Misplaced Pages

Zirconium monophosphide

Article snapshot taken from Wikipedia with creative commons attribution-sharealike license. Give it a read and then ask your questions in the chat. We can research this topic together.
(Redirected from Zirconium phosphide) "Zirconium phosphide" redirects here. For the diphosphide, see Zirconium diphosphide.
Zirconium phosphide
Names
IUPAC name Phosphinidinzirconium
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
EC Number
  • 234-866-8
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/P.ZrKey: VQYKQHDWCVUGBB-UHFFFAOYSA-N
SMILES
  • P#
Properties
Chemical formula PZr
Molar mass 122.198 g·mol
Appearance solid
Hazards
GHS labelling:
Pictograms GHS09: Environmental hazardGHS05: CorrosiveGHS06: Toxic
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Zirconium monophosphide is a binary inorganic compound of zirconium metal and phosphorus with the chemical formula ZrP.

Preparation

Zirconium monophosphide can be prepared from direct reaction of zirconium powders with red phosphorus:

4 Zr + P4 → 4 ZrP

Physical properties

The α-form of zirconium monophosphide has a NaCl crystal structure. The β-form structure is hexagonal. The α-form is a superconductor if cooled below 5K.

References

  1. "Zirconium Phosphide". American Elements. Retrieved 7 March 2024.
  2. Irani, K. S.; Gingerich, K. A. (1 October 1963). "Structural transformation of zirconium phosphide". Journal of Physics and Chemistry of Solids. 24 (10): 1153–1158. doi:10.1016/0022-3697(63)90231-2. ISSN 0022-3697. Retrieved 7 March 2024.
  3. O'Bannon, Loran (6 December 2012). Dictionary of Ceramic Science and Engineering. Springer Science & Business Media. p. 283. ISBN 978-1-4613-2655-7. Retrieved 7 March 2024.
  4. Li, Zhen; Chen, Ning; Wang, Jigang; Li, Peishen; Guo, Ming; Wang, Qiang; Li, Chunhong; Wang, Changzheng; Guo, Tao; Chen, Shaowei (12 October 2017). "Efficient reduction of nitric oxide using zirconium phosphide powders synthesized by elemental combination method" (PDF). Scientific Reports. 7 (1): 13044. doi:10.1038/s41598-017-13616-5. PMC 5638856. PMID 29026175.
  5. Swanson, Howard Eugene (1962). Standard X-ray Diffraction Powder Patterns: Data for 46 substances. National Bureau of Standards. p. 75. Retrieved 7 March 2024.
  6. Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 3769. ISBN 978-0-412-30120-9. Retrieved 7 March 2024.
Phosphorus compounds
Phosphides
Other compounds
Zirconium compounds
Zr(II)
Zr(III)
Zr(IV)
Acids and complexes
Organozirconium(IV)
Phosphides
Binary phosphides
PH3 He
Li3P Be BP CP
+C 		N +O F Ne
Na3P Mg3P2 AlP +Si
-SiP 		P S +Cl Ar
K3P Ca3P2
CaP 		ScP TiP V CrP
Cr3P 		Mn FeP CoP
Co2P
Co3P2 		NixPy Cu3P Zn3P2
ZnP2 		GaP -GeP AsP Se +Br Kr
Rb Sr3P2 YP ZrP
ZrP2 		NbP Mo3P
MoP
MoP2 		Tc Ru2P Rh Pd Ag3P Cd3P2 InP SnP3 SbP +Te +I Xe
CsxPy Ba * LuP HfP Ta W Re OsP2 Ir PtP2 AuP Hg Tl PbP7 BiP Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
* LaP CeP PrP
PrP5 		NdP Pm SmP
SmP5 		EuP GdP TbP DyP HoP ErP TmP YbP
** AcP ThP7 Pa UP NpP PuP Am Cm BkP Cf Es Fm Md No
Ternary phosphides
Quaternary phosphides
Quinary phosphides
See also
Categories: