Misplaced Pages

Borate phosphate

Article snapshot taken from Wikipedia with creative commons attribution-sharealike license. Give it a read and then ask your questions in the chat. We can research this topic together.
(Redirected from Borate phosphates)
Borate phosphate
Identifiers
3D model (JSmol)
ChemSpider
InChI
  • 1:1: InChI=1S/BO3.H3O4P/c2-1(3)4;1-5(2,3)4/h;(H3,1,2,3,4)/q-3;/p-3Key: IVHMVLWSSMPWPQ-UHFFFAOYSA-K
SMILES
  • 1:1: B()().P(=O)()
Properties
Chemical formula BO7P
Molar mass 153.78 g·mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Borate phosphates are mixed anion compounds containing separate borate and phosphate anions. They are distinct from the borophosphates where the borate is linked to a phosphate via a common oxygen atom. The borate phosphates have a higher ratio of cations to number of borates and phosphates, as compared to the borophosphates.

There are also organic esters of both borate and phosphate, e.g. NADH-borate.

Production

In the high temperature method, ingredients are heated together at atmospheric pressure. Products are anhydrous, and production or borophosphates is likely.

The boron flux method involves dissolving ingredients such as an ammonium phosphate and metal carbonate in an excess of molten boric acid.

Use

Borate phosphates are of research interest for their optical, electrooptical or magnetic properties.

List

chem mw crystal system space group unit cell Å volume density comment references
Be3(BO3)(PO4) hexagonal SHG
α-Mg3 orthorhombic Immm a=8·495, b=4·886, c=12·565 Z=4
Mg3 monoclinic Cm
Mg3 hexagonal P6_2m
Lüneburgite Mg3(PO4)2 · 6H2O triclinic 2.05 Biaxial (-) nα = 1.520 – 1.522 nβ = 1.540 – 1.541 nγ = 1.545 – 1.548

2V 52° to 60°

Max birefringence δ = 0.025 – 0.026

Ca3 monoclinic a=8.602 b=4.891 c=12.806 β=102.30
Seamanite Mn3(PO4)(OH)2 orthorhombic Pbnm a = 7.81 Å, b = 15.11 Å, c = 6.69 Å Z=4 789.48 3.08 Biaxial (+) nα = 1.640 nβ = 1.663 nγ = 1.665

2V 40°

Max birefringence δ = 0.025

Laptevite-(Ce) Ca6(Fe,Mn)Y3REE7(SiO4)3(PO4)(B3Si3O18)(BO3)F11 trigonal R3m a = 10.804, c = 27.726 Z=3 2802.6 4.61 Uniaxial (-) nω = 1.741 nε = 1.720

Max birefringence δ = 0.021

(CoPO4)4, B5O6(OH)4N(CH3)4(CH3NH3) 1036.10 orthorhombic I222 a=6.7601 b=7.5422 c=34.822 Z=2 1775.4 1.938 red
Co3 monoclinic Cm a=9.774, b=12.688, c=4.9057, β=119.749°; Z=4 528.2 purple
α-Zn3 349.89 orthorhombic a=8.438 b=4.884 c=12.558
α-Zn3 349.89 monoclinic Cm a=9.725 b=12.720 c=4.874 β=119.80 Z=4
β-Zn3 349.89 hexagonal P-6 a=8.4624 c=13.0690 Z=6 810.51 4.301 colourless
α-Sr3 orthorhombic a=9.0561, b=9.7984, c=13.9531
Sr10(BO2) P3_ a=9.7973, c=7.3056, Z=1 607.29
SrCo2(BO3)(PO4) 359.26 monoclinic P21/c a=6.485 b=9.270 c=10.066 β=111.14 Z=4 548.7 4.349 red
Byzantievite Ba5(Ca,REE,Y)22(Ti,Nb)18(SiO4)44(BO3)9O2243(H2O)1.5 trigonal R3 a = 9.1202, c = 102.145 7,357.9 4.10 Uniaxial (-) nω = 1.940 nε = 1.860

