Muthukumar, T.; Muthukumar, M. (1 November 2013). "Assessment of metal accumulation capacity of Brachiaria ramosa collected from cement waste dumping area for the remediation of metal contaminated soil". Ecological Engineering. 60: 96–98. Bibcode:2013EcEng..60...96L. doi:10.1016/j.ecoleng.2013.07.043.
Bibliography
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Mikhail Boldyrev; et al. (3 July 2018). "Lead: properties, history, and applications" (PDF). WikiJournal of Science. 1 (2): 7. doi:10.15347/WJS/2018.007. ISSN 2470-6345. Wikidata Q56050531.
- Acton, Q. A., ed. (2013). Issues in Global Environment—Pollution and Waste Management: 2012 Edition. ScholarlyEditions. ISBN 978-1-4816-4665-9.
- Agency for Toxic Substances and Disease Registry (20 August 2007). "Information for the Community: Lead Toxicity" (MP4 webcast, 82 MB). Archived from the original on 16 October 2022. Retrieved 11 February 2017.
- Agency for Toxic Substances and Disease Registry (2017). "Lead Toxicity. What Are U.S. Standards for Lead Levels?". Archived from the original on 12 March 2020. Retrieved 12 June 2018.
- Alsfasser, R. (2007). Moderne anorganische Chemie [Modern inorganic chemistry] (in German). Walter de Gruyter. ISBN 978-3-11-019060-1.
- American Geophysical Union (2017). "Human Activity Has Polluted European Air for 2000 Years". Eos Science News. Archived from the original on 27 June 2017. Retrieved 4 July 2017.
- Amstock, J. S. (1997). Handbook of Glass in Construction. McGraw-Hill Professional. ISBN 978-0-07-001619-4.
- Anderson, J. (1869). "Malleability and ductility of metals". Scientific American. 21 (22): 341–43. doi:10.1038/scientificamerican11271869-341.
- Ashikari, M. (2003). "The memory of the women's white faces: Japaneseness and the ideal image of women". Japan Forum. 15 (1): 55–79. doi:10.1080/0955580032000077739. S2CID 144510689.
- Assi, M. A.; Hezmee, M. N. M.; Haron, A. W.; et al. (2016). "The detrimental effects of lead on human and animal health". Veterinary World. 9 (6): 660–671. doi:10.14202/vetworld.2016.660-671. ISSN 0972-8988. PMC 4937060. PMID 27397992.
- Auer, Charles M.; Kover, Frank D.; Aidala, James V.; Greenwood, Mark (1 March 2016). Toxic Substances: A Half Century of Progress (PDF) (Report). EPA Alumni Association. Retrieved 1 January 2019.
- Audsley, G. A. (1965). The Art of Organ Building. Vol. 2. Courier. ISBN 978-0-486-21315-6.
- Baird, C.; Cann, N. (2012). Environmental Chemistry (5th ed.). W. H. Freeman and Company. ISBN 978-1-4292-7704-4.
- Becker, M.; Förster, C.; Franzen, C.; et al. (2008). "Persistent radicals of trivalent tin and lead". Inorganic Chemistry. 47 (21): 9965–78. doi:10.1021/ic801198p. PMID 18823115.
- Beeman, J. W.; Bellini, F.; Cardani, L.; et al. (2013). "New experimental limits on the α decays of lead isotopes". European Physical Journal A. 49 (50): 50. arXiv:1212.2422. Bibcode:2013EPJA...49...50B. doi:10.1140/epja/i2013-13050-7. S2CID 119280082.
- Beiner, G. G.; Lavi, M.; Seri, H.; et al. (2015). "Oddy Tests: Adding the Analytical Dimension". Collection Forum. 29 (1–2): 22–36. doi:10.14351/0831-4985-29.1.22. ISSN 0831-4985.
- Bharara, M. S.; Atwood, D. A. (2006). "Lead: Inorganic ChemistryBased in part on the article Lead: Inorganic Chemistry by Philip G. Harrison which appeared in the Encyclopedia of Inorganic Chemistry, First Edition". Lead: Inorganic Chemistry. doi:10.1002/0470862106.ia118. ISBN 978-0470860786.
- Bisel, S. C.; Bisel, J. F. (2002). "Health and nutrition at Herculaneum". In Jashemski, W. F.; Meyer, F. G. (eds.). The Natural History of Pompeii. Cambridge University Press. pp. 451–75. ISBN 978-0-521-80054-9.
- Bisson, M. S.; Vogel, J. O. (2000). Ancient African Metallurgy: The Sociocultural Context. Rowman & Littlefield. ISBN 978-0-7425-0261-1.
- Blakemore, J. S. (1985). Solid State Physics. Cambridge University Press. ISBN 978-0-521-31391-9.
- Bouchard, M. F.; Bellinger, D. C.; Weuve, J.; et al. (2009). "Blood Lead Levels and Major Depressive Disorder, Panic Disorder, and Generalized Anxiety Disorder in US Young Adults". Archives of General Psychiatry. 66 (12): 1313–9. doi:10.1001/archgenpsychiatry.2009.164. ISSN 0003-990X. PMC 2917196. PMID 19996036.
- Bremner, H. A. (2002). Safety and Quality Issues in Fish Processing. Elsevier. ISBN 978-1-85573-678-8.
- Brenner, G. A. (2003). Webster's New World American Idioms Handbook. John Wiley & Sons. ISBN 978-0-7645-2477-6.
- Brescia, F. (2012). Fundamentals of Chemistry: A Modern Introduction. Elsevier. ISBN 978-0-323-14231-1.
- Bretherick, L. (2016). Bretherick's Handbook of Reactive Chemical Hazards. Elsevier. ISBN 978-1-4831-6250-8.
- Bunker, B. C.; Casey, W. H. (2016). The Aqueous Chemistry of Oxides. Oxford University Press. ISBN 978-0-19-938425-9.
- Burbidge, E. M.; Burbidge, G. R.; Fowler, W. A.; et al. (1957). "Synthesis of the Elements in Stars". Reviews of Modern Physics. 29 (4): 547–654. Bibcode:1957RvMP...29..547B. doi:10.1103/RevModPhys.29.547.
- Burleson, M. (2001). The Ceramic Glaze Handbook: Materials, Techniques, Formulas. Sterling. ISBN 9781579904395.
