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Caesium sulfate

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Caesium sulfate
Names
Other names Cesium sulfate
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.589 Edit this at Wikidata
EC Number
  • 233-662-6
PubChem CID
UNII
CompTox Dashboard (EPA)
InChI
  • InChI=1S/2Cs.H2O4S/c;;1-5(2,3)4/h;;(H2,1,2,3,4)/q2*+1;/p-2Key: FLJPGEWQYJVDPF-UHFFFAOYSA-L
  • InChI=1/2Cs.H2O4S/c;;1-5(2,3)4/h;;(H2,1,2,3,4)/q2*+1;/p-2Key: FLJPGEWQYJVDPF-NUQVWONBAO
SMILES
  • ..S()(=O)=O
Properties
Chemical formula Cs2SO4
Molar mass 361.87 g/mol
Density 4.243 g/cm, solid
Melting point 1,010 °C (1,850 °F; 1,280 K)
Solubility in water 167 g/100 ml (0 °C)
179 g/100 ml (20 °C)
Solubility insoluble in ethanol, acetone
Magnetic susceptibility (χ) -116.0·10 cm/mol
Hazards
GHS labelling:
Pictograms GHS07: Exclamation markGHS08: Health hazard
Signal word Warning
Hazard statements H302, H361, H412
Precautionary statements P201, P202, P264, P270, P273, P281, P301+P312, P308+P313, P330, P405, P501
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose) 2830 mg/kg (oral, rat)
Related compounds
Other anions Caesium hydrogen sulfate
Other cations Lithium sulfate
Sodium sulfate
Potassium sulfate
Rubidium sulfate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). ☒verify (what is  ?) Infobox references
Chemical compound

Caesium sulfate or cesium sulfate is the inorganic compound and salt with the formula Cs2SO4. It is a white water-soluble solid that is used to prepare dense aqueous solutions for use in isopycnic (or "density-gradient") centrifugation. It is isostructural with potassium salt.

  • Coordination sphere of one of two types of Cs+ site in Cs2SO4. Coordination sphere of one of two types of Cs site in Cs2SO4.
  • Environment of sulfate anion in β-Cs2SO4. Environment of sulfate anion in β-Cs2SO4.

References

  1. Weast, Robert C., ed. (1981). CRC Handbook of Chemistry and Physics (62nd ed.). Boca Raton, Florida: CRC Press. p. B-92. ISBN 0-8493-0462-8..
  2. https://chem.nlm.nih.gov/chemidplus/rn/10294-54-9
  3. Nord, A.G. "The crystal structure of cesium sulfate, beta-Cs2SO4" Acta Chemica Scandinavica, Series A: 1976, 30, p198.

External links

Caesium compounds
Compounds containing the sulfate group (SO2−4)
H2SO4 He
Li2SO4 BeSO4 B2S2O9
-BO3
+BO3
esters
ROSO−3
(RO)2SO2
+CO3
+C2O4
(NH4)2SO4
[N2H5]HSO4
(NH3OH)2SO4
NOHSO4
+NO3
H2OSO4 +F Ne
Na2SO4
NaHSO4
MgSO4 Al2(SO4)3
Al2SO4(OAc)4
Si +PO4 SO2−4
HSO3HSO4
(HSO4)2
+SO3
+Cl Ar
K2SO4
KHSO4
CaSO4 Sc2(SO4)3 TiOSO4 VSO4
V2(SO4)3
VOSO4
CrSO4
Cr2(SO4)3
MnSO4 FeSO4
Fe2(SO4)3
CoSO4
Co2(SO4)3
NiSO4
Ni2(SO4)3
CuSO4
Cu2SO4
SO4
ZnSO4 Ga2(SO4)3 Ge(SO4)2 As +SeO3 +Br Kr
RbHSO4
Rb2SO4
SrSO4 Y2(SO4)3 Zr(SO4)2 Nb2O2(SO4)3 MoO(SO4)2
MoO2(SO4)
Tc Ru(SO4)2 Rh2(SO4)3 PdSO4 Ag2SO4
AgSO4
CdSO4 In2(SO4)3 SnSO4
Sn(SO4)2
Sb2(SO4)3 TeOSO4 I2(SO4)3
(IO)2SO4
+IO3
Xe
Cs2SO4
CsHSO4
BaSO4 * Lu2(SO4)3 Hf(SO4)2 Ta WO(SO4)2 Re2O5(SO4)2 OsSO4
Os2(SO4)3
Os(SO4)2
IrSO4
Ir2(SO4)3
Pt2(SO4)5 AuSO4
Au2(SO4)3
Hg2SO4
HgSO4
Tl2SO4
Tl2(SO4)3
PbSO4
Pb(SO4)2
Bi2(SO4)3 PoSO4
Po(SO4)2
At Rn
Fr RaSO4 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La2(SO4)3 Ce2(SO4)3
Ce(SO4)2
Pr2(SO4)3 Nd2(SO4)3 Pm2(SO4)3 Sm2(SO4)3 EuSO4
Eu2(SO4)3
Gd2(SO4)3 Tb2(SO4)3 Dy2(SO4)3 Ho2(SO4)3 Er2(SO4)3 Tm2(SO4)3 Yb2(SO4)3
** Ac2(SO4)3 Th(SO4)2 Pa U2(SO4)3
U(SO4)2
UO2SO4
Np(SO4)2 Pu(SO4)2 Am2(SO4)3 Cm2(SO4)3 Bk Cf2(SO4)3 Es Fm Md No
Sulfur compounds
Sulfides and
disulfides
Sulfur halides
Sulfur oxides
and oxyhalides
Sulfites
Sulfates
Sulfur nitrides
Thiocyanates
Organic compounds
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