Max birefringence δ = 0.080

16 different layers in structure

Rhabdoborite Mg12(V,Mo,W)1 · 5O6{xxFx} (x < 1) hexagonal P63 a = 10.6314, c = 4.5661 446.95
CsNa2Y2(BO3)(PO4)2 605.46 orthorhombic Cmcm a=6.9491 b=14.907 c=10.6201 Z=4 1100.2 3.655 colourless
CsZn4(BO3)(PO4)2 679.30 orthorhombic Pbca a=14.49 b=10.02 c=16.45 Z=8 2388 3.779 colourless
Ba3(BO3)(PO4) hexagonal P63mc a=5.4898, c=14.7551, Z=2
Ba3(BO3)(PO4) monoclinic P2/m a = 11.7947, b = 9.6135, c = 12.9548, β= 111.25° 1369.08
Ba11B26O44(PO4)2(OH)6 monoclinic P21/c a=6.891, b=13.629, c=25.851, β=90.04°
Ba3(ZnB5O10)PO4 786.41 orthorhombic Pnm21 a = 10.399 b = 7.064 c = 8.204 Z=2 602.6 4.334
La7O6(BO3)(PO4)2 monoclinic a=7.019 b=17.915 c=12.653 β=97.52 1577.27
Pr7O6(BO3)(PO4)2 monoclinic P121/n1 a=6.8939 b=17.662 c=12.442 β=97.24 Z=4 1502.9 green
Nd7O6(BO3)(PO4)2 monoclinic a=6.862 b=17.591 c=12.375 β=97.18 1482.12
Sm7O6(BO3)(PO4)2 monoclinic P121/n1 a=6.778 b=17.396 c=12.218 β=96.96 Z=4 1430.0 yellow
CsNa2Sm2(BO3)(PO4)2 728.34 orthorhombic Cmcm a=7.0631 b=15.288 c=10.725 Z=4 1158.1 4.177 colourless
CsNa2Ho2(BO3)(PO4)2
CsNa2Er2(BO3)(PO4)2
CsNa2Tm2(BO3)(PO4)2
Gd7O6(BO3)(PO4)2 monoclinic a=6.704 b=17.299 c=12.100 β=96.94 1393.11
Dy7O6(BO3)(PO4)2 monoclinic a=6.623 b=17.172 c=11.960 β=96.76 1350.84
K3Yb22 R3_ a=5.6809, c=36.594 Z=3 1022.8
CsNa2Yb2(BO3)(PO4)2
K3Lu22 R3_ a=5.6668, c=36.692 Z=3 1020.4
CsNa2Lu2(BO3)(PO4)2 777.58 orthorhombic Cmcm a = 6.8750 b = 14.6919 c = 10.5581 1066.44 4.843
Pb4O(BO3)(PO4) 998.54 monoclinic P21/c a=10.202 b=7.005 c=12.92 β=113.057 Z=4 849.6 7.807 colourless
LiPb4(BO3)(PO4)2 1084.85 orthorhombic Pbca a=12.613 b=6.551 c=25.63 Z=8 2095 6.875 colourless
Bi4O3(BO3)(PO4) 1037.70 orthorhombic Pbca a=5.536 b=14.10 c=22.62 Z=8 1766 7.807 colourless
Th2 monoclinic P21/c a=8.4665, b=7.9552, c=8.2297, β= 103.746° Z = 4
Ba5·nH2O interlocking nanotubes; absorbs water from air
U2 645.84 monoclinic P21/c a = 8.546, b = 7.753, c = 8.163 β = 102.52° Z=4 528.0 8.12 generated at 12.5 GPa + 1000 °C; emerald green
1746.97 monoclinic P21/n a = 6.5014, b =22.4302, c =9.7964 β = 90.241° Z=2 1428.57 4.061 orange

