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Samarium(III) acetate

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Samarium(III) acetate
Names
Other names Samarium ethanoate
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
EC Number
  • 233-950-1
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/3C2H4O2.Sm/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3Key: JPDBEEUPLFWHAJ-UHFFFAOYSA-K
  • hydrate: InChI=1S/3C2H4O2.H2O.Sm/c3*1-2(3)4;;/h3*1H3,(H,3,4);1H2;/q;;;;+3/p-3Key: LKSVMAKMHXTSQX-UHFFFAOYSA-K
  • tetrahydrate: InChI=1S/3C2H4O2.4H2O.Sm/c3*1-2(3)4;;;;;/h3*1H3,(H,3,4);4*1H2;Key: NIVHQHOGEFRWEZ-UHFFFAOYSA-N
SMILES
  • CC(=O).CC(=O).CC(=O).
  • hydrate: CC(=O).CC(=O).CC(=O).O.
  • tetrahydrate: CC(=O).CC(=O).CC(=O).O.O.O.O.
Properties
Chemical formula Sm(CH3COO)3
Molar mass 345.51
Appearance pale yellow powder
Density 1.94 g·cm
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Samarium(III) acetate is an acetate salt of samarium, with the chemical formula of Sm(CH3COO)3. It exists in the hydrate and tetrahydrate form. Its tetrahydrate can be obtained by dissolving samarium(III) oxide in 50% acetic acid solution, crystallizing and vacuum drying. The mixed anion acetate Cl2·H2O and Cl can be crystallized from SmCl3·6H2O and SmOCl in acetic acid solution respectively.

References

  1. ^ "SAMARIUM ACETATE HYDRATE | 100587-91-5". ChemicalBook. Retrieved 2023-03-19.
  2. Meyer G, Lossin A, Schleid T. Samarium (III) acetate-chloride hydrates: dimers and chains. European Journal of Solid State and Inorganic Chemistry, 1991, 28(Suppl.): 529-534.
Samarium compounds
Samarium(II)
Samarium(III)
Organosamarium(III)
Acetyl halides and salts of the acetate ion
AcOH He
LiOAc Be(OAc)2
Be4O(OAc)6
B(OAc)3
B2O(OAc)4
AcOAc
ROAc
NH4OAc AcOOH FAc
FOAc
Ne
NaOAc
NaH(OAc)2
Mg(OAc)2 Al(OAc)3
ALSOL
Al(OAc)2OH
Al(OH)2OAc
Al2SO4(OAc)4
Si P S ClAc
ClOAc
Ar
KOAc Ca(OAc)2 Sc(OAc)3 Ti(OAc)4 VO(OAc)3 Cr(OAc)2
Cr(OAc)3
Mn(OAc)2
Mn(OAc)3
Fe(OAc)2
Fe(OAc)3
Co(OAc)2 Ni(OAc)2 CuOAc
Cu(OAc)2
Zn(OAc)2 Ga(OAc)3 Ge As(OAc)3 Se BrAc
BrOAc
Kr
RbOAc Sr(OAc)2 Y(OAc)3 Zr(OAc)4 Nb Mo(OAc)2 Tc Ru2(OAc)4Cl
Ru(OAc)3
Rh2(OAc)4 Pd(OAc)2 AgOAc Cd(OAc)2 In(OAc)3 Sn(OAc)2
Sn(OAc)4
Sb(OAc)3 Te IAc
IOAc
I(OAc)3
Xe
CsOAc Ba(OAc)2 * Lu(OAc)3 Hf Ta W Re Os Ir Pt(OAc)2 Au(OAc)3 Hg2(OAc)2
Hg(OAc)2
TlOAc
Tl(OAc)3
Pb(OAc)2
Pb(OAc)4
Bi(OAc)3 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(OAc)3 Ce(OAc)3 Pr(OAc)3 Nd(OAc)3 Pm Sm(OAc)3 Eu(OAc)3 Gd(OAc)3 Tb(OAc)3 Dy(OAc)3 Ho(OAc)3 Er(OAc)3 Tm(OAc)3 Yb(OAc)3
** Ac(OAc)3 Th(OAc)4 Pa UO2(OAc)2 Np Pu Am Cm Bk Cf Es Fm Md No
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