| |||||||||||||||||||||||||||||||||||||||||||
Standard atomic weight Ar°(Eu) | |||||||||||||||||||||||||||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| |||||||||||||||||||||||||||||||||||||||||||
Naturally occurring europium (63Eu) is composed of two isotopes, Eu and Eu, with Eu being the most abundant (52.2% natural abundance). While Eu is observationally stable (theoretically can undergo alpha decay with half-life over 5.5×10 years), Eu was found in 2007 to be unstable and undergo alpha decay. The half-life is measured to be (4.62 ± 0.95(stat.) ± 0.68(syst.)) × 10 years which corresponds to 1 alpha decay per two minutes in every kilogram of natural europium. Besides the natural radioisotope Eu, 36 artificial radioisotopes have been characterized, with the most stable being Eu with a half-life of 36.9 years, Eu with a half-life of 13.516 years, Eu with a half-life of 8.593 years, and Eu with a half-life of 4.7612 years. The majority of the remaining radioactive isotopes, which range from Eu to Eu, have half-lives that are less than 12.2 seconds. This element also has 18 metastable isomers, with the most stable being Eu (t1/2 12.8 hours), Eu (t1/2 9.3116 hours) and Eu (t1/2 96 minutes).
The primary decay mode before the most abundant stable isotope, Eu, is electron capture, and the primary mode after is beta decay. The primary decay products before Eu are isotopes of samarium and the primary products after are isotopes of gadolinium.
List of isotopes
Nuclide |
Z | N | Isotopic mass (Da) |
Half-life |
Decay mode |
Daughter isotope |
Spin and parity |
Natural abundance (mole fraction) | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Excitation energy | Normal proportion | Range of variation | |||||||||||||||||
Eu | 63 | 67 | 129.96357(54)# | 1.1(5) ms |
2+# | ||||||||||||||
Eu | 63 | 68 | 130.95775(43)# | 17.8(19) ms | 3/2+ | ||||||||||||||
Eu | 63 | 69 | 131.95437(43)# | 100# ms | β | Sm | |||||||||||||
p | Sm | ||||||||||||||||||
Eu | 63 | 70 | 132.94924(32)# | 200# ms | β | Sm | 11/2−# | ||||||||||||
Eu | 63 | 71 | 133.94651(21)# | 0.5(2) s | β | Sm | |||||||||||||
β, p (rare) | Pm | ||||||||||||||||||
Eu | 63 | 72 | 134.94182(32)# | 1.5(2) s | β | Sm | 11/2−# | ||||||||||||
β, p | Pm | ||||||||||||||||||
Eu | 63 | 73 | 135.93960(21)# | 3.3(3) s | β (99.91%) | Sm | (7+) | ||||||||||||
β, p (.09%) | Pm | ||||||||||||||||||
Eu | 0(500)# keV | 3.8(3) s | β (99.91%) | Sm | (3+) | ||||||||||||||
β, p (.09%) | Pm | ||||||||||||||||||
Eu | 63 | 74 | 136.93557(21)# | 8.4(5) s | β | Sm | 11/2−# | ||||||||||||
Eu | 63 | 75 | 137.93371(3) | 12.1(6) s | β | Sm | (6−) | ||||||||||||
Eu | 63 | 76 | 138.929792(14) | 17.9(6) s | β | Sm | (11/2)− | ||||||||||||
Eu | 63 | 77 | 139.92809(6) | 1.51(2) s | β (95.1(7)%) | Sm | 1+ | ||||||||||||
