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Selenophosphate

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A selenophosphate is a chemical compound containing phosphate anions substituted with selenium. Over 7000 compounds are known with a bond between selenium and phosphorus. Compared to phosphorus-sulfur compounds selenophosphates are less thermally stable, and more easily destroyed by water. However they are more stable than tellurophosphates which have an even weaker phosphorus-tellurium bond. Selenophosphates have an oxidation number for phosphorus of +5. But in many there are bonds between phosphorus atoms, reducing the oxidation state to +4, Some may be termed selenophosphites.


Different structural anions include hexaselenohypodiphosphate and with decalin structure and with dicyclobutane structure.

Selenophosphates are coloured, often orange. They are semiconductors.

The first selenodiphosphate was discovered in 1973 by H. Hahn.

Selenophosphate compounds may have some or all of the selenium replaced by sulfur.

Formation

Selenophosphates can be produced by melting phosphorus selenide with metal selenides.

Molecular biology

Selenocysteine is produced in many organisms from a selenophosphate. In humans and other eucaryotes, this is facilitated by the enzyme selenophosphate synthetase 1. Selenium is connected to phosphorus using a reaction with selenide and adenosine triphosphate

List

formula name mw crystal system space group unit cell Å volume density comments references
4·2py water stable
(NH4)4(P2Se6)(H2O)2 triclinic P1 a=7.3306 b=7.3761 c=9.5501 α =70.405° β =74.109° γ =60.681° Z=1 420.37 2.544
4·H2O water stable
(NBu4)2P2Se8 bis(Tetrabutylammonium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenide acetonitrile solvate monoclinic P21/c a 9.6284 b 16.9553 c 16.0899 β 96.875° chair config
(NBu4)3P9Se14 orange-red
bis(1-Butyl-3-methylimidazolium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenide monoclinic P21/n a =7.6642 b =10.9948 c =17.0380 β =91.211° chair config
bis(tetrakis(Acetonitrile-N)-lithium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenide orthorhombic Pbam a 20.0535(6)Å b 12.1200(5)Å c 15.0831 cradle config
bis((Tetrapyridine)-lithium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenide triclinic P1 a 10.1582 b 10.7716 c 12.750 α 95.271° β 94.847° γ 114.219° cradle config