References

  1. ^ Huang, Shengshi; Yu, Hongwei; Han, Jian; Pan, Shilie; Jing, Qun; Wang, Ying; Dong, Lingyun; Wu, Hongping; Yang, Zhihua; Wang, Xian (August 2014). "The Effect of the Ratio of [M/(B+P)] on the Configuration of Anionic Groups: Synthesis of the Borate-Phosphate LiPb 4 (BO 3 )(PO 4 ) 2". European Journal of Inorganic Chemistry. 2014 (22): 3467–3473. doi:10.1002/ejic.201402389.
  2. Kim, Danny H.; Marbois, Beth N.; Faull, Kym F.; Eckhert, Curtis D. (June 2003). "Esterification of borate with NAD+ and NADH as studied by electrospray ionization mass spectrometry and11B NMR spectroscopy". Journal of Mass Spectrometry. 38 (6): 632–640. Bibcode:2003JMSp...38..632K. doi:10.1002/jms.476. PMID 12827632.
  3. ^ Yilmaz, Aysen; Bu, Xianhui; Kizilyalli, Meral; Kniep, Rudiger; Stucky, Galen D. (February 2001). "Cobalt Borate Phosphate, Co3[BPO7], Synthesis and Characterization". Journal of Solid State Chemistry. 156 (2): 281–285. Bibcode:2001JSSCh.156..281Y. doi:10.1006/jssc.2000.8963.
  4. He, Zhangzhen; Moriyama, Hiroshi (2003). "A Model of New VUV NLO Materials Based on Borate: A Novel Noncentrosymmetric Borophosphate Compound Be 3 BPO 7". MRS Proceedings. 788: L8.23. doi:10.1557/PROC-788-L8.23. ISSN 0272-9172.
  5. ^ Gözel, G.; Baykal, A.; Kizilyalli, M.; Kniep, R. (December 1998). "Solid-State Synthesis, X-ray Powder Investigation and IR Study of α-Mg3[BPO7]". Journal of the European Ceramic Society. 18 (14): 2241–2246. doi:10.1016/S0955-2219(98)00152-6.
  6. "Lüneburgite". www.mindat.org. Retrieved 2020-12-15.
  7. Korybska-Sadło, Iwona; Sitarz, Maciej; Król, Magdalena; Gunia, Piotr (2016-10-20). "Vibrational spectroscopic characterization of the magnesium borate-phosphate mineral lüneburgite". Spectroscopy Letters. 49 (9): 606–612. Bibcode:2016SpecL..49..606K. doi:10.1080/00387010.2016.1236819. ISSN 0038-7010. S2CID 99999165.
  8. "Seamanite". www.mindat.org. Retrieved 2020-12-15.
  9. Ewald, Bastian; Huang, Ya-Xi; Kniep, Rüdiger (August 2007). "Structural Chemistry of Borophosphates, Metalloborophosphates, and Related Compounds". Zeitschrift für anorganische und allgemeine Chemie (in German). 633 (10): 1517–1540. doi:10.1002/zaac.200700232.
  10. "Laptevite-(Ce)". www.mindat.org. Retrieved 2020-12-15.
  11. Lin, Zhuojia; Wragg, David S.; Lightfoot, Philip; Morris, Russell E. (2009). "A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis". Dalton Transactions (27): 5287–9. doi:10.1039/b904450g. ISSN 1477-9226. PMID 19565080.
  12. Bluhm, K.; Park, C. H. (1997-01-01). "Die Synthese und Kristallstruktur des Borat-Phosphats: α -Zn3(BO3)(PO4) / Synthesis and Crystal Structure of the Borate-Phosphate: α-Zn3(BO3)( PO4)". Zeitschrift für Naturforschung B. 52 (1): 102–106. doi:10.1515/znb-1997-0120. ISSN 1865-7117. S2CID 100783759.
  13. Zhang, Erpan; Zhao, Sangen; Zhang, Jianxiu; Fu, Peizhen; Yao, Jiyong (2011-01-15). "The β-modification of trizinc borate phosphate, Zn 3 (BO 3 )(PO 4 )". Acta Crystallographica Section E. 67 (1): i3. Bibcode:2011AcCrE..67I...3Z. doi:10.1107/S1600536810051871. ISSN 1600-5368. PMC 3050272. PMID 21522511.
  14. Tekin, Berna (August 2007). "Bazi Metal İçeren Boratli, Fosfatli ve Borfosfatli Bi̇leşi̇kleri̇n Sentezi̇ ve Yapisal Karakteri̇zasyonu" (PDF).
  15. Chen, Shuang; Hoffmann, Stefan; Carrillo-Cabrera, Wilder; Akselrud, Lev G.; Prots, Yurii; Schwarz, Ulrich; Zhao, Jing-Tai; Kniep, Rüdiger (March 2010). "Sr10[(PO4)5.5(BO4)0.5](BO2): Growth and crystal structure of a strontium phosphate orthoborate metaborate closely related to the apatite-type crystal structure". Journal of Solid State Chemistry. 183 (3): 658–661. Bibcode:2010JSSCh.183..658C. doi:10.1016/j.jssc.2009.12.026.
