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Scandium acetate

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Scandium acetate
Names
Other names Scandium(III) acetate
Scandium ethanoate
Scandium(III) ethanoate
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.021.159 Edit this at Wikidata
EC Number
  • 223-274-5
PubChem CID
CompTox Dashboard (EPA)
SMILES
  • CC(=O)O.CC(=O)O.CC(=O)O.
Properties
Chemical formula C6H9O6Sc
Molar mass 222.088 g·mol
Appearance white solid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Scandium acetate is a compound, with the chemical formula of Sc(CH3COO)3. It exists in the anhydrous and the hydrate forms. It can be obtained by reacting scandium hydroxide or scandium oxide with acetic acid. It is a colorless, water-soluble solid. It decomposes into scandium oxide at high temperature. It can be used to prepare other scandium-containing materials.

The structure of the anhydrous form was determined by X-ray crystallography. It consists of a chain of octahedral Sc(III) centers linked by bridging acetate ligands.

References

  1. ^ Fuchs, Robert; Strähle, Joachim (1984). "Die Kristallstruktur von Sc(CH3COO)3, ein Metall(III)acetat mit Kettenstruktur" [Crystal Structure of Sc(CH3COO)3, a Metal(III) Acetate with a Chain Structure]. Zeitschrift für Naturforschung B. 39 (12): 1662–1663. doi:10.1515/znb-1984-1206.
  2. Krasil'Nikov, V. N.; Gyrdasova, O. I.; Baklanova, I. V.; Perelyaeva, L. A.; Zhilina, E. F.; Vovkotrub, É. G. (2012). "Structure and luminescence properties of nanostructured solid-state solutions of Sc1−xEux(CH3CO2)3". Theoretical and Experimental Chemistry. 48 (2): 113–117. doi:10.1007/s11237-012-9247-9.
  3. Xin, Chengrong; Zhang, Qilong; Yang, Hui (2013). "Synthesis and Properties Study of BaTi0.95Sc0.05O3−δ Nanopowders and Ceramics". Piezoelectrics & Acoustooptics (in Chinese). 35 (3): 412–415.
Scandium compounds
Acetyl halides and salts of the acetate ion
AcOH He
LiOAc Be(OAc)2
Be4O(OAc)6
B(OAc)3
B2O(OAc)4
AcOAc
ROAc
NH4OAc AcOOH FAc
FOAc
Ne
NaOAc
NaH(OAc)2
Mg(OAc)2 Al(OAc)3
ALSOL
Al(OAc)2OH
Al(OH)2OAc
Al2SO4(OAc)4
Si P S ClAc
ClOAc
Ar
KOAc Ca(OAc)2 Sc(OAc)3 Ti(OAc)4 VO(OAc)3 Cr(OAc)2
Cr(OAc)3
Mn(OAc)2
Mn(OAc)3
Fe(OAc)2
Fe(OAc)3
Co(OAc)2 Ni(OAc)2 CuOAc
Cu(OAc)2
Zn(OAc)2 Ga(OAc)3 Ge As(OAc)3 Se BrAc
BrOAc
Kr
RbOAc Sr(OAc)2 Y(OAc)3 Zr(OAc)4 Nb Mo(OAc)2 Tc Ru2(OAc)4Cl
Ru(OAc)3
Rh2(OAc)4 Pd(OAc)2 AgOAc Cd(OAc)2 In(OAc)3 Sn(OAc)2
Sn(OAc)4
Sb(OAc)3 Te IAc
IOAc
I(OAc)3
Xe
CsOAc Ba(OAc)2 * Lu(OAc)3 Hf Ta W Re Os Ir Pt(OAc)2 Au(OAc)3 Hg2(OAc)2
Hg(OAc)2
TlOAc
Tl(OAc)3
Pb(OAc)2
Pb(OAc)4
Bi(OAc)3 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(OAc)3 Ce(OAc)3 Pr(OAc)3 Nd(OAc)3 Pm Sm(OAc)3 Eu(OAc)3 Gd(OAc)3 Tb(OAc)3 Dy(OAc)3 Ho(OAc)3 Er(OAc)3 Tm(OAc)3 Yb(OAc)3
** Ac(OAc)3 Th(OAc)4 Pa UO2(OAc)2 Np Pu Am Cm Bk Cf Es Fm Md No
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