Na2P4Se2 red-brown; P4 bicyclo structure
Na3PSe4 cubic I43m a=7.3094 Z=2 3.53 Na ion conductor 1 mS cm
Na4P2Se6 orthorhombic Cmca a = 11.836 b = 13.311 c = 8.061 Z = 4 1270.0 3.283
Na4(P2Se6)(H2O)6 monoclinic P21/c a 26.0636 b 7.2350 c 20.7197 β 113.387° Z=8 3586.13 2.726
Mg2P2Se6 R3 a = 6.404 c = 20.194 Z=3
KPSe6 orthorhombic Pca21 a = 11.49 b = 6.791 c = 11.29 Z = 4 orange; NLO χ≈142.8 pm V; band gap 2.1 eV
K4Sc2(PSe4)2(P2Se6) monoclinic C2/c a=22.668Å b=6.8147Å c=19.828 β=113.91°
K2P2Se6 trigonal P3121 a = 7.2728, c = 18.872 Z = 3 at 298 K; SHG 50× AgGaSe2
K2P2Se6 trigonal P3121 a = 14.4916 c = 18.7999 Z = 12 at 173 K
K3PSe4·2Se6 cubic Fd3 a = 16.415 at 193 K
K4(P2Se6)(H2O)4 orthorhombic Cmca a =11.921 b =12.46 c =11.752 Z=4 1745.6 2.908
K6P8Se18 1903.66 monoclinic P21/n a=9.746 b=8.332 c=23.054 β=90.54° Z=2 1872.1 3.377 orange
Ca2P2Se6 monoclinic P21/n a = 9.664 b = 7.519 c = 6.859 β = 92.02°
K4Sc2(PSe4)2(P2Se6) 737.82 monoclinic C2/c a=22.668 b=6.815 c=19.828 β =113.91° Z=8 2800.2 3.500 orange-yellow; turns red in air; band gap 2.25 eV
KTiPSe5
K4Ti2(P2Se9)2(P2Se7) black
Cr2P2Se6
LiCrP2Se6
MnPSe3 trigonal R3 band gap 2.5 eV
K2MnP2Se6 monoclinic P21/n a=6.5349 b=12.696 c=7.589 β=102.67° Z=2 614.3
FePSe3
Fe2P2Se6 trigonal R3 band gap 1.3 eV
K2FeP2Se6 monoclinic P21/n a=6.421 b=12.720 c=7.535 β=102.58 Z=2 600.7 red
CuP2Se 2D semiconductor; metallises under pressure
m-Cu4P2Se6 monoclinic P21/c a 6.370 b 11.780 c 20.013 β 90.03°
Cu3PSe4 orthorhombic Pmn21 a=7.700 b=6.677 c=6.385 328.3
t-Cu4P2Se6 triclinic P1 a 7.104 b 11.889 c 12.759 α 74.35° β 79.63° γ 80.85°
Cu4P3Se4 triclinic P1 a 6.440 b 7.085 c 10.616 α 73.11° β 74.86° γ 77.00°
Cu4P4Se3 monoclinic P21/c a 16.446 b 6.515 c 17.339 β 119.08°
CuP2Se orthorhombic Pbca a 5.608 b 6.496 c 16.570
CuAl trigonal R3 a = 6.2795 c = 19.9713 Z =3
K2Cu2P4Se10 1118.78 monoclinic P21/n a=10.627 b=7.767 c=11.966 β=109.125° Z=2 933.2 3.981 red
K3Cu3P3Se9 monoclinic P21/c a = 8.741 b = 10.774, c = 20.033, β = 92.96°
Et=Ethyl; diethyl diselenophosphate hexaselenodiphosphate(IV)
iPr=isopropyl
CuCr monoclinic C2/m a=6.193 b=10.724 c=6.909 β=107.2° Z=2 690.2 4.9 melt 730 °C; dark red
Zn2P2Se6 R3 a = 6.290 c = 19.93 Z=3
K2ZnP2Se6 monoclinic P21/c a = 12.537 b = 7.274 c = 14.164 β = 109.63° Z = 4 1216 yellow