  16. Gou, Wenbin; He, Zhangzhen; Yang, Ming; Zhang, Weilong; Cheng, Wendan (2013-03-04). "Synthesis and Magnetic Properties of a New Borophosphate SrCo 2 BPO 7 with a Four-Column Ribbon Structure". Inorganic Chemistry. 52 (5): 2492–2496. doi:10.1021/ic3023979. ISSN 0020-1669. PMID 23406089.
  17. "Byzantievite". www.mindat.org. Retrieved 2020-12-15.
  18. Sokolova, E.; Hawthorne, F. C.; Pautov, L. A.; Agakhanov, A. A. (April 2010). "Byzantievite, Ba 5 (Ca, REE ,Y) 22 (Ti,Nb) 18 (SiO 4 ) 4 [(PO 4 ),(SiO 4 )] 4 (BO 3 ) 9 O 21 [(OH),F] 43 (H 2 O) 1.5 : the crystal structure and crystal chemistry of the only known mineral with the oxyanions (BO 3 ), (SiO 4 ) and (PO 4 )". Mineralogical Magazine. 74 (2): 285–308. Bibcode:2010MinM...74..285S. doi:10.1180/minmag.2010.074.2.285. ISSN 0026-461X. S2CID 95182192.
  19. "Rhabdoborite-(V)". www.mindat.org. Retrieved 2020-12-15.
  20. Zhao, Dan; Xue, Yali; Zhang, Ruijuan; Fan, Yanping; Liu, Baozhong; Li, Yanan; Zhang, Shirui (2020). "Design, synthesis, crystal structure and luminescent properties introduced by Eu 3+ of a new type of rare-earth borophosphate CsNa 2 REE 2 (BO 3 )(PO 4 ) 2 (REE = Y, Gd)". Dalton Transactions. 49 (29): 10104–10113. doi:10.1039/D0DT00389A. ISSN 1477-9226. PMID 32662492. S2CID 220519447.
  21. Guo, Fengjiao; Hu, Cong; Wang, Ying; Han, Jian; Yang, Zhihua; Pan, Shilie (2018). "Insights of BO 3 –PO 4 replacement for the design and synthesis of a new borate–phosphate with unique 1∞[Zn 4 BO 11 ] chains and two new phosphates". Inorganic Chemistry Frontiers. 5 (2): 327–334. doi:10.1039/C7QI00548B. ISSN 2052-1553.
  22. Ma, H.W.; Liang, J.K.; Wu, L.; Liu, G.Y.; Rao, G.H.; Chen, X.L. (October 2004). "Ab initio structure determination of new compound Ba3(BO3)(PO4)". Journal of Solid State Chemistry. 177 (10): 3454–3459. Bibcode:2004JSSCh.177.3454M. doi:10.1016/j.jssc.2003.12.027.
  23. Gözel, Güller (1993). "Preparation and structural investigation of alkaline-earth metal borophosphates – Tez Arşivi". tezarsivi.com. Retrieved 2021-03-01.
  24. Heyward, Carla; McMillen, Colin D.; Kolis, Joseph (July 2013). "Hydrothermal synthesis and structural analysis of new mixed oxyanion borates: Ba11B26O44(PO4)2(OH)6, Li9BaB15O27(CO3) and Ba3Si2B6O16". Journal of Solid State Chemistry. 203: 166–173. Bibcode:2013JSSCh.203..166H. doi:10.1016/j.jssc.2013.04.022.
  25. Yu, Hongwei; Zhang, Weiguo; Young, Joshua; Rondinelli, James M.; Halasyamani, P. Shiv (December 2015). "Design and Synthesis of the Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Ba 3 (ZnB 5 O 10 )PO 4". Advanced Materials. 27 (45): 7380–7385. Bibcode:2015AdM....27.7380Y. doi:10.1002/adma.201503951. PMID 26459262. S2CID 35637169.
  26. ^ Shi, Ying; Liang, Jingkui; Zhang, Hao; Yang, Jinling; Zhuang, Weidong; Rao, Guanghui (February 1997). "X-Ray Powder Diffraction and Vibrational Spectra Studies of Rare Earth Borophosphates,Ln7O6(BO3)(PO4)2(Ln=La, Nd, Gd, and Dy)". Journal of Solid State Chemistry. 129 (1): 45–52. Bibcode:1997JSSCh.129...45S. doi:10.1006/jssc.1996.7227.
  27. ^ Ewald, B.; Prots, Yu.; Kniep, R. (April 2004). "Refinement of the crystal structures of praseodymium- and samariumoxoborate- bis(oxophosphate)-oxide, Ln7O6[BO3][PO4]2, (Ln = Pr, Sm)". Zeitschrift für Kristallographie – New Crystal Structures. 219 (1–4): 233–235. doi:10.1524/ncrs.2004.219.14.233. ISSN 2197-4578. S2CID 96530323.
