(Redirected from Samarium antimonide )
Chemical compound
Samarium antimonide is a binary inorganic compound of samarium and antimony with the formula SmSb. It forms crystals.
Preparation
Samarium antimonide can be prepared by heating samarium and antimony in a vacuum:
S
m
+
S
b
→
1922
o
C
S
m
S
b
{\displaystyle {\mathsf {Sm+Sb\ {\xrightarrow {1922^{o}C}}\ SmSb}}}
Physical properties
Samarium antimonide forms cubic crystals , space group Fm 3m , cell parameters a = 0.6271 nm, Z = 4, and structure like sodium chloride .
The compound melts congruently at a temperature of ≈2000 °C or 1922 °C.
References
^ Диаграммы состояния двойных металлических систем . Vol. 3 Книга 2. М.: Машиностроение. 2000. ISBN 5-217-02932-3 . {{cite book }}
: Unknown parameter |agency=
ignored (help )
B. Predel (1998). "Sb-Sm (Antimony-Samarium)". Landolt-Börnstein - Group IV Physical Chemistry . 5J : 1–2. doi :10.1007/10551312_2677 . ISBN 3-540-61742-6 .
^ H. Okamoto (2000). "Sb-Sm (Antimony-Samarium)". Journal of Phase Equilibria . 21 (4): 414–415. doi :10.1361/105497100770340002 .
Salts and covalent derivatives of the antimonide ion
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