- California Department of Fish and Wildlife. "Nonlead Ammunition in California". www.wildlife.ca.gov. Retrieved 17 May 2017.
- de Callataÿ, F. (2005). "The Graeco-Roman economy in the super long-run: Lead, copper, and shipwrecks". Journal of Roman Archaeology. 18: 361–72. doi:10.1017/S104775940000742X. S2CID 232346123.
- Cama, T. (2017). "Interior secretary repeals ban on lead bullets". The Hill. Retrieved 30 May 2018.
- Cangelosi, V. M.; Pecoraro, V. L. (2015). "Lead". In Roduner, E. (ed.). Nanoscopic Materials: Size-Dependent Phenomena and Growth Principles. Royal Society of Chemistry. pp. 843–875. ISBN 978-1-78262-494-3.
- Casciani, D. (2014). "Did removing lead from petrol spark a decline in crime?". BBC News. Retrieved 30 January 2017.
- Calvo Rebollar, Miguel (2019). Construyendo la Tabla Periódica. Zaragoza, Spain: Prames. ISBN 978-84-8321-908-9.
- Ceccarelli, P. (2013). Ancient Greek Letter Writing: A Cultural History (600 BC- 150 BC). OUP Oxford. ISBN 978-0-19-967559-3.
- Centers for Disease Control and Prevention (1997). "Update: blood lead levels--United States, 1991-1994". Morbidity and Mortality Weekly Report. 46 (7): 141–146. ISSN 0149-2195. PMID 9072671.
- Centers for Disease Control and Prevention (2015). "Radiation and Your Health". Retrieved 28 February 2017.
- Chapurukha Kusimba (20 June 2017). "Making Cents of Currency's Ancient Rise". Smithsonian Magazine. Retrieved 5 November 2021.
- Christensen, N. E. (2002). "Relativistic Solid State Theory". In Schwerdtfeger, P. (ed.). Relativistic Electronic Structure Theory — Fundamentals. Theoretical and Computational Chemistry. Vol. 11. Elsevier. pp. 867–68. doi:10.1016/s1380-7323(02)80041-3. ISBN 978-0-08-054046-7.
- Claudio, Elizabeth S.; Godwin, Hilary Arnold; Magyar, John S. (2002). "Fundamental Coordination Chemistry, Environmental Chemistry, and Biochemistry of Lead(II)". Progress in Inorganic Chemistry, Volume 51. John Wiley & Sons, Inc. pp. 1–144. doi:10.1002/0471267287.ch1. ISBN 978-0-471-26534-4.
- Cohen, A. R.; Trotzky, M. S.; Pincus, D. (1981). "Reassessment of the Microcytic Anemia of Lead Poisoning". Pediatrics. 67 (6): 904–906. doi:10.1542/peds.67.6.904. PMID 7232054. S2CID 42146120.
- Committee on Evaluation of EPA Guidelines for Exposure to Naturally Occurring Radioactive Materials; Commission on Life Sciences; Division on Earth and Life Studies; National Research Council (1999). Evaluation of Guidelines for Exposures to Technologically Enhanced Naturally Occurring Radioactive Materials. National Academies Press. pp. 26, 30–32. ISBN 978-0-309-58070-0.
- Concordia University (2016). Lead acid batteries (PDF) (Report). Retrieved 17 February 2019.
- Considine, D. M.; Considine, G. D. (2013). Van Nostrand's Scientific Encyclopedia. Springer Science & Business Media. ISBN 978-1-4757-6918-0.
- Copper Development Association. "Leaded Coppers". copper.org. Retrieved 10 July 2016.
- Cotnoir, B. (2006). The Weiser Concise Guide to Alchemy. Weiser Books. ISBN 978-1-57863-379-1.
- Cox, P. A. (1997). The Elements: Their Origin, Abundance and Distribution. Oxford University Press. ISBN 978-0-19-855298-7.
- Crow, J. M. (2007). "Why use lead in paint?". Chemistry World. Royal Society of Chemistry. Retrieved 22 February 2017.
- Dart, R. C.; Hurlbut, K. M.; Boyer-Hassen, L. V. (2004). "Lead". In Dart, R. C. (ed.). Medical Toxicology (3rd ed.). Lippincott Williams & Wilkins. p. 1426. ISBN 978-0-7817-2845-4.
- Davidson, A.; Ryman, J.; Sutherland, C. A.; et al. (2014). "Lead". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a15_193.pub3. ISBN 978-3-527-30673-2.
- de Marcillac, Pierre; Coron, Noël; Dambier, Gérard; et al. (2003). "Experimental detection of α-particles from the radioactive decay of natural bismuth". Nature. 422 (6934): 876–78. Bibcode:2003Natur.422..876D. doi:10.1038/nature01541. PMID 12712201. S2CID 4415582.
- Delile, H.; Blichert-Toft, J.; Goiran, J.-P.; et al. (2014). "Lead in ancient Rome's city waters". Proceedings of the National Academy of Sciences. 111 (18): 6594–99. Bibcode:2014PNAS..111.6594D. doi:10.1073/pnas.1400097111. ISSN 0027-8424. PMC 4020092. PMID 24753588.
- Deltares; Netherlands Organisation for Applied Scientific Research (2016). Lood en zinkemissies door jacht [Lead and zinc emissions from hunting] (PDF) (Report) (in Dutch). Archived from the original (PDF) on 12 April 2019. Retrieved 18 February 2017.
- Dieter, R. K.; Watson, R. T. (2009). "Transmetalation reactions producing organocopper compounds". In Rappoport, Z.; Marek, I. (eds.). The Chemistry of Organocopper Compounds. Vol. 1. John Wiley & Sons. pp. 443–526. ISBN 978-0-470-77296-6.
- Donnelly, J. (2014). Deep Blue. Hachette Children's Group. ISBN 978-1-4449-2119-9.
- Downs, A. J.; Adams, C. J. (2017). The Chemistry of Chlorine, Bromine, Iodine and Astatine: Pergamon Texts in Inorganic Chemistry. Elsevier. ISBN 978-1-4831-5832-7.
- Duda, M. B. (1996). Traditional Chinese Toggles: Counterweights and Charms. Editions Didier Millet. ISBN 978-981-4260-61-9.
- Ede, A.; Cormack, L. B. (2016). A History of Science in Society, Volume I: From the Ancient Greeks to the Scientific Revolution, Third Edition. University of Toronto Press. ISBN 978-1-4426-3503-6.
