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Isotopes of aluminium

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Isotopes of aluminium (13Al)
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
Al trace 7.17×10 y β84% Mg
ε16% Mg
γ
Al 100% stable
Standard atomic weight Ar°(Al)
  • 26.9815384±0.0000003
  • 26.982±0.001 (abridged)

Aluminium or aluminum (13Al) has 23 known isotopes from Al to Al and 4 known isomers. Only Al (stable isotope) and Al (radioactive isotope, t1/2 = 7.2×10 y) occur naturally, however Al comprises nearly all natural aluminium. Other than Al, all radioisotopes have half-lives under 7 minutes, most under a second. The standard atomic weight is 26.9815385(7). Al is produced from argon in the atmosphere by spallation caused by cosmic-ray protons. Aluminium isotopes have found practical application in dating marine sediments, manganese nodules, glacial ice, quartz in rock exposures, and meteorites. The ratio of Al to Be has been used to study the role of sediment transport, deposition, and storage, as well as burial times, and erosion, on 10 to 10 year time scales. Al has also played a significant role in the study of meteorites.

List of isotopes


Nuclide
Z N Isotopic mass (Da)
Half-life
Decay
mode

Daughter
isotope

Spin and
parity
Isotopic
abundance
Excitation energy
Al 13 8 21.0278(13) >1.1 zs p Mg (5/2+)
Al 13 9 22.01942310(32) 91.1(5) ms β, p (55%) Na (4)+
β (44%) Mg
β, 2p (1.10%) Ne
β, α (0.038%) Ne
Al 13 10 23.00724435(37) 446(6) ms β (98.78%) Mg 5/2+
β, p (1.22%) Na
Al 13 11 23.99994760(24) 2.053(4) s β (99.96%) Mg 4+
β, α (0.035%) Ne
β, p (0.0016%) Na
Al 425.8(1) keV 130(3) ms IT (82.5%) Al 1+
β (17.5%) Mg
β, α (0.028%) Ne
Al 13 12 24.990428308(69) 7.1666(23) s β Mg 5/2+
Al 13 13 25.986891876(71) 7.17(24)×10 y β (85%) Mg 5+ Trace
EC (15%)
Al 228.306(13) keV 6.3460(5) s β Mg 0+
Al 13 14 26.981538408(50) Stable 5/2+ 1.0000
Al 13 15 27.981910009(52) 2.245(5) min β Si 3+
Al 13 16 28.98045316(37) 6.56(6) min β Si 5/2+
Al 13 17 29.9829692(21) 3.62(6) s β Si 3+
Al 13 18 30.9839498(24) 644(25) ms β (>98.4%) Si 5/2+
β, n (<1.6%) Si
Al 13 19 31.9880843(77) 32.6(5) ms β (99.3%) Si 1+
β, n (0.7%) Si
Al 956.6(5) keV 200(20) ns IT Al (4+)
Al 13 20 32.9908777(75) 41.46(9) ms β (91.5%) Si 5/2+
β, n (8.5%) Si
Al 13 21 33.9967819(23) 53.73(13) ms β (74%) Si 4−
β, n (26%) Si
Al 46.4(17) keV 22.1(2) ms β (89%) Si 1+
β, n (11%) Si
Al 13 22 34.9997598(79) 38.16(21) ms β (64.2%) Si (5/2+,3/2+)
β, n (35.8%) Si
Al 13 23 36.00639(16) 90(40) ms β (>69%) Si
β, n (<31%) Si
Al 13 24 37.01053(19) 11.4(3) ms β, n (52%) Si 5/2+#
β (<47%) Si
β, 2n (>1%) Si
Al 13 25 38.01768(16)# 9.0(7) ms β, n (84%) Si 0−#
β (16%) Si
Al 13 26 39.02307(32)# 7.6(16) ms β, n (97%) Si 5/2+#
β (3%) Si
Al 13 27 40.03094(32)# 5.7(3 (stat), 2 (sys)) ms β, n (64%) Si
β, 2n (20%) Si
β (16%) Si
Al 13 28 41.03713(43)# 3.5(8 (stat), 4 (sys)) ms β, n (86%) Si 5/2+#
β, 2n (11%) Si
β (3%) Si
Al 13 29 42.04508(54)# 3# ms
Al 13 30 43.05182(64)# 4# ms
β? Si 5/2+#
This table header & footer:
  1. Al – Excited nuclear isomer.
  2. ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. Modes of decay:
    IT: Isomeric transition
  5. Bold symbol as daughter – Daughter product is stable.
  6. ( ) spin value – Indicates spin with weak assignment arguments.
  7. ^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  8. Used in radiodating events early in the Solar System's history and meteorites
  9. cosmogenic

Aluminium-26

Main article: Aluminium-26
The decay level scheme for Al and Al to Mg.

Cosmogenic aluminium-26 was first described in studies of the Moon and meteorites. Meteorite fragments, after departure from their parent bodies, are exposed to intense cosmic-ray bombardment during their travel through space, causing substantial Al production. After falling to Earth, atmospheric shielding protects the meteorite fragments from further Al production, and its decay can then be used to determine the meteorite's terrestrial age. Meteorite research has also shown that Al was relatively abundant at the time of formation of our planetary system. Most meteoriticists believe that the energy released by the decay of Al was responsible for the melting and differentiation of some asteroids after their formation 4.55 billion years ago.

References

  1. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  2. Mougeot, X. (2019). "Towards high-precision calculation of electron capture decays". Applied Radiation and Isotopes. 154 (108884). doi:10.1016/j.apradiso.2019.108884.
  3. "Standard Atomic Weights: Aluminium". CIAAW. 2017.
  4. Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  5. Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
  6. Kostyleva, D.; Xu, X.-D.; Mukha, I.; et al. (2024-09-03). "Observation and spectroscopy of the proton-unbound nucleus Al". Physical Review C. 110 (3). arXiv:2406.04771. doi:10.1103/PhysRevC.110.L031301. ISSN 2469-9985.
  7. Campbell, S. E.; Bollen, G.; Brown, B. A.; Dockery, A.; Ireland, C. M.; Minamisono, K.; Puentes, D.; Rickey, B. J.; Ringle, R.; Yandow, I. T.; Fossez, K.; Ortiz-Cortes, A.; Schwarz, S.; Sumithrarachchi, C. S.; Villari, A. C. C. (9 April 2024). "Precision Mass Measurement of the Proton Dripline Halo Candidate Al 22". Physical Review Letters. 132 (15). doi:10.1103/PhysRevLett.132.152501.
  8. ^ "Physics 6805 Topics in Nuclear Physics". Ohio State University. Archived from the original on 2 September 2021. Retrieved 12 June 2019.
  9. ^ Crawford, H. L.; Tripathi, V.; Allmond, J. M.; et al. (2022). "Crossing N = 28 toward the neutron drip line: first measurement of half-lives at FRIB". Physical Review Letters. 129 (212501): 212501. Bibcode:2022PhRvL.129u2501C. doi:10.1103/PhysRevLett.129.212501. PMID 36461950. S2CID 253600995.
  10. Diehl, R (13 Dec 2005). "Al in the inner Galaxy" (PDF). Astronomy & Astrophysics. 449 (3): 1025–1031. doi:10.1051/0004-6361:20054301. Retrieved 12 June 2019.
  11. R. T. Dodd (1986). Thunderstones and Shooting Stars. Harvard University Press. pp. 89–90. ISBN 978-0-674-89137-1.

External links

Isotopes of the chemical elements
Group 1 2   3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
Period Hydrogen and
alkali metals
Alkaline
earth metals
Pnicto­gens Chal­co­gens Halo­gens Noble gases
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