Names | |
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IUPAC name Neptunium(III) fluoride | |
Other names Neptunium trifluoride | |
Identifiers | |
CAS Number | |
3D model (JSmol) | |
PubChem CID |
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InChI
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Properties | |
Chemical formula | NpF3 |
Molar mass | 294 g/mol |
Appearance | Purple solid |
Structure | |
Crystal structure | Trigonal, hP8 |
Space group | P63/mmc, No. 194 |
Lattice constant | a = 0.7129 nm, c = 0.7288 nm |
Lattice volume (V) | 0.32077 nm |
Formula units (Z) | 6 |
Thermochemistry | |
Heat capacity (C) | 94 ± 3 J/mol·K |
Std molar entropy (S298) |
131 ± 3 J/mol·K |
Std enthalpy of formation (ΔfH298) |
−1529 ± 8 kJ/mol |
Gibbs free energy (ΔfG) | -1461 ± 8 kJ/mol |
Related compounds | |
Other anions | Neptunium(III) chloride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references |
Neptunium(III) fluoride or neptunium trifluoride is a salt of neptunium and fluorine with the formula NpF3.
Synthesis
Neptunium(III) fluoride can be prepared by reacting neptunium dioxide with a gas mixture of hydrogen and hydrogen fluoride at 500 °C:
References
- ^ Haire, Richard G. (2006). "Neptunium". In Morss; Edelstein, Norman M.; Fuger, Jean (eds.). The Chemistry of the Actinide and Transactinide Elements (3rd ed.). Dordrecht, The Netherlands: Springer Science+Business Media. pp. 730–736. doi:10.1007/1-4020-3598-5_9. ISBN 1-4020-3555-1.
- Zachariasen, W. H. (1949). "Crystal chemical studies of the 5f-series of elements. XII. New compounds representing known structure types". Acta Crystallographica. 2 (6): 388–390. doi:10.1107/S0365110X49001016.
Neptunium compounds | |||
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Np(III) | |||
Np(IV) |
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Np(V) | |||
Np(VI) | |||
Np(VII) |
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