- Emsley, J. (2011). Nature's Building Blocks: An A-Z Guide to the Elements. Oxford University Press. ISBN 978-0-19-960563-7.
- "Encyclopedia Judaica: Ossuaries and Sarcophagi". www.jewishvirtuallibrary.org. Retrieved 14 July 2018.
- Eschnauer, H. R.; Stoeppler, M. (1992). "Wine—An enological specimen bank". In Stoeppler, M. (ed.). Hazardous Materials in the Environment. Elsevier Science. pp. 49–72 (58). doi:10.1016/s0167-9244(08)70103-3. ISBN 978-0-444-89078-8.
- Evans, J. W. (1908). "V.— The meanings and synonyms of plumbago". Transactions of the Philological Society. 26 (2): 133–79. doi:10.1111/j.1467-968X.1908.tb00513.x.
- Finger, S. (2006). Doctor Franklin's Medicine. University of Pennsylvania Press. ISBN 978-0-8122-3913-3.
- Fiorini, E. (2010). "2.000 years-old Roman Lead for physics" (PDF). ASPERA: 7–8. Archived from the original (PDF) on 26 April 2018. Retrieved 29 October 2016.
- Frankenburg, F. R. (2014). Brain-Robbers: How Alcohol, Cocaine, Nicotine, and Opiates Have Changed Human History. ABC-CLIO. ISBN 978-1-4408-2932-1.
- Frebel, A. (2015). Searching for the Oldest Stars: Ancient Relics from the Early Universe. Princeton University. ISBN 978-0-691-16506-6.
- Freeman, K. S. (2012). "Remediating soil lead with fishbones". Environmental Health Perspectives. 120 (1): a20 – a21. doi:10.1289/ehp.120-a20a. PMC 3261960. PMID 22214821.
- Funke, K. (2013). "Solid State Ionics: from Michael Faraday to green energy—the European dimension". Science and Technology of Advanced Materials. 14 (4): 1–50. Bibcode:2013STAdM..14d3502F. doi:10.1088/1468-6996/14/4/043502. PMC 5090311. PMID 27877585.
- Gale, W. F.; Totemeier, T. C. (2003). Smithells Metals Reference Book. Butterworth-Heinemann. ISBN 978-0-08-048096-1.
- Gilfillan, S. C. (1965). "Lead poisoning and the fall of Rome". Journal of Occupational Medicine. 7 (2): 53–60. ISSN 0096-1736. PMID 14261844.
- Gill, T.; Libraries Board of South Australia (1974). The history and topography of Glen Osmond, with map and illustrations. Libraries Board of South Australia. ISBN 9780724300358.
- Graedel, T. E.; et al. (2010). Metal stocks in Society – Scientific Synthesis (PDF) (Report). International Resource Panel. p. 17. ISBN 978-92-807-3082-1. Archived from the original (PDF) on 26 April 2018. Retrieved 18 April 2017.
- Grandjean, P. (1978). "Widening perspectives of lead toxicity". Environmental Research. 17 (2): 303–21. Bibcode:1978ER.....17..303G. doi:10.1016/0013-9351(78)90033-6. PMID 400972.
- Greenwood, N. N.; Earnshaw, A. (1998). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-7506-3365-9.
- Grout, J. (2017). "Lead poisoning and Rome". Encyclopaedia Romana. Retrieved 15 February 2017.
- Guberman, D. E. (2016). "Lead" (PDF). 2014 Minerals Yearbook (Report). United States Geological Survey. Retrieved 8 May 2017.
- Gulbinska, M. K. (2014). Lithium-ion Battery Materials and Engineering: Current Topics and Problems from the Manufacturing Perspective. Springer. p. 96. ISBN 978-1-4471-6548-4.
- Guruswamy, S. (2000). Engineering properties and applications of lead alloys. Marcel Dekker. ISBN 978-0-8247-8247-4.
- Hadlington, T. J. (2017). On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes. Springer. ISBN 978-3-319-51807-7.
- Harbison, R. D.; Bourgeois, M. M.; Johnson, G. T. (2015). Hamilton and Hardy's Industrial Toxicology. John Wiley & Sons. ISBN 978-0-470-92973-5.
- Hauser, P. C. (2017). "Analytical Methods for the Determination of Lead in the Environment". In Astrid, S.; Helmut, S.; Sigel, R. K. O. (eds.). Lead: Its Effects on Environment and Health (PDF). Metal Ions in Life Sciences. Vol. 17. de Gruyter. pp. 49–60. doi:10.1515/9783110434330-003. ISBN 9783110434330. PMID 28731296.
- Hernberg, S. (2000). "Lead Poisoning in a Historical Perspective" (PDF). American Journal of Industrial Medicine. 38 (3): 244–54. doi:10.1002/1097-0274(200009)38:3<244::AID-AJIM3>3.0.CO;2-F. PMID 10940962. Archived from the original (PDF) on 21 September 2017. Retrieved 1 March 2017.
- "A History of Cosmetics from Ancient Times". Cosmetics Info. Archived from the original on 14 July 2016. Retrieved 18 July 2016.
- Hodge, T. A. (1981). "Vitruvius, lead pipes and lead poisoning". American Journal of Archaeology. 85 (4): 486–91. doi:10.2307/504874. JSTOR 504874. S2CID 193094209.
- Hong, S.; Candelone, J.-P.; Patterson, C. C.; et al. (1994). "Greenland ice evidence of hemispheric lead pollution two millennia ago by Greek and Roman civilizations" (PDF). Science. 265 (5180): 1841–43. Bibcode:1994Sci...265.1841H. doi:10.1126/science.265.5180.1841. PMID 17797222. S2CID 45080402.
- Hunt, A. (2014). Dictionary of Chemistry. Routledge. ISBN 978-1-135-94178-9.
- IAEA - Nuclear Data Section (2017). "Livechart - Table of Nuclides - Nuclear structure and decay data". www-nds.iaea.org. International Atomic Energy Agency. Retrieved 31 March 2017.
- Insight Explorer; IPEN (2016). New Study Finds Lead Levels in a Majority of Paints Exceed Chinese Regulation and Should Not be on Store Shelves (PDF) (Report). Retrieved 3 May 2018.
