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Iron(II) cyanide

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Iron(II) cyanide
Names
IUPAC name Iron(II) cyanide
Identifiers
CAS Number
3D model (JSmol)
ChEBI
ChemSpider
EC Number
  • 237-875-5
KEGG
PubChem CID
InChI
  • InChI=1S/2CN.Fe/c2*1-2;/q2*-1;+2Key: OXNSNGFUWQVOKD-UHFFFAOYSA-N
SMILES
  • #N.#N.
Properties
Chemical formula Fe(CN)2
Molar mass 107.881
Appearance pale green solid
Related compounds
Other cations cobalt(II) cyanide
nickel(II) cyanide
Related compounds potassium ferrocyanide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound
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Find sources: "Iron(II) cyanide" – news · newspapers · books · scholar · JSTOR (September 2023)

Iron(II) cyanide is an inorganic compound with the empirical formula Fe(CN)2. It may have a Fe2 structure.

Production

Iron(II) cyanide can be produced by dissolving ammonium ferrocyanide at 320 °C.

3 (NH4)4Fe(CN)6 → Fe2Fe(CN)6 + 12 NH4CN

Reaction

Iron(II) cyanide can react with potassium hydroxide solvent to produce iron(II) hydroxide and potassium ferrocyanide.

Fe2Fe(CN)6 + 4 KOH → 2 Fe(OH)2 + K4Fe(CN)6

References

  1. ^ 氰化铁(II) [Iron(II) cyanide]. 锰分族 铁系 铂系 [Manganese, Iron, and Platinum Groups]. 无机化学丛书 . Vol. 9. 科学出版社 . p. 171.
Salts and covalent derivatives of the cyanide ion
HCN He
LiCN Be(CN)2 B(CN)3 C(CN)4
C2(CN)2
NH4CN
ONCN
O2NCN
N3CN
OCN
-NCO
O(CN)2
FCN Ne
NaCN Mg(CN)2 Al(CN)3 Si(CN)4
(CH3)3SiCN
P(CN)3 SCN
-NCS
(SCN)2
S(CN)2
ClCN Ar
KCN Ca(CN)2 Sc(CN)3 Ti V Cr(CN)6 Mn Fe(CN)2
Fe(CN)6
Fe(CN)6
Co(CN)2
Co(CN)
5
Ni(CN)2
Ni(CN)4
Ni(CN)4
CuCN Zn(CN)2 Ga(CN)3 Ge(CN)2
Ge(CN)4
As(CN)3
(CH3)2AsCN
(C6H5)2AsCN
SeCN
(SeCN)2
Se(CN)2
BrCN Kr
RbCN Sr(CN)2 Y(CN)3 Zr Nb Mo(CN)8 Tc Ru Rh Pd(CN)2 AgCN Cd(CN)2 In(CN)3 Sn(CN)2 Sb(CN)3 Te(CN)2
Te(CN)4
ICN Xe
CsCN Ba(CN)2 * Lu(CN)3 Hf Ta W(CN)8 Re Os Ir Pt(CN)4
Pt(CN)6
AuCN
Au(CN)2
Hg2(CN)2
Hg(CN)2
TlCN Pb(CN)2 Bi(CN)3 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(CN)3 Ce(CN)3
Ce(CN)4
Pr(CN)3 Nd Pm Sm(CN)3 Eu(CN)3 Gd(CN)3 Tb Dy(CN)3 Ho(CN)3 Er Tm Yb(CN)3
** Ac(CN)3 Th(CN)4 Pa UO2(CN)2 Np Pu Am Cm Bk Cf Es Fm Md No
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