LiGaP2Se6
K4GeP4Se12 orthorhombic Pca21 a=13.9465 b=7.2435 c=24.0511
K4Ge4-xPxSe12 monoclinic P21/c a = 6.7388 b = 13.489 c = 6.3904 β = 91.025°
K7As3(P2Se6)4 monoclinic P21/c a=25.0706 b=9.5948 c=59.6227 β=93.384° melt 388 °C
K6As2(P2Se6)3 monoclinic P21/c a 8.0898 b 23.3142 c 12.1919 β 124.809° melt 410 °C; orange; band gap 2.2 eV
RbPSe6 orthorhombic Pca21 a = 11.776 b = 6.858 c = 11.460 Z = 4 NLO χ≈150 pm V
Rb2P2Se6 trigonal P3121 a = 7.2982 c = 19.002 and Z = 3 100 K
Rb4P2Se9 monoclinic C2/c a = 9.725 b = 10.468 c = 19.155 β = 93.627° Z = 4 1946.1 3.804
Rb4P6Se12 orthorhombic Pca21 a =16.409 b =10.64 c =15.105 bicyclic with >PP< bridge and -SePSe2PSe2Se- ring
Rb10P4Se25
Rb4(P2Se6)(H2O)4 orthorhombic Pnnm a 9.834 b 12.456 c 7.585 Z=2 929.1 3.395
RbTiPSe5
Rb4Ti2(P2Se9)2(P2Se7) orthorhombic Fdd2 a=35.55 b=37.315 c=6.574 Z=4 8772 3.956 black
Rb2MnP2Se6
Rb2ZnP2Se6 triclinic P1 a = 7.494 b = 7.601 c = 12.729 α = 96.57° β = 105.52° γ = 110.54° Z = 2 636.6
Rb4GeP4Se12 orthorhombic Pca21 a=14.1881 b=7.3566 c=24.2914
Rb6Ge2P2Se14 triclinic P1 a = 7.2463 b = 9.707 c = 11.987 α = 79.516° β = 89.524° γ = 68.281° band gap 2.2 eV
Sr2P2Se6 monoclinic P21/n a = 9.844 b = 7.788 c = 6.963 β = 91.50° Z=2
NaYP2Se6 647.6 triclinic P1 a=6.9456 b=7.4085 c=9.5306 α=88.819° β=87.748° γ=89.580° Z=2 yellow follow up refs
KYP2Se6 orthorhombic P212121 a = 6.7366 b = 7.4286 c = 21.603 Z = 4
Cp′′ = C5H3tBu2 1269.41 monoclinic P21/n a=15.2831 b=9.91947 c=18.6250 β=102.835° Z=2 2753 1.531 dark purple
KZrPSe6 orthorhombic Pmc21 a=3.7079 b=15.074 c=18.491
RbZrPSe6
KNb2PSe10 monoclinic Pc a=7.2931 b=15.612 c=13.557 β=106.64° resistivity 4.5 Ω·cm
RbNb2PSe10 monoclinic Pc a=7.381 b=7.8359 c=13.564 β=106.75°
K3RuP5Se10 monoclinic P21/m a 11.2099 b 7.2868 c 12.3474 β 93.958°
PdPSe semiconductor
K2PdP2Se6
Rb2PdP2Se6
Ag4P2Se6 1013.69 orthorhombic P212121 a=6.5760 b=11.5819 c=14.137 Z=4 1076.8 5.966 melt 642 °C; dark red
AgAl monoclinic C2/m a=6.348 b=10.989 c=7.028 β=107.2° Z=2 melt 588 °C; yellow
K2Ag2P2Se6 monoclinic P21/c a=8.528 b=11.251 c=20.975 β=93.24° Z=4 2009 orange
AgCrP2Se6 monoclinic C2/m a=6.305 b=10.917; c=6.991 β=107.7° Z=2 melt 720 °C; dark red
AgCrP2Se6 P3112 a=6.3257 c=20.0198 layered; antiferromagnetic <42K; band gap 1.240 eV
AgGa orthorhombic Pbca α=12.169 b=22.484 c=7.473 Z=4 2044.7 melt 450 °C; orange