- Ismawati, Yuyun; Primanti, Andita; Brosché, Sara; Clark, Scott; Weinberg, Jack; Denney, Valerie (2013). Timbal dalam Cat Enamel Rumah Tangga di Indonesia (PDF) (Report) (in Indonesian). BaliFokus & IPEN. Retrieved 26 December 2018.
- Jensen, C. F. (2013). Online Location of Faults on AC Cables in Underground Transmission. Springer. ISBN 978-3-319-05397-4.
- Jones, P. A. (2014). Jedburgh Justice and Kentish Fire: The Origins of English in Ten Phrases and Expressions. Constable. ISBN 978-1-47211-389-4.
- Kaupp, M. (2014). "Chemical bonding of main-group elements" (PDF). In Frenking, G.; Shaik, S. (eds.). The Chemical Bond: Chemical Bonding Across the Periodic Table. John Wiley & Sons. pp. 1–24. doi:10.1002/9783527664658.ch1. ISBN 9783527664658. S2CID 17979350.
- Kellett, C. (2012). Poison and Poisoning: A Compendium of Cases, Catastrophes and Crimes. Accent Press. ISBN 978-1-909335-05-9. Archived from the original on 9 June 2019.
- King, R. B. (1995). Inorganic Chemistry of Main Group Elements. VCH Publishers. ISBN 978-1-56081-679-9.
- Konu, J.; Chivers, T. (2011). "Stable Radicals of the Heavy p-Block Elements". In Hicks, R. G. (ed.). Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds. John Wiley & Sons. doi:10.1002/9780470666975.ch10. ISBN 978-0-470-77083-2.
- Kosnett, M. J. (2006). "Lead". In Olson, K. R. (ed.). Poisoning and Drug Overdose (5th ed.). McGraw-Hill Professional. p. 238. ISBN 978-0-07-144333-3.
- Krestovnikoff, M.; Halls, M. (2006). Scuba Diving. Dorling Kindersley. ISBN 978-0-7566-4063-7.
- Kroonen, G. (2013). Etymological Dictionary of Proto-Germanic. Leiden Indo-European Etymological Dictionary Series. Vol. 11. Brill. ISBN 978-90-04-18340-7.
- Langmuir, C. H.; Broecker, W. S. (2012). How to Build a Habitable Planet: The Story of Earth from the Big Bang to Humankind. Princeton University Press. ISBN 978-0-691-14006-3.
- Lauwerys, R. R.; Hoet, P. (2001). Industrial Chemical Exposure: Guidelines for Biological Monitoring, Third Edition. CRC Press. ISBN 978-1-4822-9383-8.
- Layton, M. (2017). "Lead faces threat of new Euro ban". shootinguk.co.uk. Retrieved 30 May 2018.
- "Lead sling bullet; almond shape; a winged thunderbolt on one side and on the other, in high relief, the inscription DEXAI "Catch!"". The British Museum. Archived from the original on 14 February 2012. Retrieved 30 April 2012.
- "Lead garden ornaments". H. Crowther Ltd. 2016. Retrieved 20 February 2017.
- "Lead in Waste Disposal". United States Environmental Protection Agency. 2016. Retrieved 28 February 2017.
- "Lead mining". The Northern Echo. Retrieved 16 February 2016.
- Levin, H. L. (2009). The Earth Through Time. John Wiley & Sons. ISBN 978-0-470-38774-0.
- Levin, R.; Brown, M. J.; Kashtock, M. E.; et al. (2008). "Lead exposures in U.S. children, 2008: Implications for prevention". Environmental Health Perspectives. 116 (10): 1285–93. Bibcode:2008EnvHP.116.1285L. doi:10.1289/ehp.11241. PMC 2569084. PMID 18941567.
- Lewis, J. (1985). "Lead Poisoning: A Historical Perspective". EPA Journal. 11 (4): 15–18. Retrieved 31 January 2017.
- Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (85th ed.). CRC Press. ISBN 978-0-8493-0484-2.
- Liu, J.; Liu, X.; Pak, V.; et al. (2015). "Early blood lead levels and sleep disturbance in preadolescence". Sleep. 38 (12): 1869–74. doi:10.5665/sleep.5230. PMC 4667382. PMID 26194570.
- Lochner, J. C.; Rohrbach, G.; Cochrane, K. (2005). "What is Your Cosmic Connection to the Elements?" (PDF). Goddard Space Flight Center. Archived from the original (PDF) on 29 December 2016. Retrieved 2 July 2017.
- Lodders, K. (2003). "Solar System abundances and condensation temperatures of the elements" (PDF). The Astrophysical Journal. 591 (2): 1220–47. Bibcode:2003ApJ...591.1220L. doi:10.1086/375492. ISSN 0004-637X. S2CID 42498829.
- Luckey, T. D.; Venugopal, B. (1979). Physiologic and Chemical Basis for Metal Toxicity. Plenum Press. ISBN 978-1-4684-2952-7.
- Macintyre, J. E. (1992). Dictionary of Inorganic Compounds. CRC Press. ISBN 978-0-412-30120-9.
- Marino, P. E.; Landrigan, P. J.; Graef, J.; et al. (1990). "A case report of lead paint poisoning during renovation of a Victorian farmhouse". American Journal of Public Health. 80 (10): 1183–85. doi:10.2105/AJPH.80.10.1183. PMC 1404824. PMID 2119148.
- Markowitz, G.; Rosner, D. (2000). ""Cater to the children": the role of the lead industry in a public health tragedy, 1900–55". American Journal of Public Health. 90 (1): 36–46. doi:10.2105/ajph.90.1.36. PMC 1446124. PMID 10630135.
- Masters, S. B.; Trevor, A. J.; Katzung, B. G. (2008). Katzung & Trevor's Pharmacology: Examination & Board Review (8th ed.). McGraw-Hill Medical. ISBN 978-0-07-148869-3.
- McCoy, S. (2017). "The End of Lead? Federal Gov't Order Bans Sinkers, Ammo". GearJunkie. Archived from the original on 8 March 2020. Retrieved 30 May 2018.
- Meija, Juris; et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry. 88 (3): 265–291. doi:10.1515/pac-2015-0305.
- Merriam-Webster. "Definition of LEAD". www.merriam-webster.com. Retrieved 12 August 2016.
- Moore, M. R. (1977). "Lead in drinking water in soft water areas—health hazards". Science of the Total Environment. 7 (2): 109–15. Bibcode:1977ScTEn...7..109M. doi:10.1016/0048-9697(77)90002-X. PMID 841299.