EC (4.9(7)%) | |||||||||||||||||||
Eu | 210(15) keV | 125(2) ms | IT (99%) | Eu | 5−# | ||||||||||||||
β(1%) | Sm | ||||||||||||||||||
Eu | 63 | 78 | 140.924931(14) | 40.7(7) s | β | Sm | 5/2+ | ||||||||||||
Eu | 96.45(7) keV | 2.7(3) s | IT (86%) | Eu | 11/2− | ||||||||||||||
β (14%) | Sm | ||||||||||||||||||
Eu | 63 | 79 | 141.92343(3) | 2.36(10) s | β (89.9(16)%) | Sm | 1+ | ||||||||||||
EC (11.1(16)%) | |||||||||||||||||||
Eu | 460(30) keV | 1.223(8) min | β | Sm | 8− | ||||||||||||||
Eu | 63 | 80 | 142.920298(12) | 2.59(2) min | β | Sm | 5/2+ | ||||||||||||
Eu | 389.51(4) keV | 50.0(5) μs | 11/2− | ||||||||||||||||
Eu | 63 | 81 | 143.918817(12) | 10.2(1) s | β | Sm | 1+ | ||||||||||||
Eu | 1127.6(6) keV | 1.0(1) μs | (8−) | ||||||||||||||||
Eu | 63 | 82 | 144.916265(4) | 5.93(4) d | β | Sm | 5/2+ | ||||||||||||
Eu | 716.0(3) keV | 490 ns | 11/2− | ||||||||||||||||
Eu | 63 | 83 | 145.917206(7) | 4.61(3) d | β | Sm | 4− | ||||||||||||
Eu | 666.37(16) keV | 235(3) μs | 9+ | ||||||||||||||||
Eu | 63 | 84 | 146.916746(3) | 24.1(6) d | β (99.99%) | Sm | 5/2+ | ||||||||||||
α (.0022%) | Pm | ||||||||||||||||||
Eu | 63 | 85 | 147.918086(11) | 54.5(5) d | β (100%) | Sm | 5− | ||||||||||||
α (9.39×10%) | Pm | ||||||||||||||||||
Eu | 63 | 86 | 148.917931(5) | 93.1(4) d | EC | Sm | 5/2+ | ||||||||||||
Eu | 63 | 87 | 149.919702(7) | 36.9(9) y | β | Sm | 5(−) | ||||||||||||
Eu | 42.1(5) keV | 12.8(1) h | β (89%) | Gd | 0− | ||||||||||||||
β (11%) | Sm | ||||||||||||||||||
IT (≤5×10%) | Eu | ||||||||||||||||||
Eu | 63 | 88 | 150.9198502(26) | 4.62×10 y | α | Pm | 5/2+ | 0.4781(6) | |||||||||||
Eu | 196.245(10) keV | 58.9(5) μs | IT | Eu | 11/2− | ||||||||||||||
Eu | 63 | 89 | 151.9217445(26) | 13.537(6) y | EC (72.09%) | Sm | 3− | ||||||||||||
β (27.9%) | Gd | ||||||||||||||||||
β (0.027%) | Sm | ||||||||||||||||||
Eu | 45.5998(4) keV | 9.3116(13) h | β (72%) | Gd | 0− | ||||||||||||||
β (28%) | Sm | ||||||||||||||||||
Eu | 65.2969(4) keV | 0.94(8) μs | 1− | ||||||||||||||||
Eu | 78.2331(4) keV | 165(10) ns | 1+ | ||||||||||||||||
Eu | 89.8496(4) keV | 384(10) ns | 4+ | ||||||||||||||||
Eu | 147.86(10) keV | 96(1) min | 8− | ||||||||||||||||
Eu | 63 | 90 | 152.9212303(26) | Observationally Stable | 5/2+ | 0.5219(6) | |||||||||||||
Eu | 63 | 91 | 153.9229792(26) | 8.593(4) y | β (99.98%) | Gd | 3− | ||||||||||||
EC (.02%) | Sm | ||||||||||||||||||
Eu | 68.1702(4) keV | 2.2(1) μs | IT | Eu | 2+ | ||||||||||||||
Eu | 145.3(3) keV | 46.3(4) min | IT | Eu | (8−) | ||||||||||||||
Eu | 63 | 92 | 154.9228933(27) | 4.7611(13) y | β | Gd | 5/2+ | ||||||||||||
Eu | 63 | 93 | 155.924752(6) | 15.19(8) d | β | Gd | 0+ | ||||||||||||
Eu | 63 | 94 | 156.925424(6) | 15.18(3) h | β | Gd | 5/2+ | ||||||||||||
Eu | 63 | 95 | 157.92785(8) | 45.9(2) min | β | Gd | (1−) | ||||||||||||