AgGa trigonal P31/c a=6.375 c=13.320 Z=2 468.81 5.05 dark red
AgScP2Se6 688.54 trigonal P31/c a=6.463 c=13.249 Z=2 482.93 4.735 orange or brown
CdPSe3
K2CdP2Se6 monoclinic P21/n dark yellow
Rb2CdP2Se6 819.05 monoclinic P21/n a=6.640 b=12.729 c=7.778 β=98.24° Z=2 650.5 4.180 dark yellow; air stable
Rb8Cd4(Se2)(PSe4)4
InPSe3
In2(P3Se9) monoclinic P21/n
LiInP2Se6 657.46 trigonal P31/c a=6.397 c=13.350 Z=2 473.15 4.615 band gap 2.06 eV
(Ph4P) monoclinic C2/c a = 23.127 b = 6.564 c = 19.083 β = 97.42° Z = 4 2873 @23 °C yellow
KInP2Se6 monoclinic P21/n a=7.511 b=6.4861 c=22.789 β=98.91° Z=4 1096.9
K5In3(μ-Se)(P2Se6)3 triclinic P1 a 7.6603 b 13.1854 c 18.378 α 87.04° β 88.659° γ 82.025°
K4In4(μ-Se)2(P2Se6)3 monoclinic P21/c a 19.707 b 7.712 c 13.229 α 90° β 106.42°
K4In2(PSe5)2(P2Se6) monoclinic Cc a=11.1564 b=22.8771 c=12.6525 β=109.039° Z=4 brick-red; air stable
K4In4(μ-Se)(P2S2.36Se3.64)3 triclinic P1 a 7.7709 b 13.0007 c 18.9382 α 105.382° β 92.632° γ 91.91°
CuInP2Se6 trigonal P31/c a=6.392 c=13.338 Z=2 472.0 5.0 melt 642 °C; dark red
AgInP2Se6 trigonal P31/c a=6.483 c=13.330 Z=2 485.2 5.2 semiconductor; melt 673 °C; dark red; band gap 1.79 eV
SnP2Se6 R3 a = 6.3213 c = 19.962 band gap 1.36–1.41 eV
Sn2P2Se6
Na11.1Sn2.1P0.9Se12 tetragonal I41/acd a=14.2446 c=28.473 Z=8 5777.4 3.403 Na ion conductivity 3.0 mS/cm
Rb3Sn(PSe5)(P2Se6) monoclinic P21/a a=14.013 b=7.3436 c=21.983 β=106.61° Z=4 black
K10Sn3(P2Se6)4 trigonal R3 a = 24.1184 c = 7.6482 @100K; band gap 1.82 eV
Rb4Sn5P4Se20 2638.41 trigonal P3m1 a=7.6163 c=18.6898 Z=1 938.91 4.64 black
Rb4Sn2Ag4(P2Se6)2 monoclinic P21/n a=11.189 b=7.688 c=21.850 β=94.31° Z=2 1874.2 4.639 black
Rb5 triclinic P1 a 11.745 b 19.23 c 7.278 α 99.97° β 107.03° γ 87.16°
Sb4(P2Se6)3 monoclinic P21/n a = 20.777 b = 7.4935 c = 9.4949 β = 91.25°
KSbP2Se6 696.55
β-KSbP2Se6 696.55 monoclinic P21 a=6.8925 b=7.8523 c=10.166 β=91.487 Z=2 550.4 4.203 dark red
AgSbP2Se6 hygroscopic
α-CsPSe6 monoclinic P21/n a = 6.877 b = 12.713 c = 11.242 β = 92.735° Z = 4 orange
β-CsPSe6 637.64 tetragonal P421c a = 12.526 c = 12.781 Z = 8 2005.3 4.224 red orange; metastable; SHG χ ~30 pm/V
Cs2P2Se8 orthorhombic Ccce a = 14.982 b = 24.579 c = 13.065 band gap 2.44 ± 0.2 eV; P2Se4 ring; third harmonic generator coefficient 2.4 ± 0.1 × 10 pm/V
Cs3PSe4 orthorhombic Pnma a = 10.0146 b = 11.990 c = 9.9286 Z = 4 1192.2 4.154
