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Zirconium disulfide

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Zirconium(IV) sulfide
Names
IUPAC name Zirconium(IV) sulfide
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.701 Edit this at Wikidata
EC Number
  • 234-885-1
PubChem CID
CompTox Dashboard (EPA)
InChI
  • InChI=1S/2S.Zr/q2*-2;+4Key: XWPGCGMKBKONAU-UHFFFAOYSA-N
SMILES
  • ..
Properties
Chemical formula ZrS2
Molar mass 155.356 g/mol
Appearance red-brown crystals
Density 3.82 g/cm
Melting point 1,480 °C (2,700 °F; 1,750 K)
Solubility in water insoluble
Structure
Crystal structure Rhombohedral, hP3
Space group P-3m1, No. 164
Coordination geometry octahedral
Hazards
Safety data sheet (SDS) MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkverify (what is  ?) Infobox references
Chemical compound

Zirconium(IV) sulfide is the inorganic compound with the formula ZrS2. It is a violet-brown solid. It adopts a layered structure similar to that of cadmium iodide.

Like the closely related titanium disulfide, ZrS2 is prepared by heating sulfur and zirconium metal. It can be purified by vapor transport using iodine.

References

  1. Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, Florida: CRC Press, pp. 4–96, ISBN 0-8493-0594-2
  2. Lawrence E. Conroy "Group IV Sulfides" Inorganic Synthesis 1970, XII, 158. doi:10.1002/9780470132432.ch28
Zirconium compounds
Zr(II)
Zr(III)
Zr(IV)
Acids and complexes
Organozirconium(IV)
Sulfides (S)
H2S He
Li2S BeS B2S3
+BO3
CS2
COS
(NH4)SH O F Ne
Na2S MgS Al2S3 SiS
SiS2
-Si
PxSy
-P
-S
2
Cl Ar
K2S CaS ScS
Sc2S3
TiS
TiS2
Ti2S3
TiS3
VS
VS2
V2S3
CrS
Cr2S3
MnS
MnS2
FeS
Fe3S4
CoxSy NixSy Cu2S
CuS
ZnS GaS
Ga2S3
GeS
GeS2
-Ge
As2S3
As4S3
-As
SeS2
+Se
Br Kr
Rb2S SrS Y2S3 ZrS2 NbS2 MoS2
MoS3
TcS2
Tc2S7
Ru Rh2S3 PdS Ag2S CdS In2S3 SnS
SnS2
-Sn
Sb2S3
Sb2S5
-Sb
TeS2 I Xe
Cs2S BaS * LuS
Lu2S3
HfS2 TaS2 WS2
WS3
ReS2
Re2S7
OsS
4
Ir2S3
IrS2
PtS
PtS2
Au2S
Au2S3
HgS Tl2S PbS
PbS2
Bi2S3 PoS At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaS
La2S3
CeS
Ce2S3
PrS
Pr2S3
NdS
Nd2S3
PmS
Pm2S3
SmS
Sm2S3
EuS
Eu2S3
GdS
Gd2S3
TbS
Tb2S3
DyS
Dy2S3
HoS
Ho2S3
ErS
Er2S3
TmS
Tm2S3
YbS
Yb2S3
** Ac2S3 ThS2 Pa US
US2
Np Pu Am Cm Bk Cf Es Fm Md No
Sulfur compounds
Sulfides and
disulfides
Sulfur halides
Sulfur oxides
and oxyhalides
Sulfites
Sulfates
Sulfur nitrides
Thiocyanates
Organic compounds


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