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Iodine nitrate

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Iodine nitrate
Names
IUPAC name iodo nitrate
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/INO3/c1-5-2(3)4Key: CCJHDZZUWZIVJF-UHFFFAOYSA-N
SMILES
  • (=O)()OI
Properties
Chemical formula INO3
Molar mass 188.908 g·mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Iodine nitrate is a chemical with formula INO3. It is a covalent molecule with a structure of I–O–NO2.

Preparation

The compound was first produced by the reaction of mercury(II) nitrate and iodine in ether.

Other nitrate salts and solvents can also be used.

As a gas it is slightly unstable, decaying with a rate constant of −3.2×10 s. The possible formation of this chemical in the atmosphere and its ability to destroy ozone have been studied. Potential reactions in this context are:

IONO2 → IO + NO2
IONO2 → I + NO3
I + O3 → IO + O2

References

  1. ^ Hassner, Alfred (15 April 2001). "Iodine Nitrate". Encyclopedia of Reagents for Organic Synthesis: ri016. doi:10.1002/047084289X.ri016. ISBN 9780470842898.
  2. ^ Barnes, Ian; Becker, Karl H.; Starcke, Juergen (November 1991). "Fourier-transform IR spectroscopic observation of gaseous nitrosyl iodine, nitryl iodine, and iodine nitrate". The Journal of Physical Chemistry. 95 (24): 9736–9740. doi:10.1021/j100177a026.
  3. Allan, B. J.; Plane, J. M. C. (September 2002). "A Study of the Recombination of IO with NO2 and the Stability of INO3: Implications for the Atmospheric Chemistry of Iodine". The Journal of Physical Chemistry A. 106 (37): 8634–8641. Bibcode:2002JPCA..106.8634A. doi:10.1021/jp020089q.
Iodine compounds
Iodine(−I)
Iodine(I)
Iodine(II)
Iodine(III)
Iodine(IV)
Iodine(V)
Iodine(VII)
Salts and covalent derivatives of the nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)−4 RONO2
+CO3
+C2O4
NO3
NH4NO3
HOONO2 FNO3
+F
Ne
NaNO3 Mg(NO3)2 Al(NO3)3
Al(NO3)−4
Si P +SO4 ClONO2
+Cl
Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)2
Fe(NO3)3
Co(NO3)2
Co(NO3)3
Ni(NO3)2 CuNO3
Cu(NO3)2
Zn(NO3)2 Ga(NO3)3 Ge As +SeO3 BrNO3
+Br
Kr
RbNO3 Sr(NO3)2 Y(NO3)3 Zr(NO3)4 NbO(NO3)3 MoO2(NO3)2 Tc Ru Rh(NO3)3 Pd(NO3)2 AgNO3 Cd(NO3)2 In(NO3)3 Sn(NO3)4 Sb4O4(OH)2(NO3)2 Te INO3
+IO3
Xe(NO3)2
CsNO3 Ba(NO3)2 * Lu(NO3)3 Hf(NO3)4 TaO(NO3)3 WO2(NO3)2 ReO3NO3 Os Ir3O(NO3)10 Pt Au(NO3)−4 Hg2(NO3)2
Hg(NO3)2
TlNO3
Tl(NO3)3
Pb(NO3)2 Bi(NO3)3
BiO(NO3)
Po(NO3)4 At Rn
FrNO3 Ra(NO3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(NO3)3 Ce(NO3)3
Ce(NO3)4
Pr(NO3)3 Nd(NO3)3 Pm(NO3)3 Sm(NO3)3 Eu(NO3)3 Gd(NO3)3 Tb(NO3)3 Dy(NO3)3 Ho(NO3)3 Er(NO3)3 Tm(NO3)3 Yb(NO3)3
** Ac(NO3)3 Th(NO3)4 PaO(NO3)3 UO2(NO3)2 Np(NO3)4 Pu(NO3)4 Am(NO3)3 Cm(NO3)3 Bk(NO3)3 Cf(NO3)3 Es Fm Md No
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