Cs4P2Se9
Cs4P2Se10 triclinic P1 a=7.359 b=7.455 c=10.142 α=85.938°, β=88.055° γ=85.609°
Cs4 1664.98 monoclinic P21/n a =10.836 b =10.5437 c =12.273 β =98.661° 1386.3 3.989 orange; melt 697; NLO
Cs5 1766.92 tetragonal P4 a =13.968 c =7.546 Z=2 1472.2 3.986 orange; NLO; band gap 2.17 eV
Cs10P8Se20 orthorhombic Pnnm a = 26.5456 b = 8.0254 c = 11.9031 Z = 2 2535.8 4.133 (PSe2)3Se rings and P2Se6
Cs4(P2Se6)(H2O)4 orthorhombic Pnnm a=10.0514 b=12.6867 c=7.8403 Z=2 999.8 3.775
K0.6Cs0.4PSe6 orthorhombic Pca21 a=11.830 b=6.908 c=11.516 Z=4 941.1 4.085 orange; band gap 2.1 eV; SHG χ ~150 pm/V
KCsP2Se8 orthorhombic Ccce a = 14.782 b = 23.954 c = 13.044 band gap 2.36 ± 0.2 eV
Cs2MnP2Se6 monoclinic P21/n 6.4761 b=13.006 c=7.974 β=93.09° Z=2 670.6
Cs2FeP2Se6
Cs2Cu2P2Se6 monoclinic P21/c a=9.958 b=13.067 c=10.720 β=102.46° Z=4 1363 dark green
Cs2ZnP2Se6 triclinic P1 a = 7.6543 b = 7.7006 c = 12.737 α = 97.007° β = 104.335° γ = 109.241° Z = 2 669.5 yellow; band gap 2.67 eV
Cs4GeP4Se12 orthorhombic Pca21 a=14.3268 b=7.6202 c=24.6301
Cs6As2(P2Se6)3 monoclinic P21/c a=19.5759 b=7.9206 c=13.0553 β=101.914° orange band gap 2.1 eV
Cs5As(P2Se6)2 tetragonal P42/m a=13.826 c=7.5173 melt 416 °C; red; band gap 2.0 eV
RbCsP2Se8 orthorhombic Ccce band gap 2.41 ± 0.2 eV
CsZrPSe6 band gap 2.0 eV
CsNb2PSe10 monoclinic Pc a=14.6257 b=7.8097 c=13.5533 β=98.557°
Cs4Pd(PSe4)2 monoclinic P21/c a = 7.491 b = 13.340 c = 10.030 β = 92.21° Z = 2 red
Cs10Pd(PSe4)4 tetragonal P42c a = 13.949 c = 11.527 Z = 4 red
Cs2PdP2Se6 tetragonal P42/mnm a = 8.5337 c = 10.5595 Z = 4 black
Cs2Ag2P2Se6 monoclinic P21/n a=6.807 b=12.517 c=8.462 β=95.75° Z=2 717.3 yellow
Cs2CdP2Se6 monoclinic P21/n yellow
Cs5In(P2Se6)2 tetragonal P42/m a = 13.886 c = 7.597 Z = 2 1464.9 @23 °C; dark orange
Cs4Sn(P2Se6)2 1721.73 trigonal R3 a=7.808 c=37.905 Z=3 2001.4 4.285 black
α-Cs2SnP2Se6 920.2 monoclinic P21/c a=10.230 b =12.990 c=10.949 β=94.529° 1450.5 4.2126 orange
Cs2SnP2Se6 monoclinic P21/c a = 10.1160 b = 12.7867 c = 11.0828 β = 94.463° @100K
Cs4(Sn3Se8)2 2828.17 tyrigonal P3m1 a=7.695 c=18.797 Z=1 964.0 4.872 black; 2D
Cs6 triclinic P1 a 9.899 b 12.416 c 7.497 α 91.62° β 110.19° γ 79.94°
CuSbP2Se6 C2/m
AgSbP2Se6 C2/m
Cs8Sb4(P2Se6)5
Ba2P2Se6 monoclinic P21/n a = 10.355 b = 7.862 c = 7.046 β = 90.83° Z=2
