Names | |
---|---|
IUPAC name iodo nitrate | |
Identifiers | |
CAS Number | |
3D model (JSmol) | |
ChemSpider | |
PubChem CID | |
CompTox Dashboard (EPA) | |
InChI
| |
SMILES
| |
Properties | |
Chemical formula | INO3 |
Molar mass | 188.908 g·mol |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references |
Iodine nitrate is a chemical with formula INO3. It is a covalent molecule with a structure of I–O–NO2.
Preparation
The compound was first produced by the reaction of mercury(II) nitrate and iodine in ether.
Other nitrate salts and solvents can also be used.
As a gas it is slightly unstable, decaying with a rate constant of −3.2×10 s. The possible formation of this chemical in the atmosphere and its ability to destroy ozone have been studied. Potential reactions in this context are:
- IONO2 → IO + NO2
- IONO2 → I + NO3
- I + O3 → IO + O2
References
- ^ Hassner, Alfred (15 April 2001). "Iodine Nitrate". Encyclopedia of Reagents for Organic Synthesis: ri016. doi:10.1002/047084289X.ri016. ISBN 9780470842898.
- ^ Barnes, Ian; Becker, Karl H.; Starcke, Juergen (November 1991). "Fourier-transform IR spectroscopic observation of gaseous nitrosyl iodine, nitryl iodine, and iodine nitrate". The Journal of Physical Chemistry. 95 (24): 9736–9740. doi:10.1021/j100177a026.
- Allan, B. J.; Plane, J. M. C. (September 2002). "A Study of the Recombination of IO with NO2 and the Stability of INO3: Implications for the Atmospheric Chemistry of Iodine". The Journal of Physical Chemistry A. 106 (37): 8634–8641. Bibcode:2002JPCA..106.8634A. doi:10.1021/jp020089q.
Iodine compounds | |
---|---|
Iodine(−I) | |
Iodine(I) | |
Iodine(II) | |
Iodine(III) | |
Iodine(IV) | |
Iodine(V) | |
Iodine(VII) |
Salts and covalent derivatives of the nitrate ion | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
|