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Phosphate sulfate

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Compound with phosphate and sulfate ions

The phosphate sulfates are mixed anion compounds containing both phosphate and sulfate ions. Related compounds include the arsenate sulfates, phosphate selenates, and arsenate selenates.

Some hydrogen phosphate sulfates are superprotonic conductors.

List

chem mw crystal system space group unit cell volume density comment references
Sanjuanite Al2(PO4)(SO4)(OH)·9H2O
Hotsonite Al11(SO4)3(PO4)2(OH)21 · 16H2O triclinic a=11.23, b=11.66 c=10.55 α=112° 32′, β=107° 32′ γ=64° 27′ refract: α = 1.519 γ = 1.521
Arangasite Al2F(PO4)(SO4)·9H2O monoclinic P2/a a = 7.073, b = 9.634, c = 10.827, β = 100.40°, Z = 2 725.7
peisleyite Na3Al16(SO4)2(PO4)10(OH)17 · 20H2O monoclinic a 13.31, b 12.62, c 23.15, β 110.0°, Z = 2 discredited
peisleyite Na2Al98(OH)6·28H2O triclinic P1 a = 9.28, b = 11.98, c = 13.25, α = 91.3, β = 75.6, γ = 67.67°, Z = 4 1308
Woodhouseite CaAl3(PO4)(SO4)(OH)6 trigonal R3m a = 6.993, c = 16.386 693.95 3.0 Uniaxial (+) nω = 1.636 nε = 1.647 Birefringence: δ = 0.011
Ardéalite Ca2H(PO4)(SO4)•4H2O monoclinic a = 5.721, b = 30.95, c = 6.265, β= 117.26° Z = 4 986.11 2.32
Destinezite Diadochite Fe2(PO4)(SO4)(OH)•6H2O triclinic P1 a = 9.570, b = 9.716, c = 7.313, α = 98.74°, β = 107.90°, γ = 63.86° Z = 2
bohuslavite Fe4(PO4)3(SO4)(OH)(H2O)10·nH2O (5 ≤ n ≤ 14) triclinic P1 a = 13.376 b = 13.338 c = 10.863 α = 92.80, β = 91.03, γ = 119.92°, Z = 2 1675.7 pink
Borickyite (Ca,Mg)(Fe,Al)4(PO4,SO4,CO3)(OH)8·3–7.5H2O
Camaronesite 2(SO4)·1–2H2O trigonal R32 a = 9.0833, c = 42.944, Z = 9 3068.5
Fe4(PO4)3(SO4)(OH)·18H2O triclinic P1 a=13.376, b 13.338, c 10.863, α 92.80, β 91.03, γ 119.92° 1675.7
vanderheydenite Zn6(PO4)2(SO4)(OH)4·7H2O monoclinic P21/n a = 6.204 b = 19.619, c = 7.782, β = 90.67° 947.1 biaxial (–) α = 1.565, β = 1.580 γ = 1.582. 2V = 39.8°
Svanbergite SrAl3(PO4)(SO4)(OH)6 trigonal R3m a = 6.97, c = 16.59 Z=3 697.98 3.2 Uniaxial (+) nω = 1.631 - 1.635 nε = 1.646 - 1.649 Birefringence: δ = 0.015
Birchite Cd2Cu2(PO4)2(SO4) ·5H2O a = 10.489 b = 20.901 c = 6.155 Z=4 1349.6 3.647 biaxial positive,

nα = 1.624, nβ = 1.636, nγ = 1.669, 2Vcalc = +63°.