- More, A. F.; Spaulding, N. E.; Bohleber, P.; et al. (2017). "Next-generation ice core technology reveals true minimum natural levels of lead (Pb) in the atmosphere: Insights from the Black Death" (PDF). GeoHealth. 1 (4): 211–219. Bibcode:2017GHeal...1..211M. doi:10.1002/2017GH000064. ISSN 2471-1403. PMC 7007106. PMID 32158988. Archived from the original (PDF) on 18 April 2020. Retrieved 28 August 2019.
- Mosseri, S.; Henglein, A.; Janata, E. (1990). "Trivalent lead as an intermediate in the oxidation of lead(II) and the reduction of lead(IV) species". Journal of Physical Chemistry. 94 (6): 2722–26. doi:10.1021/j100369a089.
- Mycyk, M.; Hryhorczuk, D.; Amitai, Y.; et al. (2005). "Lead". In Erickson, T. B.; Ahrens, W. R.; Aks, S. (eds.). Pediatric Toxicology: Diagnosis and Management of the Poisoned Child. McGraw-Hill Professional. ISBN 978-0-07-141736-5.
- Nakashima, T.; Hayashi, H.; Tashiro, H.; et al. (1998). "Gender and hierarchical differences in lead-contaminated Japanese bone from the Edo period". Journal of Occupational Health. 40 (1): 55–60. doi:10.1539/joh.40.55. S2CID 71451911.
- National Council on Radiation Protection and Measurements (2004). Structural Shielding Design for Medical X-ray Imaging Facilities. ISBN 978-0-929600-83-3.
- National Institute for Occupational Safety and Health. "NIOSH Pocket Guide to Chemical Hazards — Lead". www.cdc.gov. Retrieved 18 November 2016.
- Navas-Acien, A. (2007). "Lead Exposure and Cardiovascular Disease—A Systematic Review". Environmental Health Perspectives. 115 (3): 472–482. Bibcode:2007EnvHP.115..472N. doi:10.1289/ehp.9785. PMC 1849948. PMID 17431501.
- Neiburger, E.J. (April 2018). "X-Rays, Archaeology and the Chopsticks of Death". Central States Archaeological Journal. 65 (2): 70–74. JSTOR 44715698.
- Nikolayev, S., ed. (2012). "*lAudh-". Indo-European Etymology. Retrieved 21 August 2016.
- Norman, N. C. (1996). Periodicity and the s- and p-Block Elements. Oxford University Press. ISBN 978-0-19-855961-0.
- Nriagu, J. O. (1983). "Saturnine gout among Roman aristocrats — Did lead poisoning contribute to the fall of the Empire?". The New England Journal of Medicine. 308 (11): 660–63. doi:10.1056/NEJM198303173081123. PMID 6338384.
- Nriagu, J. O.; Kim, M-J. (2000). "Emissions of lead and zinc from candles with metal-core wicks". Science of the Total Environment. 250 (1–3): 37–41. Bibcode:2000ScTEn.250...37N. doi:10.1016/S0048-9697(00)00359-4. PMID 10811249.
- Occupational Safety and Health Administration. "Substance data sheet for occupational exposure to lead". www.osha.gov. Archived from the original on 16 March 2018. Retrieved 1 July 2017.
- Olinsky-Paul, T. (2013). "East Penn and Ecoult battery installation case study webinar" (PDF). Clean Energy States Alliance. Retrieved 28 February 2017.
- Palmieri, R., ed. (2006). The Organ. Psychology Press. ISBN 978-0-415-94174-7.
- "surma". Oxford English Dictionary (2nd ed.). Oxford University Press. 2009.
- Park, J. H.; Bolan, N.; Meghara, M.; et al. (2011). "Bacterial-assisted immobilization of lead in soils: Implications for remediation" (PDF). Pedologist: 162–74. Archived from the original (PDF) on 26 November 2015.
- Parker, R. B. (2005). The New Cold-Molded Boatbuilding: From Lofting to Launching. WoodenBoat Books. ISBN 978-0-937822-89-0.
- Parthé, E. (1964). Crystal Chemistry of Tetrahedral Structures. CRC Press. ISBN 978-0-677-00700-7.
- Pauling, L. (1947). General Chemistry. W. H. Freeman and Company. ISBN 978-0-486-65622-9.
- Peneva, S. K.; Djuneva, K. D.; Tsukeva, E. A. (1981). "RHEED study of the initial stages of crystallization and oxidation of lead and tin". Journal of Crystal Growth. 53 (2): 382–396. Bibcode:1981JCrGr..53..382P. doi:10.1016/0022-0248(81)90088-9. ISSN 0022-0248.
- Petzel, S.; Juuti, M.; Sugimoto, Yu. (2004). "Environmental Stewardship with Regional Perspectives and Drivers of the Lead-free Issue". In Puttlitz, K. J.; Stalter, K. A. (eds.). Handbook of Lead-Free Solder Technology for Microelectronic Assemblies. CRC Press. ISBN 978-0-8247-5249-1.
- Polyanskiy, N. G. (1986). Fillipova, N. A (ed.). Аналитическая химия элементов: Свинец [Analytical Chemistry of the Elements: Lead] (in Russian). Nauka.
- Prasad, P. J. (2010). Conceptual Pharmacology. Universities Press. ISBN 978-81-7371-679-9. Retrieved 21 June 2012.
- "Primary Lead Refining Technical Notes". LDA International. Archived from the original on 22 March 2007. Retrieved 7 April 2007.
- Progressive Dynamics, Inc. "How Lead Acid Batteries Work: Battery Basics". progressivedyn.com. Archived from the original on 19 November 2018. Retrieved 3 July 2016.
- Putnam, B. (2003). The Sculptor's Way: A Guide to Modelling and Sculpture. Dover Publications. ISBN 978-0-486-42313-5.
- Pyykkö, P. (1988). "Relativistic effects in structural chemistry". Chemical Reviews. 88 (3): 563–94. doi:10.1021/cr00085a006.
- Rabinowitz, M. B. (1995). "Imputing lead sources from blood lead isotope ratios". In Beard, M. E.; Allen Iske, S. D. (eds.). Lead in Paint, Soil, and Dust: Health Risks, Exposure Studies, Control Measures, Measurement Methods, and Quality Assurance. ASTM. pp. 63–75. doi:10.1520/stp12967s. ISBN 978-0-8031-1884-3.