Ba3(PSe4)2 monoclinic P21/a a = 12.282 b = 6.906 c = 18.061 β = 90.23° Z = 4
Ba3PO4PSe4 triclinic P1 a=6.779 b=7.108 c=12.727 α=82.45 β=78.88 γ=81.34 Z=2 orange
KBaPSe4 orthorhombic Pnma a=11.972 b=6.973 c=10.388 Z=4 pale orange
KLaP2Se6 713.71 monoclinic P21/c a=12.425 b=7.8047 c=11.9279 β=109.612° 1089.6 4.351 yellow
K2La(P2Se6)1/2(PSe4) monoclinic P21/n a = 9.4269 b = 7.2054 c = 21.0276 β = 97.484° Z = 4
K3La(PSe4)2 monoclinic P21/c a = 9.5782 b = 17.6623 c = 9.9869 β = 90.120° Z = 4
K3LaP2Se8
K4La0.67(PSe4)2 orthorhombic Ibam a = 19.0962 b = 9.1408 c = 10.2588 Z = 4
K6LaP4Se16
K8.5La1+1/3(PSe4)4 orthorhombic Ccca a = 18.2133 b = 38.0914 c = 10.2665 Z = 8
Ce4(P2Se6)3 722.06 monoclinic P21/c a = 6.8057 b = 22.969 c = 11.7226 β = 124.096° Z = 6 4.741 orange
NaCeP2Se6 monoclinic P21/c a = 12.1422 b = 7.6982 c = 11.7399 β = 111.545° Z=4 yellow
KCeP2Se6 monoclinic P21/c
Cu0.4Ce1.2P2Se6 monoclinic P21/c a = 12.040 b = 7.6418 c = 11.700 β = 111.269° Z = 4 yellow
Rb2CeP2Se7 monoclinic P21/n red; air sensitive
Rb3CeP2Se8 1090.13 monoclinic P21/c a = 9.6013 b = 18.0604 c = 10.0931 β = 90.619° Z = 4 1750.07 4.137 orange; air sensitive
Rb9Ce(PSe4)4 monoclinic C2/c a=21.446 b=10.575 c=18.784 β =115.94° Z=4 3831 3.980 orange; air and water destroyed; soluble in 18-crown-6 + dmf; band gap 2.26 eV
AgCeP2Se6 monoclinic P21/c a = 9.971 b = 7.482 c = 11.757 β = 145.630° Z=2 orange
CsCe monoclinic P21/c a = 12.9786 b = 7.7624 c = 11.9843 β = 106.589° Z = 4
KPrP2Se6 monoclinic P21/c
Cs2PrP2Se7 monoclinic P21/n a=10.2118 b=7.2423 c=20.3741 β =98.624° Z=4
Eu2P2Se6 monoclinic P21/n a = 9.779 b = 7.793 c = 6.957 β = 91.29° Z=2
LiEuPSe4 orthorhombic Ama2 a = 10.5592 b = 10.415 c = 6.4924 Z = 4 red; air unstable
Na8Eu2(Si2Se6)2 monoclinic C2/m a=7.090 b=12.228 c=7.950 β=107.427° Z = 1 657.6
KEuPSe4 monoclinic P21/m a = 6.8469 b = 6.9521 c = 9.0436 β = 107.677° Z = 2 red; air unstable
KEuPSe4 orthorhombic Pnma a = 17.516 b = 7.0126 c = 6.9015 Z = 4
K4Eu(PSe4)2 orthorhombic Ibam a = 19.020 b = 9.131 c = 10.198 Z = 4
Cs3GdP2Se8 monoclinic P21/c
NaSmP2Se6 709.94 triclinic P1 a 6.8368 b 7.5312 c 9.557 α 90.799° β 91.910° γ 90.351° Z=2 red
Na9Sm(Ge2Se6)2 monoclinic C2/m a = 7.916 b = 12.244 c = 7.105 β = 106.99° Z = 1 658.6
KSmP2Se6 725.15 monoclinic P21 a=6.7888 b=7.6185 c=10.1962 β=91.508 Z=2 527.17 4.568 red