Corkite PbFe3(OH)6SO4PO4 trigonal R3m a = 7.32, c = 17.02 Z=3 781.2 4.295 Uniaxial (-) nω = 1.930 nε = 1.930 n = 1.93 - 1.96 Birefringence 0.03
BaAl3(PO4)(SO4)(OH)6 trigonal R3m a = , c = Z=3
hinsdalite (Pb,Sr)Al3(PO4)(SO4)(OH)6
Tsumebite Pb2Cu(PO4,SO4)(OH)
Delvauxite CaFe4(PO4,SO4)2(OH)8·4–6H2O
Rossiantonite Al3(PO4)(SO4)2(OH)2(H2O)10·4H2O triclinic P1 a = 10.3410, b = 10.9600, c = 11.1446, α = 86.985, β = 65.727, γ = 75.064°, Z = 2 1110.5
Schlossmacherite (H3O,Ca)Al3(AsO4,PO4,SO4)2(OH)6
Arthurite Cu(Fe)2(AsO4,PO4,SO4)2(O,OH)2·4(H2O)
cobaltarthurite
Phosphoinnelite Ba4Na3Ti3Si4O14(PO4,SO4)2(O,F)3 triclinic P1? a = 5.38, b = 7.10, c = 14.76; α = 99.00°, β = 94.94°, γ = 90.14° Z = 1 555 3.82 biaxial (+), α = 1.730, β = 1.745, and γ = 1.764, 2V 90°
Francolite (Ca, Mg, Sr, Na)10(PO4, SO4, CO3)6F2–3
Al4(UO2)2(PO4)4(SO4)(OH)2 · 18H2O
Al4(UO2)2(PO4)4(SO4)(OH)2 · 20H2O
Coconinoite Fe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 20H2O monoclinic C2/c a =12.45, b = 12.96, c = 17.22, β = 105.7°
xiangjiangite Fe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 22H2O tetragonal a = 7.17 Å, b = 7.17 Å, c = 22.22 Å Z=1 1,142 Biaxial (-) nα = 1.558 nβ = 1.576 nγ = 1.593 2V: 87°