- "Radioactive Decay Series" (PDF). Nuclear Systematics. MIT OpenCourseWare. 2012. Retrieved 28 April 2018.
- Ramage, C. K., ed. (1980). Lyman Cast Bullet Handbook (3rd ed.). Lyman Products Corporation.
- Randerson, J. (2002). "Candle pollution". New Scientist (2348). Retrieved 7 April 2007.
- Reddy, A.; Braun, C. L. (2010). "Lead and the Romans". Journal of Chemical Education. 87 (10): 1052–55. Bibcode:2010JChEd..87.1052R. doi:10.1021/ed100631y.
- Renfrew, Daniel (2019). Life without lead: contamination, crisis, and hope in Uruguay. Oakland, California: University of California Press. ISBN 978-0-520-96824-0. OCLC 1102765674.
- Retief, F.; Cilliers, L. P. (2006). "Lead poisoning in ancient Rome". Acta Theologica. 26 (2): 147–64 (149–51). doi:10.4314/actat.v26i2.52570.
- Rich, V. (1994). The International Lead Trade. Woodhead Publishing. ISBN 978-0-85709-994-5.
- Rieuwerts, J. (2015). The Elements of Environmental Pollution. Routledge. ISBN 978-0-415-85919-6.
- Riva, M. A.; Lafranconi, A.; d'Orso, M. I.; et al. (2012). "Lead poisoning: Historical aspects of a paradigmatic "occupational and environmental disease"". Safety and Health at Work. 3 (1): 11–16. doi:10.5491/SHAW.2012.3.1.11. PMC 3430923. PMID 22953225.
- Roederer, I. U.; Kratz, K.-L.; Frebel, A.; et al. (2009). "The end of nucleosynthesis: Production of lead and thorium in the early galaxy". The Astrophysical Journal. 698 (2): 1963–80. arXiv:0904.3105. Bibcode:2009ApJ...698.1963R. doi:10.1088/0004-637X/698/2/1963. S2CID 14814446.
- Rogalski, A. (2010). Infrared Detectors (2nd ed.). CRC Press. ISBN 978-1-4200-7671-4. Retrieved 19 November 2016.
- Röhr, C. (2017). "Binare Zintl-Phasen" [Binary Zintl Phases]. Intermetallische Phasen [Intermettallic Phases] (in German). Universitat Freiburg. Retrieved 18 February 2017.
- Rudolph, A. M.; Rudolph, C. D.; Hostetter, M. K.; et al. (2003). "Lead". Rudolph's Pediatrics (21st ed.). McGraw-Hill Professional. p. 369. ISBN 978-0-8385-8285-5.
- Samson, G. W. (1885). The divine law as to wines. J. B. Lippincott & Co.
- Scarborough, J. (1984). "The myth of lead poisoning among the Romans: An essay review". Journal of the History of Medicine and Allied Sciences. 39 (4): 469–475. doi:10.1093/jhmas/39.4.469. PMID 6389691.
- Schoch, R. M. (1996). Case Studies in Environmental Science. West Publishing. ISBN 978-0-314-20397-7.
- Schoeters, G.; Den Hond, E.; Dhooge, W.; et al. (2008). "Endocrine disruptors and abnormalities of pubertal development" (PDF). Basic & Clinical Pharmacology & Toxicology. 102 (2): 168–175. doi:10.1111/j.1742-7843.2007.00180.x. hdl:1854/LU-391408. PMID 18226071.
- Sharma, H. R.; Nozawa, K.; Smerdon, J. A.; et al. (2013). "Templated three-dimensional growth of quasicrystalline lead". Nature Communications. 4: 2715. Bibcode:2013NatCo...4.2715S. doi:10.1038/ncomms3715. PMID 24185350.
- Sharma, H. R.; Smerdon, J. A.; Nugent, P. J.; et al. (2014). "Crystalline and quasicrystalline allotropes of Pb formed on the fivefold surface of icosahedral Ag-In-Yb". The Journal of Chemical Physics. 140 (17): 174710. Bibcode:2014JChPh.140q4710S. doi:10.1063/1.4873596. PMID 24811658.
- Silverman, M. S. (1966). "High-pressure (70-k) synthesis of new crystalline lead dichalcogenides". Inorganic Chemistry. 5 (11): 2067–69. doi:10.1021/ic50045a056.
- Singh, P. (2017). "Over 73% of paints found to have excessive lead: Study". Times of India. Retrieved 3 May 2018.
- Sinha, S. P.; Shelly; Sharma, V.; et al. (1993). "Neurotoxic effects of lead exposure among printing press workers". Bulletin of Environmental Contamination and Toxicology. 51 (4): 490–93. Bibcode:1993BuECT..51..490S. doi:10.1007/BF00192162. PMID 8400649. S2CID 26631583.
- Slater, J. C. (1964). "Atomic Radii in Crystals". The Journal of Chemical Physics. 41 (10): 3199–3204. Bibcode:1964JChPh..41.3199S. doi:10.1063/1.1725697. ISSN 0021-9606.
- Smirnov, A. Yu.; Borisevich, V. D.; Sulaberidze, A. (2012). "Evaluation of specific cost of obtainment of lead-208 isotope by gas centrifuges using various raw materials". Theoretical Foundations of Chemical Engineering. 46 (4): 373–78. doi:10.1134/s0040579512040161. S2CID 98821122.
- Sokol, R. C. (2005). "Lead exposure and its effects on the reproductive system". In Golub, M. S. (ed.). Metals, Fertility, and Reproductive Toxicity. CRC Press. pp. 117–53. doi:10.1201/9781420023282.ch6 (inactive 1 November 2024). ISBN 978-0-415-70040-5.
{{cite book}}: CS1 maint: DOI inactive as of November 2024 (link) - Stabenow, F.; Saak, W.; Weidenbruch, M. (2003). "Tris(triphenylplumbyl)plumbate: An anion with three stretched lead–lead bonds". Chemical Communications (18): 2342–2343. doi:10.1039/B305217F. PMID 14518905.
- Stone, R. (1997). "An Element of Stability". Science. 278 (5338): 571–572. Bibcode:1997Sci...278..571S. doi:10.1126/science.278.5338.571. S2CID 117946028.