  28. Zhao, Dan; Shi, Lin-Ying; Zhang, Rui-Juan; Xue, Ya-Li (2020-12-01). "Synthesis, crystal structure and luminescence properties of a new samarium borate phosphate, CsNa 2 Sm 2 (BO 3 )(PO 4 ) 2". Acta Crystallographica Section C: Structural Chemistry. 76 (12): 1068–1075. doi:10.1107/S2053229620014576. ISSN 2053-2296. PMID 33273144. S2CID 227283126.
  29. ^ Zhao, Dan; Xue, Ya-Li; Fan, Yun-Chang; Zhang, Rui-Juan; Zhang, Shi-Rui (June 2021). "A new series of rare-earth borate-phosphate family CsNa2Ln2(BO3)(PO4)2 (Ln = Ho, Er, Tm, Yb): Tunnel structure, upconversion luminescence and optical thermometry properties". Journal of Alloys and Compounds. 866: 158801. doi:10.1016/j.jallcom.2021.158801. S2CID 233561777.
  30. ^ Zhou, Yan; Hoffmann, Stefan; Huang, Ya-Xi; Prots, Yurii; Schnelle, Walter; Menezes, Prashanth W.; Carrillo-Cabrera, Wilder; Sichelschmidt, Jörg; Mi, Jin-Xiao; Kniep, Rüdiger (June 2011). "K3Ln[OB(OH)2]2[HOPO3]2 (Ln=Yb, Lu): Layered rare-earth dihydrogen borate monohydrogen phosphates". Journal of Solid State Chemistry. 184 (6): 1517–1522. Bibcode:2011JSSCh.184.1517Z. doi:10.1016/j.jssc.2011.04.023.
  31. ^ Wang, Ying; Pan, Shilie; Huang, Shengshi; Dong, Lingyun; Zhang, Min; Han, Shujuan; Wang, Xian (2014). "Structural insights for the design of new borate–phosphates: synthesis, crystal structure and optical properties of Pb 4 O(BO 3 )(PO 4 ) and Bi 4 O 3 (BO 3 )(PO 4 )". Dalton Trans. 43 (34): 12886–12893. doi:10.1039/C4DT01199F. ISSN 1477-9226. PMID 25020047.
  32. Lipp, C.; Burns, P. C. (2011-10-01). "Th2[BO4][PO4]: A RARE EXAMPLE OF AN ACTINIDE BORATE-PHOSPHATE". The Canadian Mineralogist. 49 (5): 1211–1220. Bibcode:2011CaMin..49.1211L. doi:10.3749/canmin.49.5.1211. ISSN 0008-4476.
  33. Wu, Shijun; Wang, Shuao; Diwu, Juan; Depmeier, Wulf; Malcherek, Thomas; Alekseev, Evgeny V.; Albrecht-Schmitt, Thomas E. (2012). "Complex clover cross-sectioned nanotubules exist in the structure of the first uranium borate phosphate". Chemical Communications. 48 (29): 3479–81. doi:10.1039/c2cc17517g. ISSN 1359-7345. PMID 22267020.
  34. Hinteregger, Ernst; Wurst, Klaus; Perfler, Lukas; Kraus, Florian; Huppertz, Hubert (2013-10-14). "High-Pressure Synthesis and Characterization of the Actinide Borate Phosphate U 2 [BO 4 ][PO 4 ]: High-Pressure Synthesis and Characterization of U 2 [BO 4 ][PO 4 ]". European Journal of Inorganic Chemistry. 2013 (30): 5247–5252. doi:10.1002/ejic.201300662. PMC 3939824. PMID 24611029.
  35. Hao, Yucheng (2017). "New Insight into the Crystal Chemistry of Uranium and Thorium Borates, Borophosphates and Borate-phosphates". p. 109.
Borates
H3BO3 He
Li2B4O7 Be B +(CO3)
+(C2O4) 		(NH4)3BO3
+NO3 		O +F Ne
Na2·8H2O
NaBO2
NaBO3
Na3BO3
Na2B8O13 		Mg3(BO3)2 AlBO3 Si -PO4
+PO4 		+S
-SO4
+SO4 		+Cl Ar
K2B4O7•4H2O
KB5O8•4H2O 		Ca3(BO3)2 ScBO3 TiBO3 -VO4 Cr Mn3(BO3)2 Fe3(BO3)2
FeBO3
FeB(OH)4 		Co3(BO3)2 Ni3(BO3)2 Cu3(BO3)2 Znx(BO3)x GaBO3
-GaO4 		-GeO4 -AsO4 -SeO4
-SeO3
+Se 		+Br Kr
Rb3BO3
RbB11O16(OH)2
Rb•2H2O 		Sr3(BO3)2 YBO3 ZrB2O5 Nb Mo Tc Ru Rh Pd Ag3BO3 Cd3(BO3)2 InBO3 Sn -SbBO4 -TeO4
-TeO3 		+I Xe
Cs3BO3
CsB5O8•4H2O 		BaB2O4 * Lu3B5O12 HfB2O5 Ta W Re Os Ir Pt Au Hg Tl3BO3 Pb3(BO3)2 BiBO3 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaB3O6 CeB3O6 Pr4B10O21 NdBO3 Pm Sm Eu Gd Tb Dy4B6O15
Dy2B4O9 		Ho4B6O15
Ho2B4O9 		ErBO3 Tm3B5O12 Yb3B5O12
** Ac Th3(BO3)4 Pa U(BO3)2 Np Pu Am Cm Bk Cf Es Fm Md No
Phosphates
H3PO4