Artificial

chem mw crystal system space group unit cell Å volume density comment references
2·HSO4·H2PO4
NH4(HSO4)0.45(H2PO4)0.55 orthorhombic
18-crown·0.50.5·H2O orthrhombic F2dd a=8.710 b= 28.868 c=31.206 Z=16 7846 1.346 dehydrate at 70°
2·HSO4·H2PO4 Monoclinic C2/c a = 28.0787 b = 11.8671 c = 14.1533 β = 100.739° Z=8 4633.46 1.303 colourless; decompose at 353K
(NH2CH2COOH)3(H2SO4)0.7(H3PO4)0.3 monoclinic called TGSP; colourless; ferroelectric, curie point 51 °C; pyroelectric
Na(HSO4)(H3PO4) monoclinic P 21 a = 5.449, b = 6.832, c = 8.718, β = 95.88°, Z = 2  322.8
K2(HSO4)(H2PO4) monoclinic P 21/c a = 11.150, b = 7.371, c = 9.436, β = 92.29°, Z = 4  774.9
K4(HSO4)3(H2PO4) triclinic P 1 a = 7.217, b = 7.521, c = 7.574, α = 71.52°, β = 88.28°, γ = 86.20°, Z = 1  389.1
K4(PO2F2)2(S2O7) 534.46 monoclinic C2/c a = 13.00, b = 7.543, c = 19.01, β = 130.07°, Z = 4 1426.5 2.489 colourless; pyrosulfate + difluorophosphate
K3
H1−xTi2(PO4)3−x(SO4)x (x=0.5–1)
Na2MgTi(SO4)(PO4)2 trigonal R3c a=8.4796 c=21.8091 Z=6 1358.1 2.818
K2MgTi(SO4)(PO4)2 cubic P213 a=9.8743 Z=4 962.84 2.872
Ca10-xNax(PO4)6-x(SO4)xF2 monoclinic
NaFe2(PO4)(SO4)2 hexagonal R3c a=8.4243 c=21.973
NaFe1.4V0.6(PO4)(SO4)2
4(PO4)2(SO4) (C14H10N4=2,2'-bi-1H-benzimidazole) 3331.96 cubic I43d a = 24.964 Z=4 15558 1.423 green
Rb2(HSO4)(H2PO4) monoclinic P21/n a=7.448, b=7.552, c=7.632, β=100.47°, Z=2 422.1
Rb2(HSO4)(H2PO4) monoclinic P21/c a=11.555, b=7.536, c=9.593, β=91.56, Z=4 853.0 at 160K
Rb4(HSO4)3(H2PO4) orthorhombic P21212 a=7.612, b=14.795, c=7.446, Z=2 838.6
18-crown·Rb0.50.5·3H2O monoclinic C2/c a=19.802 b=8.447 c=25.777 β=101.00° Z=8 4232 1.572 dehydrate at 70°
Rb2MgTi(SO4)(PO4)2
Sr4(PO4)2SO4
NaZrMg(PO4)(SO4)2 hexagonal R3c
NaZrCo(PO4)(SO4)2 hexagonal R3c
NaZrNi(PO4)(SO4)2 hexagonal R3c
NaZrCu(PO4)(SO4)2 hexagonal R3c
NaZrZn(PO4)(SO4)2 hexagonal R3c
NaZrAl(PO4)2(SO4) hexagonal R3c
NaZrFe(PO4)2(SO4) hexagonal R3c
H3OSb2(SO4)2(PO4) triclinic P1 a=5.134 b=7.908 c=12.855, α=81.401° β=87.253° γ=86.49°
KSb2(SO4)2(PO4) triclinic P1 a=5.1453 =7.9149 c=12.6146, α=82.054° β=87.715° γ=86.655°
RbSb2(SO4)2(PO4) triclinic P1 a=5.1531 b=7.957 c=12.845, α=81.801° β=87.676° γ=86.703°
Cs2(HSO4)(H2PO4) cubic ao=4.926 >105 °C but can be supercooled
Cs2(HSO4)(H2PO4) monoclinic P21/n a = 7.856 b = 7.732 c = 7.827, β= 99.92° Z=2 468.3 3.261 can substitute 2.3% ammonium; proton conductivity at 110 °C is 3×10 Ωcm
Cs3(HSO4)2(H2PO4) monoclinic C2/c a=19.824 b=7.859 c=19.047 β=100.20° Z=4 1387.2 3.302 stable against water solution 298-313K; phase transition at 411K
Cs4(HSO4)3(H2PO4) monoclinic C2/c a=19.945 b=7.8565 c=8.9949 β=100.119° Z=3 1387.5 3.301 colourless
Cs5(HSO4)2(H2PO4)3 cubic I43d a=14.5668 over 381K goes to tetragonal a=4.965 c=5.016
Cs6H(HSO4)3(H2PO4)4 cubic I43d a=14.4758 3033.38 3.236 colourless
Cs5(HSO4)3(H2PO4)2 monoclinic C2/c a=34.07 Å,b=7.661,c=9.158,β=90.44° 2390 3.198
18-crown·Cs0.50.5·3H2O monoclinic C2/c a=19.840 b=8.460 c=26.19 β=101.14 Z=8 4313 1.689 dehydrate at 70°
CsNH4(HSO4)(H2PO4)
Cs3NH4(HSO4)3(H2PO4)
Cs2MgTi(SO4)(PO4)2
Ba4(PO4)2SO4
NaBa6Zr(PO4)5SO4 cubic I43d a = 10.5449 Z=4 1172.54 eulytite mineral structure
Ba2Sr2(PO4)2SO4
Ba3Sr(PO4)2SO4
Ce2O(HPO4)2(SO4). 4H2O Ce
Ce2O(HPO4)2.4(SO4)0.6. 2H2O Ce
0.5 monoclinic P21/a a=12.999 b=7.150 c=9.212 β=95.33 cream colour
KSr2Eu(PO4)2SO4
RbSr2Eu(PO4)2SO4
CsSr2Eu(PO4)2SO4
0.5 monoclinic P21/a a = 12.938 b = 6.834 c = 9.100 β = 88.12°
Pb2Mg2(PO4)2SO4
MgPb3(PO4)2(SO4) cubic I43d a = 10.299 Z=4 1092.4 5.67
CaPb3(PO4)2(SO4) cubic I43d a = 10.296 Z=4 1091.5 5.77
MnPb3(PO4)2(SO4) cubic I43d a = 10.258 Z=4 1079.4 5.92
CoPb3(PO4)2(SO4) cubic I43d a = 10.356 Z=4 1110.6 5.78
NiPb3(PO4)2(SO4) cubic I43d a = 10.434 Z=4 1135.9 5.65
CuPb3(PO4)2(SO4) cubic I43d a = 10.422 Z=4 1132.0 5.70
ZnPb3(PO4)2(SO4) cubic I43d a = 10.449 Z=4 1140.8 5.67
CdPb3(PO4)2(SO4) cubic I43d a = 10.315 Z=4 1097.5 6.17
SrPb3(PO4)2(SO4) cubic I43d a = 10.369 Z=4 1114.8 5.93
Th2(PO4)2SO4·2 H2O decompose 450 °C

Organic derivatives

A catenated sulfophosphate has the sulfur and phosphorus joined by an oxygen atom. In biochemistry, metabolism of sulfate may use such a group, for example with adenosine-5'-phosphosulfate.