Eu | 63 | 96 | 158.929089(8) | 18.1(1) min | β | Gd | 5/2+ | ||||||||||||
Eu | 63 | 97 | 159.93197(22)# | 38(4) s | β | Gd | 1(−) | ||||||||||||
Eu | 63 | 98 | 160.93368(32)# | 26(3) s | β | Gd | 5/2+# | ||||||||||||
Eu | 63 | 99 | 161.93704(32)# | 10.6(10) s | β | Gd | |||||||||||||
Eu | 63 | 100 | 162.93921(54)# | 7.7(4) s | β | Gd | 5/2+# | ||||||||||||
Eu | 964.5(10) keV | 911(24) ns | (13/2−) | ||||||||||||||||
Eu | 63 | 101 | 163.94299(64)# | 4.16(19) s | β | Gd | |||||||||||||
Eu | 63 | 102 | 164.94572(75)# | 2.163+0.139 −0.120 s |
β | Gd | 5/2+# | ||||||||||||
Eu | 63 | 103 | 165.94997(86)# | 1.277+0.100 −0.145 s |
β (99.37%) | Gd | |||||||||||||
β, n (0.63%) | Gd | ||||||||||||||||||
Eu | 63 | 104 | 166.95321(86)# | 852+76 −54 ms |
β (98.05%) | Gd | 5/2+# | ||||||||||||
β, n (1.95%) | Gd | ||||||||||||||||||
Eu | 63 | 105 | 440+48 −47 ms |
β (96.05%) | Gd | ||||||||||||||
β, n (3.95%) | Gd | ||||||||||||||||||
Eu | 63 | 106 | 389+92 −88 ms |
β (85.38%) | Gd | ||||||||||||||
β, n (14.62%) | Gd | ||||||||||||||||||
Eu | 63 | 107 | 197+74 −71 ms |
β | Gd | ||||||||||||||
β, n | Gd | ||||||||||||||||||
This table header & footer: |
- Eu – Excited nuclear isomer.
- ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
- # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
- Bold half-life – nearly stable, half-life longer than age of universe.
- ^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
-
Modes of decay:
EC: Electron capture IT: Isomeric transition
p: Proton emission - Bold italics symbol as daughter – Daughter product is nearly stable.
- Bold symbol as daughter – Daughter product is stable.
- ( ) spin value – Indicates spin with weak assignment arguments.
- primordial radionuclide
- ^ Fission product
- Believed to undergo α decay to Pm with a half-life over 5.5×10 years
Europium-155
t½ (year) |
Yield (%) |
Q (keV) |
βγ | |
---|---|---|---|---|
Eu | 4.76 | 0.0803 | 252 | βγ |
Kr | 10.76 | 0.2180 | 687 | βγ |
Cd | 14.1 | 0.0008 | 316 | β |
Sr | 28.9 | 4.505 | 2826 | β |
Cs | 30.23 | 6.337 | 1176 | βγ |
Sn | 43.9 | 0.00005 | 390 | βγ |
Sm | 94.6 | 0.5314 | 77 | β |
Europium-155 is a fission product with a half-life of 4.76 years. It has a maximum decay energy of 252 keV. In a thermal reactor (almost all current nuclear power plants), it has a low fission product yield, about half of one percent as much as the most abundant fission products.
Eu's large neutron capture cross section (about 3900 barns for thermal neutrons, 16000 resonance integral) means that most of even the small amount produced is destroyed in the course of the nuclear fuel's burnup. Yield, decay energy, and half-life are all far less than that of Cs and Sr, so Eu is not a significant contributor to nuclear waste.
