Osmium(III) chloride - Misplaced Pages

Osmium(III) chloride
Names

Other names trichloroosmium, osmium trichloride
Identifiers
CAS Number	13444-93-4 anhydrous 14996-60-2 trihydrate
3D model (JSmol)	Interactive image
ChemSpider	75306
ECHA InfoCard	100.033.247
EC Number	236-587-7
PubChem CID	83468
CompTox Dashboard (EPA)	3065457
InChI InChI=1S/3ClH.Os/h3*1H;/q;;;+3/p-3Key: UAIHPMFLFVHDIN-UHFFFAOYSA-K
SMILES Cl(Cl)Cl
Properties
Chemical formula	Cl₃Os
Molar mass	296.58 g·mol
Appearance	black-brown crystals
Melting point	560 °C (1,040 °F; 833 K)
Solubility in water	soluble
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references

Chemical compound

Osmium(III) chloride is an inorganic chemical compound of osmium metal and chlorine with the chemical formula OsCl₃.

Synthesis

Osmium(III) chloride can be made by a reaction of chlorine with osmium:

2Os + 3Cl₂ → 2OsCl₃

It can also be made by heating of osmium(IV) chloride:

2OsCl₄ → 2OsCl₃ + Cl₂

Osmium(III) chloride forms black-brown crystals.

Osmium(III) chloride forms a hydrate of the composition OsCl₃·3H₂O with dark green crystals.

Osmium(III) chloride hydrate is used as a precursor material for the production of dichlorodihydridoosmium complex compounds and other compounds.

It is the precursor to a variety of arene complexes.

"Osmium(III) chloride". Sigma Aldrich. Retrieved 31 March 2023.
Lide, David R. (19 June 2003). 1998 Freshman Achievement Award. CRC Press. p. 4-79. ISBN 978-0-8493-0594-8. Retrieved 31 March 2023.
"Osmium(III) chloride". heraeus.com. Retrieved 31 March 2023.
"Osmium(III) chloride hydrate, Thermo Scientific Chemicals | Fisher Scientific". fishersci.se. Retrieved 31 March 2023.
"Osmium(III) chloride hydrate". Sigma Aldrich. Retrieved 31 March 2023.
Bell, Andrew G.; Koźmiński, Wiktor; Linden, Anthony; von Philipsborn, Wolfgang (1996). "Os NMR Study of (η-Arene)osmium(II) Complexes: Separation of Electronic and Steric Ligand Effects". Organometallics. 15 (14): 3124–3135. doi:10.1021/om960053i.