References

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Phosphates
H3PO4

 He
Li3PO4 Be BPO4
+BO3 		C (NH4)3PO4
(NH4)2HPO4
NH4H2PO4
-N 		O +F Ne
Na3PO4
Na2HPO4
NaH2PO4 		Mg3(PO4)2 AlPO4 Si P +SO4
-S 		Cl Ar
K3PO4
K2HPO4
KH2PO4 		Ca3(PO4)2 ScPO4 Ti VPO4 CrPO4 Mn3(PO4)2
MnPO4 		Fe3(PO4)2
FePO4 		Co3(PO4)2 Ni3(PO4)2 Cu3(PO4)2 Zn3(PO4)2 GaPO4 Ge As -Se Br Kr
Rb3PO4 Sr3(PO4)2 YPO4 Zr3(PO4)4 Nb Mo Tc Ru Rh Pd Ag3PO4 Cd3(PO4)2 InPO4 Sn SbPO4
-SbO4 		Te I Xe
Cs3PO4 Ba3(PO4)2 * LuPO4 Hf Ta W Re Os Ir Pt AuPO4 Hg Tl3PO4 Pb3(PO4)2 BiPO4 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaPO4 CePO4 PrPO4 NdPO4 PmPO4 SmPO4 EuPO4 GdPO4 TbPO4 DyPO4 HoPO4 ErPO4 TmPO4 YbPO4
** AcPO4 Th3(PO4)4 Pa U(PO4)2 Np PuPO4 AmPO4 CmPO4 Bk Cf Es Fm Md No
Compounds containing the sulfate group (SO2−4)
H2SO4 He
Li2SO4 BeSO4 B2S2O9
-BO3
+BO3 		esters
ROSO−3
(RO)2SO2
+CO3
+C2O4 		(NH4)2SO4
[N2H5]HSO4
(NH3OH)2SO4
NOHSO4
+NO3 		H2OSO4 +F Ne
Na2SO4
NaHSO4 		MgSO4 Al2(SO4)3
Al2SO4(OAc)4 		Si +PO4 SO2−4
HSO3HSO4
(HSO4)2
+SO3 		+Cl Ar
K2SO4
KHSO4 		CaSO4 Sc2(SO4)3 TiOSO4 VSO4
V2(SO4)3
VOSO4 		CrSO4
Cr2(SO4)3 		MnSO4 FeSO4
Fe2(SO4)3 		CoSO4
Co2(SO4)3 		NiSO4
Ni2(SO4)3 		CuSO4
Cu2SO4
SO4 		ZnSO4 Ga2(SO4)3 Ge(SO4)2 As +SeO3 +Br Kr
RbHSO4
Rb2SO4 		SrSO4 Y2(SO4)3 Zr(SO4)2 Nb2O2(SO4)3 MoO(SO4)2
MoO2(SO4) 		Tc Ru(SO4)2 Rh2(SO4)3 PdSO4 Ag2SO4
AgSO4 		CdSO4 In2(SO4)3 SnSO4
Sn(SO4)2 		Sb2(SO4)3 TeOSO4 I2(SO4)3
(IO)2SO4
+IO3 		Xe
Cs2SO4
CsHSO4 		BaSO4 * Lu2(SO4)3 Hf(SO4)2 Ta WO(SO4)2 Re2O5(SO4)2 OsSO4
Os2(SO4)3
Os(SO4)2 		IrSO4
Ir2(SO4)3 		Pt2(SO4)5 AuSO4
Au2(SO4)3 		Hg2SO4
HgSO4 		Tl2SO4
Tl2(SO4)3 		PbSO4
Pb(SO4)2 		Bi2(SO4)3 PoSO4
Po(SO4)2 		At Rn
Fr RaSO4 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La2(SO4)3 Ce2(SO4)3
Ce(SO4)2 		Pr2(SO4)3 Nd2(SO4)3 Pm2(SO4)3 Sm2(SO4)3 EuSO4
Eu2(SO4)3 		Gd2(SO4)3 Tb2(SO4)3 Dy2(SO4)3 Ho2(SO4)3 Er2(SO4)3 Tm2(SO4)3 Yb2(SO4)3
** Ac2(SO4)3 Th(SO4)2 Pa U2(SO4)3
U(SO4)2
UO2SO4 		Np(SO4)2 Pu(SO4)2 Am2(SO4)3 Cm2(SO4)3 Bk Cf2(SO4)3 Es Fm Md No
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