Some Eu is also produced by successive neutron capture on Eu (nonradioactive, 350 barns thermal, 1500 resonance integral, yield is about 5 times as great as Eu) and Eu (half-life 8.6 years, 1400 barns thermal, 1600 resonance integral, fission yield is extremely small because beta decay stops at Sm). However, the differing cross sections mean that both Eu and Eu are destroyed faster than they are produced.
Eu is a prolific emitter of gamma radiation.
Isotope | Half-life | Relative yield | Thermal neutron | Resonance integral |
---|---|---|---|---|
Eu-153 | Stable | 5 | 350 | 1500 |
Eu-154 | 8.6 years | Nearly 0 | 1500 | 1600 |
Eu-155 | 4.76 years | 1 | 3900 | 16000 |
References
- Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
- "Standard Atomic Weights: Europium". CIAAW. 1995.
- Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
- Belli, P.; et al. (2007). "Search for α decay of natural europium". Nuclear Physics A. 789 (1–4): 15–29. Bibcode:2007NuPhA.789...15B. doi:10.1016/j.nuclphysa.2007.03.001.
- Casali, N.; Nagorny, S. S.; Orio, F.; Pattavina, L.; et al. (2014). "Discovery of the Eu α decay". Journal of Physics G: Nuclear and Particle Physics. 41 (7): 075101. arXiv:1311.2834. Bibcode:2014JPhG...41g5101C. doi:10.1088/0954-3899/41/7/075101. S2CID 116920467.
- "Adopted Levels for Eu" (PDF). NNDC Chart of Nuclides.
- "Adopted Levels for Eu". NNDC Chart of Nuclides.
- Danevich, F. A.; Andreotti, E.; Hult, M.; Marissens, G.; Tretyak, V. I.; Yuksel, A. (2012). "Search for α decay of Eu to the first excited level of Pm using underground γ-ray spectrometry". European Physical Journal A. 48 (157): 157. arXiv:1301.3465. Bibcode:2012EPJA...48..157D. doi:10.1140/epja/i2012-12157-7. S2CID 118657922.
- Belli, P.; Bernabei, R.; Danevich, F. A.; et al. (2019). "Experimental searches for rare alpha and beta decays". European Physical Journal A. 55 (8): 140–1–140–7. arXiv:1908.11458. Bibcode:2019EPJA...55..140B. doi:10.1140/epja/i2019-12823-2. ISSN 1434-601X. S2CID 201664098.
- ^ Kiss, G. G.; Vitéz-Sveiczer, A.; Saito, Y.; et al. (2022). "Measuring the β-decay properties of neutron-rich exotic Pm, Sm, Eu, and Gd isotopes to constrain the nucleosynthesis yields in the rare-earth region". The Astrophysical Journal. 936 (107): 107. Bibcode:2022ApJ...936..107K. doi:10.3847/1538-4357/ac80fc. hdl:2117/375253.
- "Archived copy" (PDF). Archived from the original (PDF) on 2011-07-06. Retrieved 2011-04-02.
{{cite web}}
: CS1 maint: archived copy as title (link)
- Isotope masses from:
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- Isotopic compositions and standard atomic masses from:
- de Laeter, John Robert; Böhlke, John Karl; De Bièvre, Paul; Hidaka, Hiroshi; Peiser, H. Steffen; Rosman, Kevin J. R.; Taylor, Philip D. P. (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry. 75 (6): 683–800. doi:10.1351/pac200375060683.
- Wieser, Michael E. (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry. 78 (11): 2051–2066. doi:10.1351/pac200678112051.
- "News & Notices: Standard Atomic Weights Revised". International Union of Pure and Applied Chemistry. 19 October 2005.
- Half-life, spin, and isomer data selected from the following sources.
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- National Nuclear Data Center. "NuDat 2.x database". Brookhaven National Laboratory.
- Holden, Norman E. (2004). "11. Table of the Isotopes". In Lide, David R. (ed.). CRC Handbook of Chemistry and Physics (85th ed.). Boca Raton, Florida: CRC Press. ISBN 978-0-8493-0485-9.