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Protactinium nitride

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Protactinium nitride
Names
Other names Protactinium mononitride, protactinium(III) nitride
Identifiers
CAS Number
3D model (JSmol)
InChI
  • InChI=1S/N.Pa/q-3;+3Key: FXGLGDPQXNUWTM-UHFFFAOYSA-N
SMILES
  • .
Properties
Chemical formula NPa
Molar mass 245.043 g·mol
Appearance crystals
Density 12.6 g/cm
Melting point 2,227 °C (4,041 °F; 2,500 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Protactinium nitride is a binary inorganic compound of protactinium and nitrogen with the chemical formula PaN.

Synthesis

The compound can be obtained from the reaction of protactinium metal and nitrogen:

2Pa + N2 → 2PaN

Also by heating protactinium tetrachloride or pentachloride in ammonia gas.

Physical properties

PaN crystals are of cubic system with Fm3m space group.

References

  1. Modak, P; Verma, Ashok K; Svane, A; Christensen, N E; Sharma, Surinder M (22 January 2014). "Structural, vibrational, elastic and topological properties of PaN under pressure". Journal of Physics: Condensed Matter. 26 (3): 035403. arXiv:1308.3050. doi:10.1088/0953-8984/26/3/035403. PMID 24351318. Retrieved 8 February 2024.
  2. Murugan, A.; Priyanga, G. Sudha; Rajeswarapalanichamy, R.; Santhosh, M.; Iyakutti, K. (1 September 2016). "First principles study of structural, electronic, mechanical and magnetic properties of actinide nitrides AnN (An = U, Np and Pu)". Journal of Nuclear Materials. 478: 197–206. Bibcode:2016JNuM..478..197M. doi:10.1016/j.jnucmat.2016.06.016. ISSN 0022-3115. Retrieved 8 February 2024.
  3. Brooks, M. S. S.; Calestani, G.; Spirlet, J. C.; Rebizant, J.; Müller, W.; Fournier, J. M.; Blaise, A. (1 October 1980). "f-Electron contribution to bonding in protactinium compounds". Physica B+C. 102 (1): 84–87. Bibcode:1980PhyBC.102...84B. doi:10.1016/0378-4363(80)90132-1. ISSN 0378-4363. Retrieved 8 February 2024.
  4. Bohet, J.; Müller, W. (1 February 1978). "Preparation and structure studies of "Van Arkel" protactinium". Journal of the Less Common Metals. 57 (2): 185–199. doi:10.1016/0022-5088(78)90238-2. ISSN 0022-5088. Retrieved 8 February 2024.
  5. Bagnall, K. W. (1973). The Actinide Elements. Elsevier Publishing Company. p. 60. ISBN 978-0-444-41041-2. Retrieved 8 February 2024.
  6. Powder Diffraction File: Sets 6-33. [Section II] Inorganic. [v.1] Sets 1-5. American Society for Testing and Materials. 1960. p. 995. Retrieved 8 February 2024.
Protactinium compounds
Pa(II)
Pa(III)
Pa(IV)
Pa(V)
Salts and covalent derivatives of the nitride ion
NH3
N2H4
+H
HN
H2N
He(N2)11
Li3N
LiN3
Be3N2
Be(N3)2
BN
-B
C2N2
β-C3N4
g-C3N4
CxNy
N2 NxOy
+O
N3F
N2F2
N2F4
NF3
+F
Ne
Na3N
NaN3
Mg3N2
Mg(N3)2
AlN Si3N4
-Si
PN
P3N5
-P
SxNy
SN
S2N2
S4N4
SN2H2
NCl3
ClN3
+Cl
Ar
K3N
KN3
Ca3N2
Ca(N3)2
ScN TiN
Ti3N4
VN CrN
Cr2N
MnxNy FexNy Co3N Ni3N Cu3N Zn3N2 GaN Ge3N4
-Ge
AsN
+As
Se4N4 Br3N
BrN3
+Br
Kr
RbN3 Sr3N2
Sr(N3)2
YN ZrN NbN β-Mo2N Tc Ru Rh PdN Ag3N Cd3N2 InN Sn SbN Te4N4? I3N
IN3
+I
Xe
CsN3 Ba3N2
Ba(N3)2
* LuN HfN
Hf3N4
TaN WN RexNy Os Ir Pt Au Hg3N2 Tl3N (PbNH) BiN Po At Rn
Fr Ra3N2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaN CeN PrN NdN PmN SmN EuN GdN TbN DyN HoN ErN TmN YbN
** Ac ThxNy PaN UxNy NpN PuN AmN CmN BkN Cf Es Fm Md No
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