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Samarium(III) antimonide

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Samarium(III) antimonide
Names
Other names
  • Samarium(III) antimony
  • Antimony-Samarium
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.045.224 Edit this at Wikidata
EC Number
  • 249-762-8
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/Sb.SmKey: JQVBLEDYHQAMKN-UHFFFAOYSA-N
SMILES
  • .
Properties
Chemical formula PrSb
Molar mass 272.12 g/mol
Density 7.3 g/cm
Melting point 1922 °C
Related compounds
Other anions SmN, SmP, SmAs, SmBi, Sm2O3
Other cations PrSb, NdSb
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Samarium antimonide is a binary inorganic compound of samarium and antimony with the formula SmSb. It forms crystals.

Preparation

Samarium antimonide can be prepared by heating samarium and antimony in a vacuum:

S m + S b   1922 o C   S m S b {\displaystyle {\mathsf {Sm+Sb\ {\xrightarrow {1922^{o}C}}\ SmSb}}}

Physical properties

Samarium antimonide forms cubic crystals, space group Fm3m, cell parameters a = 0.6271 nm, Z = 4, and structure like sodium chloride.

The compound melts congruently at a temperature of ≈2000 °C or 1922 °C.

References

  1. ^ Диаграммы состояния двойных металлических систем. Vol. 3 Книга 2. М.: Машиностроение. 2000. ISBN 5-217-02932-3. {{cite book}}: Unknown parameter |agency= ignored (help)
  2. B. Predel (1998). "Sb-Sm (Antimony-Samarium)". Landolt-Börnstein - Group IV Physical Chemistry. 5J: 1–2. doi:10.1007/10551312_2677. ISBN 3-540-61742-6.
  3. ^ H. Okamoto (2000). "Sb-Sm (Antimony-Samarium)". Journal of Phase Equilibria. 21 (4): 414–415. doi:10.1361/105497100770340002.
Salts and covalent derivatives of the antimonide ion
-SbH
SbH3
+H
He
Li3Sb Be ?BSb R3Sb SbN -SbO
various
-SbF4
-SbF6
Ne
Na3Sb
NaSb3
Mg3Sb2 AlSb Si +P +S
-SbS3
-SbS4
+Cl4
+Cl2
-SbCl6
Ar
?K3Sb Ca ScSb Ti V CrSb MnSb
Mn2Sb
Fe2Sb
FeSb2
CoSb
CoSb3
NiSb
Ni3Sb
NiSb2
CuSb
Cu2Sb
Cu3Sb
Cu5Sb
ZnSb
Zn3Sb2
Zn4Sb3
GaSb GeSb AsSb
-As1-xSbx
+Se +Br
+Br2
Kr
Rb3Sb
RbSb3
SrSb3 YSb ZrSb Nb3Sb Mo Tc Ru RhSb various Ag1-xSbx
Ag3Sb
CdSb
Cd3Sb2
InSb SnSb Sb
Sb4
-Sb
+Te +I Xe
Cs3Sb
Cs4Sb2
Ba3Sb2
BaSb3
* LuSb ?HfSb ?TaSb W Re Os Ir PtSb
Pt3Sb
PtSb2
Pt4Sb3
AuSb
AuSb2
Hg TlSb PbSb BiSb
Bi1−xSbx

Bi2Sb2
Po At Rn
Fr3Sb Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaSb ?CeSb PrSb NdSb PmSb SmSb Eu5Sb3
Eu11Sb10
Eu2Sb3
GdSb TbSb DySb HoSb
HoSb2
ErSb TmSb
TmSb
YbSb
** Ac ?ThSb
ThSb2
Th3Sb4
Pa U NpSb Pu AmSb CmSb BkSb
?BkSb
Cf Es Fm Md No
Samarium compounds
Samarium(II)
Samarium(III)
Organosamarium(III)
Antimony compounds
Antimonides
Sb(III)
Organoantimony(III) compounds
Sb(III,V)
Sb(V)
Organoantimony(V) compounds
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