CsSmP2Se6 orthorhombic P212121 a = 6.8867 b = 7.5448 c = 22.152 Z = 4
NaGdP2Se6 715.94 triclinic P1 a 6.8464 b 7.4916 c 9.5372 α 90.813° β 92.026° γ 90.241° Z=2 yellow
KGdP2Se6 monoclinic P21 a=6.7802 b=7.5809 c=10.1967 β=91.638 Z=2 523.97 4.640 yellow
Rb2GdP2Se7 1037.73 monoclinic P21/n a = 10.137 b = 7.212 c = 20.299 β = 98.23° Z = 4 1468.8 4.692 orange; air sensitive
NaTbP2Se6 717.61 triclinic P1 a 6.8854 b 7.4580 c 9.5196 α 89.068° β 87.899° γ 89.974° Z=2 yellow
KTbP2Se6 monoclinic P21 a=6.7609 b=7.5570 c=10.2158 β=91.732 Z=2 521.71 4.671 yellow
KTbP2Se6 orthorhombic red over 9.2 GPa
NaDyP2Se6 721.19 triclinic P1 a 6.9114 b 7.4258 c 9.5256 α 88.914° β 87.829° γ 89.695° Z=2 yellow
CsEr monoclinic P21/c a = 7.5381 b = 12.8192 c = 12.7647 β = 106.898° Z = 4
AgErP2Se6 810.83 trigonal P31/c a=6.578 c=13.410 Z=2 502.6 5.358 dark brown
AgTmP2Se6 812.50 trigonal P31/c a=6.567 c=13.422 Z=2 501.27 5.383 dark brown
K3AuP2Se8 monoclinic Cc a = 7.122 b = 12.527 c = 18.666 β = 96.06° Z = 4
Rb3AuP2Se8 monoclinic Cc
Cs3AuP2Se8 monoclinic Cc
K2Au2P2Se6 monoclinic C2/m a = 12.289 b = 7.210 c = 8.107 β = 115.13° Z = 2 black
Rb2Au2P2Se6 monoclinic C2/m
Rb2Au2P2Se6 monoclinic P21/n a=11.961 b=10.069 c=32.137 β=91.37° Z=12 3869 4.653 @-120 °C black
Hg2P2Se6
K2HgP2Se6 monoclinic P21/c a=13.031 b=7.308 c=14.167 β=110.63° Z=4 1262.6 4.285 dark yellow
Rb2HgP2Se6 monoclinic P21/c drak yellow
Rb8Hg4(Se2)(PSe4)4 P42/n a=17.654 c=7.226
Tl4P2Se6 trigonal R3 a=6.3808 c= 20.014 melt 963 K
TlInP2Se6 triclinic P1 a=6.4488 b=7.5420 c=12.166 α=100.72° β=93.63° γ=113.32° melt 875K
TlSbP2Se6 monoclinic P21 a = 6.843 b = 7.841 c = 9.985 β = 90.77° Z = 2 melt 720K; band gap 1.75 eV
Pb2P2Se6 monoclinic Pn a = 9.742 b = 7.662 c = 6.898 β=91.44° Z=2 514.73 6.13 melt 812 °C;band gap 1.88 eV
Na1.5Pb0.75PSe4 cubic I43d a=14.3479 Z=16 band gap 2 eV
RbPbPSe4 red water stable
Rb4Pb(PSe4)2 orthorhombic Ibam a = 19.134 b = 9.369 c = 10.488 Z = 4 orange water unstable
CsPbPSe4 orthorhombic Pnma a = 18.607 b = 7.096 c = 6.612 Z = 4 red water stable
Cs4Pb(PSe4)2 orange water unstable
Bi4(P2Se6)3 monoclinic P21/n a = 20.869 b = 7.4745 c = 9.5923 β = 91.73°
β-Bi4(P2Se6)3 triclinic P1 a = 12.2303 b = 6.7640 c = 17.866 α = 90.493° β = 94.133° γ = 91.163° black
KBiP2Se6 783.78 monoclinic P21 a 6.9183 b 7.663 c 10.239 β 91.508° Z=2 542.6 4.797