- Street, A.; Alexander, W. (1998). Metals in the Service of Man (11th ed.). Penguin Books. ISBN 978-0-14-025776-2.
- Szczepanowska, H. M. (2013). Conservation of Cultural Heritage: Key Principles and Approaches. Routledge. ISBN 978-0-415-67474-4.
- Takahashi, K.; Boyd, R. N.; Mathews, G. J.; et al. (1987). "Bound-state beta decay of highly ionized atoms" (PDF). Physical Review C. 36 (4): 1522–1528. Bibcode:1987PhRvC..36.1522T. doi:10.1103/physrevc.36.1522. OCLC 1639677. PMID 9954244. Archived from the original (PDF) on 21 October 2014. Retrieved 27 August 2013.
- Tarragó, A. (2012). "Case Studies in Environmental Medicine (CSEM) Lead Toxicity" (PDF). Agency for Toxic Substances and Disease Registry. Archived from the original (PDF) on 13 October 2022. Retrieved 25 February 2017.
- Tétreault, J.; Sirois, J.; Stamatopoulou, E. (1998). "Studies of lead corrosion in acetic acid environments". Studies in Conservation. 43 (1): 17–32. doi:10.2307/1506633. JSTOR 1506633.
- Theodore Low De Vinne (1899). The Practice of Typography: A Treatise on the Processes of Type-making, the Point System, the Names, Sizes, Styles, and Prices of Plain Printing Types. Century Company.
- "Think Lead research summary" (PDF). The Lead Sheet Association. Archived from the original (PDF) on 20 February 2017. Retrieved 20 February 2017.
- Thomson, T. (1830). The History of Chemistry. Henry Colburn and Richard Bentley (publishers). ISBN 9780405066238.
- Thornton, I.; Rautiu, R.; Brush, S. M. (2001). Lead: The Facts (PDF). International Lead Association. ISBN 978-0-9542496-0-1. Archived from the original (PDF) on 26 July 2020. Retrieved 5 February 2017.
- Thürmer, K.; Williams, E.; Reutt-Robey, J. (2002). "Autocatalytic oxidation of lead crystallite surfaces". Science. 297 (5589): 2033–35. Bibcode:2002Sci...297.2033T. doi:10.1126/science.297.5589.2033. PMID 12242437. S2CID 6166273.
- Tolliday, B. (2014). "Significant growth in lead usage underlines its importance to the global economy". International Lead Association. Archived from the original on 28 February 2017. Retrieved 28 February 2017.
Global demand for lead has more than doubled since the early 1990s and almost 90% of use is now in lead–acid batteries
- "Toronto museum explores history of contraceptives". ABC News. 2003. Retrieved 13 February 2016.
- "Toxic Substances Portal – Lead". Agency for Toxic Substances and Disease Registry. Archived from the original on 6 June 2011.
- "Toxicological Profile for Lead" (PDF). Agency for Toxic Substances and Disease Registry/Division of Toxicology and Environmental Medicine. 2007. Archived from the original (PDF) on 1 July 2017.
- "Trace element emission from coal". IEA Clean Coal Centre. 2012. Archived from the original on 11 March 2020. Retrieved 1 March 2017.
- Tuček, K.; Carlsson, J.; Wider, H. (2006). "Comparison of sodium and lead-cooled fast reactors regarding reactor physics aspects, severe safety and economical issues" (PDF). Nuclear Engineering and Design. 236 (14–16): 1589–98. Bibcode:2006NuEnD.236.1589T. doi:10.1016/j.nucengdes.2006.04.019.
- Tungate, M. (2011). Branded Beauty: How Marketing Changed the Way We Look. Kogan Page Publishers. ISBN 978-0-7494-6182-9.
- UK Marine SACs Project (1999). "Lead". Water Quality (Report). Archived from the original on 17 February 2020. Retrieved 10 June 2018.
- United Nations Environment Programme (2010). Final review of scientific information on lead (PDF). Chemicals Branch, Division of Technology, Industry and Economics. Retrieved 31 January 2017.
- United States Environmental Protection Agency (2010). "Metallurgical Industry:Secondary Lead Processing". AP 42 Compilation of Air Pollutant Emission Factors (5th ed.). Retrieved 20 May 2018.
- United States Environmental Protection Agency (2000). "Regulatory Status of Waste Generated by Contractors and Residents from Lead-Based Paint Activities Conducted in Households (August 2000)". Retrieved 28 February 2017.
- United States Environmental Protection Agency (2005). "Best Management Practices for Lead at Outdoor Shooting Ranges" (PDF). Retrieved 12 June 2018.
- United States Food and Drug Administration (2015). Q3D Elemental Impurities Guidance for Industry (PDF) (Report). United States Department of Health and Human Services. p. 41. Retrieved 15 February 2017.
- United States Geological Survey (1973). Geological Survey Professional Paper. United States Government Publishing Office. p. 314.
- United States Geological Survey (2005). Lead (PDF) (Report). Retrieved 20 February 2016.
- United States Geological Survey (2017). "Lead" (PDF). Mineral Commodities Summaries. Retrieved 8 May 2017.
- University of California Nuclear Forensic Search Project. "Decay Chains". Nuclear Forensics: A Scientific Search Problem. Retrieved 23 November 2015.
- Vasmer, M. (1986–1987) . Trubachyov, O. N.; Larin, B. O. (eds.). Этимологический словарь русского языка [Russisches etymologisches Worterbuch] (in Russian) (2nd ed.). Progress. Retrieved 4 March 2017.
- Vogel, N. A.; Achilles, R. (2013). The Preservation and Repair of Historic Stained and Leaded Glass (PDF) (Report). United States Department of the Interior. Retrieved 30 October 2016.
- Waldron, H. A. (1985). "Lead and lead poisoning in antiquity". Medical History. 29 (1): 107–08. doi:10.1017/S0025727300043878. PMC 1139494.
- Wani, A. L.; Ara, A.; Usman, J. A. (2015). "Lead toxicity: A review". Interdisciplinary Toxicology. 8 (2): 55–64. doi:10.1515/intox-2015-0009. PMC 4961898. PMID 27486361.
- Weast, R. C.; Astle, M. J.; Beyer, W. H. (1983). CRC Handbook of Chemistry and Physics: A Ready-reference Book of Chemical and Physical Data. CRC Press. ISBN 978-0-8493-0464-4.
