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Zirconium(IV) acetate

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It has been suggested that this article be merged into Zirconyl acetate. (Discuss) Proposed since November 2024.
Zirconium(IV) acetate
Identifiers
CAS Number
3D model (JSmol)
ECHA InfoCard 100.021.982 Edit this at Wikidata
CompTox Dashboard (EPA)
InChI
  • InChI=1S/12C2H4O2.4H2O.4O.6Zr/c12*1-2(3)4;;;;;;;;;;;;;;/h12*1H3,(H,3,4);4*1H2;;;;;;;;;;/q;;;;;;;;;;;;;;;;4*-2;6*+4/p-16Key: RGWBNEKRIQDQRP-UHFFFAOYSA-A
SMILES
  • ..............CC(=O).CC(=O).CC(=O).CC(=O).CC(=O).CC(=O).CC(=O).CC(=O).CC(=O).CC(=O).CC(=O).CC(=O)
Properties
Chemical formula C24H40O32Zr6
Molar mass 1387.896 g·mol
Appearance white solid
Solubility in water soluble
Related compounds
Related compounds zirconium dioxide, zirconium(IV) chloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Zirconium acetate usually refers to the chemical formula Zr6O4(OH)4(O2CCH3)12. It forms by the reaction of zirconyl chloride and acetate. Claims of Zr(O2CCH3)4 have been superseded by experiments using X-ray crystallography.

The species Zr6O4(OH)4(O2CCH3)12 is a common precursor to metal-organic frameworks (MOFs).

References

  1. Pavlov, V. L.; Lysenko, Yu. A.; Kalinichenko, A. A. Synthesis and properties of zirconium tetraacetate.(in Russian) Zhurnal Neorganicheskoi Khimii, 1972. 17(12). ISSN 0044-457X
  2. Hennig, Christoph; Weiss, Stephan; Kraus, Werner; Kretzschmar, Jerome; Scheinost, Andreas C. (2017). "Solution Species and Crystal Structure of Zr(IV) Acetate". Inorganic Chemistry. 56 (5): 2473–2480. doi:10.1021/acs.inorgchem.6b01624. PMID 28199091.
  3. Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni; Guillou, Nathalie; Lamberti, Carlo; Bordiga, Silvia; Lillerud, Karl Petter (2008). "A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability". Journal of the American Chemical Society. 130 (42): 13850–13851. Bibcode:2008JAChS.13013850C. doi:10.1021/ja8057953. PMID 18817383.
Zirconium compounds
Zr(II)
Zr(III)
Zr(IV)
Acids and complexes
Organozirconium(IV)
Acetyl halides and salts of the acetate ion
AcOH He
LiOAc Be(OAc)2
Be4O(OAc)6
B(OAc)3
B2O(OAc)4
AcOAc
ROAc
NH4OAc AcOOH FAc
FOAc
Ne
NaOAc
NaH(OAc)2
Mg(OAc)2 Al(OAc)3
ALSOL
Al(OAc)2OH
Al(OH)2OAc
Al2SO4(OAc)4
Si P S ClAc
ClOAc
Ar
KOAc Ca(OAc)2 Sc(OAc)3 Ti(OAc)4 VO(OAc)3 Cr(OAc)2
Cr(OAc)3
Mn(OAc)2
Mn(OAc)3
Fe(OAc)2
Fe(OAc)3
Co(OAc)2 Ni(OAc)2 CuOAc
Cu(OAc)2
Zn(OAc)2 Ga(OAc)3 Ge As(OAc)3 Se BrAc
BrOAc
Kr
RbOAc Sr(OAc)2 Y(OAc)3 Zr(OAc)4 Nb Mo(OAc)2 Tc Ru2(OAc)4Cl
Ru(OAc)3
Rh2(OAc)4 Pd(OAc)2 AgOAc Cd(OAc)2 In(OAc)3 Sn(OAc)2
Sn(OAc)4
Sb(OAc)3 Te IAc
IOAc
I(OAc)3
Xe
CsOAc Ba(OAc)2 * Lu(OAc)3 Hf Ta W Re Os Ir Pt(OAc)2 Au(OAc)3 Hg2(OAc)2
Hg(OAc)2
TlOAc
Tl(OAc)3
Pb(OAc)2
Pb(OAc)4
Bi(OAc)3 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(OAc)3 Ce(OAc)3 Pr(OAc)3 Nd(OAc)3 Pm Sm(OAc)3 Eu(OAc)3 Gd(OAc)3 Tb(OAc)3 Dy(OAc)3 Ho(OAc)3 Er(OAc)3 Tm(OAc)3 Yb(OAc)3
** Ac(OAc)3 Th(OAc)4 Pa UO2(OAc)2 Np Pu Am Cm Bk Cf Es Fm Md No
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