CuBiP2Se6 R3 a = 6.553 c = 39.76 lamellar; p-type semiconductor; work function 5.26 eV
AgBiP2Se6 R3 a = 6.652 c = 39.61 lamellar
Cs5BiP4Se12 orthorhombic Pmc21 a = 7.5357 b = 13.7783 c = 28.0807 Z = 4 band gap 1.85 eV; melt 590 °C
α-TlBiP2Se6 monoclinic P2l/c a =12.539 b =7.499 c =12.248 β =113.731° chains; band gap 1.23,1eV
β-TlBiP2Se6 monoclinic P2l/c a =12.25 b =7.5518 c =22.834 β =97.65° melt 544 °C; layers; band gap 1.27 eV
K2ThP3Se9 triclinic P1 a = 10.4582 b = 16.5384 c = 10.2245 α = 107.637 β = 91.652 γ = 90.343° Z = 2
β-K2ThP3Se9 monoclinic P21/n a = 10.2697 b = 7.7765 c = 20.472 β = 92.877° Z = 4 yellow
Rb2ThP3Se9 triclinic P1 a = 10.5369 b = 16.6914, c = 10.2864 α = 107.614° β = 92.059° γ = 90.409° Z = 2
Rb7Th2P6Se21 triclinic P1 a = 11.531 b = 12.359 c = 16.161 α = 87.289° β = 75.903° γ = 88.041° Z = 2 red; band gap 2.0 eV
Cs4Th4P4Se26 orthorhombic Pbca a = 12.0130 b = 14.5747 c = 27.134 Z = 8 orange; (P2Se9) anion
Cs4Th2P5Se17 monoclinic P2l/c a = 10.238 b = 32.182 c = 10.749 β = 95.832° Z = 4
K2UP3Se9 triclinic P1 a = 10.407( b = 16.491 c = 10.143 α= 107.51° β = 91.74° γ = 90.28° Z = 4 black
Rb4U2P5Se17 triclinic P1 a =10.0824 b = 10.6905 c = 15.7845 α = 84.678 β = 76.125 γ = 85.874° @100K
Rb4U4P4Se26 3470.84 orthorhombic Pbca a=11.9779 b=14.4874 c=27.1377 Z=4 4709.17 4.895 U
Cs2U2(P2Se9)(Se2)2 orthorhombic Pbca a 11.769 b 14.389 c 26.537 black


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Extra reading

Salts and covalent derivatives of the selenide ion
H2Se
H2Se2
+H
-H 		He
Li2Se Be SexByOz CSe2
OCSe
(CH3)2Se 		(NH4)2Se O F Ne
Na2Se MgSe Al2Se3 Si PxSey
-P 		+S Cl Ar
K2Se CaSe Sc2Se3 TiSe2 V CrSe
Cr2Se3 		MnSe
MnSe2 		FeSe CoSe NiSe Cu2Se
CuSe 		ZnSe GaSe
Ga2Se3
-Ga 		GeSe
GeSe2
-Ge 		As2Se3
As4Se3 		Se
n 		Br Kr
Rb2Se SrSe Y2Se3 Zr NbSe2
NbSe3 		MoSe2 Tc Ru Rh Pd Ag2Se CdSe InSe
In2Se3 		SnSe
SnSe2
-Sn 		Sb2Se3 Te +I Xe
Cs2Se BaSe * LuSe
Lu2Se3 		Hf TaSe2 WSe2
WSe3 		ReSe2 Os Ir PtSe2 Au HgSe Tl2Se PbSe Bi2Se3 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg CnSe Nh Fl Mc Lv Ts Og
 
* LaSe
La2Se3 		CeSe
Ce2Se3 		PrSe
Pr2Se3 		NdSe
Nd2Se3 		Pm SmSe
Sm2Se3 		EuSe
Eu2Se3 		GdSe
Gd2Se3 		TbSe
Tb2Se3 		DySe
Dy2Se3 		HoSe
Ho2Se3 		ErSe
Er2Se3 		TmSe
Tm2Se3 		YbSe
Yb2Se3
** Ac ThSe2 Pa USe2 Np PuSe Am Cm Bk Cf Es Fm Md No
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