Aurosilane - Misplaced Pages

Aurosilane
Names

IUPAC name Tetraaurosilane
Other names Silicon tetraauride
Identifiers
CAS Number	12421-46-4
3D model (JSmol)	Interactive image
InChI InChI=1S/4Au.SiKey: HAWKSDAOUYSVMB-UHFFFAOYSA-N
SMILES ()()
Properties
Chemical formula	SiAu₄
Molar mass	675.159
Related compounds
Other anions	silane
Other cations	caesium auride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references

Chemical compound

Aurosilane is an inorganic compound with a chemical formula of SiAu₄. In this compound, gold acts as an electron acceptor with a valence of -1. Aurosilane has been isolated as a type of gold silane. Its unit cell parameters are a=5.658, c=5.605 A. The LUMO and the four Si-Au bonding orbitals of SiAu₄ are similar to those of SiH₄.

In addition, silicon can also form other compounds with gold such as Si₃Au₃

References

Kiran, Boggavarapu; Li, Xi; Zhai, Hua-Jin; Cui, Li-Feng; Wang, Lai-Sheng (2004-04-13). "[SiAu4]: Aurosilane". Angewandte Chemie International Edition. 43 (16): 2125–2129. doi:10.1002/anie.200353602. ISSN 1433-7851. PMID 15083462.
Tasci, Emre S.; Sluiter, Marcel H.F.; Pasturel, Alain; Villars, Pierre (January 2010). "Liquid structure as a guide for phase stability in the solid state: Discovery of a stable compound in the Au–Si alloy system". Acta Materialia. 58 (2): 449–456. Bibcode:2010AcMat..58..449T. doi:10.1016/j.actamat.2009.09.023. Archived from the original on 2020-02-12. Retrieved 2019-11-19.
Atomic Clusters: From Gas Phase to Deposited. Elsevier. 2007-05-24. ISBN 978-0-08-047595-0.
Kiran, Boggavarapu; Li, Xi; Zhai, Hua-Jin; Wang, Lai-Sheng (2006). "Gold as hydrogen: Structural and electronic properties and chemical bonding in Si3Au3+/0/-and comparisons to Si3H3+/0/-" (PDF). The Journal of Chemical Physics. 125 (125): 133204. Bibcode:2006JChPh.125m3204K. doi:10.1063/1.2216707. PMID 17029451. Archived from the original (PDF) on 2015-12-25. Retrieved 2023-05-20.

External reading

Pyykkö, Pekka (October 2002). "Relativity, Gold, Closed-Shell Interactions, and CsAu⋅NH₃". Angewandte Chemie International Edition. 41 (19): 3573–3578. doi:10.1002/1521-3773(20021004)41:19<3573::AID-ANIE3573>3.0.CO;2-R. PMID 12370896.
Wang, Lai-Sheng (2010). "Covalent gold" (PDF). Physical Chemistry Chemical Physics. 12 (31): 8694–8705. Bibcode:2010PCCP...12.8694W. doi:10.1039/c003886e. PMID 20567749. Archived from the original (PDF) on 2016-03-04. Retrieved 2023-05-20.

v t e Silicon compounds
Si(II)	SiO SiS
Si(III)	Si₂H₆ Si₂Cl₆
Si(IV)	SiBr₄ SiC SiCl₄ SiF₄ SiH₄ SiI₄ SiAu₄ SiO₂ SiS₂ Si₃N₄ Si(N₃)₄ Si₂N₂O Si₂Cl₆O SiF₃Cl

Gold compounds

Gold(-I)

Gold(I)

Organogold(I) compounds	(AuC₆H₂(CH₃)₃)₅ (C₂H₅)₃PAuSC₅H₅O(CO₂CH₃)₃CH₂OCOCH₃ AuSC₅H₅O(OH)₃CH₂OH NaAuSCH₂CHOHCH₂SO₃ BrAuSC₄H₈ ClAuSC₄H₈ ClAuS(CH₃)₂ ClAuP(C₆H₅)₃ Na₂AuSCHCO₂CH₂CO₂ NaAuSCHCO₂CH₂CO₂H

Gold(II)

Gold(I,III)

Au₄Cl₈

Gold(III)

Aurates(III)	HAuCl₄ NaAuCl₄ HAuBr₄ HAu(NO₃)₄ ClO₂Au(ClO₄)₄ NaAuO₂

Gold(V)

Gold(VI)

AuF
₆ (predicted)

This inorganic compound–related article is a stub. You can help Misplaced Pages by expanding it.

Categories: