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Chromium(II) oxide

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Chromium(II) oxide
Names
IUPAC name chromium(II) oxide
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/Cr.OKey: XVOFZWCCFLVFRR-UHFFFAOYSA-N
SMILES
  • O=
Properties
Chemical formula CrO
Molar mass 67.996 g/mol
Appearance black
Melting point 300 °C (572 °F; 573 K) (decomposes)
Structure
Crystal structure cubic, cF8
Space group Fm3m, No. 225
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). ☒verify (what is  ?) Infobox references
Chemical compound

Chromium(II) oxide (CrO) is an inorganic compound composed of chromium and oxygen. It is a black powder that crystallises in the rock salt structure. Hypophosphites may reduce chromium(III) oxide to chromium(II) oxide:

H3PO2 + 2 Cr2O3 → 4 CrO + H3PO4

It is readily oxidized by the atmosphere. CrO is basic, while CrO3 is acidic, and Cr2O3 is amphoteric.

CrO occurs in the spectra of luminous red novae, which occur when two stars collide. It is not known why red novae are the only objects that feature this molecule; one possible explanation is an as-yet-unknown nucleosynthesis process.

See also

References

  1. Satish. Anand, Raj. Kumar (1989), Dictionary of Inorganic Chemistry, Anmol Publications, ISBN 978-81-7041-236-6
  2. Egon Wiberg, Arnold Frederick Holleman (2001) Inorganic Chemistry, Elsevier ISBN 0-12-352651-5
  3. Chemistry 7th edition, by Raymond Chang page 645 (problem 15.100)
  4. Kamiński, T.; Mason, E.; Tylenda, R.; Schmidt, M. R. (2015). "Post-outburst spectra of a stellar-merger remnant of V1309 Scorpii: From a twin of V838 Monocerotis to a clone of V4332 Sagittarii". Astronomy & Astrophysics. 580: A34. arXiv:1504.03421. Bibcode:2015A&A...580A..34K. doi:10.1051/0004-6361/201526212. S2CID 118566357.
Chromium compounds
Chromium(0)
Organochromium(0) compounds
  • Cr(C6H6)2
  • CrC6H6(CO)3
  • Chromium(I)
    Organochromium(I) compounds
    Chromium(II)
    Organochromium(II) compounds
    Chromium(II, III)
    Chromium(III)
    Chromium(IV)
    Chromium(V)
    Chromium(VI)
    Polyatomic ion
    Oxides
    Mixed oxidation states
    +1 oxidation state
    +2 oxidation state
    +3 oxidation state
    +4 oxidation state
    +5 oxidation state
    +6 oxidation state
    +7 oxidation state
    +8 oxidation state
    Related
    Oxides are sorted by oxidation state. Category:Oxides
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