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Names | |||
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IUPAC name Potassium dicyanoargentate(I) | |||
Other names
Potassium argentocyanide Potassium silver cyanide | |||
Identifiers | |||
CAS Number | |||
3D model (JSmol) | |||
ChEMBL | |||
ChemSpider | |||
ECHA InfoCard | 100.007.316 | ||
EC Number |
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PubChem CID | |||
UNII | |||
UN number | 1588 | ||
CompTox Dashboard (EPA) | |||
InChI
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SMILES
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Properties | |||
Chemical formula | KAg(CN)2 | ||
Molar mass | 199.001 g/mol | ||
Appearance | White crystals | ||
Density | 2.36 g/cm | ||
Solubility in water | Soluble | ||
Solubility | Insoluble in acids | ||
Refractive index (nD) | 1.625 | ||
Hazards | |||
Safety data sheet (SDS) | CAMEO Chemicals MSDS | ||
Related compounds | |||
Other anions | Potassium dicyanoaurate | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). N verify (what is ?) Infobox references |
Potassium dicyanoargentate is an inorganic compound with the formula KAg(CN)2. A white solid, it is the K salt of the linear coordination complex . It forms upon treatment of virtually any silver salt with two equivalents of potassium cyanide.
Uses and reactions
KAg(CN)2 is significant adventitious product of gold mining using cyanide as an extractant.
It can be used in silver plating, as a bactericide, and in the manufacture of antiseptics.
It forms a variety of coordination polymers, a property that exploits the bridging tendency of the cyanide ligand.
References
- Liu, Wenqi; Jones, Leighton O.; Wu, Huang; Stern, Charlotte L.; Sponenburg, Rebecca A.; Schatz, George C.; Stoddart, J. Fraser (2021). "Supramolecular Gold Stripping from Activated Carbon Using α-Cyclodextrin". Journal of the American Chemical Society. 143 (4): 1984–1992. doi:10.1021/jacs.0c11769. PMID 33378203. S2CID 229930811.
- "Potassium Silver Cyanide". CAMEO Chemicals. NOAA.
- Shorrock, Carolyn J.; Xue, Bao-Yu; Kim, Peter B.; Batchelor, Raymond J.; Patrick, Brian O.; Leznoff, Daniel B. (2002). "Heterobimetallic Coordination Polymers Incorporating [M(CN)2]- (M = Cu, Ag) and [Ag2(CN)3]- Units: Increasing Structural Dimensionality via M−M' and M···NC Interactions". Inorganic Chemistry. 41 (25): 6743–6753. doi:10.1021/ic025850p. PMID 12470070.
Silver compounds | |||
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Silver(0,I) | |||
Silver(I) |
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Silver(II) | |||
Silver(III) | |||
Silver(I,III) |
Potassium compounds | |
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H, (pseudo)halogens | |
chalcogens | |
pnictogens | |
B, C group | |
transition metals | |
organic |
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