- "Weatherings to Parapets and Cornices". The Lead Sheet Association. Archived from the original on 20 February 2017. Retrieved 20 February 2017.
- Webb, G. A. (2000). Nuclear Magnetic Resonance. Royal Society of Chemistry. ISBN 978-0-85404-327-9.
- Webb, G. W.; Marsiglio, F.; Hirsch, J. E. (2015). "Superconductivity in the elements, alloys and simple compounds". Physica C: Superconductivity and Its Applications. 514: 17–27. arXiv:1502.04724. Bibcode:2015PhyC..514...17W. doi:10.1016/j.physc.2015.02.037. S2CID 119290828.
- Whitten, K. W.; Gailey, K. D.; David, R. E. (1996). General chemistry with qualitative analysis (3rd ed.). Saunders College. ISBN 978-0-03-012864-6.
- Wiberg, E.; Wiberg, N.; Holleman, A. F. (2001). Inorganic Chemistry. Academic Press. ISBN 978-0-12-352651-9.
- Wilkes, C. E.; Summers, J. W.; Daniels, C. A.; et al. (2005). PVC Handbook. Hanser. ISBN 978-1-56990-379-7.
- Willey, D. G. (1999). "The physics behind four amazing demonstrations — CSI". Skeptical Inquirer. 23 (6). Retrieved 6 September 2016.
- Winder, C. (1993a). "The history of lead — Part 1". LEAD Action News. 2 (1). ISSN 1324-6011. Archived from the original on 31 August 2007. Retrieved 5 February 2016.
- Winder, C. (1993b). "The history of lead — Part 3". LEAD Action News. 2 (3). ISSN 1324-6011. Archived from the original on 31 August 2007. Retrieved 12 February 2016.
- Windholz, M. (1976). Merck Index of Chemicals and Drugs (9th ed.). Merck & Co. ISBN 978-0-911910-26-1. Monograph 8393.
- Wood, J. R.; Hsu, Y-T.; Bell, C. (2021). "Sending Laurion Back to the Future: Bronze Age Silver and the Source of Confusion" (PDF). Internet Archaeology. 56 (9). doi:10.11141/ia.56.9. S2CID 236973111.
- World Health Organization (1995). Environmental Health Criteria 165: Inorganic Lead (Report). Retrieved 10 June 2018.
- World Health Organization (2000). "Lead" (PDF). Air quality guidelines for Europe. Regional Office for Europe. pp. 149–53. ISBN 978-92-890-1358-1. OCLC 475274390.
- World Health Organization (2018). "Lead poisoning and health". Retrieved 17 February 2019.
- World Nuclear Association (2015). "Nuclear Radiation and Health Effects". Archived from the original on 24 December 2015. Retrieved 12 November 2015.
- Wrackmeyer, B.; Horchler, K. (1990). "Pb-NMR Parameters". Annual Reports on NMR Spectroscopy. Vol. 22. Academic Press. pp. 249–303. doi:10.1016/S0066-4103(08)60257-4. ISBN 978-0-08-058405-8.
- Yong, L.; Hoffmann, S. D.; Fässler, T. F. (2006). "A low-dimensional arrangement of clusters in 2K2Pb9·(en)1.5". Inorganica Chimica Acta. 359 (15): 4774–78. doi:10.1016/j.ica.2006.04.017.
- Young, S. (2012). "Battling lead contamination, one fish bone at a time". Compass. United States Coast Guard. Archived from the original on 14 June 2013. Retrieved 11 February 2017.
- Yu, L.; Yu, H. (2004). Chinese Coins: Money in History and Society. Long River Press. ISBN 978-1-59265-017-0.
- Zhang, X.; Yang, L.; Li, Y.; et al. (2012). "Impacts of lead/zinc mining and smelting on the environment and human health in China". Environmental Monitoring and Assessment. 184 (4): 2261–73. Bibcode:2012EMnAs.184.2261Z. doi:10.1007/s10661-011-2115-6. PMID 21573711. S2CID 20372810.
- Zhao, F. (2008). Information Technology Entrepreneurship and Innovation. IGI Global. p. 440. ISBN 978-1-59904-902-1.
- Zuckerman, J. J.; Hagen, A. P. (1989). Inorganic Reactions and Methods, the Formation of Bonds to Halogens. John Wiley & Sons. ISBN 978-0-471-18656-4.
- Zweifel, H. (2009). Plastics Additives Handbook. Hanser. ISBN 978-3-446-40801-2.
- Zýka, J. (1966). "Analytical study of the basic properties of lead tetraacetate as oxidizing agent". Pure and Applied Chemistry. 13 (4): 569–81. doi:10.1351/pac196613040569 (inactive 3 December 2024). S2CID 96821219.
{{cite journal}}: CS1 maint: DOI inactive as of December 2024 (link)
Further reading
- Astrid, S.; Helmut, S.; Sigel, R. K. O., eds. (2017). Lead: Its Effects on Environment and Health. Metal Ions in Life Sciences. Vol. 17. De Gruyter. ISBN 978-3-11-044107-9. Table of contents
- Casas, J. S.; Sordo, J., eds. (2006). Lead Chemistry, Analytical Aspects. Environmental Impacts and Health Effects. Elsevier. ISBN 978-0-444-52945-9.
- Hunt, A.; Abraham, J. L.; Judson, B.; Berry, C. L. (2003). "Toxicologic and epidemiologic clues from the characterization of the 1952 London smog fine particulate matter in archival autopsy lung tissues". Environmental Health Perspectives. 111 (9): 1209–1214. Bibcode:2003EnvHP.111.1209H. doi:10.1289/ehp.6114. PMC 1241576. PMID 12842775.
- Ingalls, Walter Renton (1865-), Lead Smelting and Refining, With Some Notes on Lead Mining
- Zhang, Hao; Wei, Kai; Zhang, Mengyu; Liu, Rutao; Chen, Yadong (2014). "Assessing the mechanism of DNA damage induced by lead through direct and indirect interactions". Journal of Photochemistry and Photobiology B: Biology. 136: 46–53. Bibcode:2014JPPB..136...46Z. doi:10.1016/j.jphotobiol.2014.04.020. PMID 24844619.
External links
- The Toxicology of Heavy Metals: Getting the Lead Out, American Society for Clinical Pathology
- COVID-19 to reduce global lead production by 5,2% in 2020 (with a figure showing global lead production, 2010–2024)
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