 He
Li3PO4 Be BPO4
+BO3 		C (NH4)3PO4
(NH4)2HPO4
NH4H2PO4
-N 		O +F Ne
Na3PO4
Na2HPO4
NaH2PO4 		Mg3(PO4)2 AlPO4 Si P +SO4
-S 		Cl Ar
K3PO4
K2HPO4
KH2PO4 		Ca3(PO4)2 ScPO4 Ti VPO4 CrPO4 Mn3(PO4)2
MnPO4 		Fe3(PO4)2
FePO4 		Co3(PO4)2 Ni3(PO4)2 Cu3(PO4)2 Zn3(PO4)2 GaPO4 Ge As -Se Br Kr
Rb3PO4 Sr3(PO4)2 YPO4 Zr3(PO4)4 Nb Mo Tc Ru Rh Pd Ag3PO4 Cd3(PO4)2 InPO4 Sn SbPO4
-SbO4 		Te I Xe
Cs3PO4 Ba3(PO4)2 * LuPO4 Hf Ta W Re Os Ir Pt AuPO4 Hg Tl3PO4 Pb3(PO4)2 BiPO4 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaPO4 CePO4 PrPO4 NdPO4 PmPO4 SmPO4 EuPO4 GdPO4 TbPO4 DyPO4 HoPO4 ErPO4 TmPO4 YbPO4
** AcPO4 Th3(PO4)4 Pa U(PO4)2 Np PuPO4 AmPO4 CmPO4 Bk Cf Es Fm Md No
Categories: