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Diruthenium phosphide

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Diruthenium phosphide
Identifiers
CAS Number
3D model (JSmol)
InChI
  • InChI=1S/P.2RuKey: DJSOWEIVMAFVIP-UHFFFAOYSA-N
SMILES
  • ..
Properties
Chemical formula PRu2
Molar mass 233.11 g·mol
Appearance crystals
Solubility in water insoluble
Related compounds
Related compounds Molybdenum monophosphide, Molybdenum diphosphide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Diruthenium phosphide is a binary inorganic compound of ruthenium metal and phosphorus with the chemical formula Ru2P.

Preparation

Diruthenium phosphide can be prepared by heating both elements in vacuum at above 1000 °C:

8 Ru + P4 → 4Ru2P

Properties

Diruthenium phosphide forms crystals of rhombic crystal system; the structure of the lead dichloride type.

Uses

Diruthenium phosphide can be used as a catalyst.

References

  1. Macintyre, Jane E. (5 December 1996). Dictionary of Inorganic Compounds, Supplement 4. CRC Press. p. 496. ISBN 978-0-412-75020-5. Retrieved 11 March 2024.
  2. Macintyre, Jane E. (15 July 1993). Dictionary of Inorganic Compounds, Supplement 1. CRC Press. p. 328. ISBN 978-0-412-49090-3. Retrieved 11 March 2024.
  3. Teller, Hanan; Krichevski, Olga; Gur, Meital; Gedanken, Aharon; Schechter, Alex (2 July 2015). "Ruthenium Phosphide Synthesis and Electroactivity toward Oxygen Reduction in Acid Solutions". ACS Catalysis. 5 (7): 4260–4267. doi:10.1021/acscatal.5b00880. ISSN 2155-5435. Retrieved 11 March 2024.
  4. Acres, Gary J. K.; Swars, Kurt (29 June 2013). Pt Platinum: Supplement Volume A 1 Technology of Platinum-Group Metals. Springer Science & Business Media. p. 242. ISBN 978-3-662-10278-7. Retrieved 11 March 2024.
  5. Liu, Tingting; Wang, Jianmei; Zhong, Changyin; Lu, Shiyu; Yang, Wenrong; Liu, Jian; Hu, Weihua; Li, Chang Ming (12 June 2019). "Benchmarking Three Ruthenium Phosphide Phases for Electrocatalysis of the Hydrogen Evolution Reaction: Experimental and Theoretical Insights". Chemistry – A European Journal. 25 (33): 7826–7830. doi:10.1002/chem.201901215. ISSN 0947-6539. PMID 30990231. S2CID 116863114. Retrieved 11 March 2024.
Phosphorus compounds
Phosphides
Other compounds
Ruthenium compounds
Ru(0)
Ru(I)
Ru(II)
Ru(II,III)
Ru(III)
Ru(IV)
Ru(V)
Ru(VI)
Ru(VII)
Ru(VIII)
Phosphides
Binary phosphides
PH3 He
Li3P Be BP CP
+C
N +O F Ne
Na3P Mg3P2 AlP +Si
-SiP
P S +Cl Ar
K3P Ca3P2
CaP
ScP TiP V CrP
Cr3P
Mn FeP CoP
Co2P
Co3P2
NixPy Cu3P Zn3P2
ZnP2
GaP -GeP AsP Se +Br Kr
Rb Sr3P2 YP ZrP
ZrP2
NbP Mo3P
MoP
MoP2
Tc Ru2P Rh Pd Ag3P Cd3P2 InP SnP3 SbP +Te +I Xe
CsxPy Ba * LuP HfP Ta W Re OsP2 Ir PtP2 AuP Hg Tl PbP7 BiP Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
* LaP CeP PrP
PrP5
NdP Pm SmP
SmP5
EuP GdP TbP DyP HoP ErP TmP YbP
** AcP ThP7 Pa UP NpP PuP Am Cm BkP Cf Es Fm Md No
Ternary phosphides
Quaternary phosphides
Quinary phosphides
See also
Categories: