Misplaced Pages

Iron phosphide

Article snapshot taken from Wikipedia with creative commons attribution-sharealike license. Give it a read and then ask your questions in the chat. We can research this topic together.
(Redirected from Iron(III) phosphide) Chemical compound
Iron phosphide
Identifiers
CAS Number
3D model (JSmol)
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/3Fe.H3P/h;;;1H3
SMILES
  • #P
Properties
Chemical formula FeP
Molar mass 86.819 g·mol
Density 6.74 g/cm
Melting point 1,100 °C (2,010 °F; 1,370 K)
Solubility in water Insoluble in water
Solubility soluble in nitric acid, HF, aqua regia
insoluble in dilute acid, alkalis
Structure
Crystal structure MnP type (Orthorhombic)
Space group Pnma (No. 62)
Lattice constant a = 519.1 pm, b = 309.9 pm, c = 579.2 pm
Lattice volume (V) 93.2 Å
Related compounds
Other cations Chromium phosphide
Manganese phosphide
Cobalt phosphide
Tungsten phosphide
Ruthenium phosphide
Related compounds Fe2P; Fe3P
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). ☒N verify (what is  ?) Infobox references
Chemical compound

Iron phosphide is a chemical compound of iron and phosphorus, with a formula of FeP.< Its physical appearance is grey needles.

Manufacturing of iron phosphide takes place at elevated temperatures, where the elements combine directly. Iron phosphide reacts with moisture and acids producing phosphine (PH3), a toxic and pyrophoric gas.

Iron phosphide is a good electric and heat conductor.

Below a Néel temperature of about 119 K, FeP takes on an helimagnetic structure.

References

  1. ^ Rundqvist, Stig; Sillén, Lars Gunnar; Timm, D.; Motzfeldt, K.; Theander, Olof; Flood, H. (1962). "Phosphides of the B31 (MnP) Structure Type". Acta Chemica Scandinavica. 16. Danish Chemical Society: 287–292. doi:10.3891/acta.chem.scand.16-0287. ISSN 0904-213X.
  2. Vereshchagin, Oleg S.; Pankin, Dmitrii V.; Smirnov, Mikhail B.; Vlasenko, Natalia S.; Shilovskikh, Vladimir V.; Britvin, Sergey N. (February 2021). "Raman spectroscopy: A promising tool for the characterization of transition metal phosphides". Journal of Alloys and Compounds. 853: 156468. doi:10.1016/j.jallcom.2020.156468.
  3. Chernyavskii, I. O.; Nikitin, S. E.; Onykiienko, Y. A.; Inosov, D. S.; Stahl, Q.; et al. (2020-08-24). "Incommensurate magnet iron monophosphide FeP: Crystal growth and characterization". Physical Review Materials. 4 (8). American Physical Society (APS): 083403. arXiv:2003.10968. Bibcode:2020PhRvM...4h3403C. doi:10.1103/physrevmaterials.4.083403. ISSN 2475-9953. S2CID 214623160.
Phosphorus compounds
Phosphides
Other compounds
Phosphides
Binary phosphides
PH3 He
Li3P Be BP CP
+C 		N +O F Ne
Na3P Mg3P2 AlP +Si
-SiP 		P S +Cl Ar
K3P Ca3P2
CaP 		ScP TiP V CrP
Cr3P 		Mn FeP CoP
Co2P
Co3P2 		NixPy Cu3P Zn3P2
ZnP2 		GaP -GeP AsP Se +Br Kr
Rb Sr3P2 YP ZrP
ZrP2 		NbP Mo3P
MoP
MoP2 		Tc Ru2P Rh Pd Ag3P Cd3P2 InP SnP3 SbP +Te +I Xe
CsxPy Ba * LuP HfP Ta W Re OsP2 Ir PtP2 AuP Hg Tl PbP7 BiP Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
* LaP CeP PrP
PrP5 		NdP Pm SmP
SmP5 		EuP GdP TbP DyP HoP ErP TmP YbP
** AcP ThP7 Pa UP NpP PuP Am Cm BkP Cf Es Fm Md No
Ternary phosphides
Quaternary phosphides
Quinary phosphides
See also
Iron compounds
Fe(−II)
Fe(0)
Fe(I)
Organoiron(I) compounds
  • (C5H5FeCO)2(CO)2
    • Fe(0,II)
    Fe(II)
    Organoiron(II) compounds
    Fe(0,III)
    Fe(II,III)
    Fe(III)
    Organoiron(III) compounds
    Fe(IV)
    Fe(VI)
    Purported
    sort
    Categories: